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1. 发明授权

US5362559A Polysilane monomolecular film and polysilane built-up film 失效
标题翻译：聚硅烷单分子膜和聚硅烷成膜
公开(公告)号：US5362559A
公开(公告)日：1994-11-08
申请号：US89634
申请日：1993-07-12
申请人： Shuji Hayase , Yoshihiko Nakano , Yukihiro Mikogami , Akira Yoshizumi , Shinji Murai , Rikako Kani
发明人： Shuji Hayase , Yoshihiko Nakano , Yukihiro Mikogami , Akira Yoshizumi , Shinji Murai , Rikako Kani
IPC分类号： B05D1/20 , C09D183/16 , B32B5/00
CPC分类号： B82Y30/00 , B05D1/202 , B82Y40/00 , C09D183/16 , Y10T428/261
摘要： Disclosed are a polysilane monomolecular film and a polysilane built-up film formed by building up a plurality of said monomolecular films, said monomolecular film consisting of a polysilane having a repeating unit represented by general formula (1) given below: ##STR1## where, R.sup.1 represents a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms or a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, R.sup.2 represents a divalent hydrocarbon group having 1 to 4 carbon atoms which can be substituted, and X represents hydroxyl group, amino group, carboxyl group, or a hydrophilic group having at least one selected from the group consisting of hydroxyl group, amino group, carboxyl group, amide linkage, ester linkage, carbamate linkage and carbonate linkage. The polysilane monomolecular film and built-up film can be formed on a substrate by an LB technique. In the films, the molecules of the polysilane having the repeating unit (1), that is, the Si-Si backbones are oriented in a fixed direction.
摘要翻译：公开了一种聚硅烷单分子膜和聚硅烷叠层膜，其通过构建多个所述单分子膜而形成，所述单分子膜由具有由以下给出的通式（1）表示的重复单元的聚硅烷组成：＆lt; IMAGE＆gt;（1 ）其中，R1表示取代或未取代的碳原子数1〜24的烷基或碳原子数6〜24的取代或未取代的芳基，R2表示可被取代的碳原子数1〜4的二价烃基，X 表示羟基，氨基，羧基或具有选自羟基，氨基，羧基，酰胺键，酯键，氨基甲酸酯键和碳酸酯键中的至少一种的亲水基团。可以通过LB技术在基板上形成聚硅烷单分子膜和积层膜。在膜中，具有重复单元（1）的聚硅烷的分子，即Si-Si主链在固定方向上取向。

2. 发明授权

US5336736A Polysilane and polysilane composition 失效
标题翻译：聚硅烷和聚硅烷组成
公开(公告)号：US5336736A
公开(公告)日：1994-08-09
申请号：US53810
申请日：1993-04-29
申请人： Yoshihiko Nakano , Shuzi Hayase , Shinji Murai , Yukihiro Mikogami , Akira Yoshizumi
发明人： Yoshihiko Nakano , Shuzi Hayase , Shinji Murai , Yukihiro Mikogami , Akira Yoshizumi
IPC分类号： C08G18/64 , C08G59/00 , C08G59/20 , C08G59/30 , C08G59/40 , C08G59/42 , C08G77/60 , C08L63/00 , C08L83/04 , C08L83/16 , G03F7/075 , C08F283/00
CPC分类号： G03F7/0754 , C08G77/60 , C08L83/16
摘要： Disclosed is a polysilane having a repeating unit represented by general formula (1) given below. Also disclosed is a polysilane composition, comprising a polysilane having a repeating unit represented by general formula (2) given below and a cross linking agent: ##STR1## where, each of R.sup.1 and R.sup.3 is hydrogen, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms or a substituted or unsubstituted aryl group having 6 to 24 carbon atoms; R.sup.2 is a divalent hydrocarbon group having to 24 carbon atoms which can be substituted; R.sup.4 is a covalent bond, or a substituted or unsubstituted alkylene group having 1 to carbon atoms, or a substituted or unsubstituted arylene group having 6 to 24 carbon atoms; each of R.sup.5 to R.sup.9 is hydrogen, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, or hydroxyl group, at least one of R.sup.5 to R.sup.9 being hydroxyl group; and X is a monovalent organic group having a reactive group capable of crosslinking upon exposure to light or by heating. If any of the polysilane and the polysilane composition of the present invention is exposed to light or heated, the polysilane molecules are crosslinked so as to provide a two or three dimensional polymer.
摘要翻译：公开了具有下述通式（1）表示的重复单元的聚硅烷。还公开了一种聚硅烷组合物，其包含具有由下述通式（2）表示的重复单元的聚硅烷和交联剂：其中，R1和R3各自为氢取代或未取代的碳原子数为1〜24的烷基或取代或未取代的碳原子数为6〜24的芳基。 R2是可被取代的具有24个碳原子的二价烃基; R4为共价键，或取代或未取代的碳原子数1〜2的亚烷基，取代或未取代的碳原子数为6〜24的亚芳基。 R5至R9各自为氢，取代或未取代的碳原子数为1〜24的烷基，取代或未取代的碳原子数为6〜24的芳基或羟基，R5〜R9中的至少一个为羟基; X是具有能够在曝光或加热时能够交联的反应性基团的一价有机基团。如果本发明的聚硅烷和聚硅烷组合物中的任何一种都被曝光或加热，则聚硅烷分子被交联以提供二维或三维聚合物。

3. 发明授权

US5811497A Aromatic curing catalyst for epoxy resins 失效
标题翻译：用于环氧树脂的芳香族固化催化剂
公开(公告)号：US5811497A
公开(公告)日：1998-09-22
申请号：US526327
申请日：1995-09-11
申请人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
发明人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
IPC分类号： C08G59/68 , C08G59/06 , C08G59/24
CPC分类号： C08G59/68 , C08G59/681
摘要： Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.
摘要翻译：本文公开了包含至少一种化合物的固化催化剂，所述化合物是取代或未取代的芳族或杂芳族化合物，并且具有（I）-O-R 1，（II）-O-CY-R 1或（III） - O-CY-X-R1，其直接键合到铠装或杂芳族环上，其数量为1至10，其中R 1可以相同或不同，并且是具有1至20个碳原子的取代或未取代的烃基， X是O或NH，Y是O或S.此外，公开了包含固化催化剂的环氧树脂组合物。

4. 发明授权

US6096836A (Hetero)aromatic ether, (thio)ester or (thio)carbonate epoxy catalyst 失效
标题翻译：（杂）芳族醚，（硫代）酯或（硫代）碳酸酯环氧催化剂
公开(公告)号：US6096836A
公开(公告)日：2000-08-01
申请号：US35307
申请日：1998-03-02
申请人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
发明人： Shuzi Hayase , Yoshihiko Nakano , Shinji Murai , Yukihiro Mikogami
IPC分类号： C08G59/68 , C08G59/06 , C08G59/24
CPC分类号： C08G59/68 , C08G59/681
摘要： Disclosed herein is a curing catalyst comprising at least one compound which is a substituted or unsubstituted aromatic or heteroaromatic compound and having any one of groups (I) --O--R.sub.1, (II) --O--CY--R.sub.1, or (III) --O--CY--X--R.sub.1, the groups being directly bonded to the armoatic or heteroaromatic ring, in a number of 1 to 10 wherein R.sub.1 may be the same or different and is a substituted or unsubstituted hydrocarbon group having 1 to 20 carbon atoms, X is O or NH and Y is O or S. Furthermore, an epoxy resin composition comprising the curing catalyst is disclosed.
摘要翻译：本文公开了包含至少一种化合物的固化催化剂，所述化合物是取代或未取代的芳族或杂芳族化合物，并且具有（I）-O-R 1，（II）-O-CY-R 1或（III） - O-CY-X-R1，其直接键合到铠装或杂芳族环上，其数量为1至10，其中R 1可以相同或不同，并且是具有1至20个碳原子的取代或未取代的烃基， X是O或NH，Y是O或S.此外，公开了包含固化催化剂的环氧树脂组合物。

5. 发明授权

US5773192A Organic silicon compound, resist, thermal polymerization composition and photopolymerization composition 失效
标题翻译：有机硅化合物，抗蚀剂，热聚合组合物和光聚合组合物
公开(公告)号：US5773192A
公开(公告)日：1998-06-30
申请号：US794587
申请日：1997-02-03
申请人： Shinji Murai , Yoshihiko Nakano , Ken Uchida , Shuji Hayase
发明人： Shinji Murai , Yoshihiko Nakano , Ken Uchida , Shuji Hayase
IPC分类号： B41M5/36 , C07F7/08 , C08F4/00 , C08G77/48 , C08G77/60 , C08L83/02 , C08L83/16 , G03F7/004 , G03F7/027 , G03F7/029 , G03F7/075 , G03F7/023 , G08G77/00
CPC分类号： G03F7/027 , B41M5/368 , C07F7/0821 , C08G77/60 , G03F7/0045 , G03F7/029 , G03F7/075 , G03F7/0757
摘要： Disclosed are an organic silicon compound having a repeating unit represented by general formula (I) shown below, a resist, a thermal polymerization composition and a photopolymerization composition containing the organic silicon compound, ##STR1## wherein R.sup.1 is a t-butyl group or a pyranyl group, R.sup.2 is an hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 1 to 24 carbon atoms, or a substituted or unsubstituted aralkyl having 7 to 24 carbon atoms, R.sup.3 is a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 24 carbon atoms or an alkoxyl group, and k represents an integer from 0 to 4.
摘要翻译：公开了具有下述通式（I）表示的重复单元的有机硅化合物，抗蚀剂，热聚合组合物和含有有机硅化合物的光聚合组合物，其中，R 2表示氢原子，取代基或未取代的碳原子数1〜24的烷基，取代或未取代的碳原子数为1〜24的芳基或取代或未取代的碳原子数为7〜24的芳烷基，R3为取代或未取代的碳原子数为1〜24的烷基取代或未取代的碳原子数为6〜24的芳基，取代或未取代的碳原子数为7〜24的芳烷基或烷氧基，k表示0〜4的整数。

6. 发明授权

US5624788A Organic silicon compound, resist thermal polymerization composition and photopolymerization composition 失效
标题翻译：有机硅化合物，抗热聚合组合物和光聚合组合物
公开(公告)号：US5624788A
公开(公告)日：1997-04-29
申请号：US490614
申请日：1995-06-15
申请人： Shinji Murai , Yoshihiko Nakano , Ken Uchida , Shuji Hayase
发明人： Shinji Murai , Yoshihiko Nakano , Ken Uchida , Shuji Hayase
IPC分类号： B41M5/36 , C07F7/08 , C08F4/00 , C08G77/48 , C08G77/60 , C08L83/02 , C08L83/16 , G03F7/004 , G03F7/027 , G03F7/029 , G03F7/075 , G03F7/023 , G08G77/00
CPC分类号： G03F7/027 , B41M5/368 , C07F7/0821 , C08G77/60 , G03F7/0045 , G03F7/029 , G03F7/075 , G03F7/0757
摘要： Disclosed are an organic silicon compound having a repeating unit represented by general formula (I) shown below, a resist, a thermal polymerization composition and a photopolymerization composition containing the organic silicon compound, ##STR1## wherein R.sup.1 is a t-butyl group or a tetrahydropyranyl group, R.sup.2 is an hydrogen atom, a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 1 to 24 carbon atoms, or a substituted or unsubstituted aralkyl having 7 to 24 carbon atoms, R.sup.3 is a substituted or unsubstituted alkyl group having 1 to 24 carbon atoms, a substituted or unsubstituted aryl group having 6 to 24 carbon atoms, a substituted or unsubstituted aralkyl group having 7 to 24 carbon atoms or an alkoxyl group, and k represents an integer from 0 to 4.
摘要翻译：公开了具有下述通式（I）表示的重复单元的有机硅化合物，抗蚀剂，热聚合组合物和含有有机硅化合物的光聚合组合物，R 2是氢原子，取代或未取代的碳原子数为1〜24的烷基，取代或未取代的碳原子数为1〜24的芳基或取代或未取代的碳原子数为7〜24的芳烷基，R3为取代或未取代的烷基，碳原子，取代或未取代的碳原子数为6〜24的芳基，取代或未取代的碳原子数为7〜24的芳烷基或烷氧基，k表示0〜4的整数。

7. 发明授权

US07126054B2 Raw material kit for electrolytic composition, electrolytic composition, and dye-sensitized solar cell 有权
标题翻译：电解组合物原料试剂盒，电解组合物和染料敏化太阳能电池
公开(公告)号：US07126054B2
公开(公告)日：2006-10-24
申请号：US10180018
申请日：2002-06-27
申请人： Shinji Murai , Hiroyasu Sumino , Satoshi Mikoshiba , Shuji Hayase
发明人： Shinji Murai , Hiroyasu Sumino , Satoshi Mikoshiba , Shuji Hayase
IPC分类号： H01L31/04
CPC分类号： H01G9/2031 , H01G9/2009 , Y02E10/542
摘要： Disclosed is a dye-sensitized solar cell comprising a gel electrolyte that contains a gelling agent and an electrolyte, wherein the gelling agent contains at least one kind of a polymer selected from the group consisting of a first polymer in which polysulfonic acid is crosslinked by a metal ion having a valency of not less than two, a second polymer in which polycarboxylic acid is crosslinked by a metal ion having a valency of not less than two, a third polymer in which a quaternary ammonium salt of polysulfonic acid is crosslinked by a metal ion having a valency of not less than two and a fourth polymer in which a quaternary ammonium salt of polycarboxylic acid is crosslinked by a metal ion having a valency of not less than two.
摘要翻译：公开了一种染料敏化太阳能电池，其包含凝胶电解质，其含有胶凝剂和电解质，其中，所述胶凝剂含有选自第一聚合物中的至少一种的聚合物，其中聚磺酸通过化合价不低于2的金属离子，多元羧酸通过不少于2价的金属离子交联的第二聚合物，其中多磺酸的季铵盐通过金属交联的第三种聚合物具有不小于2的化合价的离子和其中多元羧酸的季铵盐通过不少于2的化合价的金属离子交联的第四聚合物。

8. 发明申请

US20070137702A1 DYE SENSITIZED SOLAR CELL AND METHOD FOR MANUFACTURING DYE SENSITIZED SOLAR CELL 有权
标题翻译： DYE SENSITIZED SOLAR CELL AND METHOD FOR MANUFACTURE THE DYE SENSITIZED SOLAR CELL
公开(公告)号：US20070137702A1
公开(公告)日：2007-06-21
申请号：US11671227
申请日：2007-02-05
申请人： Shinji Murai , Satoshi Mikoshiba , Hiroyasu Sumino , Shuji Hayase
发明人： Shinji Murai , Satoshi Mikoshiba , Hiroyasu Sumino , Shuji Hayase
IPC分类号： H01L31/00
CPC分类号： H01G9/2009 , H01G9/2031 , Y02E10/542 , Y02P70/521
摘要： The present invention provides a dye sensitized solar cell comprising an n-type semiconductor electrode containing a dye, an opposed electrode, and a gel electrolyte arranged between the n-type semiconductor and the opposed electrode and containing a gelling agent and an electrolyte that contains iodine, wherein the gelling agent contains a compound including an N-containing group and at least one atomic group selected from a group consisting of a sulfonic group and a carboxylic group.
摘要翻译：本发明提供了一种染料敏化太阳能电池，其包含n型半导体电极，其含有染料，相对电极和布置在n型半导体和相对电极之间的凝胶电解质，并含有胶凝剂和含有碘的电解质其中，所述胶凝剂含有包含含氮基团和至少一个选自磺酸基和羧基的原子团的化合物。

9. 发明授权

US07196264B2 Dye sensitized solar cell and method for manufacturing dye sensitized solar cell 有权
标题翻译：染料敏化太阳能电池和染料敏化太阳能电池的制造方法
公开(公告)号：US07196264B2
公开(公告)日：2007-03-27
申请号：US10326131
申请日：2002-12-23
申请人： Shinji Murai , Satoshi Mikoshiba , Hiroyasu Sumino , Shuji Hayase
发明人： Shinji Murai , Satoshi Mikoshiba , Hiroyasu Sumino , Shuji Hayase
IPC分类号： H01L31/00
CPC分类号： H01G9/2009 , H01G9/2031 , Y02E10/542 , Y02P70/521
摘要： The present invention provides a dye sensitized solar cell comprising an n-type semiconductor electrode containing a dye, an opposed electrode, and a gel electrolyte arranged between the n-type semiconductor and the opposed electrode and containing a gelling agent and an electrolyte that contains iodine, wherein the gelling agent contains a compound including an N-containing group and at least one atomic group selected from a group consisting of a sulfonic group and a carboxylic group.
摘要翻译：本发明提供了一种染料敏化太阳能电池，其包含n型半导体电极，其含有染料，相对电极和布置在n型半导体和相对电极之间的凝胶电解质，并含有胶凝剂和含有碘的电解质其中，所述胶凝剂含有包含含氮基团和至少一个选自磺酸基和羧基的原子团的化合物。

10. 发明授权

US06437090B1 Curing catalyst, resin composition, resin-sealed semiconductor device and coating material 失效
标题翻译：固化催化剂，树脂组合物，树脂密封半导体装置和涂料
公开(公告)号：US06437090B1
公开(公告)日：2002-08-20
申请号：US09334915
申请日：1999-06-17
申请人： Shinji Murai , Shuji Hayase , Shinetsu Fujieda , Rumiko Hayase , Yasuyuki Hotta
发明人： Shinji Murai , Shuji Hayase , Shinetsu Fujieda , Rumiko Hayase , Yasuyuki Hotta
IPC分类号： C08G5968
CPC分类号： C08G59/18 , C08G59/68
摘要： A curing catalyst comprising at least one of a cationic curing catalyst component and an organo-metallic compound component. At least one of these components is capable of reversibly repeating the dissolution and precipitation through heating and cooling. The cationic curing catalyst component includes in its molecule at least one substituted or unsubstituted hydrocarbon group having 10 or more carbon atoms, or at least one cyclic organic structure having a substituted or unsubstituted hydrocarbon group having 10 or more carbon atoms.
摘要翻译：包含阳离子固化催化剂组分和有机金属化合物组分中的至少一种的固化催化剂。这些组分中的至少一种能够通过加热和冷却可逆地重复溶解和沉淀。阳离子固化催化剂组分在其分子中包含至少一个具有10个或更多个碳原子的取代或未取代的烃基，或至少一个具有取代或未取代的具有10个或更多个碳原子的烃基的环状有机结构。

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