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    • 7. 发明申请
    • SECONDARY BATTERY
    • US20230137208A1
    • 2023-05-04
    • US18090947
    • 2022-12-29
    • MURATA MANUFACTURING CO., LTD.
    • Takatoshi MUNAOKAShinichi KATAYAMAAtsushi OUKIMasaki KURATSUKATakashige FUJIKAWAYousuke SHIMA
    • H01M10/0569H01M4/525H01M4/485H01M10/0525
    • A secondary battery includes a positive electrode, a negative electrode, and an electrolytic solution. The positive electrode includes a lithium-nickel composite oxide. The negative electrode includes a lithium-titanium composite oxide. The electrolytic solution includes a carboxylic acid ester. The carboxylic acid ester includes at least one of ethyl acetate, propyl acetate, ethyl propionate, or propyl propionate. A first oxygen spectrum and a second oxygen spectrum are detectable by a surface analysis of the positive electrode by X-ray photoelectron spectroscopy. The first oxygen spectrum has a peak within a range of binding energy that is greater than or equal to 528 eV and less than or equal to 531 eV. The second oxygen spectrum has a peak within a range of binding energy that is greater than 531 eV and less than or equal to 535 eV. A ratio of an intensity of the first oxygen spectrum to an intensity of the second oxygen spectrum is greater than or equal to 0.30 and less than or equal to 0.80. A third oxygen spectrum and a fourth oxygen spectrum are detectable by a surface analysis of the negative electrode by the X-ray photoelectron spectroscopy. The third oxygen spectrum has a peak within a range of binding energy that is greater than or equal to 528 eV and less than or equal to 531 eV. The fourth oxygen spectrum has a peak within a range of binding energy that is greater than 531 eV and less than or equal to 535 eV. A ratio of an intensity of the third oxygen spectrum to an intensity of the fourth oxygen spectrum is greater than or equal to 0.82 and less than or equal to 1.35.
    • 10. 发明申请
    • METHOD FOR MANUFACTURING LITHIUM ION BATTERIES
    • US20230131454A1
    • 2023-04-27
    • US17907444
    • 2021-03-30
    • HFG
    • Fabien GABEN
    • H01M10/0525H01M10/058H01M50/403H01M4/04H01M50/491
    • A method for manufacturing a lithium ion battery with a capacitance greater than 1 mA h, including the deposition of at least one dense layer, which can be an anode and/or a cathode and/or an electrolyte, by a method of depositing a dense layer. The method includes: supplying a substrate and a suspension of non-agglomerated nanoparticles of a material P; depositing a layer on the substrate using the suspension; drying the layer thus obtained; densifying the dried layer by mechanical compression and/or heat treatment. The method of depositing being characterised in that the suspension of non-agglomerated nanoparticles of material P includes nanoparticles of material P having a size distribution, said size being characterised by the value of D50 thereof, such that: the distribution includes nanoparticles of material P of a first size D1 between 20 nm and 50 nm, and nanoparticles of material P of a second size D2 characterised by a value D50 at least five times less than that of D1, or the distribution has a mean size of nanoparticles of material P less than 50 nm, and a standard deviation to mean size ratio greater than 0.6.