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1. 发明授权

US08283278B2 Process for sulfurizing hydrocarbon treatment catalysts 有权
标题翻译：硫化烃处理催化剂的方法
公开(公告)号：US08283278B2
公开(公告)日：2012-10-09
申请号：US12879514
申请日：2010-09-10
申请人： Pierre Dufresne , Eric Nagy , Pauline Galliou
发明人： Pierre Dufresne , Eric Nagy , Pauline Galliou
IPC分类号： B01J31/00
CPC分类号： C10G45/02 , B01J23/882 , B01J31/0215 , B01J37/0203 , B01J37/12 , B01J37/20 , C10G2300/207 , C10G2300/705
摘要： The present invention relates to a process for sulfurizing a hydrocarbon treatment catalyst, comprising: at least a first step of depositing, on the surface of the catalyst, one or more sulfurization auxiliaries of formula (I): and at least a second step of placing the catalyst in contact with a sulfur-containing gaseous mixture containing hydrogen and a sulfur compound.
摘要翻译：本发明涉及一种用于使烃处理催化剂硫化的方法，包括：至少第一步骤，在催化剂的表面上沉积一种或多种式（I）的硫化助剂：和至少第二步，所述催化剂与含有氢和硫化合物的含硫气体混合物接触。

2. 发明授权

US08278234B2 Process for the regeneration of catalysts for the treatment of hydrocarbons 有权
标题翻译：用于再生用于处理烃的催化剂的方法
公开(公告)号：US08278234B2
公开(公告)日：2012-10-02
申请号：US12574381
申请日：2009-10-06
申请人： Pauline Galliou , Eric Nagy , Pierre Dufresne
发明人： Pauline Galliou , Eric Nagy , Pierre Dufresne
IPC分类号： B01J38/02
CPC分类号： B01J37/0203 , B01J23/85 , B01J23/94 , B01J31/0209 , B01J31/0212 , B01J31/0215 , B01J31/0218 , B01J31/0229 , B01J31/0271 , B01J31/4015 , B01J37/20 , B01J38/12 , B01J38/52 , C10G45/08 , C10G2300/4093
摘要： A subject-matter of the present invention is a process for the regeneration of a catalyst comprising at least one metal from Group VIII and at least one metal from Group VIB which are deposited on a refractory oxide support, comprising: at least one first step of heat treatment of the catalyst in the presence of oxygen and at a temperature ranging from 350° C. to 550° C.; at least one second step of deposition, at the surface of the catalyst, of one or more additive(s) of formula (I):
摘要翻译：本发明的主题是一种催化剂的再生方法，该催化剂包含至少一种来自第VIII族的金属和至少一种沉积在难熔氧化物载体上的VIB族金属，包括：至少一个第一步骤在氧气存在下，在350℃至550℃的温度范围内对催化剂进行热处理。在催化剂的表面上沉积一种或多种式（I）的添加剂的至少一个第二步骤：

3. 发明授权

US08088705B2 Process for sulfurization or presulfurization of solid particles of a catalyst or an adsorbent 有权
标题翻译：催化剂或吸附剂的固体颗粒的硫化或预硫化方法
公开(公告)号：US08088705B2
公开(公告)日：2012-01-03
申请号：US12117805
申请日：2008-05-09
申请人： Pierre Dufresne , Franck Labruyere , Maxime Meens , Loredana Romano
发明人： Pierre Dufresne , Franck Labruyere , Maxime Meens , Loredana Romano
IPC分类号： F26B19/00
CPC分类号： B01J8/16 , B01J8/1809 , B01J8/1818 , B01J8/1836 , B01J8/40 , B01J23/72 , B01J23/882 , B01J27/043 , B01J27/047 , B01J27/0515 , B01J37/20 , B01J2208/00017 , B01J2208/00061 , B01J2208/00212 , B01J2208/00371 , B01J2208/00407 , B01J2208/00415 , B01J2208/0053 , B01J2219/1944 , C10G45/04 , C10G2300/207 , Y10S502/514
摘要： The invention relates to a process for incorporating sulfur in the porosity of the solid particles of a catalyst for the conversion of hydrocarbons or an adsorbent. This process is carried out off-site in the presence of hydrogen sulfide that is pure or diluted in hydrogen or nitrogen, a process in which said particles are made to rise or fall in a sulfur incorporation zone that comprises at least one vibratory helical coil that is essentially tubular in shape and that comprises at least two turns, whereby said particles are subjected to a temperature profile over the majority of their path in said coil and whereby said particles are brought into contact with at least one fluid on at least one portion of their path.
摘要翻译：本发明涉及在用于转化烃或吸附剂的催化剂的固体颗粒的孔隙中掺入硫的方法。这种方法是在氢气或氮气中纯化或稀释的硫化氢存在下进行的，所述硫化氢在硫掺入区中上升或下降，其中包含至少一个振动螺旋线圈，基本上是管状的并且包括至少两匝，由此所述颗粒在所述线圈中的大部分路径上经受温度分布，并且由此使所述颗粒在至少一个部分上与至少一个流体接触他们的路径

4. 发明授权

US07713905B2 Off-site treatment for hydrogenation catalysts 有权
标题翻译：氢化催化剂的现场处理
公开(公告)号：US07713905B2
公开(公告)日：2010-05-11
申请号：US10554873
申请日：2004-04-28
申请人： Pierre Dufresne , Franck Labruyere , François Locatelli
发明人： Pierre Dufresne , Franck Labruyere , François Locatelli
IPC分类号： B01J27/02 , B01J27/043 , B01J27/045
CPC分类号： C10G49/02 , B01J37/14 , B01J37/20 , C10G49/04 , C10G2300/705
摘要： The present invention concerns a process for “ex situ” treatment of a hydrogenation catalyst containing nickel prior to use, consisting of carrying out three steps, namely bringing the catalyst into contact with at least one sulphur-containing compound or agent (the step termed selectivation), treating said catalyst with hydrogen at a temperature of more than 250° C. (the step termed reduction) and passivation of said catalyst.
摘要翻译：本发明涉及一种在使用前对含镍的氢化催化剂进行“非原位”处理的方法，包括进行三个步骤，即使催化剂与至少一种含硫化合物或试剂接触（称为选择性的步骤），在大于250℃的温度（所述还原步骤）和所述催化剂的钝化下用氢气处理所述催化剂。

5. 发明申请

US20060154813A1 Oxidizing heat treatment passivation of sulphide hydrotreatment catalyst 有权
公开(公告)号：US20060154813A1
公开(公告)日：2006-07-13
申请号：US10529378
申请日：2003-09-25
申请人： Pierre Dufresne , Franck Labruyere
发明人： Pierre Dufresne , Franck Labruyere
IPC分类号： B01J38/12 , B01J27/02
CPC分类号： B01J37/20 , B01J23/882 , B01J33/00 , B01J37/14 , C10G49/02 , C10G2300/705
摘要： This invention relates to a process of ex-situ oxidizing passivation of catalysts for hydroconversion of hydrocarbons and especially of hydrotreating, in their sulfide state, process in which the sulfurized catalyst is brought into contact with an oxidizing gas flow that can be dry or wet, during heat treatment at more than 50° C. This invention, for passivation of sulfide phases, can be equally well implemented for a process that takes place in a fixed bed or a fluidized bed, for example a moving bed.

6. 发明授权

US06753291B2 Process for sulfiding an additive-containing catalyst 有权
标题翻译：用于硫化含添加剂的催化剂的方法
公开(公告)号：US06753291B2
公开(公告)日：2004-06-22
申请号：US09829638
申请日：2001-04-10
申请人： Sonja Eijsbouts , Frans Lodewijk Plantenga , Pierre Dufresne , Franck Labruyere , Leendert Arie Gerritsen
发明人： Sonja Eijsbouts , Frans Lodewijk Plantenga , Pierre Dufresne , Franck Labruyere , Leendert Arie Gerritsen
IPC分类号： B01J2702
CPC分类号： B01J31/0254 , B01J23/85 , B01J27/188 , B01J31/0202 , B01J31/0205 , B01J31/0218 , B01J31/0237 , B01J37/20 , C10G45/08 , C10G2300/705
摘要： The present invention pertains to a process for sulfiding a catalyst composition comprising at least one hydrogenation metal component of Group VI and/or Group VIII of the Periodic Table, and an organic additive wherein the catalyst composition is first contacted with an organic liquid, followed by the catalyst being contacted with hydrogen and a sulfur-containing compound in the gaseous phase, wherein less than about 40%, preferably less than about 35%, more preferably less than about 25%, most preferably less than about 15%, of the sulfur present in the sulfided catalyst is added with the organic liquid. The process of the present invention makes it possible to use additive-containing catalysts without loss of activity in units which cannot effect gas phase start-up or are required to carry out a pressure test. The organic liquid may be a hydrocarbon with a boiling range of about 150-500° C., preferably gasoline, white spirit, diesel, gas oil, mineral lube oil, or white oil. The step of contacting the catalyst with hydrogen and a sulfur-containing compound may take place in one step at a temperature of about 150-450° C. It may also take place in two steps, with the first step being performed at a temperature which is lower than that of the second step, with the first step being carried out at a temperature of about 100-250° C. and the second step at a temperature of about 150-450° C.
摘要翻译：本发明涉及一种硫化催化剂组合物的方法，该催化剂组合物包含至少一种元素周期表第VI族和/或第Ⅷ族氢化金属组分和一种有机添加剂，其中催化剂组合物首先与有机液体接触，催化剂在气相中与氢气和含硫化合物接触，其中少于约40％，优选小于约35％，更优选小于约25％，最优选小于约15％的硫存在于硫化催化剂中的有机液体中加入。本发明的方法使得可以在不能实现气相启动或需要进行压力试验的单位中使用不含活性的添加剂的催化剂。有机液体可以是沸点为约150-500℃的烃，优选汽油，白酒，柴油，瓦斯油，矿物润滑油或白油。使催化剂与氢气和含硫化合物接触的步骤可以在约150-450℃的温度下在一个步骤中进行。它也可以在两个步骤中进行，第一步是在低于第二步骤，第一步骤在约100-250℃的温度下进行，第二步在约150-450℃的温度下进行。

7. 发明授权

US5854162A Offsite regeneration process for a catalyst containing at least one precious metal 失效
标题翻译：含有至少一种贵金属的催化剂的非现场再生方法
公开(公告)号：US5854162A
公开(公告)日：1998-12-29
申请号：US949683
申请日：1997-10-14
申请人： Pierre Dufresne , Nilanjan Brahma
发明人： Pierre Dufresne , Nilanjan Brahma
IPC分类号： B01J23/90 , B01J23/40 , B01J23/96 , B01J38/02 , B01J38/12 , B01J38/44 , C10G35/06 , C10G35/085 , B01J20/34 , B01J38/18 , B01J38/22
CPC分类号： B01J23/96 , B01J38/44 , C10G35/085
摘要： The invention concerns a process for the regeneration of a used hydrocarbon treatment catalyst, preferably a reforming catalyst, containing at least one precious metal preferably platinum, optionally at least one additional metal selected from the group formed by metals from groups 7, 8, 9, 10, 13 and 14 of the periodic classification of the elements and copper, optionally and preferably at least one halogen, preferably chlorine, and at least one porous support, preferably alumina, said process comprising at least one of the following two successive steps: at least one step (1) for the combustion of the coke present on said catalyst, carried out in the presence of an oxygen-containing gas, at a temperature in the range of 300.degree. C. to 680.degree. C. for a time in the range 0.3 to 7 hours, at least one step (2) for oxyhalogenation, preferably oxychlorination, carried out in a controlled air atmosphere, at a temperature in the range 350.degree. C. to 550.degree. C., for a time in the range 0.3 to 3 hours and in the presence of a halogenated compound, wherein said process is carried out offsite, and in that a moving bed furnace is used for combustion step (1) and for oxyhalogenation step (2).
摘要翻译：本发明涉及一种用于再生含有至少一种贵金属，优选铂，或任选至少一种另外的金属的二烃类处理催化剂，优选重整催化剂的方法，所述另外的金属选自组7,8,9，元素和铜的任选和优选至少一种卤素，优选氯，和至少一种多孔载体，优选氧化铝的周期性分类的10,13和14，所述方法包括以下两个连续步骤中的至少一个：在在含氧气体的存在下，在300℃至680℃的温度范围内，存在于所述催化剂上的焦炭燃烧的至少一个步骤（1）一段时间范围为0.3〜7小时，在受控空气气氛中，在350℃〜550℃的温度范围内进行卤代卤化，优选氧氯化的至少一个步骤（2），时间范围为0.3 到3 小时，并且在卤代化合物的存在下，其中所述方法在异地进行，并且移动床炉用于燃烧步骤（1）和用于卤代卤化步骤（2）。

8. 发明授权

US5306860A Method of hydroisomerizing paraffins emanating from the Fischer-Tropsch process using catalysts based on H-Y zeolite 失效
标题翻译：使用基于H-Y沸石的催化剂从费 - 托方法发出的烷烃加氢异构化方法
公开(公告)号：US5306860A
公开(公告)日：1994-04-26
申请号：US886224
申请日：1992-05-21
申请人： Pierre-Henri Bigeard , Alain Billon , Pierre Dufresne , Samuel Mignard
发明人： Pierre-Henri Bigeard , Alain Billon , Pierre Dufresne , Samuel Mignard
IPC分类号： C10G65/04 , C07C5/13 , C07C5/22
CPC分类号： C10G65/043 , Y10S208/95 , Y10S585/946
摘要： For Hydroisomerizering charges emanating from the Fischer-Tropsch process:a) hydrogen is reacted with the charge in contact with a catalyst 1 in a first reaction zone, the catalyst 1 comprising at least one alumina-based matrix and at least one hydro-dehydrogenation component andb) the effluent from the first reaction zone is put into contact with a catalyst 2 in a second reaction zone, the catalyst 2 comprising:20 to 97% by weight of at least one matrix,3 to 80% by weight of at least one Y zeolite in hydrogen form, the zeolite being characterized by an SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of over 4.5; a sodium content of less than 1% by weight determined at 1100.degree. C. under calcining conditions; an a.sub.o crystal parameter of the elemental mesh of less than 24.70.times.10.sup.-10 m; and a specific surface area determined by the BET method of over 400 m.sup.2.g.sup.-1, andat least one hydro-dehydrogenation component.
摘要翻译：对于从费 - 托方法产生的加氢异构化电荷：a）氢与在第一反应区中与催化剂1接触的电荷反应，催化剂1包含至少一种基于氧化铝的基体和至少一个氢脱氢组分和b）来自第一反应区的流出物与第二反应区中的催化剂2接触，催化剂2包含：至少一种基质20至97重量％，至少3至80重量％一种Y型沸石为氢形式，沸石的特征在于SiO 2 / Al 2 O 3摩尔比超过4.5; 在1100℃下在煅烧条件下测定的钠含量小于1重量％元素网的ao晶体参数小于24.70×10-10 m; 并且通过BET法测定的比表面积超过400m 2·g -1，和至少一种加氢脱氢组分。

9. 发明授权

US4766099A Catalyst for oil hydrorefining or mild hydrocracking of heavy oil charges to produce middle distillates 失效
标题翻译：用于油加氢精制或轻度加氢裂化重油装料以生产中间馏分的催化剂
公开(公告)号：US4766099A
公开(公告)日：1988-08-23
申请号：US860927
申请日：1986-05-08
申请人： Pierre Dufresne , Christian Marcilly
发明人： Pierre Dufresne , Christian Marcilly
IPC分类号： C10G47/12 , B01J21/16 , B01J27/128 , B01J27/132 , B01J29/04 , C10G49/02
CPC分类号： B01J29/049 , B01J21/16 , C10G49/02 , B01J2229/42
摘要： The invention concerns a catalyst comprising:(a) a carrier containing at least 20% by weight of a fluorinated bridged clay of the smectite group,(b) an amorphous matrix containing at least 10% by weight of alumina, and(c) at least one group VIII metal or metal compound or an association of at least one group VI B metal or metal compound with at least one metal or compound of a metal selected from group VIII non-noble metal. The metals amount, calculated as oxide(s), in proportion to the final catalyst weight, is from 0.01 to 5% for the group VIII noble metals, from 0.01 to 20% for group VIII non-noble metals and from 5 to 40% for the association of group VI B metals with group VII non-noble metals.The carrier amount is such that the florinated bridged clay content of the final catalyst is at least 12% by weight; the matrix amount forms the complement to 100% by weight of the catalyst.The catalysts according to the invention can be used for mild hydrocracking operations having as an object improving the viscosity of the lubricating oils and hydrocracking of heavy oil cuts so as to obtain middle distillates: kerosene and gas oils
摘要翻译：本发明涉及一种催化剂，其包含：（a）载体，其含有至少20重量％的蒙皂石基团的氟化桥接粘土，（b）含有至少10重量％氧化铝的无定形基质，和（c）至少一种VIII族金属或金属化合物或至少一种VIB族金属或金属化合物与至少一种选自第VIII族非贵金属的金属或化合物的缔合。与最终催化剂重量成比例的氧化物计算的金属量，对于VIII族贵金属为0.01〜5％，对于VIII族非贵金属为0.01〜20％，为5〜40％第VIB族金属与第VII族非贵金属的结合。载体量使得最终催化剂的桥连粘土含量至少为12重量％基质量与催化剂的100重量％形成补体。根据本发明的催化剂可用于温和的加氢裂化操作，其作为改善润滑油的粘度和重油馏分的加氢裂化的目的，以获得中间馏分：煤油和瓦斯油

10. 发明授权

US4738941A Hydrocracking catalyst for the production of middle distillates 失效
标题翻译：用于生产中间馏分的加氢裂化催化剂
公开(公告)号：US4738941A
公开(公告)日：1988-04-19
申请号：US041946
申请日：1987-04-24
申请人： Pierre Dufresne , Christian Marcilly
发明人： Pierre Dufresne , Christian Marcilly
IPC分类号： C10G47/18 , B01J29/06 , B01J29/10 , C10G47/16
CPC分类号： B01J29/106 , C10G47/16
摘要： The invention relates to a new hydrocarbon hydroconversion catalyst, which is a mixture of an amorphous matrix, a zeolite and at least one metal of Group VIII and optionally of Group VI, the zeolite having a SiO.sub.2 /Al.sub.2 O.sub.3 molar ratio of about between 8 and 70, a sodium content of less than 0.15% by weight, a unit mesh parameter a.sub..degree. of between 24.55 and 24.24.times.10.sup.-10 m, a sodium ion recovery capacity C.sub.Na, expressed in grams of sodium per 100 grams of modified zeolite, greater than 0.85, a specific surface area greater than 400 m.sup.2 g.sup.-1, a water vapor adsorption capacity at 25.degree. C. (with a P/Po ratio of 0.10) greater than 6% by weight, a pore distribution between 1 and 20% of the pore volume contained essentially in pores of diameters between 20 and 80.times.10.sup.-10m, the remaining pore volume being contained essentially in pores of diameters less than 20.times.10.sup.-10 m, the matrix being characterized by the following textural properties:S.gtoreq.100 m.sup.2.g.sup.-1Vpt.gtoreq.0.4 cm.sup.3.g.sup.-1V.sub.75 .gtoreq.0.25 cm.sup.3.g.sup.-1V.sub.75 /Vpt.gtoreq.0.5.
摘要翻译：本发明涉及一种新的烃加氢转化催化剂，其是无定形基体，沸石和至少一种第VIII族金属和任选的第VI族的混合物，SiO 2 / Al 2 O 3摩尔比约为8至70的沸石，钠含量小于0.15重量％，单位网格参数a DEG在24.55和24.24x10-10微米之间，钠离子回收能力CNa以每克克改变的沸石表示的钠，大于0.85 ，比表面积大于400m2g-1，25℃下的水蒸汽吸附容量（P / Po比为0.10）大于6重量％，孔隙分布在孔的1〜20％体积基本上包含在20至80×10 -10 m之间的直径的孔中，剩余的孔体积基本上包含在小于20×10 -10 m的直径的孔中，该基质的特征在于以下织构性质：S> = 100m 2·g -1 Vpt> / = 0.4 cm3.g-1 V75> / = 0.25 cm3.g-1 V75 / Vpt> / = 0.5。

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