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1. 发明申请

US20080255307A1 Copolymers comprising low surface tension (meth)acrylates 审中-公开
标题翻译：包含低表面张力（甲基）丙烯酸酯的共聚物
公开(公告)号：US20080255307A1
公开(公告)日：2008-10-16
申请号：US12132928
申请日：2008-06-04
申请人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
发明人： Kurt G. Olson , Simion Coca , James B. O'Dwyer , Joanne H. Smith
IPC分类号： C08G63/00
CPC分类号： C08F220/10
摘要： The present invention is directed to a copolymer that includes a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers. The copolymer has a polydispersity index of less than 2.5. The present invention further includes a controlled radical polymerization method to make the above described low surface tension containing copolymers. The method includes the steps of adding a first radically polymerizable low surface tension (meth)acrylate monomer and one or more other radically polymerizable ethylenically unsaturated monomers to a solution containing a suitable atom transfer radical polymerization (ATRP) initiator.
摘要翻译：本发明涉及包含第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体的共聚物。共聚物的多分散指数小于2.5。本发明还包括制备上述低表面张力共聚物的受控自由基聚合方法。该方法包括将第一自由基聚合性低表面张力（甲基）丙烯酸酯单体和一种或多种其它可自由基聚合的烯属不饱和单体加入到含有合适的原子转移自由基聚合（ATRP）引发剂的溶液中的步骤。

2. 发明授权

US07125931B2 Thermosetting compositions containing alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US07125931B2
公开(公告)日：2006-10-24
申请号：US10887733
申请日：2004-07-09
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A thermosetting composition that includes an ungelled copolymer composition and a crosslinking agent. The ungelled copolymer composition includes a functional group-containing copolymer that includes segments of alternating residues derived from a donor monomer composition comprising an acceptor monomer composition. The donor monomer composition includes one or both of isobutylene and diisobutylene, and the acceptor monomer composition includes acrylic monomers and monomers containing functional groups. The ungelled copolymer composition is substantially free of transition metals and Lewis acids, and the copolymer is substantially free of maleate-type monomer residues and fumarate-type monomer residues. The crosslinking agent has at least two functional groups that are reactive with the functional groups of the copolymer. The thermosetting composition may be in liquid, powder, or dispersed form and may be applied by traditional or electrocoating methods.

3. 发明授权

US06992137B2 Alternating copolymers of isobutylene type monomers 失效
公开(公告)号：US06992137B2
公开(公告)日：2006-01-31
申请号：US10697413
申请日：2003-10-30
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F8/00
CPC分类号： C09D201/02 , C08F8/00 , C08F10/00 , C08F20/00
摘要： A copolymer composition that includes a copolymer comprised of at least 30 mol % of residues having the following alternating residues from a donor monomer and from an acceptor monomer. The copolymer contains at least 15 mol % of an isobutylene type donor monomer and at least 15 mol % of an acrylic monomer as an acceptor monomer. The copolymer is substantially free of maleate or fumarate monomer segments and the copolymer composition is substantially free of Lewis acids and transition metals. Also disclosed is a thermosetting composition that includes a reactant comprising functional groups, a crosslinking agent having at least two functional groups that are reactive with the functional groups first reactant, and a copolymer flow control agent that includes the copolymer composition as well as substrates coated with the thermosetting composition.

4. 发明授权

US06900279B2 Compositions containing copolymers of post-polymerization reacted (meth) acrylate monomers 失效
标题翻译：含有后聚合反应的（甲基）丙烯酸酯单体的共聚物的组合物
公开(公告)号：US06900279B2
公开(公告)日：2005-05-31
申请号：US10348367
申请日：2003-01-21
申请人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
发明人： Simion Coca , Gregory J. McCollum , James B. O'Dwyer , Edward R. Coleridge , Steven V. Barancyk
IPC分类号： B05D7/24 , B05D1/00 , B05D3/02 , B05D3/06 , B05D7/00 , B32B27/30 , C08F8/00 , C08F210/00 , C08F210/10 , C08F210/14 , C08F220/10 , C08F290/04 , C08G18/62 , C08G18/79 , C08G18/80 , C08K5/092 , C08L23/20 , C08L23/22 , C08L33/06 , C08L33/14 , C08L63/00 , C08L101/00 , C09D7/12 , C09D109/00 , C09D109/02 , C09D123/22 , C09D133/00 , C09D133/02 , C09D133/06 , C09D133/08 , C09D133/14 , C09D133/24 , C09D157/04 , C09D163/00 , C09D167/00 , C09D175/04 , C09D201/00 , C08F120/54 , C08F120/10
CPC分类号： B05D7/57 , B05D1/007 , B05D3/0209 , B05D3/067 , B05D7/53 , C08F8/00 , C08F210/10 , C08F220/10 , C08F290/046 , C08G18/6229 , C08G18/792 , C08G18/798 , C08G18/8025 , C08G18/807 , C08G18/8074 , C08G2150/20 , C08L33/068 , C09D123/22 , C09D133/062 , C09D133/08 , Y10T428/31504 , Y10T428/31511 , C08F220/00 , C08F220/12 , C08F210/00 , C08L2666/28 , C08L2666/02 , C08F214/18 , C08F2500/03 , C08F2500/02 , C08F212/00 , C08F222/00 , C08F2500/26 , C08L2666/04
摘要： A composition that includes a non-gelled copolymer that includes one or more residues of a first polymerizable ethylenically unsaturated monomer containing a pendant amide, ester or carboxylic acid group. The nearest neighboring monomer residues of the majority of the first monomer residues along the copolymer molecule do not contain pendant carbonyl functional groups. The amide, ester or carboxylic acid group of the residues of the first monomer are the post polymerization transesterification, transamidification or hydrolysis reaction product of a C1-C4 alkyl ester group in the unreacted first monomer with a compound selected from amine functional compounds and hydroxy functional compounds. The reacted copolymer is substantially free of cyclical structures resulting from the transesterification, transamidification or hydrolysis reaction. The compositions may be thermosetting compositions useful in multi-layer composite coatings.
摘要翻译：包含非凝胶共聚物的组合物，其包含含有侧酰胺，酯或羧酸基团的第一可聚合烯属不饱和单体的一个或多个残基。沿着共聚物分子的大部分第一单体残基的最邻近的单体残基不含有羰基官能团。第一单体的残基的酰胺，酯或羧酸基是C 1 -C 4烷基酯基的后聚合酯交换，转酰胺化或水解反应产物在未反应的第一单体中与选自胺官能化合物和羟基官能化合物的化合物反应。反应的共聚物基本上不含由酯交换，酰胺化或水解反应产生的循环结构。组合物可以是可用于多层复合涂层的热固性组合物。

5. 发明授权

US06677422B2 Method of making alternating copolymers of isobutylene type monomers 失效
标题翻译：制备异丁烯型单体的交替共聚物的方法
公开(公告)号：US06677422B2
公开(公告)日：2004-01-13
申请号：US10077559
申请日：2002-02-15
申请人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
发明人： Simion Coca , Edward R. Coleridge , Gregory J. McCollum , James B. O'Dwyer , James E. Poole , Victoria A. Trettel
IPC分类号： C08F1000
CPC分类号： C08F220/12
摘要： A method of making a copolymer composition containing a copolymer, which includes the steps of (a) providing a donor monomer composition that includes an isobutylene type monomer; (b) mixing the donor monomer composition with an ethylenically unsaturated monomer composition that includes one or more ethylenically unsaturated acceptor monomers, and is substantially free of maleate type monomers and fumarate type monomers, and (c) polymerizing the mixture resulting from step (b) in the presence of a free radical polymerization initiator. The polymerization is carried out in the substantial absence of Lewis acids and/or transition metals. The isobutylene type monomer is present at a molar excess of at least 10 mol % based on the molar concentration of monomers in the ethylenically unsaturated monomer composition. The ethylenically unsaturated acceptor monomers are present in an amount of at least 15 mol % of the total monomer composition.
摘要翻译：一种制备含有共聚物的共聚物组合物的方法，其包括以下步骤：（a）提供包含异丁烯型单体的供体单体组合物; （b）将供体单体组合物与包含一种或多种烯键式不饱和受体单体的烯属不饱和单体组合物混合，并且基本上不含马来酸盐型单体和富马酸盐型单体，和（c）将由步骤（b）得到的混合物聚合，在自由基聚合引发剂存在下进行。基本上不存在路易斯酸和/或过渡金属进行聚合。基于烯属不饱和单体组合物中单体的摩尔浓度，异丁烯型单体的摩尔过量为至少10摩尔％。烯属不饱和受体单体的存在量为总单体组合物的至少15摩尔％。

6. 发明授权

US06462125B1 Pigment dispersions containing dispersants prepared by controlled radical polymerization having hydrophilic and hydrophobic segments 失效
标题翻译：含有通过具有亲水和疏水链段的受控自由基聚合制备的分散剂的颜料分散体
公开(公告)号：US06462125B1
公开(公告)日：2002-10-08
申请号：US09464946
申请日：1999-12-16
申请人： Daniela White , Simion Coca , James B. O'Dwyer
发明人： Daniela White , Simion Coca , James B. O'Dwyer
IPC分类号： C08J3100
CPC分类号： C09D17/001 , C09B67/009
摘要： A pigment dispersion that includes a pigment, an aqueous carrier, and a pigment dispersant. The pigment dispersant is prepared by atom transfer radical polymerization initiated and has the polymer chain structure: &phgr;—(G)p—(E)a—T where G is a residue of at least One ethylenically unsaturated monomer; E is a hydrophilic residue of at least one ethylenically unsaturated monomer; &phgr; is a hydrophobic residue of or derived from an initiator; T is or is derived from a radically transferable group from the initiator, p and s represent average numbers of residues occurring in a block of residues; p and s are each individually selected such that said pigment dispersant has a number average molecular weight of at least 250.
摘要翻译：包含颜料，水性载体和颜料分散剂的颜料分散体。颜料分散剂通过引发原子转移自由基聚合制备，并具有聚合物链结构：其中G是至少一个烯属不饱和单体的残基; E是至少一种烯属不饱和单体的亲水性残基; phi是引发剂的疏水残基或衍生自引发剂; T是衍生自起始基团的可自由转移的基团，p和s代表在残基块中发生的残基的平均数; p和s各自单独选择，使得所述颜料分散剂的数均分子量为至少250。

7. 发明授权

US06294014B1 Pigment dispersions containing dispersants prepared by controlled radical polymerization and having pendent hydrophilic polymeric segments 失效
标题翻译：含有分散剂的颜料分散体，其通过可控自由基聚合制备并具有侧链亲水性聚合物链段
公开(公告)号：US06294014B1
公开(公告)日：2001-09-25
申请号：US09464917
申请日：1999-12-16
申请人： Brian E. Woodworth , Simion Coca , James B. O'Dwyer
发明人： Brian E. Woodworth , Simion Coca , James B. O'Dwyer
IPC分类号： C08L5106
CPC分类号： C09B67/0085 , C09B67/0066
摘要： A pigment dispersion comprising pigment, an aqueous carrier selected from water and a mixture of water and at least one organic solvent, and a pigment dispersant is described. The pigment dispersant is prepared by controlled radical polymerization, e.g., atom transfer radical polymerization, of a radically polymerizable monomer in the presence of a polymeric initiator having at least one radically transferable group. The polymeric initiator forms the polymeric backbone segment of the pigment dispersant, and the monomer forms polymeric segments that are pendent to the polymeric backbone segment. The pigment dispersant has comb-like architecture in which the polymeric backbone segment is hydrophobic, and at least a portion of each pendent polymeric segment is hydrophilic.
摘要翻译：描述了包含颜料，选自水和水与至少一种有机溶剂的混合物的水性载体和颜料分散剂的颜料分散体。在具有至少一个可自由基转移基团的聚合物引发剂的存在下，通过可自由基聚合的单体的可控自由基聚合，例如原子转移自由基聚合制备颜料分散剂。聚合引发剂形成颜料分散剂的聚合物主链段，并且单体形成与聚合物骨架链段相反的聚合链段。颜料分散剂具有梳状结构，其中聚合物骨架链段是疏水性的，并且每个侧链聚合链段的至少一部分是亲水的。

8. 发明授权

US06265489B1 Thermosetting compositions containing carboxylic acid functional polymers prepared by atom transfer radical polymerization 失效
标题翻译：含有通过原子转移自由基聚合制备的羧酸官能聚合物的热固性组合物
公开(公告)号：US06265489B1
公开(公告)日：2001-07-24
申请号：US09375017
申请日：1999-08-16
申请人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
发明人： Karen A. Barkac , Simion Coca , James R. Franks , Kurt A. Humbert , Paul H. Lamers , Roxalana L. Martin , James B. O'Dwyer , Kurt G. Olson , Daniela White
IPC分类号： C08L3302
CPC分类号： C09D133/02 , C08L63/00 , C09D133/064 , C08L2666/14
摘要： A thermosetting composition comprising a co-reactable solid, particulate mixture of (a) polycarboxylic acid functional polymer, and (b) epoxide functional crosslinking agent having at least two epoxide groups, e.g., triglycidyl isocyanurate (TGIC), is described. The polycarboxylic acid functional polymer is prepared by atom transfer radical polymerization and has well defined polymer chain architecture and polydispersity index of less than 2.0. The thermosetting compositions of the present invention have utility as powder coatings compositions.
摘要翻译：描述了包含（a）多元羧酸官能聚合物和（b）具有至少两个环氧基团的环氧官能交联剂例如三缩水甘油基异氰脲酸酯（TGIC）的共反应固体，颗粒混合物的热固性组合物。聚羧酸官能聚合物通过原子转移自由基聚合制备，并且具有良好的聚合物链结构和小于2.0的多分散指数。本发明的热固性组合物可用作粉末涂料组合物。

9. 发明授权

US5506325A Coating composition having improved rheology control and copolymer, mixture and process therefor 失效
标题翻译：具有改进的流变控制和共聚物，混合物和方法的涂料组合物
公开(公告)号：US5506325A
公开(公告)日：1996-04-09
申请号：US356808
申请日：1994-12-15
申请人： Shanti Swarup , James R. Christenson , B. Keith Johnston , James B. O'Dwyer , Edward R. Coleridge , Andrew T. Carroll
发明人： Shanti Swarup , James R. Christenson , B. Keith Johnston , James B. O'Dwyer , Edward R. Coleridge , Andrew T. Carroll
IPC分类号： B05D5/06 , C08F20/10 , C08F220/10 , C09D4/06 , C09D155/00 , C09D163/00 , C09D175/04 , C09K3/00
CPC分类号： C09D155/005 , C08F20/10 , C09D175/04
摘要： A non-gelled copolymer is prepared from: I) at least one ethylenically unsaturated aliphatic or aromatic monomer that is unsubstituted with reactive functionality and/or has hydroxyl functionality, II) an ethylenically unsaturated monomer having one acid functional group; and III) an ethylenically unsaturated oligomeric monomer having a number average molecular weight of about 1500 to about 4000 and which is derived from a hydroxyl functional acid having a predominantly hydrocarbon chain of from about 10 to 19 carbon atoms. The amounts of the monomers based upon the total solid weight of reactants used to prepare the copolymer are: about 80 to about 95 for I; about 3 to about 6 percent for II; and about 2 to about 14 percent for III. The ungelled copolymer can be present with hydrophobic amorphous fumed silica in amounts of about 50 to about 90 for the copolymer and about 10 to about 50 all as percentages by weight based on the weight of the two components. The ungelled copolymer alone or with the silica can be present along with coating components like film forming polymers, aqueous and/or organic solvent vehicles and optionally one or more pigments. In the colored and/or clear coating compositions and in the methods of their application to substrates, the amount of the silica is up to about 2.5 percent by weight, and the ratio of the copolymer to the silica is generally in the range of from about 9:1 to 1:1 to yield coatings with good rheology control.
摘要翻译：非胶凝共聚物由以下制备：I）至少一种未反应的官能团和/或具有羟基官能团的烯属不饱和脂族或芳族单体，II）具有一个酸官能团的烯属不饱和单体; 和III）数均分子量为约1500至约4000的烯键式不饱和低聚单体，其衍生自主要具有约10至19个碳原子的烃链的羟基官能酸。基于用于制备共聚物的反应物的总固体重量，单体的量为：对于I为约80至约95; II的约3〜6％而III级约为2％至14％。无凝胶共聚物可以以共聚物的约50至约90的量的疏水性无定形热解法二氧化硅存在，并且基于两种组分的重量以重量百分数计约10至约50。单独或与二氧化硅的未凝胶共聚物可以与涂层组分如成膜聚合物，水性和/或有机溶剂载体以及任选的一种或多种颜料一起存在。在有色和/或透明涂料组合物及其应用于底物的方法中，二氧化硅的量高达约2.5重量％，并且共聚物与二氧化硅的比例通常在约 9：1至1：1，以获得具有良好流变学控制的涂层。

10. 发明授权

US4997882A Acid or anhydride grafted chlorinated polyolefin reacted with monoalcohol and polyepoxide 失效
标题翻译：酸或酸酐接枝的氯化聚烯烃与一元醇和聚环氧化物反应
公开(公告)号：US4997882A
公开(公告)日：1991-03-05
申请号：US376441
申请日：1989-07-07
申请人： Jonathan T. Martz , James B. O'Dwyer , Marvis E. Hartman
发明人： Jonathan T. Martz , James B. O'Dwyer , Marvis E. Hartman
IPC分类号： B05D3/10 , B05D7/02 , C08F8/14 , C08G59/14 , C08J7/04 , C09D163/00
CPC分类号： C08J7/047 , C08F8/14 , C08J2323/02 , C08J2451/00
摘要： Disclosed is an ungelled, modified chlorinated polyolefin resin suitable for providing a highly adherent, solvent resistant film on a thermoplastic polyolefin substrate. The modified chlorinated polyolefin resin is prepared by grafting an unsaturated polycarboxylic acid and/or an unsaturated acid anhydride onto a chlorinated polyolefin resin to form an acid- and/or anhydride-modified chlorinated polyolefin resin. The resulting acid- and/or anhydride-modified chlorinated polyolefin resin is reacted with an organic monohydric alcohol to form an esterified product containing acid functionality. The resulting esterified product is reacted with a polyepoxide to form the ungelled modified chlorinated polyolefin resin.Also disclosed is a method of preparing an ungelled modified chlorinated polyolefin resin of the invention, a coating composition containing a resin of the invention, and a method of forming a hardened film from the coating composition on a thermoplastic polyolefin substrate.
摘要翻译：公开了一种未凝胶化的改性氯化聚烯烃树脂，其适于在热塑性聚烯烃基材上提供高粘附性，耐溶剂性的膜。通过将不饱和多羧酸和/或不饱和酸酐接枝到氯化聚烯烃树脂上以形成酸和/或酸酐改性的氯化聚烯烃树脂来制备改性氯化聚烯烃树脂。将所得酸和/或酸酐改性的氯化聚烯烃树脂与有机一元醇反应形成含有酸官能团的酯化产物。所得酯化产物与聚环氧化物反应形成未凝胶化的改性氯化聚烯烃树脂。还公开了制备本发明的未凝胶化改性氯化聚烯烃树脂的方法，含有本发明树脂的涂料组合物和在热塑性聚烯烃基材上由涂料组合物形成硬化膜的方法。

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