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    • 3. 发明授权
    • Process for producing olefin polymers
    • 生产烯烃聚合物的方法
    • US07741419B2
    • 2010-06-22
    • US10550021
    • 2005-03-30
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • C08F4/642C08F4/6592B01J31/22
    • C08F10/00C08F4/65912Y10S526/943C08F4/65927C08F2/06C08F210/16C08F210/14C08F2500/12C08F2500/08
    • A process for producing an olefin polymer is provided, in which ethylene and at least one kind or more of monomers selected from α-olefins are polymerized by a high temperature solution polymerization in a temperature range between 120 and 300° C., in the presence of an olefin polymerization catalyst composed of a bridged metallocene compound represented by general formula [I] described below and at least one kind or more compounds (B) selected from (b-1) an organoaluminum oxy-compound, (b-2) a compound capable of forming an ion pair in a reaction with the bridged metallocene compound mentioned above, and (b-3) an organoaluminum compound. According to the high temperature solution polymerization of the present invention, it has become possible to obtain a polymer having a high molecular weight with high polymerization activity that was so far unattainable, and when the polymer is a copolymer, it is a process for producing a high molecular weight olefin polymer with a large comonomer content, a narrow composition distribution, and a narrow molecular weight distribution.
    • 提供了一种制备烯烃聚合物的方法,其中乙烯和至少一种或多种选自α-烯烃的单体通过高温溶液聚合在120-300℃的温度范围内聚合, 的由下述通式[I]表示的桥连金属茂化合物和至少一种以上选自(b-1)有机铝氧化合物,(b-2)a 能够与上述桥连茂金属化合物反应形成离子对的化合物和(b-3)有机铝化合物。 根据本发明的高温溶液聚合,可以获得迄今为止无法实现的具有高聚合活性的高分子量聚合物,并且当聚合物是共聚物时,它是制备 具有大的共聚单体含量的高分子量烯烃聚合物,组成分布窄,分子量分布窄。
    • 5. 再颁专利
    • Process for producing olefin polymers
    • 生产烯烃聚合物的方法
    • USRE42957E1
    • 2011-11-22
    • US12974458
    • 2005-03-30
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • C08F4/642C08F4/6592B01J31/22
    • C08F10/00C08F4/65912Y10S526/943C08F4/65927C08F2/06C08F210/16C08F210/14C08F2500/12C08F2500/08
    • A process for producing an olefin polymer is provided, in which ethylene and at least one kind or more of monomers selected from α-olefins are polymerized by a high temperature solution polymerization in a temperature range between 120 and 300° C., in the presence of an olefin polymerization catalyst composed of a bridged metallocene compound represented by general formula [I] described below and at least one kind or more compounds (B) selected from (b-1) an organoaluminum oxy-compound, (b-2) a compound capable of forming an ion pair in a reaction with the bridged metallocene compound mentioned above, and (b-3) an organoaluminum compound. According to the high temperature solution polymerization of the present invention, it has become possible to obtain a polymer having a high molecular weight with high polymerization activity that was so far unattainable, and when the polymer is a copolymer, it is a process for producing a high molecular weight olefin polymer with a large comonomer content, a narrow composition distribution, and a narrow molecular weight distribution.
    • 提供了一种制备烯烃聚合物的方法,其中乙烯和至少一种或多种选自α-烯烃的单体通过高温溶液聚合在120-300℃的温度范围内聚合, 的由下述通式[I]表示的桥连金属茂化合物和至少一种以上选自(b-1)有机铝氧化合物,(b-2)a 能够与上述桥连茂金属化合物反应形成离子对的化合物和(b-3)有机铝化合物。 根据本发明的高温溶液聚合,可以获得迄今为止无法实现的具有高聚合活性的高分子量聚合物,并且当聚合物是共聚物时,它是制备 具有大的共聚单体含量的高分子量烯烃聚合物,组成分布窄,分子量分布窄。
    • 6. 发明申请
    • Process for producing olefin polymers
    • 生产烯烃聚合物的方法
    • US20060270812A1
    • 2006-11-30
    • US10550021
    • 2005-03-30
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • Yasushi TohiKenji SugimuraToshiyuki Tsutsui
    • C08F4/44
    • C08F10/00C08F4/65912Y10S526/943C08F4/65927C08F2/06C08F210/16C08F210/14C08F2500/12C08F2500/08
    • A process for producing an olefin polymer is provided, in which ethylene and at least one kind or more of monomers selected from α-olefins are polymerized by a high temperature solution polymerization in a temperature range between 120 and 300° C., in the presence of an olefin polymerization catalyst composed of a bridged metallocene compound represented by general formula [I] described below and at least one kind or more compounds (B) selected from (b-1) an organoaluminum oxy-compound, (b-2) a compound capable of forming an ion pair in a reaction with the bridged metallocene compound mentioned above, and (b-3) an organoaluminum compound. According to the high temperature solution polymerization of the present invention, it has become possible to obtain a polymer having a high molecular weight with high polymerization activity that was so far unattainable, and when the polymer is a copolymer, it is a process for producing a high molecular weight olefin polymer with a large comonomer content, a narrow composition distribution, and a narrow molecular weight distribution.
    • 提供一种制备烯烃聚合物的方法,其中乙烯和至少一种或多种选自α-烯烃的单体通过高温溶液聚合在120-300℃的温度范围内聚合,在存在下 的由下述通式[I]表示的桥连金属茂化合物和至少一种以上选自(b-1)有机铝氧化合物,(b-2)a 能够与上述桥连茂金属化合物反应形成离子对的化合物和(b-3)有机铝化合物。 根据本发明的高温溶液聚合,可以获得迄今为止无法实现的具有高聚合活性的高分子量聚合物,并且当聚合物是共聚物时,它是制备 具有大的共聚单体含量的高分子量烯烃聚合物,组成分布窄,分子量分布窄。