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    • 1. 发明授权
    • Method and apparatus for reclaiming oil from waste plastic
    • 从废塑料回收油的方法和设备
    • US6011187A
    • 2000-01-04
    • US945458
    • 1997-10-27
    • Hirotoshi HorizoeTakeshi AmariHiroshi NagaiShizuo YasudaYuji KaiharaYoshimasa KawamiYasumasa Matsukawa
    • Hirotoshi HorizoeTakeshi AmariHiroshi NagaiShizuo YasudaYuji KaiharaYoshimasa KawamiYasumasa Matsukawa
    • B29B17/02C10G1/00C10G1/02C10G1/10C10B1/04C08J1/16
    • B29B17/02C10G1/00C10G1/006C10G1/02C10G1/10B29B17/04B29B2017/0496B29K2027/06B29K2101/10Y02P70/26Y02W30/622Y02W30/625
    • This invention provides a method for reclaiming oil from waste plastic in such a way that thermosetting resins and solid foreign matter in the plastic will not pose a problem. This method greatly reduces the burden of presorting the garbage or industrial waste. To achieve this objective when oil is to be reclaimed from a waste plastic containing chlorine compounds, such as vinyl chloride, the plastic must first be stripped of chlorine. Prior to pyrolysis, while being conveyed forward in a continuous stream, the plastic is mixed with heated sand and/or an additive agent to raise its temperature to 250-350.degree. C. This creates a product which is comprised of a mixture of sand and substantially dechlorinated plastic. The product is mixed with heated sand to heat it directly to a temperature of 350-500.degree. C. It is maintained at this temperature until pyrolysis occurs. In order to obtain high-quality oil with a low boiling point, a first gas/liquid separation process separates the product obtained from the aforesaid pyrolysis into liquid high-boiling point oil, gaseous low-boiling point oil and low molecular-weight gases, and recirculates the liquid high-boiling point oil to the pyrolysis process, and a second gas/liquid separation process separates the gaseous low-boiling point oil and low molecular-weight gases into liquid low-boiling point oil and low molecular-weight gases. The first and second gas/liquid separation process are connected in sequence.
    • PCT No.PCT / JP97 / 00572 Sec。 371日期1998年1月8日 102(e)日期1998年1月8日PCT提交1997年2月27日PCT公布。 公开号WO97 / 31990 日期1997年9月4日本发明提供了一种从废塑料中回收油的方法,使得塑料中的热固性树脂和固体异物不会造成问题。 这种方法大大减轻了预处理垃圾或工业废物的负担。 为了达到这个目的,当油从含氯化合物(如氯乙烯)的废塑料中回收时,塑料必须先被除去氯。 在热解之前,当在连续流中向前输送时,将塑料与加热的砂和/或添加剂混合以将其温度升高至250-350℃。这产生了由砂和 基本上脱氯塑料。 将产物与加热的沙子混合,直接加热到350-500℃的温度。保持在该温度直到发生热解。 为了获得低沸点的优质油,第一气/液分离方法将从上述热分解得到的产物分离成液体高沸点油,气态低沸点油和低分子量气体, 并将液体高沸点油再循环到热解过程中,并且第二气/液分离过程将气态低沸点油和低分子量气体分离成液体低沸点油和低分子量气体。 第一和第二气/液分离过程依次连接。
    • 3. 发明授权
    • Method to concentrate and purify alcohol
    • 浓缩和纯化酒精的方法
    • US5053563A
    • 1991-10-01
    • US332933
    • 1990-02-20
    • Hirotoshi HorizoeMasura MakiTetsuya TanimotoMasaaki Yanagi
    • Hirotoshi HorizoeMasura MakiTetsuya TanimotoMasaaki Yanagi
    • B01D1/28B01D3/14B01D11/04C07C29/86
    • B01D11/0407B01D1/2843B01D3/143C07C29/86Y02E50/17Y02P20/544Y02P20/57
    • The present invention relates to a method and an apparatus to condense and rectify alcohol, and more particularly to a method and an apparatus suitable for the energy-saving condensation and rectification of high-purity alcohol from the synthesized alcohol, the used alcohol aqueous solution in food industry and the fermented alcohol.The invention provides a method, which makes it possible to extract and recover alcohol of 99 wt % or higher with small quantity of propane solvent, using the propane in supercritical or pseudocritical conditions in the process of condensation and recovery of alcohol from aqueous solution of alcohol. Further, the method makes it possible to condense alcohol to the concentration of 95 wt % or higher by increasing the selectivity of alcohol through the cooling of the propane to liquid state.
    • PCT No.PCT / JP88 / 00298 Sec。 371日期1990年2月20日 102(e)日期1990年2月20日PCT提交1988年3月22日PCT公布。 出版物WO89 / 01042 日本1989年2月9日。本发明涉及一种用于冷凝和精馏醇的方法和装置,更具体地涉及一种适用于从合成的醇中进行高纯度醇的节能冷凝和精馏的方法和装置 ,食品工业中使用的醇水溶液和发酵酒精。 本发明提供了一种方法,其可以在少量丙烷溶剂中使用丙烷在超临界或伪临界条件下在醇的水溶液中冷凝和回收醇的过程中提取和回收99重量%或更高的醇 。 此外,该方法可以通过将丙烷冷却至液态来提高醇的选择性,使醇浓缩至95重量%以上。
    • 4. 发明授权
    • Method and apparatus for reclaiming oil from waste plastic
    • 从废塑料回收油的方法和设备
    • US06172271B2
    • 2001-01-09
    • US09438307
    • 1999-11-12
    • Hirotoshi HorizoeTakeshi AmariHiroshi NagaiShizuo YasudaYuji KaiharaYoshimasa KawamiYasumasa Matsukawa
    • Hirotoshi HorizoeTakeshi AmariHiroshi NagaiShizuo YasudaYuji KaiharaYoshimasa KawamiYasumasa Matsukawa
    • C10G100
    • B29B17/02B29B17/04B29B2017/0496B29K2027/06B29K2101/10C10G1/00C10G1/006C10G1/02C10G1/10Y02P70/26Y02W30/622Y02W30/625
    • This invention provides a method for reclaiming oil from waste plastic in such a way that thermosetting resins and solid foreign matter in the plastic will not pose a problem. This method greatly reduces the burden of presorting the garbage or industrial waste. To achieve this objective when oil is to be reclaimed from a waste plastic containing chlorine compounds, such as vinyl chloride, the plastic must first be stripped of chlorine. Prior to pyrolysis, while being conveyed forward in a continuous stream, the plastic is mixed with heated sand and/or an additive agent to raise its temperature to 250-350° C. This creates a product which is comprised of a mixture of sand and substantially dechlorinated plastic. The product is mixed with heated sand to heat it directly to a temperature of 350-500° C. It is maintained at this temperature until pyrolysis occurs. In order to obtain high-quality oil with a low boiling point, a first gas/liquid separation process separates the product obtained from the aforesaid pyrolysis into liquid high-boiling point oil, gaseous low-boiling point oil and low molecular-weight gases, and recirculates the liquid high-boiling point oil to the pyrolysis process, and a second gas/liquid separation process separates the gaseous low-boiling point oil and low molecular-weight gases into liquid low-boiling point oil and low molecular-weight gases. The first and second gas/liquid separation process are connected in sequence.
    • 本发明提供了一种从废塑料中回收油的方法,使得塑料中的热固性树脂和固体异物不会造成问题。 这种方法大大减轻了预处理垃圾或工业废物的负担。 为了达到这个目的,当油从含氯化合物(如氯乙烯)的废塑料中回收时,塑料必须先被除去氯。 在热解之前,当在连续流中向前输送时,将塑料与加热的砂和/或添加剂混合以将其温度升高至250-350℃。这产生了由砂和 基本上脱氯塑料。 将产物与加热的沙子混合,将其直接加热至350-500℃的温度。保持在该温度直至发生热解。 为了获得低沸点的优质油,第一气/液分离方法将从上述热分解得到的产物分离成液体高沸点油,气态低沸点油和低分子量气体, 并将液体高沸点油再循环到热解过程中,第二气/液分离过程将气态低沸点油和低分子量气体分离成液体低沸点油和低分子量气体。 第一和第二气/液分离过程依次连接。
    • 6. 发明授权
    • Process for the recovery of absolute ethanol by vapor compression
extractive distillation
    • 通过蒸气压缩萃取蒸馏回收无水乙醇的方法
    • US5294304A
    • 1994-03-15
    • US29961
    • 1993-03-09
    • Yoshikazu KanoHirotoshi HorizoeTetsuya TanimotoItsuo Yamamoto
    • Yoshikazu KanoHirotoshi HorizoeTetsuya TanimotoItsuo Yamamoto
    • C07C29/84B01D3/40
    • C07C29/84Y02P20/124Y10S203/14
    • This invention relates to a process for the production of absolute alcohol from aqueous alcohol, whereby saving of energy to a greater extent is rendered possible in a more simple process, as compared with the prior art azeotropic distillation method using benzene or cyclohexane. That is, aqueous alcohol is subjected to extractive distillation in a first distillation column under such a condition that a liquid and gas of a solvent simultaneously coexist using low pressure propane, propylene and butane as the solvent, absolute alcohol substantially free from water is recovered from the bottom of the distillation column and subjected to stripping of hydrocarbons in a second distillation column, during which the gaseous phases of the first and second distillation columns are mixed and compressed, utilized through recompression as a heat source of a reboiler of the first distillation column, subjected to separation of water content and recycled to the upper parts of the first and second distillation columns. In accordance with the process, the energy required can largely be reduced.In Examples, the energy required for producing 1 kg of absolute alcohol is reduced to 1/5 to 1/10 of the prior art azeotropic distillation method, which shows the advantages of the present invention.According to the process of the present invention, installations such as compressors, heat exchangers, decanters, etc. can be omitted and the installation cost can be reduced by about 30%.
    • 本发明涉及一种从含水醇生产无水酒精的方法,与现有技术的使用苯或环己烷的共沸蒸馏方法相比,能够以更简单的方法将能量节省到更大程度。 也就是说,将含水醇在第一蒸馏塔中进行萃取蒸馏,其条件是使用低压丙烷,丙烯和丁烷作为溶剂同时共存的溶剂的液体和气体,基本上不含水的绝对醇从 蒸馏塔的底部并在第二蒸馏塔中进行烃的汽提,在此期间第一和第二蒸馏塔的气相被混合和压缩,通过再压缩作为第一蒸馏塔的再沸器的热源 经过水分离并再循环到第一和第二蒸馏塔的上部。 根据该过程,所需的能量可以大大降低。 在实施例中,生产1kg无水乙醇所需的能量降低到现有技术共沸蒸馏方法的1/5至1/10,这表明本发明的优点。 根据本发明的方法,可以省略诸如压缩机,热交换器,倾析器等的设备,并且可以将安装成本降低约30%。