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    • 1. 发明申请
    • SCRATCH COLOR-DEVELOPABLE INK AND INVISIBLE INFORMATION PRINTED SHEET
    • 切割颜色可见的墨水和不可见的信息印刷表
    • US20100021702A1
    • 2010-01-28
    • US12448163
    • 2007-12-19
    • Hisashi WakasugiFujio TakasakiKazuhiro HandaMasahiro MiyauchiHaruhiko Ikeda
    • Hisashi WakasugiFujio TakasakiKazuhiro HandaMasahiro MiyauchiHaruhiko Ikeda
    • B32B3/10C09D11/02
    • B41M5/136B41M5/145C09D11/037C09D11/50Y10T428/24802
    • Disclosed are a scratch color-developable ink comprising an electron-donating colorless or light-color dye precursor, an electron-accepting color developer and a varnish, wherein a solid particle component contained therein has an average particle diameter of 0.3 to 25 μm, a scratch color-developable ink comprising an electron-donating colorless or light-color dye precursor, an electron-accepting color developer and a varnish, wherein an azaphthalide compound is contained as the electron-donating colorless or light-color dye precursor, and an invisible information printed sheet obtained by printing invisible information on a support with the above scratch color-developable ink.The above scratch color-developable ink makes invisible information visible easily by scratching with a finger nail although the color of an invisible information printed portion is hard to develop by frictional contact during usual handling, gives a high developed color intensity and is free from the occurrence of dust during the visualization of invisible information.
    • 公开了包含给电子的无色或浅色染料前体,电子接受显色剂和清漆的刮痕显色油墨,其中包含的固体颗粒组分的平均粒径为0.3-25微米, 包含给电子的无色或浅色染料前体,电子接受显色剂和清漆的刮刮显色油墨,其中包含氮化萘化合物作为给电子的无色或浅色染料前体,并且不可见 通过使用上述划痕彩色显影油墨在支撑体上印刷不可见信息而获得的信息印刷纸。 上述刮擦性显影墨水通过用手指指尖轻易地看不见信息,尽管在通常的操作过程中,不可见的信息印刷部分的颜色通过摩擦接触难以发展,给出高度显色的颜色强度并且没有发生 在看不见的信息的可视化中的灰尘。
    • 3. 发明授权
    • Heat-sensitive recording sheet
    • 热敏记录纸
    • US4617582A
    • 1986-10-14
    • US622246
    • 1984-06-19
    • Masahiro MiyauchiMasahiro Higuchi
    • Masahiro MiyauchiMasahiro Higuchi
    • B41M5/337B41M5/18
    • B41M5/3375
    • In a heat-sensitive recording sheet having a heat-sensitive coating layer comprising a colorless to light-colored dye precursor as color former and a color developer which causes said dye precursor to develop a color by reacting with said dye precursor when heated, the color development sensitivity of said sheet, particularly at low temperatures, is enhanced by using benzyl p-hydroxybenzoate as said color developer and allowing said heat-sensitive coating layer to further comprise a terephthalic acid ester having a melting point of 60.degree. C. or higher and a fatty acid amide or derivative thereof having a melting point of 60.degree. C. or higher.
    • 在具有包含作为成色剂的无色至浅色染料前体的热敏性涂层的热敏记录片和通过加热时使所述染料前体与所述染料前体反应而形成颜色的显色剂,所述颜色 通过使用对羟基苯甲酸苄酯作为所述彩色显影剂,使所述热敏涂层进一步包含熔点为60℃以上的对苯二甲酸酯,并且 具有熔点为60℃以上的脂肪酸酰胺或其衍生物。
    • 4. 发明授权
    • Heat-sensitive recording sheet
    • 热敏记录纸
    • US4614956A
    • 1986-09-30
    • US741905
    • 1985-06-06
    • Masahiro Miyauchi
    • Masahiro Miyauchi
    • B41M5/42B41M5/18
    • B41M5/423
    • In a heat-sensitive recording sheet comprising (1) a substrate, (2) a heat-sensitive color-developing layer provided on said substrate, composed essentially of a colorless or light-colored dye precursor and a color developer capable of allowing said dye precursor to develop a color by reacting with the dye precursor when heated and, as necessary, (3) an overcoat layer provided on said heat-sensitive color-developing layer, improvements in printability, storability, etc. can be obtained by allowing the heat-sensitive color-developing layer and/or the overcoat layer to contain a boric acid ester.
    • 在包括(1)基底的热敏记录片材中,(2)设置在所述基底上的基本上由无色或浅色染料前体组成的热敏显色层和能够使所述染料 通过加热时与染料前体反应形成颜色的前体,根据需要,(3)设置在所述热敏显色层上的外涂层,可以通过使热量可以获得改善印刷性,保存性等 敏感色显影层和/或外涂层含有硼酸酯。
    • 6. 发明授权
    • Method for specifically detecting analyte using photocurrent, and electrode, measuring cell and measuring device for use therein
    • 使用光电流专门检测分析物的方法,以及用于其中的电极,测量元件和测量装置
    • US08092670B2
    • 2012-01-10
    • US11992858
    • 2006-09-28
    • Makoto BekkiHitoshi OharaShuji SonezakiKoki KanehiraYumi OgamiHiroshi IshikawaYumi OsakiHiromasa TokudomeYoko YamadaMasahiro Miyauchi
    • Makoto BekkiHitoshi OharaShuji SonezakiKoki KanehiraYumi OgamiHiroshi IshikawaYumi OsakiHiromasa TokudomeYoko YamadaMasahiro Miyauchi
    • G01N27/26G01N33/48G01N33/487G01N33/49G01N33/493G01N33/50G01N33/53G01N33/533
    • G01N33/5438
    • A method, an electrode, a measuring cell, and a measuring device are disclosed which can detect and quantitatively determine an analyte having specific bonding properties, in a highly sensitive, simple and accurate manner using photocurrent. This method comprises contacting a working electrode and a counter electrode with an electrolyte medium, wherein the working electrode has an analyte immobilized thereon through a probe substance and wherein the analyte is bonded to a sensitizing dye; irradiating the working electrode with light to photoexcite the sensitizing dye; and detecting photocurrent flowing between the working electrode and the counter electrode, wherein the photocurrent is generated by transfer of electrons from the photoexcited sensitizing dye to the working electrode. The working electrode comprises an electron accepting layer comprising an electron accepting substance capable of accepting electrons released from the sensitizing dye in response to photoexcitation, wherein the probe substance is supported on a surface of the electron accepting layer. The electron accepting substance is an oxide semiconductor having an energy level lower than that of a lowest unoccupied molecular orbit (LUMO) of the sensitizing dye. The electrolyte medium comprises an electrolyte and at least one solvent selected from an aprotic solvent and a protic solvent, wherein the electrolyte comprises a salt capable of providing an oxidized sensitizing dye with electrons.
    • 公开了一种方法,电极,测量单元和测量装置,其可以使用光电流以高灵敏度,简单和准确的方式检测和定量地确定具有特定粘合特性的分析物。 该方法包括使工作电极和对电极与电解质介质接触,其中工作电极通过探针物质固定在其上的分析物,并且其中分析物与致敏染料结合; 用光照射工作电极对光敏染料进行光刺激; 并且检测在工作电极和对电极之间流动的光电流,其中通过将电子从光激发敏化染料转移到工作电极而产生光电流。 工作电极包括电子接受层,其包含能够响应于光激发而接受从感光染料释放的电子的电子接受物质,其中探针物质被负载在电子接受层的表面上。 电子接受物质是具有比敏化染料的最低未占据分子轨道(LUMO)的能级更低的氧化物半导体。 电解质介质包括电解质和至少一种选自非质子溶剂和质子溶剂的溶剂,其中电解质包含能够提供氧化的致敏染料与电子的盐。
    • 7. 发明申请
    • Method for Specifically Detecting Analyte Using Photocurrent, and Electrode, Measuring Cell and Measuring Device for Use Therein
    • 使用光电流特异性检测分析物的方法,电极,测量单元及其使用的测量装置
    • US20090294305A1
    • 2009-12-03
    • US11992858
    • 2006-09-28
    • Makoto BekkiHitoshi OharaShuji SonezakiKoki KanehiraYumi OgamiHiroshi IshikawaYumi OsakiHiromasa TokudomeYoko YamadaMasahiro Miyauchi
    • Makoto BekkiHitoshi OharaShuji SonezakiKoki KanehiraYumi OgamiHiroshi IshikawaYumi OsakiHiromasa TokudomeYoko YamadaMasahiro Miyauchi
    • G01N27/26G01F1/64
    • G01N33/5438
    • A method, an electrode, a measuring cell, and a measuring device are disclosed which can detect and quantitatively determine an analyte having specific bonding properties, in a highly sensitive, simple and accurate manner using photocurrent. This method comprises contacting a working electrode and a counter electrode with an electrolyte medium, wherein the working electrode has an analyte immobilized thereon through a probe substance and wherein the analyte is bonded to a sensitizing dye; irradiating the working electrode with light to photoexcite the sensitizing dye; and detecting photocurrent flowing between the working electrode and the counter electrode, wherein the photocurrent is generated by transfer of electrons from the photoexcited sensitizing dye to the working electrode. The working electrode comprises an electron accepting layer comprising an electron accepting substance capable of accepting electrons released from the sensitizing dye in response to photoexcitation, wherein the probe substance is supported on a surface of the electron accepting layer. The electron accepting substance is an oxide semiconductor having an energy level lower than that of a lowest unoccupied molecular orbit (LUMO) of the sensitizing dye. The electrolyte medium comprises an electrolyte and at least one solvent selected from an aprotic solvent and a protic solvent, wherein the electrolyte comprises a salt capable of providing an oxidized sensitizing dye with electrons.
    • 公开了一种方法,电极,测量单元和测量装置,其可以使用光电流以高灵敏度,简单和准确的方式检测和定量地确定具有特定粘合特性的分析物。 该方法包括使工作电极和对电极与电解质介质接触,其中工作电极通过探针物质固定在其上的分析物,并且其中分析物与致敏染料结合; 用光照射工作电极对光敏染料进行光刺激; 并且检测在工作电极和对电极之间流动的光电流,其中通过将电子从光激发敏化染料转移到工作电极而产生光电流。 工作电极包括电子接受层,其包含能够响应于光激发而从感光染料中释放的电子的受电子物质,其中探针物质被负载在电子接受层的表面上。 电子接受物质是具有比敏化染料的最低未占据分子轨道(LUMO)的能级更低的氧化物半导体。 电解质介质包括电解质和至少一种选自非质子溶剂和质子溶剂的溶剂,其中电解质包含能够提供氧化的致敏染料与电子的盐。