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    • 6. 发明授权
    • Polysilane monomolecular film and polysilane built-up film
    • 聚硅烷单分子膜和聚硅烷成膜
    • US5362559A
    • 1994-11-08
    • US89634
    • 1993-07-12
    • Shuji HayaseYoshihiko NakanoYukihiro MikogamiAkira YoshizumiShinji MuraiRikako Kani
    • Shuji HayaseYoshihiko NakanoYukihiro MikogamiAkira YoshizumiShinji MuraiRikako Kani
    • B05D1/20C09D183/16B32B5/00
    • B82Y30/00B05D1/202B82Y40/00C09D183/16Y10T428/261
    • Disclosed are a polysilane monomolecular film and a polysilane built-up film formed by building up a plurality of said monomolecular films, said monomolecular film consisting of a polysilane having a repeating unit represented by general formula (1) given below: ##STR1## where, R.sup.1 represents a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms or a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, R.sup.2 represents a divalent hydrocarbon group having 1 to 4 carbon atoms which can be substituted, and X represents hydroxyl group, amino group, carboxyl group, or a hydrophilic group having at least one selected from the group consisting of hydroxyl group, amino group, carboxyl group, amide linkage, ester linkage, carbamate linkage and carbonate linkage. The polysilane monomolecular film and built-up film can be formed on a substrate by an LB technique. In the films, the molecules of the polysilane having the repeating unit (1), that is, the Si-Si backbones are oriented in a fixed direction.
    • 公开了一种聚硅烷单分子膜和聚硅烷叠层膜,其通过构建多个所述单分子膜而形成,所述单分子膜由具有由以下给出的通式(1)表示的重复单元的聚硅烷组成:< IMAGE>(1 )其中,R1表示取代或未取代的碳原子数1〜24的烷基或碳原子数6〜24的取代或未取代的芳基,R2表示可被取代的碳原子数1〜4的二价烃基,X 表示羟基,氨基,羧基或具有选自羟基,氨基,羧基,酰胺键,酯键,氨基甲酸酯键和碳酸酯键中的至少一种的亲水基团。 可以通过LB技术在基板上形成聚硅烷单分子膜和积层膜。 在膜中,具有重复单元(1)的聚硅烷的分子,即Si-Si主链在固定方向上取向。