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    • 2. 发明授权
    • Composite graphite particles and lithium rechargeable battery using the same
    • 复合石墨颗粒和锂可充电电池使用相同
    • US08999580B2
    • 2015-04-07
    • US12097001
    • 2006-12-20
    • Chiaki SotowaMasataka Takeuchi
    • Chiaki SotowaMasataka Takeuchi
    • H01M4/13H01M4/58H01M10/0525H01M4/133H01M4/587H01M10/0569H01M4/02
    • H01M10/0525H01M4/133H01M4/587H01M10/0569H01M2004/021Y02E60/122Y02P70/54Y02T10/7011Y10T428/2991
    • The invention provides composite graphite particles, comprising a core material consisting of graphite having a interlayer distance d(002) of 0.337 nm or less and a surface layer consisting of graphite in which the intensity ratio ID/IG (R value) between the peak intensities (ID) in a range of 1300 to 1400 cm−1 and ( IG) in a range of 1580 to 1620 cm−1 as measured by Raman scattering spectroscopy is 0.3 or higher, wherein the peak intensity ratio I110/I004 between the peak intensities (I110)of face (110) and (I004)of face (004) obtained by XRD measurement on the graphite crystal is 0.15 or higher when the graphite has been mixed with a binder and pressure-molded to a density of 1.55 to 1.65 g/cm3, which composite graphite particles are useful in a secondary battery negative electrode having a high capacity, high charge/discharge characteristics and an excellent charging property, and also provides a paste for negative electrode, a negative electrode and a lithium secondary battery using the composite graphite.
    • 本发明提供复合石墨颗粒,其包含由石墨构成的芯材,其中层间距离d(002)为0.337nm或更小,以及由石墨组成的表面层,其中峰强度之间的强度比ID / IG(R值) 通过拉曼散射光谱法测定的范围为1300〜1400cm -1的范围((IG))为1580〜1620cm -1的范围(IG)为0.3以上,峰强度之间的峰强度比I110 / I004 当将石墨与粘合剂混合并加压成型为1.55至1.65克的密度时,在石墨晶体上通过XRD测量获得的面(004)的面(110)和(I004)的(I110)为0.15以上 / cm3,该复合石墨颗粒可用于具有高容量,高充电/放电特性和优异的充电特性的二次电池负极中,并且还提供负极,负极和锂二次电池用糊料 使用复合石墨。