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    • 5. 发明授权
    • Novel yellow azo dyes and dichroic liquid crystal composition made
therewith
    • 新的黄色偶氮染料和二色液晶组合物
    • US4308164A
    • 1981-12-29
    • US175002
    • 1980-08-04
    • Siegfried AftergutHerbert S. Cole
    • Siegfried AftergutHerbert S. Cole
    • C09B35/04C09B43/20C09K19/60C09K3/34G02F1/13
    • C09B35/04C09B43/20C09K19/601Y10S534/01
    • Novel yellow azo dye compositions and a liquid crystal composition containing the yellow azo dye composition are disclosed. The yellow azo dye composition, having terminal ester groups has the general formula: ##STR1## wherein R and R' are acyl groups having the formula: ##STR2## and R.sub.2 is an alkyl or substituted alkyl wherein the alkyl has at least 4 carbon atoms, or R.sub.2 is an aryl, arylalkyl, substituted aryl or substituted arylalkyl. When the yellow azo dichroic dyes are used as a guest in a host liquid crystal material, they form a novel liquid crystal composition for use in liquid crystal displays. The disclosure also embraces a method of improving the black color of dichroic dyes for use in black liquid crystal displays, wherein a dye composition having a mixture of dichroic dyes of various colors and containing at least one yellow azo dichroic dye as described above is added to a host liquid crystal material. The mixture of dichroic dyes of various colors must be one which absorbs radiation in the spectral range of about 400-700 nm to produce the substantially black color for use in black liquid crystal displays.
    • 公开了新的黄色偶氮染料组合物和含有黄色偶氮染料组合物的液晶组合物。 具有末端酯基的黄色偶氮染料组合物具有以下通式:其中R和R'是具有下式的酰基:其中R 2是烷基或取代的烷基,其中烷基具有至少4个碳原子 ,或R 2为芳基,芳基烷基,取代的芳基或取代的芳基烷基。 当黄色偶氮二色性染料用作主体液晶材料中的客体时,它们形成用于液晶显示器的新型液晶组合物。 本公开还包括改进用于黑色液晶显示器中的二色性染料的黑色的方法,其中将具有各种颜色的二色性染料和至少一种如上所述的黄色偶氮二色性染料的混合物的染料组合物加入到 主体液晶材料。 各种颜色的二色性染料的混合物必须是在约400-700nm的光谱范围内吸收辐射的混合物,以产生用于黑色液晶显示器的基本黑色。
    • 6. 发明授权
    • Substituted phenyl-azo-phenylene-azo-phenyl dyes
    • 取代的苯基 - 偶氮 - 亚苯基 - 偶氮苯基染料
    • US3956268A
    • 1976-05-11
    • US262066
    • 1972-06-12
    • Ruedi Altermatt
    • Ruedi Altermatt
    • C09B31/043C09B43/20C07C31/04C07C31/08C07C31/14C07C43/18
    • C09B43/20C09B31/043
    • This invention provides novel disperse dyes of formula I, ##SPC1##in which R.sub.1 signifies hydrogen, cyano, alkyl or alkoxy,R.sub.2 signifies unsubstituted alkylcarbonyloxy; alkylcarbonyloxy substituted by halogen, alkoxy, alkylcarbonyl, aryl or phenoxy; unsubstituted benzoyloxy, benzoyloxy substituted by one or more substituents selected from halogen, alkyl and nitro; unsubstituted alkoxycarbonyloxy; alkoxycarbonyloxy substituted by halogen, or phenyl; phenoxycarbonyloxy; 2-pyridyl or 4-pyridyl,R.sub.3 signifies formyl, unsubstituted alkylcarbonyl; alkylcarbonyl substituted by halogen, cyano, alkoxy, alkylcarbonyl, aryl or aryloxy; benzoyl; benzoyl substituted by one or more substituents selected from halogen, nitro and alkyl; unsubstituted alkoxycarbonyl; alkoxycarbonyl substituted by halogen, aryl or alkoxy; phenoxycarbonyl; unsubstituted alkylsulphonyl; unsubstituted phenylsulphonyl or phenylsulphonyl substituted by alkyl,Rings A and B may be substituted,And X.sub.1 and X.sub.2, which may be the same or different, each signifies an alkylene radical of 1 to 6 carbon atoms,Provided that the compounds contain no sulphonic acid groups.These dyes are useful for dyeing higher molecular weight, hydrophobic fibers, such as linear aromatic polyesters, synthetic polyamides, secondary cellulose acetate and cellulose triacetate on which they build up well and exhibit good fastness to light, thermofixation, sublimation, pleating, washing, perspiration, dry cleaning, lubricants, rubbing, cross dyeings, ozone, gas fumes and chlorine.
    • 本发明提供了式I的新型分散染料,其中R1表示氢,氰基,烷基或烷氧基,R2表示未取代的烷基羰基氧基; 由卤素,烷氧基,烷基羰基,芳基或苯氧基取代的烷基羰氧基; 未取代的苯甲酰氧基,被一个或多个选自卤素,烷基和硝基的取代基取代的苯甲酰氧基; 未取代的烷氧基羰基氧基; 被卤素取代的烷氧基羰基氧基,或苯基; 苯氧基羰基氧基; 2-吡啶基或4-吡啶基,R3表示甲酰基,未取代的烷基羰基; 氰基,烷氧基,烷基羰基,芳基或芳氧基取代的烷基羰基; 苯甲酰 由一个或多个选自卤素,硝基和烷基的取代基取代的苯甲酰基; 未取代的烷氧羰基; 被卤素,芳基或烷氧基取代的烷氧基羰基; 苯氧基羰基; 未取代的烷基磺酰基; 未取代的苯基磺酰基或被烷基取代的苯基磺酰基,RINGS A和B可以被取代,可以相同或不同的,X 1和X 2各自表示1至6个碳原子的亚烷基,提供的化合物不含有磺酸基团 。
    • 7. 发明授权
    • Novel yellow azo dyes and dichroic liquid crystal compositions made
therewith
    • 新型的黄色偶氮染料和二色液晶组合物
    • US4308161A
    • 1981-12-29
    • US175004
    • 1980-08-04
    • Siegfried AftergutHerbert S. Cole
    • Siegfried AftergutHerbert S. Cole
    • C09B35/35C09B43/20C09K19/60C09K3/34C09B31/16G02F1/13
    • C09B35/35C09B43/20C09K19/601Y10S534/01
    • Novel yellow azo dye compositions and a liquid crystal composition containing the yellow azo dye composition are disclosed. The yellow azo dye composition, having terminal ester groups, has the general formula: ##STR1## wherein R and R' are acyl groups having the formula: ##STR2## and R.sub.2 is an alkyl or substituted alkyl wherein the alkyl has at least 4 carbon atoms, or R.sub.2 is an aryl, arylalkyl, substituted aryl or substituted arylalkyl. When the yellow azo dichroic dyes are used alone, or in combination with other dyes, as a guest in a host liquid crystal material, they form a novel liquid crystal composition for use in liquid crystal displays. The disclosure also embraces a method of improving the black color of dichroic dyes for use in black liquid crystal displays, wherein a dye composition having a mixture of dichroic dyes of various colors and containing at least one yellow azo dichroic dye, as described above, is added to a host liquid crystal material. The mixture of dichroic dyes of various colors must be one which absorbs radiation in the spectral range of about 400-700 nm to produce the substantially black color for use in black liquid crystal displays.
    • 公开了新的黄色偶氮染料组合物和含有黄色偶氮染料组合物的液晶组合物。 具有末端酯基的黄色偶氮染料组合物具有以下通式:其中R和R'是具有下式的酰基,其中R 2是烷基或取代的烷基,其中烷基具有至少4个碳 原子,或者R2是芳基,芳基烷基,取代的芳基或取代的芳基烷基。 当黄色偶氮二色性染料单独使用或与其它染料组合使用时,作为主体液晶材料中的客体,它们形成用于液晶显示器的新型液晶组合物。 本发明还包括一种改进用于黑色液晶显示器中的二色性染料的黑色的方法,其中如上所述,具有各种颜色的二色性染料和至少一种黄色偶氮二色性染料的混合物的染料组合物是 加入到主体液晶材料中。 各种颜色的二色性染料的混合物必须是在约400-700nm的光谱范围内吸收辐射的混合物,以产生用于黑色液晶显示器的基本黑色。
    • 8. 发明授权
    • New water-insoluble azo dyes
    • 新型水不溶性偶氮染料
    • US4257942A
    • 1981-03-24
    • US949092
    • 1978-10-06
    • Francesco DeFeoRoberto Cipolli
    • Francesco DeFeoRoberto Cipolli
    • C09B29/08C09B31/04C09B31/043C09B31/047C09B43/20D06P1/18C09B29/22C07C107/06C09B31/02
    • D06P1/18C09B29/0834C09B31/04C09B31/041C09B31/043C09B31/047C09B43/20
    • The present invention relates to the synthesis of new dyes having the following general formula: ##STR1## wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic seriesX is an ethylene group, optionally substituted by halogen-methyl, alkyl C.sub.1 -C.sub.4, aryl, aralkyl or CH.sub.2 OCO(HN).sub.n R (wherein R and n have the meanings hereinafter defined);R is alkyl C.sub.1 -C.sub.8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C.sub.1 -C.sub.4, alkoxyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.8 ; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C.sub.2 -C.sub.8, optionally substituted by halogen, CN, COOH;R.sup.1 and R.sup.2, either like or unlike each other, may be alkyl C.sub.1 -C.sub.4 optionally substituted by halogen or CN groups; aralkyl;R.sup.3 is H; halogen, alkyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.4, optionally substituted.n is 0 or 1.
    • 本发明涉及具有以下通式的新染料的合成:其中:D是碳环或杂环系列的可重氮化组分的残基X是任选被卤素 - 甲基,烷基C1取代的亚乙基 -C4,芳基,芳烷基或CH2OCO(HN)nR(其中R和n具有以下定义的含义); R是任选被卤素,CN,COOH取代的C 1 -C 8烷基; 任选被一个或多个卤素原子取代的芳基,C 1 -C 4烷基,C 1 -C 4烷氧基, 烷氧基C1-C4; 烷氧基C1-C8; 芳氧基; 芳烷氧基 环烷氧基 芳烷基 任选被卤素取代的萘基; 烯基C2-C8,任选被卤素,CN,COOH取代; R1和R2可以相同或不同,可以是任选被卤素或CN基团取代的C 1 -C 4烷基; 芳烷基 R3为H; 卤素,C1-C4烷基; 烷氧基C1-C4,任选取代。 n为0或1。
    • 9. 发明授权
    • Phenylazophenyl dyes having an alkoxyacylamino group on the coupling
component radical
    • 在偶联成分基团上具有烷氧基酰氨基的苯基苯基染料
    • US4042580A
    • 1977-08-16
    • US554547
    • 1975-03-03
    • Wolfgang Groebke
    • Wolfgang Groebke
    • C09B43/12C09B43/20C09B29/08C09B29/26C09B43/18
    • C09B43/12C09B43/20
    • Compounds of the formula ##STR1## wherein R.sub.1 is chloro, bromo, cyano, nitro, alkylsulfonyl, substituted alkylsulfonyl, phenylsulfonyl or substituted phenylsulfonyl,R.sub.2 is hydrogen, chloro or bromo,R.sub.3 is hydrogen, chloro, bromo or acylamino, with the proviso that at least one of R.sub.2 and R.sub.3 is hydrogen,R.sub.4 is hydrogen, alkyl, substituted alkyl, alkoxy or substituted alkoxy,Each of R.sub.5 and R.sub.6 is independently alkyl or substituted alkyl, wherein each substituent of substituted alkyl is independently chloro, bromo, cyano, hydroxy, alkoxy, chloroalkoxy, bromoalkoxy, cyanoalkoxy, formyloxy, alkylcarbonyloxy, substituted alkylcarbonyloxy, benzoyloxy, substituted benzoyloxy, alkoxycarbonyl, substituted alkoxycarbonyl, phenoxycarbonyl, substituted phenoxycarbonyl, alkoxycarbonyloxy, substituted alkoxycarbonyloxy, phenoxycarbonyloxy or substituted phenoxycarbonyloxy,R.sub.7 is alkyl or substituted alkyl,X is --CO--, --CO.sub.2 -- or --SO.sub.2 --, and n is 2, 3 or 4.These compounds are highly suitable for use as disperse dyes. As such they are employed for dyeing high molecular weight synthetic and regenerated organic fibers, either in loose form, as yarn or in the various textile forms. The dyes are of high tinctorial strength, have good affinity, are resistant to sublimation, and give dyeings of notably good light and wet fastness.
    • 其中R 1是氯,溴,氰基,硝基,烷基磺酰基,取代的烷基磺酰基,苯基磺酰基或取代的苯基磺酰基,R 2是氢,氯或溴,R 3是氢,氯,溴或酰基氨基,条件是 R 2和R 3中的至少一个是氢,R 4是氢,烷基,取代的烷基,烷氧基或取代的烷氧基,每个R 5和R 6独立地是烷基或取代的烷基,其中取代的烷基的每个取代基独立地是氯,溴,氰基, 羟基,烷氧基,氯代烷氧基,溴代烷氧基,氰基烷氧基,甲酰氧基,烷氧基羰基氧基,取代的烷基羰基氧基,苯甲酰氧基,取代的苯甲酰氧基,烷氧基羰基,取代的烷氧基羰基,苯氧基羰基,取代的苯氧基羰基,烷氧基羰基氧基,取代的烷氧基羰基氧基,苯氧基羰氧基或取代的苯氧基羰氧基,R7是烷基或取代的烷基,X 是-CO - , - CO 2 - 或-SO 2 - ,n是2,3或4。
    • 10. 发明授权
    • Novel yellow azo dyes and dichroic liquid crystal composition made
therewith
    • 新的黄色偶氮染料和二色液晶组合物
    • US4308163A
    • 1981-12-29
    • US175003
    • 1980-08-04
    • Siegfried AftergutHerbert S. Cole
    • Siegfried AftergutHerbert S. Cole
    • C09B35/35C09B43/20C09K19/60C09K3/34C09B31/16G02F1/13
    • C09K19/601C09B35/35C09B43/20Y10S534/01
    • Novel yellow azo dye compositions and a liquid crystal composition containing the yellow azo dye composition are disclosed. The yellow azo dye composition, having terminal ester groups has the general formula: ##STR1## wherein R and R' are acyl groups having the formula: ##STR2## and R.sub.2 is an alkyl or substituted alkyl wherein the alkyl has at least 4 carbon atoms, or R.sub.2 is an aryl, arylalkyl, substituted aryl or substituted arylalkyl. When the yellow azo dichroic dyes are used as a guest in a host liquid crystal material, they form a novel liquid crystal composition for use in liquid crystal displays. The disclosure also embraces a method of improving the black color of dichroic dyes for use in black liquid crystal displays, wherein a dye composition having a mixture of dichroic dyes of various colors and containing at least one yellow azo dichroic dyes as described above is added to a host liquid crystal material. The mixture of dichroic dyes of various colors must be one which absorbs radiation in the spectral range of about 400-700 nm to produce the substantially black color for use in black liquid crystal displays.
    • 公开了新的黄色偶氮染料组合物和含有黄色偶氮染料组合物的液晶组合物。 具有末端酯基的黄色偶氮染料组合物具有以下通式:其中R和R'是具有下式的酰基,其中R 2是烷基或取代的烷基,其中烷基具有 至少4个碳原子,或者R 2是芳基,芳基烷基,取代的芳基或取代的芳基烷基。 当黄色偶氮二色性染料用作主体液晶材料中的客体时,它们形成用于液晶显示器的新型液晶组合物。 本公开还包括改进用于黑色液晶显示器中的二色性染料的黑色的方法,其中将具有各种颜色的二色性染料和至少一种如上所述的黄色偶氮二色性染料的混合物的染料组合物加入到 主体液晶材料。 各种颜色的二色性染料的混合物必须是在约400-700nm的光谱范围内吸收辐射的混合物,以产生用于黑色液晶显示器的基本黑色。