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    • 4. 发明授权
    • Method for preparing a nano-calcium carbonate slurry from waste gypsum as calcium source, the product and use thereof
    • 从废石膏作为钙源制备纳米碳酸钙浆料的方法,产品及其用途
    • US08846562B2
    • 2014-09-30
    • US13871245
    • 2013-04-26
    • Sufang WuPeiqiang Lan
    • Sufang WuPeiqiang Lan
    • B01J21/18B01J27/232B01J20/30C22B26/20
    • C22B26/20B01J20/041B01J20/3078B01J27/232B01J2220/4806B01J2220/4875C01F11/18C01P2002/88C01P2004/64
    • The present invention discloses a process for producing a nano calcium carbonate slurry from a feedstock of waste gypsum, wherein: an aqueous gypsum slurry of the feedstock is mixed with ammonia water by stirring; with CO2 injected in the slurry is under continuous stirring until the calcium sulfate in the waste gypsum is completely carbonated into nano calcium carbonate; after filtration, the filter cake is dispersed in water to obtain the nano calcium carbonate slurry. This process is easy to operate and to obtain a low-cost and a lower decomposition temperature of calcium carbonate. The present invention also discloses a nano calcium carbonate slurry and its application in preparation of a CaO-based carbon dioxide adsorbent and complex catalyst used for a reactive sorption enhanced reforming process for hydrogen production from methane. The CaO-based carbon dioxide adsorbent prepared shows good cycle stability and fast sorption rate, and complex catalyst used for reactive sorption enhanced methane steam reforming can obtain the hydrogen with purity of more than 90%.
    • 本发明公开了一种由废石膏原料生产纳米碳酸钙浆料的方法,其中:通过搅拌将原料的水性石膏浆料与氨水混合; 在浆料中注入的二氧化碳在连续搅拌下直到废石膏中的硫酸钙完全碳酸化成纳米碳酸钙; 过滤后,将滤饼分散在水中,得到纳米碳酸钙浆料。 该方法易于操作并获得碳酸钙的低成本和低分解温度。 本发明还公开了一种纳米碳酸钙浆料及其在制备用于从甲烷制氢的反应性吸附增强重整方法中的CaO基二氧化碳吸附剂和复合催化剂的应用。 制备的CaO型二氧化碳吸附剂显示良好的循环稳定性和快速吸附速率,用于反应性吸附增强甲烷蒸汽重整的复合催化剂可以获得纯度高于90%的氢。