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1. 发明授权

US09676682B2 Catalyst complex and use thereof in alkane oligomerization 有权
公开(公告)号：US09676682B2
公开(公告)日：2017-06-13
申请号：US14483008
申请日：2014-09-10
申请人： Alan Stuart Goldman , Robert J. Saxton , Oleg Mironov
发明人： Alan Stuart Goldman , Robert Timothy Stibrany , Robert J. Saxton , Oleg Mironov
IPC分类号： B01J21/00 , B01J23/00 , B01J25/00 , B01J29/00 , B01J31/00 , C07C5/03 , C07C5/333 , C07C5/48 , C07C2/32 , C07C5/52 , B01J31/02 , B01J31/18 , B01J31/24
CPC分类号： C07C5/03 , B01J31/0208 , B01J31/183 , B01J31/2409 , B01J2231/20 , B01J2231/766 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C2/32 , C07C5/333 , C07C5/48 , C07C5/52 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C11/02 , C07C9/00
摘要： Provided is a Group 9 novel metal catalyst complex further comprising a ketone-containing cocatalyst. The metal catalyst complex is useful in generating olefins from alkanes with great efficiency. In one embodiment, provided is an iridium catalyst complex useful in the dehydrogenation of alkanes comprising a ketone-containing cocatalyst and iridium complexed with a tridentate ligand. Also provided is a novel dehydrogenation method which utilizes the catalyst composition. In other embodiments, a novel process for preparing oligomers from alkanes utilizing the catalyst composition is provided.

2. 发明申请

US20170107116A1 HIGH SURFACE AREA LAYERED DOUBLE HYDROXIDES 审中-公开
公开(公告)号：US20170107116A1
公开(公告)日：2017-04-20
申请号：US15129137
申请日：2015-03-25
申请人： SCG Chemicals Co., Ltd.
发明人： Dermot O'Hare , Chunping Chen , Aunchana Wangriya , Anchalee Wangariyakawee
IPC分类号： C01F11/18 , B01J27/25 , B01J27/053 , B01J31/26 , B01J31/28 , B01J31/02 , B01J35/10 , B01J35/02 , B01J37/03 , B01J37/02 , B01J20/22 , B01J20/04 , B01J20/08 , B01J20/28 , B01J20/30 , C09D1/00 , C01F11/46 , C01F11/36 , C01G53/00 , C01G51/00 , C01G3/00 , B01J27/236
CPC分类号： C01F11/18 , B01J20/041 , B01J20/043 , B01J20/045 , B01J20/08 , B01J20/22 , B01J20/28016 , B01J20/28061 , B01J20/3085 , B01J27/053 , B01J27/236 , B01J27/25 , B01J31/0208 , B01J31/26 , B01J31/28 , B01J35/026 , B01J35/1019 , B01J37/0236 , B01J37/031 , C01F7/002 , C01F7/004 , C01F7/005 , C01F11/36 , C01F11/46 , C01G3/006 , C01G51/006 , C01G53/006 , C01P2002/22 , C01P2002/72 , C01P2004/03 , C01P2004/50 , C01P2004/60 , C01P2004/61 , C01P2006/12 , C01P2006/14 , C09D1/00
摘要： Layered double hydroxides having a high surface area (at least 125 m2/g) and the formula (I) [Mz+1-xM′y+x(OH)2]a+(Xn-)a/n+bH2O.c(AMO-solvent) (I) wherein M and M′ are different and each is a charged metal cation (and must be present), z=1 or 2; y=3 or 4, 0

3. 发明申请

US20160339415A1 Composite Catalyst for the Photocatalytic Isomerisation of Norbornadiene to Prepare Quadricyclane and Process for Making the Catalyst 审中-公开
标题翻译：用于光催化异构化降冰片二烯制备四环烷的复合催化剂及其制备方法
公开(公告)号：US20160339415A1
公开(公告)日：2016-11-24
申请号：US14648896
申请日：2014-05-23
申请人： TIANJIN UNIVERSITY
发明人： Jijun ZOU , Xiangwen ZHANG , Li WANG , Qingfa WANG
IPC分类号： B01J31/02 , B01J31/34 , C07C5/22 , B01J37/04 , B01J37/00 , B01J35/00 , B01J31/38 , B01J31/36
CPC分类号： B01J31/0208 , B01J21/063 , B01J23/002 , B01J23/02 , B01J23/06 , B01J23/20 , B01J23/30 , B01J29/89 , B01J31/0237 , B01J31/0271 , B01J31/34 , B01J31/36 , B01J31/38 , B01J35/004 , B01J37/009 , B01J37/0203 , B01J37/0236 , B01J37/04 , C07C5/2213 , C07C5/222 , C07C5/2266 , C07C2521/06 , C07C2521/08 , C07C2523/02 , C07C2523/06 , C07C2523/20 , C07C2523/30 , C07C2529/70 , C07C2531/02 , C07C2531/34 , C07C2531/36 , C07C2531/38 , C07C2603/86 , C07C13/68
摘要： The present invention discloses a composite catalyst for the photocatalytic isomerisation of norbornadiene to prepare quadricyclane, comprising: a solid photocatalyst, selected from the group consisting of TiO2, Ti-MCM-41, Ti-SBA-15, ZnO, WO3, Ta2O5 or SrTiO3; and an organic photo-sensitizer loaded on the surface or in the channel of said solid photocatalyst, selected from benzophenone, acetophenone, Michler's Ketone, tetraethyl Michler's Ketone, and diethyl Michler's Ketone, where the organic photo-sensitizer is present in the solid photocatalyst in an amount of 0.5% to 20% by weight. The catalyst of the invention can catalyze a target reaction under the condition that no solvent is used, and the yield of the target product quadricyclane is higher. Furthermore, the catalyst of the invention has a stable activity, and it can be recycled. The invention further discloses a process for preparing the composite catalyst.
摘要翻译：本发明公开了一种用于降冰片二烯的光催化异构化制备四环烷的复合催化剂，其包括：选自TiO 2，Ti-MCM-41，Ti-SBA-15，ZnO，WO 3，Ta 2 O 5或SrTiO 3的固体光催化剂 ; 和负载在所述固体光催化剂的表面或通道中的有机光敏剂，其选自二苯甲酮，苯乙酮，米ler酮，四乙基米ler酮和二乙基米ler酮，其中有机光敏剂存在于固体光催化剂中为0.5〜20重量％。本发明的催化剂可以在不使用溶剂的情况下催化目标反应，目标产物四环素的收率更高。此外，本发明的催化剂具有稳定的活性，可以回收利用。本发明还公开了一种制备复合催化剂的方法。

4. 发明申请

US20150073185A1 Novel Catalyst Complex and Use Thereof in Alkane Oligomerization 有权
标题翻译：新型催化剂配合物及其在烷基低聚反应中的应用
公开(公告)号：US20150073185A1
公开(公告)日：2015-03-12
申请号：US14483008
申请日：2014-09-10
申请人： Alan Stuart Goldman , Robert Timothy Stibrany , Robert J. Saxton , Oleg MIRONOV
发明人： Alan Stuart Goldman , Robert Timothy Stibrany , Robert J. Saxton , Oleg MIRONOV
IPC分类号： B01J31/12 , C07C2/06 , C07C5/03 , C07C5/333 , C07C5/48
CPC分类号： C07C5/03 , B01J31/0208 , B01J31/183 , B01J31/2409 , B01J2231/20 , B01J2231/766 , B01J2531/824 , B01J2531/827 , B01J2531/828 , C07C2/32 , C07C5/333 , C07C5/48 , C07C5/52 , C07C2531/02 , C07C2531/14 , C07C2531/22 , C07C2531/24 , C07C11/02 , C07C9/00
摘要： Provided is a Group 9 novel metal catalyst complex further comprising a ketone-containing cocatalyst. The metal catalyst complex is useful in generating olefins from alkanes with great efficiency. In one embodiment, provided is an iridium catalyst complex useful in the dehydrogenation of alkanes comprising a ketone-containing cocatalyst and iridium complexed with a tridentate ligand. Also provided is a novel dehydrogenation method which utilizes the catalyst composition. In other embodiments, a novel process for preparing oligomers from alkanes utilizing the catalyst composition is provided.
摘要翻译：提供了另外包含含酮助催化剂的第9族新型金属催化剂络合物。金属催化剂络合物可用于以高效率从烷烃产生烯烃。在一个实施方案中，提供了一种可用于含有酮的助催化剂和与三齿配体络合的铱的烷烃脱氢的铱催化剂络合物。还提供了一种利用催化剂组合物的新型脱氢方法。在其它实施方案中，提供了利用催化剂组合物从烷烃制备低聚物的新方法。

5. 发明申请

US20120220685A1 PHOTO-LATENT TITANIUM CATALYSTS 审中-公开
标题翻译：钛酸钡催化剂
公开(公告)号：US20120220685A1
公开(公告)日：2012-08-30
申请号：US13395467
申请日：2010-09-09
申请人： Tobias Hintermann , Didier Bauer , Antoine Carroy , Caroline Lordelot , Rachel Kohli Steck
发明人： Tobias Hintermann , Didier Bauer , Antoine Carroy , Caroline Lordelot , Rachel Kohli Steck
IPC分类号： C08G18/32 , C09D11/10 , C09D175/04 , C08F4/76 , C09J175/04
CPC分类号： B01J31/2234 , B01J31/0208 , B01J31/2213 , B01J31/2226 , B01J2231/34 , B01J2531/46 , C08G18/222 , C08G18/6216 , C08G18/792 , C09D175/04
摘要： The present invention provides a photolatent Ti-chelate catalyst formulation, comprising (i) at least one compound of the formula (I) wherein R1 is C1-C20alkyl or C2-C20alkyl which is interrupted by one or more non-consecutive O-atoms; Y is formula (II) or optionally substituted phenyl; Y1 is formula (III) or optionally substituted phenyl; Y2 is formula (IV) or optionally substituted phenyl; Y3 is formula (V) or optionally substituted phenyl; R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are hydrogen, halogen, optionally substituted C1-C20alkyl, or R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13 independently of each other are optionally substituted C6-C14aryl, provided that only one of R2, R3, R4 is hydrogen and only one of R5, R6, R7 is hydrogen and only one of R8, R9, R10 is hydrogen and only one of R11, R12, R13 is hydrogen; and (ii) at least one chelate ligand compound of the formula IIa, IIb or IIc, wherein Y′ is formula (VI) or formula (VII); Y′1 is formula (VIII) or formula (IX); R′2, R′3, R′4, R′5, R′6 and R′7 independently of each other have on of the meanings as given for R2, R3, R4, R5, R6, R7, R8, R9, R10, R11, R12 and R13; and R′14, R′15 and R′16 independently of each other have on of the meanings as given for R14, R15 and R16.
摘要翻译：本发明提供了一种光催化剂钛螯合催化剂制剂，其包含（i）至少一种式（I）化合物，其中R 1是被一个或多个非连续O原子间隔的C 1 -C 20烷基或C 2 -C 20烷基; Y是式（II）或任选取代的苯基; Y1是式（III）或任选取代的苯基; Y2是式（IV）或任选取代的苯基; Y 3是式（V）或任选取代的苯基; R2，R3，R4，R5，R6，R7，R8，R9，R10，R11，R12和R13彼此独立地是氢，卤素，任选取代的C 1 -C 20烷基，或者R 2，R 3，R 4，R 5，R 6，R 7 R 8，R 9，R 10，R 11，R 12和R 13彼此独立地是任选取代的C 6 -C 14芳基，条件是R 2，R 3，R 4中只有一个是氢，并且R 5，R 6，R 7中只有一个是氢， R8，R9，R10是氢，R11，R12，R13中只有一个是氢; 和（ii）式IIa，IIb或IIc的至少一种螯合配体化合物，其中Y'为式（VI）或式（VII）; Y'1是式（VIII）或式（IX）; R'2，R'3，R'4，R'5，R'6和R'7彼此独立地具有对R2，R3，R4，R5，R6，R7，R8，R9给出的含义，R10，R11，R12和R13; 并且R 14，R'15和R 16彼此独立地具有对R 14，R 15和R 16给出的含义。

6. 发明授权

US07993495B2 Signal activated decontaminating coating 有权
标题翻译：信号激活去污涂层
公开(公告)号：US07993495B2
公开(公告)日：2011-08-09
申请号：US11471877
申请日：2006-06-21
申请人： Patrick J. Kinlen , Yiwei Ding , James K. Bashkin , Shifeng Hou
发明人： Patrick J. Kinlen , Yiwei Ding , James K. Bashkin , Shifeng Hou
IPC分类号： C01B15/01 , C01B15/00 , A62D3/38
CPC分类号： C01B15/00 , A61L2/03 , A61L2/16 , A61L2/232 , A62D3/38 , A62D2101/02 , A62D2203/10 , B01J31/006 , B01J31/0208 , B01J31/184 , B01J2231/70 , B01J2531/72 , B01J2531/842 , C01B15/01 , C01B15/0295 , C09D105/04
摘要： A method is provided for decontaminating a surface that is susceptible to contamination by a contaminant by applying to the surface a coating which produces a decontaminating agent for the contaminant in response to a signal, connecting the electroactive coating to a source of a signal, and when the surface is contaminated, applying the signal to the electroactive coating, thereby producing one or more decontaminating agents which neutralize or destroy the contaminant. Coatings for practicing the method and articles that have been protected by the novel coatings are also provided.
摘要翻译：提供了一种方法，用于对易受污染物污染的表面进行净化，通过向表面施加响应于信号产生污染物的净化剂的涂层，将电活性涂层连接到信号源，以及何时表面被污染，将信号施加到电活性涂层，从而产生一种或多种中和或破坏污染物的去污剂。还提供了用于实施由新颖涂层保护的方法和制品的涂料。

7. 发明申请

US20100021375A1 CATALYST FOR THE CHEMICAL DECOMPOSITION OF METALHYDRIDE 审中-公开
标题翻译：催化剂用于化学分解金属氢化物
公开(公告)号：US20100021375A1
公开(公告)日：2010-01-28
申请号：US12507817
申请日：2009-07-23
申请人： Alex Silberman , Shmuel Keren
发明人： Alex Silberman , Shmuel Keren
IPC分类号： C01B3/04 , B01J31/02 , B01J31/06 , B01J29/04
CPC分类号： C01B3/04 , B01J23/74 , B01J27/1853 , B01J31/0208 , B01J31/0237 , B01J31/0244 , B01J2531/025 , B01J2531/845 , Y02E60/364
摘要： The invention relates in general to the field of catalysts, in particular to a catalyst. More specifically, the invention relates to a catalyst for metal hydride chemical decomposition. In an embodiment of the invention, there is provided a catalyst for the chemical decomposition of metal hydrides, comprising a transition metal, or an alloy of several elements, wherein at least one of said elements is a transition metal; and an organic molecule.
摘要翻译：本发明一般涉及催化剂领域，特别涉及催化剂领域。更具体地说，本发明涉及一种用于金属氢化物化学分解的催化剂。在本发明的一个实施方案中，提供了用于金属氢化物的化学分解的催化剂，其包含过渡金属或几种元素的合金，其中至少一种所述元素是过渡金属; 和有机分子。

8. 发明授权

US06960693B2 Oxidation reaction process catalyzed by phase-transfer catalyst controlling reaction 有权
标题翻译：通过相转移催化剂控制反应催化氧化反应过程
公开(公告)号：US06960693B2
公开(公告)日：2005-11-01
申请号：US10432874
申请日：2001-11-29
申请人： Zuwei Xi , Yu Sun , Kunlan Li , Ning Zhou
发明人： Zuwei Xi , Yu Sun , Kunlan Li , Ning Zhou
IPC分类号： C07D333/32 , B01J27/186 , B01J31/00 , B01J31/02 , C07B33/00 , C07B61/00 , C07C29/48 , C07C35/08 , C07C45/28 , C07C45/29 , C07C47/228 , C07C49/04 , C07C49/10 , C07C49/403 , C07C49/78 , C07C49/825 , C07C51/285 , C07C51/31 , C07C55/14 , C07C59/185 , C07C67/42 , C07C69/12 , C07C315/02 , C07C317/04 , C07C317/14 , C07D301/06 , C07D301/12 , C07D303/04 , C07D309/30 , C07C321/00 , C07C45/00 , C07D313/00 , C07F15/00
CPC分类号： B01J27/186 , B01J31/006 , B01J31/0208 , B01J31/0239 , B01J31/0244 , B01J31/1815 , B01J31/2243 , B01J2531/64 , B01J2531/66 , B01J2531/96 , B01J2531/985 , C07B33/00 , C07C29/48 , C07C45/294 , C07C51/31 , C07C315/02 , C07C2601/14 , C07D301/06 , C07D301/12 , C07D303/04 , C07D315/00 , Y02P20/584 , C07C35/08 , C07C49/78 , C07C47/228 , C07C49/10 , C07C49/403 , C07C47/575 , C07C49/04 , C07C59/347 , C07C317/14
摘要： The present invention relates to an oxidation reaction catalyzed by a reaction controlled phase-transfer catalyst having the general formula of [R1R2R3R4N]xHy[A] or QmMO3(L). The catalysts themselves are not soluble in the reaction medium, but can form an active species that is soluble in the reaction medium under the action of one of the reactants. The active species can in turn react selectively with another reactant. When one of the reactants is completely consumed, the catalyst will separated out from the reacting system and can be recovered by means of simple separation method. The recovered catalyst can be recycled with comparable efficiency as that of the original catalyst. The separation of said catalyst is similar to that of heterogeneous catalyst while said catalyst will completely exhibit the characteristics of homogeneous catalyst during the reaction. The catalytic oxidation reaction system is especially suitable for the large-scale industrial production of epoxy cyclohexane from cyclohexene or of epoxy propane from propylene.
摘要翻译：本发明涉及通过反应控制的相转移催化剂催化氧化反应，其具有通式[R 1 R 2 R 3 R 3 N R 4 N]] - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - - （L）。催化剂本身不溶于反应介质，但可以在一种反应物的作用下形成可溶于反应介质的活性物质。活性物质又可以选择性地与另一种反应物反应。当其中一种反应物被完全消耗时，催化剂将从反应体系中分离出来并且可以通过简单的分离方法回收。回收的催化剂可以与原始催化剂的效率相当的效率再循环。所述催化剂的分离类似于非均相催化剂，而所述催化剂在反应期间将完全表现出均相催化剂的特性。催化氧化反应体系特别适用于从环己烯或丙烯环氧丙烷大规模工业生产环氧环己烷。

9. 发明授权

US4966876A Transesterification of triglycerides 失效
标题翻译：甘油三酯的酯交换反应
公开(公告)号：US4966876A
公开(公告)日：1990-10-30
申请号：US396933
申请日：1989-08-22
申请人： Viswanatha Sankaran
发明人： Viswanatha Sankaran
IPC分类号： B01J31/02 , C11C3/10
CPC分类号： C11C3/10 , B01J31/0201 , B01J31/0202 , B01J31/0208 , B01J31/0212 , B01J2231/40 , B01J2231/49
摘要： A process for converting liquid triglycerides into solid triglycerides by means of random transesterifications achieved through the use of catalytically active combinations comprising the reaction product of mixtures of dihydroxy and trihydroxy alcohols with mixtures of alkali metal hydroxides, and with ketones. The catalytically active materials can be employed in directed transesterifications in which the transesterification reaction mixture is subjected to a series of heating and cooling cycles during which higher melting fats are formed and precipitated from solution, causing an equilibrium shift that results in the formation and precipitation of still additional higher melting fats. An especially desirable catalytically active combination comprises the reaction product of 1, 2 propanediol, 1,3 propanediol and glycerol, with sodium hydroxide and potassium hydroxide, and in a preferred embodiment, the reaction product is combined with acetone to form the catalytically active combination.

10. 发明授权

US4894435A Polymerization of olefin/carbon monoxide with non-transition metal salt, bidentate p ligand and carboxylic acid ester 失效
标题翻译：烯烃/一氧化碳与非过渡金属盐，二齿配位体配位体和羧酸酯的聚合
公开(公告)号：US4894435A
公开(公告)日：1990-01-16
申请号：US248066
申请日：1988-09-23
申请人： Eit Drent
发明人： Eit Drent
IPC分类号： B01J31/28 , C08G67/00 , C08G67/02
CPC分类号： C08G67/02 , B01J31/0208 , B01J31/0209 , B01J31/0225 , B01J31/04 , B01J31/1895 , B01J31/24 , B01J31/2409 , B01J2231/14 , B01J2531/824
摘要： The process of producing linear alternating polymers of carbon monoxide and at least one ethylenically unsaturated hydrocarbon in the presence of novel catalyst composition prepared from a palladium compound, a non-transition metal salt of a non-hydrohalogenic acid having a pKa less than 6, bidentate phosphorus ligand and a ketone or ester carboxylic compound.

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