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1. 发明授权

US09339798B2 Catalyst for the epoxidation of oelfins 有权
标题翻译：催化剂用于环氧化海藻素
公开(公告)号：US09339798B2
公开(公告)日：2016-05-17
申请号：US14788861
申请日：2015-07-01
申请人： Saint-Gobain Ceramics & Plastics, Inc.
发明人： Michael A. Richard , John R. Lockemeyer
IPC分类号： B01J27/047 , B01J27/02 , C07D301/04 , C07D301/10 , B01J21/04 , B01J23/50 , B01J27/055 , B01J35/10 , B01J23/66
CPC分类号： B01J27/047 , B01J21/04 , B01J23/50 , B01J23/66 , B01J27/02 , B01J27/055 , B01J35/1085 , B01J35/109 , B01J35/1095 , C07D301/04 , C07D301/10 , Y02P20/52
摘要： The carrier of the present invention includes at least 85 wt percent alpha alumina, at least 0.06 wt percent SiO2 and no more than 0.04 wt percent Na2O. The carrier has a water absorption no greater than 0.35 g/g and a ratio of water absorption (g/g) to surface area (m2/g) no greater than 0.50 g/m2. Another aspect of the invention is a catalyst for the epoxidation of olefins which comprises the above described carrier and silver dispersed thereon, where the carrier has a monomodal, bimodal or multimodal pore distribution and where the quantity of silver is between 5 and 50 wt/%, relative to the weight of the catalyst. A reactor system for the epoxidation of olefins is also disclosed.
摘要翻译：本发明的载体包括至少85wt％的α氧化铝，至少0.06wt％的SiO 2和不超过0.04wt％的Na 2 O. 载体的吸水率不大于0.35g / g，吸水率（g / g）与表面积（m2 / g）不大于0.50g / m 2。本发明的另一方面是用于环氧化烯烃的催化剂，其包含分散在其上的上述载体和银，其中载体具有单峰，双峰或多峰孔分布，并且其中银的量为5至50重量％，相对于催化剂的重量。还公开了用于烯烃环氧化的反应器系统。

2. 发明申请

US20140066294A1 Hydroconversion Multi-Metallic Catalysts and Method for Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20140066294A1
公开(公告)日：2014-03-06
申请号：US14019360
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman
发明人： Jinyi Han , Alexander E. Kuperman
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst consists essentially of molybdenum sulfide and tungsten sulfide, wherein the catalyst contains at least 0.1 mol % of Mo and at least 0.1 mol % of W, on a transition metal basis.
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。自支撑的MMS催化剂基本上由硫化钼和硫化钨组成，其中催化剂在过渡金属的基础上含有至少0.1mol％的Mo和至少0.1mol％的W。

3. 发明申请

US20140066293A1 Hydroconversion Multi-Metallic Catalyst and Method For Making Thereof 有权
标题翻译：加氢转化多金属催化剂及其制备方法
公开(公告)号：US20140066293A1
公开(公告)日：2014-03-06
申请号：US14019319
申请日：2013-09-05
申请人： Jinyi Han , Alexander E. Kuperman
发明人： Jinyi Han , Alexander E. Kuperman
IPC分类号： B01J27/051 , B01J27/049
CPC分类号： B01J27/0515 , B01J27/043 , B01J27/047 , B01J27/049 , B01J27/051 , B01J35/002 , B01J35/1014 , B01J35/1038 , C10G45/08
摘要： The invention relates to a self-supported mixed metal sulfide (MMS) catalyst for hydrotreating hydrocarbon feedstock and to a method for preparing the catalyst. The self-supported MMS catalyst contains Ni:W in a mole ratio of 1:3 to 4:1, on a transition metal basis. The self supported MMS catalyst is characterized as having an HYD reaction rate constant of at least 15% higher than that of a catalyst comprising nickel sulfide alone or a catalyst comprising tungsten sulfide alone, when compared on same metal molar basis in hydrotreating of benzene as a feedstock at identical process conditions.
摘要翻译：本发明涉及一种用于加氢处理烃原料的自支撑混合金属硫化物（MMS）催化剂及其制备方法。自支撑的MMS催化剂以过渡金属为基础，含有摩尔比为1:3至4:1的Ni:W。自支撑的MMS催化剂的特征在于，与单独的硫化镍或仅含硫化钨的催化剂相比，HYD反应速率常数比单独的硫化镍催化剂高至少15％，当与原料在相同的工艺条件下。

4. 发明申请

US20140027344A1 METHODS AND SYSTEMS FOR UPGRADING HEAVY OIL USING CATALYTIC HYDROCRACKING AND THERMAL COKING 有权
标题翻译：使用催化水解和热处理提高重油的方法和系统
公开(公告)号：US20140027344A1
公开(公告)日：2014-01-30
申请号：US13561479
申请日：2012-07-30
申请人： Everette Harris , Jeffrey Gendler
发明人： Everette Harris , Jeffrey Gendler
IPC分类号： C10G65/10 , B01J8/02 , B01J8/00
CPC分类号： C10G69/06 , B01J23/28 , B01J27/043 , B01J27/047 , B01J27/051 , B01J35/026 , B01J35/108 , B01J35/109 , B01J37/04 , B01J37/086 , B01J37/20 , C10B55/00 , C10B57/045 , C10G9/005 , C10G47/12 , C10G2300/206
摘要： Methods and systems for hydroprocessing heavy oil feedstocks to form upgraded material use a colloidal or molecular catalyst dispersed within heavy oil feedstock, pre-coking hydrocracking reactor, separator, and coking reactor. The colloidal or molecular catalyst promotes upgrading reactions that reduce the quantity of asphaltenes or other coke forming precursors in the feedstock, increase hydrogen to carbon ratio in the upgraded material, and decrease boiling points of hydrocarbons in the upgraded material. The methods and systems can be used to upgrade vacuum tower bottoms and other low grade heavy oil feedstocks. The result is one or more of increased conversion level and yield, improved quality of upgraded hydrocarbons, reduced coke formation, reduced equipment fouling, processing of a wider range of lower quality feedstocks, and more efficient use of supported catalyst if used with the colloidal or molecular catalyst, as compared to a conventional hydrocracking process or a conventional thermal coking process.
摘要翻译：用于加氢处理重油原料以形成改质材料的方法和系统使用分散在重油原料，预焦化加氢裂化反应器，分离器和焦化反应器内的胶体或分子催化剂。胶体或分子催化剂促进升级反应，其降低原料中沥青质或其他焦炭形成前体的量，提高改质材料中的氢碳比，并降低改质材料中烃的沸点。该方法和系统可用于升级真空塔塔底部和其他低等级重油原料。结果是提高的转化水平和产率，提高的碳氢化合物的质量，降低的焦炭形成，减少的设备结垢，加工更宽范围的较低质量原料的一个或多个，以及如果与胶体或胶体一起使用，则更有效地使用负载型催化剂分子催化剂，与传统的加氢裂化方法或常规的热焦化方法相比。

5. 发明申请

US20130068613A1 AMORPHOUS TRANSITION METAL SULPHIDE FILMS OR SOLIDS AS EFFICIENT ELECTROCATALYSTS FOR HYDROGEN PRODUCTION FROM WATER OR AQUEOUS SOLUTIONS 审中-公开
标题翻译：非晶态过渡金属硫化物膜或固体作为从水或水溶液中生产氢的有效电解质
公开(公告)号：US20130068613A1
公开(公告)日：2013-03-21
申请号：US13641276
申请日：2011-03-31
申请人： Xile Hu , Daniel Merki , Heron Vrubel
发明人： Xile Hu , Daniel Merki , Heron Vrubel
IPC分类号： C25B11/04 , B01J27/047 , B01J27/051
CPC分类号： C25B11/0447 , B01J27/047 , B01J27/051 , B01J27/0515 , C01G39/06 , C25B1/04 , C25B11/0405 , C25B11/0415 , C25B11/0421 , C25B11/0442 , Y02E60/366
摘要： The present invention relates to amorphous transition metal sulphides as electrocatalysts for hydrogen production from water or aqueous solutions and use thereof in electrodes and electrolysers.
摘要翻译：本发明涉及无定形过渡金属硫化物作为用于从水或水溶液中产生氢气的电催化剂，以及在电极和电解槽中的用途。

6. 发明授权

US08088705B2 Process for sulfurization or presulfurization of solid particles of a catalyst or an adsorbent 有权
标题翻译：催化剂或吸附剂的固体颗粒的硫化或预硫化方法
公开(公告)号：US08088705B2
公开(公告)日：2012-01-03
申请号：US12117805
申请日：2008-05-09
申请人： Pierre Dufresne , Franck Labruyere , Maxime Meens , Loredana Romano
发明人： Pierre Dufresne , Franck Labruyere , Maxime Meens , Loredana Romano
IPC分类号： F26B19/00
CPC分类号： B01J8/16 , B01J8/1809 , B01J8/1818 , B01J8/1836 , B01J8/40 , B01J23/72 , B01J23/882 , B01J27/043 , B01J27/047 , B01J27/0515 , B01J37/20 , B01J2208/00017 , B01J2208/00061 , B01J2208/00212 , B01J2208/00371 , B01J2208/00407 , B01J2208/00415 , B01J2208/0053 , B01J2219/1944 , C10G45/04 , C10G2300/207 , Y10S502/514
摘要： The invention relates to a process for incorporating sulfur in the porosity of the solid particles of a catalyst for the conversion of hydrocarbons or an adsorbent. This process is carried out off-site in the presence of hydrogen sulfide that is pure or diluted in hydrogen or nitrogen, a process in which said particles are made to rise or fall in a sulfur incorporation zone that comprises at least one vibratory helical coil that is essentially tubular in shape and that comprises at least two turns, whereby said particles are subjected to a temperature profile over the majority of their path in said coil and whereby said particles are brought into contact with at least one fluid on at least one portion of their path.
摘要翻译：本发明涉及在用于转化烃或吸附剂的催化剂的固体颗粒的孔隙中掺入硫的方法。这种方法是在氢气或氮气中纯化或稀释的硫化氢存在下进行的，所述硫化氢在硫掺入区中上升或下降，其中包含至少一个振动螺旋线圈，基本上是管状的并且包括至少两匝，由此所述颗粒在所述线圈中的大部分路径上经受温度分布，并且由此使所述颗粒在至少一个部分上与至少一个流体接触他们的路径

7. 发明申请

US20110177334A1 MANGANESE TETRATHIOTUNGSTATE MATERIAL 有权
标题翻译： MANGANESE TETRATHIOTUNGSTATESTATE材料
公开(公告)号：US20110177334A1
公开(公告)日：2011-07-21
申请号：US13010879
申请日：2011-01-21
申请人： Michael Anthony REYNOLDS , Charles Roy Donaho
发明人： Michael Anthony REYNOLDS , Charles Roy Donaho
IPC分类号： C01G45/00 , C01B17/00 , D02G3/02 , B01J23/34 , B82Y30/00
CPC分类号： B01J35/06 , B01J27/047 , B01J35/023 , B01J35/1014 , B01J35/1019 , B01J37/082 , C01G45/006 , C10G33/02 , C10G47/02 , C10G47/06
摘要： The present invention is directed to a manganese tetrathiotungstate composition.
摘要翻译：本发明涉及一种四硫酸锰组合物。

8. 发明申请

US20070015941A1 Catalyst for the production of methyl mercaptan from methanol and hydrogen sulfide 有权
标题翻译：用于从甲醇和硫化氢生产甲硫醇的催化剂
公开(公告)号：US20070015941A1
公开(公告)日：2007-01-18
申请号：US10554701
申请日：2004-04-23
申请人： Alexandra Brand , Veronika Quaschning
发明人： Alexandra Brand , Veronika Quaschning
IPC分类号： C07C319/02
CPC分类号： B01J37/20 , B01J21/04 , B01J23/30 , B01J27/047 , B01J27/053 , B01J27/188 , B01J37/28 , C07C319/08 , C07C321/04
摘要： The invention relates to a catalyst for the synthesis of methyl mercaptan from hydrogen sulfide and methanol and to a process for preparing methyl mercaptans. The catalyst comprises active aluminum oxide on which an alkali metal tungstate and ammonium salts have been deposited.
摘要翻译：本发明涉及用于从硫化氢和甲醇合成甲硫醇的催化剂以及制备甲硫醇的方法。催化剂包含其上沉积有碱金属钨酸盐和铵盐的活性氧化铝。

9. 发明申请

US20060201854A1 Methods and mixing systems for introducing catalyst precursor into heavy oil feedstock 审中-公开
标题翻译：将催化剂前体引入重油原料的方法和混合系统
公开(公告)号：US20060201854A1
公开(公告)日：2006-09-14
申请号：US11374369
申请日：2006-03-13
申请人： Roger Lott
发明人： Roger Lott
IPC分类号： C10G47/24 , C10G47/02 , B01J19/00
CPC分类号： C10G47/00 , B01F3/088 , B01F2003/105 , B01J8/0015 , B01J27/047 , B01J27/051 , B01J35/0013 , B01J37/02 , B01J37/086 , B01J38/00 , B01J38/68 , B01J2208/00752 , C10G45/00 , C10G49/04 , C10G65/02 , C10G65/12 , C10G2300/1033 , C10G2300/107 , C10G2300/1077 , C10G2300/802
摘要： Methods and systems for mixing a catalyst precursor with a heavy oil feedstock preparatory to hydroprocessing the heavy oil feedstock in a reactor to form an upgraded feedstock. Achieving very good dispersion of the catalyst precursor facilitates and maximizes the advantages of the colloidal or molecular hydroprocessing catalyst. A catalyst precursor and a heavy oil feedstock having a viscosity greater than the viscosity of the catalyst precursor are provided. The catalyst precursor is pre-mixed with a hydrocarbon oil diluent, forming a diluted catalyst precursor. The diluted precursor is then mixed with at least a portion of the heavy oil feedstock so as to form a catalyst precursor-heavy oil feedstock mixture. Finally, the catalyst precursor-heavy oil feedstock mixture is mixed with any remainder of the heavy oil feedstock, resulting in the catalyst precursor being homogeneously dispersed on a colloidal and/or molecular level within the heavy oil feedstock.
摘要翻译：用于混合催化剂前体与重油原料的方法和系统，其准备在反应器中加氢处理重油原料以形成升级的原料。实现催化剂前体的非常好的分散有助于并最大化胶体或分子加氢处理催化剂的优点。提供了具有大于催化剂前体粘度的粘度的催化剂前体和重油原料。催化剂前体与烃油稀释剂预混合，形成稀释的催化剂前体。然后将稀释的前体与至少一部分重油原料混合，以形成催化剂前体 - 重油原料混合物。最后，将催化剂前体 - 重油原料混合物与任何其余的重油原料混合，导致催化剂前体均匀地分散在重油原料内的胶体和/或分子水平上。

10. 发明授权

US5236881A Coal extract hydrocracking catalyst 失效
标题翻译：煤提取液加氢裂化催化剂
公开(公告)号：US5236881A
公开(公告)日：1993-08-17
申请号：US867352
申请日：1992-04-13
申请人： Michael A. Jones
发明人： Michael A. Jones
IPC分类号： B01J27/047 , C10G1/00 , C10G47/06
CPC分类号： C10G1/002 , B01J27/047 , C10G47/06
摘要： A coal extract hydrocracking catalyst having particular utility in a two stage coal extracting process which has a first liquid hydrogen donor solvent oil extraction stage and a second stage comprising catalytic hydrocracking of the extract. Desired levels of hydrocracking and hydrogenation of the extract, with an acceptable level of naphthene formation, are achieved by using on the coal extract hydrocracking catalyst a mixture of a promoted W or Mo catalyst with an unpromoted W or Mo catalyst.
摘要翻译：一种煤提取物加氢裂化催化剂，其特征在于在具有第一液体氢供体溶剂油萃取阶段的二阶段采煤过程中具有特殊用途，第二阶段包括提取物的催化加氢裂化。通过在煤提取物加氢裂化催化剂上使用促进的W或Mo催化剂与未萃取的W或Mo催化剂的混合物，可以获得所需提取物的加氢裂化和氢化水平，具有可接受的环烷烃形成水平。

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