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    • 9. 发明授权
    • Cyclical deposition of refractory metal silicon nitride
    • 难熔金属氮化硅的循环沉积
    • US07892602B2
    • 2011-02-22
    • US11422826
    • 2006-06-07
    • Hua ChungLing ChenBarry L. Chin
    • Hua ChungLing ChenBarry L. Chin
    • C23C16/34
    • C23C16/45531C23C16/34H01L21/28562H01L21/76843
    • Methods for depositing a metal silicon nitride layer on a substrate during an atomic layer deposition (ALD) process. The methods provide positioning a substrate within a process chamber containing a centralized expanding channel that conically tapers towards and substantially covers the substrate, flowing a process gas into the centralized expanding channel to form a circular flow pattern, exposing the substrate to the process gas having the circular flow pattern, and exposing the substrate sequentially to chemical precursors during an ALD process to form a metal silicon nitride material. In one example, the ALD process provides sequentially pulsing a metal precursor, a nitrogen precursor, and a silicon precursor into the process gas having the circular flow pattern. The metal silicon nitride material may contain tantalum or titanium. In other examples, the process gas or the substrate may be exposed to a plasma.
    • 在原子层沉积(ALD)工艺中在衬底上沉积金属氮化硅层的方法。 该方法提供了将处理室中的衬底定位在处理室内,该处理室包含集中的扩展通道,该通道朝向并基本上覆盖衬底呈锥形锥形,将工艺气体流入集中扩展通道以形成圆形流动图案,将衬底暴露于具有 圆形流动图案,并且在ALD工艺期间将衬底依次暴露于化学前体以形成金属氮化硅材料。 在一个实例中,ALD工艺顺序地将金属前体,氮前体和硅前体顺序地引入到具有圆形流动图案的工艺气体中。 金属氮化硅材料可以包含钽或钛。 在其它实例中,工艺气体或衬底可以暴露于等离子体。