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    • 2. 发明授权
    • Hydrous polyolefin resin composition, preexpanded particles produced therefrom, process for producing the same, and expanded molding
    • 含水聚烯烃树脂组合物,由其制备的预剥离颗粒,其制备方法和膨胀成型
    • US06596782B1
    • 2003-07-22
    • US09155544
    • 1998-09-25
    • Kenji MogamiTsuyoshi MihayashiKyoichi NakamuraNaruhiko Akamatsu
    • Kenji MogamiTsuyoshi MihayashiKyoichi NakamuraNaruhiko Akamatsu
    • C08J916
    • C08J9/18B29C44/3461C08J9/0061C08J2203/10C08J2323/02
    • A water-containing polyolefin resin composition containing a polyolefin resin and a hydrophilic polymer and having a water content of 1 to 50% by weight which is suitable for use in preparation of polyolefin resin pre-expanded particles, and pre-expanded particles of a polyolefin resin prepared by pre-expanding the water-containing polyolefin resin composition the particles having a an apparent expansion ratio of 5 to 60, a closed cell ratio of 80 to 100% and an average cell diameter of 50 to 500 &mgr;m. The pre-expanded particles can be prepared without using a volatile blowing agent by dispersing resin particles made of a polyolefin resin composition containing a polyolefin resin and a hydrophilic polymer into an aqueous dispersion medium in a closed vessel to form a dispersion, heating to a temperature not lower than the softening point of the polyolefin resin to produce water-containing resin particles having a water content of 1 to 50% by weight, and releasing the aqueous dispersion from the closed vessel into a lower pressure than the inner pressure of the closed vessel, thereby expanding the water-containing resin particles. When the releasing of the dispersion from the vessel is conducted after raising the inner pressure to 25 to 75 kg/cm2G by introducing nitrogen gas, air or an inorganic gas including them as a main component into the vessel, pre-expanded particles providing foams having good physical properties and a high expansion ratio are obtained.
    • 含有聚烯烃树脂和亲水性聚合物的水含量聚烯烃树脂组合物,其水含量为1-50重量%,其适用于制备聚烯烃树脂预发泡颗粒和聚烯烃预发泡颗粒 通过将含水聚烯烃树脂组合物的表观膨胀率为5〜60,闭孔率为80〜100%,平均泡孔直径为50〜500μm的颗粒预膨胀而制备的树脂。 可以通过将含有聚烯烃树脂和亲水性聚合物的聚烯烃树脂组合物制成的树脂颗粒分散在密闭容器中的水性分散介质中而不使用挥发性发泡剂来制备预发泡颗粒,以形成分散体,加热到温度 不低于聚烯烃树脂的软化点,以产生水含量为1至50重量%的含水树脂颗粒,并将水分散体从密闭容器中释放到比密封容器的内部压力低的压力 从而使含水树脂颗粒膨胀。 当通过将氮气,空气或其中包含它们的无机气体作为主要成分将内部压力升高到25至75kg / cm2G之后进行容器的分散时,预发泡颗粒提供具有 获得良好的物理性能和高膨胀率。
    • 3. 发明授权
    • Water-containing polypropylene resin composition and pre-expanded particles made thereof
    • 含水聚丙烯树脂组合物和由其制成的预发泡颗粒
    • US06214896B1
    • 2001-04-10
    • US09472183
    • 1999-12-27
    • Kenji MogamiYasumitsu MunakataKenichi Senda
    • Kenji MogamiYasumitsu MunakataKenichi Senda
    • C08J922
    • C08J9/0061C08J9/18C08J2201/03C08J2323/10C08J2400/14C08L23/0876C08L23/10C08L2666/04
    • There is provided a pre-expanded particle having a high expansion ratio and excellent flexibility and cushioning property. The in-mold articles made thereof do not lose mechanical strength, heat resistance, and water resistance, without conventional volatile organic foaming agents or carbon dioxide gas. A pre-expanded particle of a polypropylene resin is prepared by pre-expanding a water-containing propylene resin composition comprising (A) 100 parts by weight of a polypropylene resin having melt flow rate (230° C., 2.16 kg load) of 10 to 70 g/10 min and tensile elongation at break of at least 300%, (B) 0.05 to 10 parts by weight of a hydrophilic polymer and (C) 0 to 3 parts by weight of a filler and having a water content of 1 to 20% by weight under a water vapor pressure at the melting point of the polypropylene resin, said particle having an apparent expansion ratio of 25 to 70 times, a closed cell content of at least 85% and an average cell diameter of 50 to 500 &mgr;m.
    • 提供了具有高膨胀率和优异的柔性和缓冲性能的预发泡颗粒。 其制成的模内制品在没有常规挥发性有机发泡剂或二氧化碳气体的情况下不会失去机械强度,耐热性和耐水性。 通过预膨胀含水丙烯树脂组合物来制备聚丙烯树脂的预发泡颗粒,该组合物包含(A)100重量份熔体流动速率(230℃,2.16kg负载)的聚丙烯树脂为10 至70g / 10分钟,断裂时的拉伸伸长率至少为300%,(B)0.05〜10重量份的亲水性聚合物和(C)0-3重量份的填料,水含量为1 至20重量%,在聚丙烯树脂的熔点下的水蒸气压下,所述颗粒的表观膨胀率为25〜70倍,闭孔含量为85%以上,平均气泡直径为50〜500 妈妈
    • 8. 发明授权
    • Polyethylene terephthalate resin composition
    • 聚对苯二甲酸乙二醇酯树脂组合物
    • US5886088A
    • 1999-03-23
    • US772215
    • 1996-10-21
    • Kazuaki MatsumotoMasahiko MihoichiYouichi OharaKazushi HirobeKenji MogamiTadashi Koyama
    • Kazuaki MatsumotoMasahiko MihoichiYouichi OharaKazushi HirobeKenji MogamiTadashi Koyama
    • C08K3/34C08K5/1515C08K5/29C08K7/02C08L67/02
    • C08K7/02C08K3/34C08K5/1515C08K5/29C08L67/02B29C43/003C08L67/025
    • There are provided a polyethylene terephthalate resin composition in which to 100 parts by weight of a polyethylene terephthalate resin (A) polymerized by use of a germanium catalyst and having at least 80% of an ethylene terephthalate repetition unit, 0.05 to 30 parts by weight of a compound selected from the group consisting of an epoxy compound having at least two intramolecular epoxy groups without any intramolecular ester linkage and a carbodiimide compound (B) is formulated, and resin compositions in which a fibrous reinforcing material (C), a block copolymer (D) and an inorganic nucleating agent (E) are further formulated in the above mentioned composition. The resin composition of the present invention is excellent in moist heat resistance, fluidity and mechanical strength, and in addition, can be subjected to high cycle molding even in a mold of a low temperature to yield a molded article with improved surface characteristics.
    • PCT No.PCT / JP96 / 00382 Sec。 371日期1996年10月21日 102(e)日期1996年10月21日PCT 1996年2月21日PCT PCT。 出版物WO96 / 26245 日本特开1996年8月29日提供了一种聚对苯二甲酸乙二醇酯树脂组合物,其中向100重量份使用锗催化剂聚合并具有至少80%的对苯二甲酸乙二醇酯重复单元聚对苯二甲酸乙二醇酯树脂(A) 配制30重量份选自具有至少两个没有分子内酯键的分子内环氧基的环氧化合物和碳二亚胺化合物(B)的化合物,其中纤维增强材料(C) ,嵌段共聚物(D)和无机成核剂(E)进一步配制在上述组合物中。 本发明的树脂组合物的耐湿热性,流动性和机械强度优异,并且即使在低温模具中也可以进行高循环成型,得到表面特性改善的成型体。
    • 9. 发明申请
    • Automotive Luggage Box
    • 汽车行李箱
    • US20080302843A1
    • 2008-12-11
    • US11658366
    • 2005-06-30
    • Kenji Mogami
    • Kenji Mogami
    • B60R7/02
    • B60R5/04
    • The present invention provides an automotive luggage box that has sufficient lightness and rigidity and that is excellent in thermal insulating properties and surface appearance/hardness. More specifically, the present invention relates to an automotive luggage box that is a luggage box 1 installed on a luggage compartment floor inside an automobile. The luggage box 1 includes a bottom face portion 2, and an upright wall portion 3 that is integral therewith. Both the bottom face portion 2 and the upright wall portion 3 are made of an injection foam molded article of a thermoplastic resin, having a foam layer 9, and non-foam layers 10 and 11 that are formed on the surface of the foam layer 9.
    • 本发明提供一种具有足够的亮度和刚性并且绝热性能和表面外观/硬度优异的汽车行李箱。 更具体地,本发明涉及一种作为安装在汽车内的行李箱楼层上的行李箱1的汽车行李箱。 行李箱1包括底面部分2和与其成一体的直立壁部分3。 底面部2和直立壁部3均由热塑性树脂的注射成型体制成,具有泡沫层9,在泡沫层9的表面形成有非泡沫层10,11。 。
    • 10. 发明授权
    • Additive for thermpolastic resins and flame retardant resin composition
    • 热塑性树脂和阻燃树脂组合物的添加剂
    • US5684071A
    • 1997-11-04
    • US670141
    • 1996-06-27
    • Kenji MogamiMasaaki NakamuraTadashi KoyamaTomomi NakashimaAkiyoshi Somemiya
    • Kenji MogamiMasaaki NakamuraTadashi KoyamaTomomi NakashimaAkiyoshi Somemiya
    • C08K5/3492C08K9/10C08K5/34
    • C08K9/10C08K5/34928
    • An additive having an improved dispersibility or adhesion property to thermoplastic resins and useful for imparting an excellent flame resistance and other properties thereto without deteriorating properties that the thermoplastic resins originally possess, such as mechanical, electrical and thermal properties and molding processability, which comprises a nitrogen-containing heterocyclic compound or its salt surface-treated with 0.1 to 50% by weight of a compound having at least two functional groups such as epoxy resin, acid anhydride or the like; and a flame retardant polyester resin composition comprising (A) a thermoplastic polyester, (B) a nitrogen-containing heterocyclic compound or its salt, (C) a compound having at least two functional groups and optionally (D) a phosphorus based flame retarder, which may be prepared by adding the component (B) previously surface-treated with the component (C) or separately adding the components (B) and (C) to the polyester (A).
    • 具有改进的热塑性树脂的分散性或粘合性的添加剂,其用于赋予优异的阻燃性和其它性能,而不会降低热塑性树脂最初具有的性能,例如机械,电和热性能和成型加工性,其包括氮 含有0.1〜50重量%的具有至少两个官能团的化合物如环氧树脂,酸酐等进行表面处理的杂环化合物或其盐; 和(A)热塑性聚酯,(B)含氮杂环化合物或其盐的阻燃聚酯树脂组合物,(C)具有至少两个官能团的化合物和任选的(D)磷系阻燃剂, 其可以通过将预先用组分(C)进行表面处理的组分(B)或分别加入组分(B)和(C)加入到聚酯(A)中来制备。