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    • 1. 发明授权
    • Process for the recovery of absolute ethanol by vapor compression
extractive distillation
    • 通过蒸气压缩萃取蒸馏回收无水乙醇的方法
    • US5294304A
    • 1994-03-15
    • US29961
    • 1993-03-09
    • Yoshikazu KanoHirotoshi HorizoeTetsuya TanimotoItsuo Yamamoto
    • Yoshikazu KanoHirotoshi HorizoeTetsuya TanimotoItsuo Yamamoto
    • C07C29/84B01D3/40
    • C07C29/84Y02P20/124Y10S203/14
    • This invention relates to a process for the production of absolute alcohol from aqueous alcohol, whereby saving of energy to a greater extent is rendered possible in a more simple process, as compared with the prior art azeotropic distillation method using benzene or cyclohexane. That is, aqueous alcohol is subjected to extractive distillation in a first distillation column under such a condition that a liquid and gas of a solvent simultaneously coexist using low pressure propane, propylene and butane as the solvent, absolute alcohol substantially free from water is recovered from the bottom of the distillation column and subjected to stripping of hydrocarbons in a second distillation column, during which the gaseous phases of the first and second distillation columns are mixed and compressed, utilized through recompression as a heat source of a reboiler of the first distillation column, subjected to separation of water content and recycled to the upper parts of the first and second distillation columns. In accordance with the process, the energy required can largely be reduced.In Examples, the energy required for producing 1 kg of absolute alcohol is reduced to 1/5 to 1/10 of the prior art azeotropic distillation method, which shows the advantages of the present invention.According to the process of the present invention, installations such as compressors, heat exchangers, decanters, etc. can be omitted and the installation cost can be reduced by about 30%.
    • 本发明涉及一种从含水醇生产无水酒精的方法,与现有技术的使用苯或环己烷的共沸蒸馏方法相比,能够以更简单的方法将能量节省到更大程度。 也就是说,将含水醇在第一蒸馏塔中进行萃取蒸馏,其条件是使用低压丙烷,丙烯和丁烷作为溶剂同时共存的溶剂的液体和气体,基本上不含水的绝对醇从 蒸馏塔的底部并在第二蒸馏塔中进行烃的汽提,在此期间第一和第二蒸馏塔的气相被混合和压缩,通过再压缩作为第一蒸馏塔的再沸器的热源 经过水分离并再循环到第一和第二蒸馏塔的上部。 根据该过程,所需的能量可以大大降低。 在实施例中,生产1kg无水乙醇所需的能量降低到现有技术共沸蒸馏方法的1/5至1/10,这表明本发明的优点。 根据本发明的方法,可以省略诸如压缩机,热交换器,倾析器等的设备,并且可以将安装成本降低约30%。
    • 2. 发明授权
    • Heat and impact resistant thermoplastic resin composition
    • 耐热冲击热塑性树脂组合物
    • US4981906A
    • 1991-01-01
    • US199850
    • 1988-05-27
    • Hiromi TomonoItsuo YamamotoYuji AokiYuji Koyama
    • Hiromi TomonoItsuo YamamotoYuji AokiYuji Koyama
    • C08L25/00C08L51/04C08L73/00C08L77/00
    • C08L51/04C08L77/00Y10S525/942
    • A heat and impact resistant thermoplastic resin composition which comprises:100 parts by weight of a resin mixture comprising from 20 to 80% by weight of a polyamide resin (A) and from 20 to 80% by weight of a graft copolymer resin (B) obtained by graft polymerizing from 30 to 65 parts by weight of a monomer mixture comprising from 30 to 80% by weight of an aromatic vinyl monomer, from 5 to 65% by weight of an N-substituted maleimide monomer and from 0 to 40% by weight of other vinyl monomer copolymerizable with these monomers (provided that the total amount of said monomer mixture is 100% by weight) to from 35 to 70 parts by weight of a conjugated diene rubber;from 0 to 40 parts by weight of a copolymer resin (C) comprising from 30 to 80% by weight of an aromatic vinyl monomer component, from 5 to 65% by weight of an N-substituted maleimide monomer component and from 0 to 40% by weight of other vinyl monomer component copolymerizable with these monomers (provided that the total amount of the monomer components is 100% by weight); andfrom 0 to 15 parts by weight of a copolymer resin (D) comprising from 60 to 90% by weight of an aromatic vinyl monomer component, from 0 to 40% by weight of a vinyl cyanide monomer component and from 0 to 40% by weight of a methyl methacrylate monomer component (provided that the total amount of the monomer components is 100% by weight).
    • 一种耐热冲击性热塑性树脂组合物,其包含:100重量份的包含20至80重量%的聚酰胺树脂(A)和20至80重量%的接枝共聚物树脂(B)的树脂混合物, 通过接枝聚合30至65重量份的单体混合物,其包含30至80重量%的芳族乙烯基单体,5至65重量%的N-取代的马来酰亚胺单体和0至40重量% 可与这些单体共聚的其它乙烯基单体的重量(条件是所述单体混合物的总量为100重量%)至35至70重量份的共轭二烯橡胶; 0至40重量份的共聚物树脂(C),其包含30至80重量%的芳族乙烯基单体组分,5至65重量%的N-取代的马来酰亚胺单体组分和0至40重量% 的单体组分可共聚的其它乙烯基单体组分(单体组分的总量为100重量%); 和0至15重量份的共聚物树脂(D),其包含60至90重量%的芳族乙烯基单体组分,0至40重量%的乙烯基氰单体组分和0至40重量% 甲基丙烯酸甲酯单体组分的重量(单体成分的总量为100重量%)。