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    • 4. 发明授权
    • Surface treatment method for making high durability universal titanium dioxide rutile pigment
    • 表面处理方法制造高耐久性通用二氧化钛金红石颜料
    • US09505022B2
    • 2016-11-29
    • US13693667
    • 2012-12-04
    • The National Titanium Dioxide Co. Ltd. (CRISTAL)
    • Ahmed Yasir VakayilAhmad I. Jomha
    • B05D5/12B05D1/18C09C1/36C09D7/12
    • B05D1/18C01P2002/80C01P2002/84C09C1/3661C09D7/62
    • A method is provided for the wet surface treatment of titanium dioxide, in order to produce durable universal grade titanium dioxide rutile pigment with superior optical properties. The method is characterized in that, a hydrous zirconia and silica composite layer is co-precipitated at acidic pH. Then, a layer of alumina is precipitated under a range of pH required for complete precipitation above the initial composite layer. The upper pH limit of the slurry during the alumina precipitation can be well controlled to avoid any chance for dissolution or damage of the composite zirconia-silica layer formed. Zirconia-silica composite layers and alumina thus precipitated advantageously improve the competence of the layers formed over a TiO2 base and provide improved durability with superior optical performance. The total surface treatment cycle time and chemicals used are minimal compared to conventional methods. Improvements in throughput and washing efficiency are also realized.
    • 提供了一种用于二氧化钛的湿表面处理的方法,以便产生具有优异光学性能的耐久的通用级二氧化钛金红石颜料。 该方法的特征在于,水合氧化锆和二氧化硅复合层在酸性pH下共沉淀。 然后,在初始复合层之上的完全沉淀所需的pH范围内沉淀出一层氧化铝。 氧化铝沉淀期间浆料的上限pH值可以很好地控制,以避免形成的复合氧化锆 - 二氧化硅层的任何溶解或损坏的机会。 氧化锆 - 二氧化硅复合层和由此沉淀的氧化铝有利地提高了形成在TiO 2基体上的层的能力,并提供了优异的光学性能的改善的耐久性。 与常规方法相比,总的表面处理循环时间和所用的化学品是最小的。 吞吐量和洗涤效率的提高也得以实现。