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    • 3. 发明授权
    • New water-insoluble azo dyes
    • 新型水不溶性偶氮染料
    • US4257942A
    • 1981-03-24
    • US949092
    • 1978-10-06
    • Francesco DeFeoRoberto Cipolli
    • Francesco DeFeoRoberto Cipolli
    • C09B29/08C09B31/04C09B31/043C09B31/047C09B43/20D06P1/18C09B29/22C07C107/06C09B31/02
    • D06P1/18C09B29/0834C09B31/04C09B31/041C09B31/043C09B31/047C09B43/20
    • The present invention relates to the synthesis of new dyes having the following general formula: ##STR1## wherein: D is the residue of a diazotizable component of the carbocyclic or heterocyclic seriesX is an ethylene group, optionally substituted by halogen-methyl, alkyl C.sub.1 -C.sub.4, aryl, aralkyl or CH.sub.2 OCO(HN).sub.n R (wherein R and n have the meanings hereinafter defined);R is alkyl C.sub.1 -C.sub.8 optionally substituted by halogen, CN,COOH; aryl optionally substituted by one or more atoms of halogen, alkyl C.sub.1 -C.sub.4, alkoxyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.8 ; Aryloxy; aralkoxy; cycloalkoxy; aralkyl; naphthyl optionally substituted by halogen; alkenyl C.sub.2 -C.sub.8, optionally substituted by halogen, CN, COOH;R.sup.1 and R.sup.2, either like or unlike each other, may be alkyl C.sub.1 -C.sub.4 optionally substituted by halogen or CN groups; aralkyl;R.sup.3 is H; halogen, alkyl C.sub.1 -C.sub.4 ; alkoxyl C.sub.1 -C.sub.4, optionally substituted.n is 0 or 1.
    • 本发明涉及具有以下通式的新染料的合成:其中:D是碳环或杂环系列的可重氮化组分的残基X是任选被卤素 - 甲基,烷基C1取代的亚乙基 -C4,芳基,芳烷基或CH2OCO(HN)nR(其中R和n具有以下定义的含义); R是任选被卤素,CN,COOH取代的C 1 -C 8烷基; 任选被一个或多个卤素原子取代的芳基,C 1 -C 4烷基,C 1 -C 4烷氧基, 烷氧基C1-C4; 烷氧基C1-C8; 芳氧基; 芳烷氧基 环烷氧基 芳烷基 任选被卤素取代的萘基; 烯基C2-C8,任选被卤素,CN,COOH取代; R1和R2可以相同或不同,可以是任选被卤素或CN基团取代的C 1 -C 4烷基; 芳烷基 R3为H; 卤素,C1-C4烷基; 烷氧基C1-C4,任选取代。 n为0或1。
    • 7. 发明授权
    • Water-soluble acid azo dye
    • 水溶性酸性偶氮染料
    • US4187218A
    • 1980-02-05
    • US886943
    • 1978-03-15
    • Fabrizio MerloGiorgio BornengoCamillo Paffoni
    • Fabrizio MerloGiorgio BornengoCamillo Paffoni
    • C09B29/08C09B31/04C09B31/047D06P1/06C09B29/36C09B29/06
    • C09B31/047C09B29/08C09B29/0803C09B31/04D06P1/06
    • This invention relates to a class of water-soluble acid azo dyes, containing at least a sulphonic group, having formula (I): ##STR1## wherein the symbols have the following meanings: A is a residue of a diazotizable aromatic or heterocyclic amine, optionally substituted;R is selected from the group consisting of H, CH.sub.3, OCH.sub.3 and OC.sub.2 H.sub.5 ;R.sub.1 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5 ;R.sub.2 is selected from the group consisting of CH.sub.3 and C.sub.2 H.sub.5.The dyes which are the object of the present invention exhibit shades varying from yellow to blue and are useful for dyeing and printing natural polyamide fibres (wool and silk) and synthetic fibres (nylon). They possess an excellent affinity in both an acid bath and a neutral bath and an excellent tinting power. The dyes obtained are characterized by a remarkable purity of shade, by an excellent stability to sunlight, to washing and to sweat, as well as by a good equalizing power on nylon.
    • 本发明涉及一类含有至少一个具有式(I)的磺酸基的水溶性酸偶氮染料:其中符号具有以下含义:A是可重氮化芳族的残基或 杂环胺,任选取代的; R选自H,CH 3,OCH 3和OC 2 H 5; R1选自CH3和C2H5; R2选自CH3和C2H5。 作为本发明的目的的染料显示从黄色到蓝色的色调,并且可用于染色和印刷天然聚酰胺纤维(羊毛和丝绸)和合成纤维(尼龙)。 它们在酸浴和中性浴中都具有极好的亲和力,并具有优异的着色力。 所得到的染料的特征在于,通过对阳光的良好的稳定性,洗涤和汗水以及通过尼龙的良好的均衡功率,具有显着的阴影纯度。