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    • 4. 发明授权
    • Laminate adhesive
    • 层压胶
    • US06908981B2
    • 2005-06-21
    • US10055928
    • 2002-01-28
    • Shigetoshi SasanoSachio Igarashi
    • Shigetoshi SasanoSachio Igarashi
    • C09J175/04B32B7/12C08G18/42C09J175/06C08L75/06
    • C09J175/06B32B7/12C08G18/4227Y10S528/905
    • A laminate adhesive that can suppress elution of a low molecular weight compounds of a composite film into the content, so as to prevent the inherent properties or performances of the content from being spoiled by the low molecular weight compounds. In the laminate adhesive, the polyester polyol contains naphthalenedicarboxylic acid and/or alkyl ester thereof as an acid component, and concentration of cyclic ester compounds in extracted water, which are extracted from a composite film bonded by the laminate adhesive by water of 0.5 mL/cm2 per unit area of the composite film, is 0.5 ppb or less in terms of dibutyl phthalate concentration measured by a gas chromatograph-flame ionization detector.
    • 可以抑制复合膜的低分子量化合物溶解成含量的层压粘合剂,以防止内容物的固有性质或性能被低分子量化合物破坏。 在层压粘合剂中,聚酯多元醇含有作为酸成分的萘二甲酸和/或其烷基酯,以及萃取水中的环状酯化合物的浓度,从由层压粘合剂通过0.5mL / 复合膜的每单位面积的2cm 2,以气相色谱 - 火焰离子化检测器测定的邻苯二甲酸二丁酯浓度为0.5ppb以下。
    • 7. 发明申请
    • Laminate adhesive
    • 层压胶
    • US20020143102A1
    • 2002-10-03
    • US10055928
    • 2002-01-28
    • Shigetoshi SasanoSachio Igarashi
    • C08K003/00
    • C09J175/06B32B7/12C08G18/4227Y10S528/905
    • A laminate adhesive that can suppress elution of a low molecular weight compounds of a composite film into the content, so as to prevent the inherent properties or performances of the content from being spoiled by the low molecular weight compounds. In the laminate adhesive, the polyester polyol contains naphthalenedicarboxylic acid and/or alkyl ester thereof as an acid component, and concentration of cyclic ester compounds in extracted water, which are extracted from a composite film bonded by the laminate adhesive by water of 0.5 mL/cm2 per unit area of the composite film, is 0.5 ppb or less in terms of dibutyl phthalate concentration measured by a gas chromatograph-flame ionization detector.
    • 可以抑制复合膜的低分子量化合物溶解成含量的层压粘合剂,以防止内容物的固有性质或性能被低分子量化合物破坏。 在层压粘合剂中,聚酯多元醇含有作为酸成分的萘二甲酸和/或其烷基酯,以及萃取水中的环状酯化合物的浓度,从由层压粘合剂通过0.5mL / 复合膜的单位面积cm 2,以气相色谱 - 火焰离子化检测器测定的邻苯二甲酸二丁酯浓度为0.5ppb以下。
    • 8. 发明授权
    • Coating composition and method for producing precoated steel sheets
    • 涂层组合物及其制备方法
    • US6018013A
    • 2000-01-25
    • US139001
    • 1998-08-24
    • Keiji YoshidaTakashi AnyashikiKazumi Itou
    • Keiji YoshidaTakashi AnyashikiKazumi Itou
    • C08G18/42C09D175/06
    • C09D175/06C08G18/4225C08G18/4227C08G18/423C08G18/4244Y10T428/31605
    • This invention relates to a coating composition for precoated steel sheets which are required to have high hardness, high workability and high distinctness of image, and to a method for producing a precoated steel sheet having a coating film of the composition. The composition is prepared by adding a compound of any of the following (a) to (c) to a coating composition consisting essentially of a polyol and containing, as the curing agent, an isocyanate compound or an amino resin, and the coating film of the composition has both high-level workability and high-level hardness.(a) Polyester compounds comprising main repeating units of a general formula (1): ##STR1## wherein n is an integer; and R is an alkylene group having 10 or less carbon atoms, or a 1,4-cyclohexylene-dimethylene group, or a neopentylene group, or a polyoxyalkylene group.(b) Polyester compounds comprising main repeating units of a general formula (2): ##STR2## wherein n is an integer of 10 or less; and R is an alkylene group having 10 or less carbon atoms, or a 1,4-cyclohexylene-dimethylene group, or a neopentylene group.(c) Compounds having the structure of a general formula (3):HO--(CH.sub.2).sub.n --O--R--O--(CH.sub.2).sub.n --OH (3)wherein n is an integer of from 2 to 10; and R is ##STR3##
    • 本发明涉及要求具有高硬度,高加工性和高清晰度的预涂钢板用涂料组合物,以及具有该组合物涂膜的预涂钢板的制造方法。 通过将以下(a)〜(c)中任一项所述的化合物添加到基本上由多元醇组成的涂料组合物中,作为固化剂含有异氰酸酯化合物或氨基树脂, 该组合物具有高水平的可加工性和高水平的硬度。 (a)包含通式(1)的主要重复单元的聚酯化合物:其中n是整数; R为碳原子数为10以下的亚烷基,1,4-亚环己基 - 二亚甲基,新戊烯基或聚氧化烯基。 (b)包含通式(2)的主要重复单元的聚酯化合物:其中n为10以下的整数; R为碳原子数为10以下的亚烷基或1,4-亚环己基 - 二亚甲基或新戊烯基。 (c)具有通式(3)结构的化合物:HO-(CH2)n-O-R-O-(CH2)n-OH(3)其中n为2至10的整数; 和R是
    • 9. 发明授权
    • Coating composition and method for producing precoated steel sheets
    • 涂层组合物及其制备方法
    • US5817731A
    • 1998-10-06
    • US707249
    • 1996-09-03
    • Kenji YoshidaTakashi AnyashikiKazumi ItouShouichi Oosuka
    • Kenji YoshidaTakashi AnyashikiKazumi ItouShouichi Oosuka
    • C09D161/32C08G18/42C09D161/20C09D167/00C09D167/02C09D175/06C08G18/80
    • C08G18/4244C08G18/4225C08G18/4227C08G18/423C09D175/06Y10T428/31605Y10T428/31609
    • This invention relates to a coating composition for precoated steel sheets which are required to have high hardness, high workability and high distinctness of image, and to a method for producing a precoated steel sheet having a coating film of the composition. The composition is prepared by adding a compound of any of the following (a) to (c) to a coating composition consisting essentially of a polyol and containing, as the curing agent, an isocyanate compound or an amino resin, and the coating film of the composition has both high-level workability and high-level hardness. (a) Polyester compounds comprising main repeating units of a general formula (1): ##STR1## wherein n is an integer; and R is an alkylene group having 10 or less carbon atoms, or a 1,4-cyclohexylene-dimethylene group, or a neopentylene group, or a polyoxyalkylene group. (b) Polyester compounds comprising main repeating units of a general formula (2): ##STR2## wherein n is an integer of 10 or less; and R is an alkylene group having 10 or less carbon atoms, or a 1,4-cyclohexylene-dimethylene group, or a neopentylene group. (c) Compounds having the structure of a general formula (3): HO--(CH.sub.2).sub.n --O--R--O--(CH.sub.2).sub.n --OH (3) wherein n is an integer of from 2 to 10; and R is ##STR3##
    • 本发明涉及要求具有高硬度,高加工性和高清晰度的预涂钢板用涂料组合物,以及具有该组合物涂膜的预涂钢板的制造方法。 通过将以下(a)〜(c)中任一项所述的化合物添加到基本上由多元醇组成的涂料组合物中,作为固化剂含有异氰酸酯化合物或氨基树脂, 该组合物具有高水平的可加工性和高水平的硬度。 (a)包含通式(1)的主要重复单元的聚酯化合物:其中n是整数; R为碳原子数为10以下的亚烷基,1,4-亚环己基 - 二亚甲基,新戊烯基或聚氧化烯基。 (b)包含通式(2)的主要重复单元的聚酯化合物:其中n为10或更小的整数; R为碳原子数为10以下的亚烷基或1,4-亚环己基 - 二亚甲基或新戊烯基。 (c)具有通式(3)结构的化合物:HO-(CH2)n-O-R-O-(CH2)n-OH(3)其中n为2至10的整数; 而R是