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    • 3. 发明授权
    • Formation and treatment of epitaxial layer containing silicon and carbon
    • 含硅和外延层的形成和处理
    • US07741200B2
    • 2010-06-22
    • US11778212
    • 2007-07-16
    • Yonah ChoYihwan Kim
    • Yonah ChoYihwan Kim
    • H01L21/425
    • H01L21/046H01L21/268H01L21/823807H01L21/823814H01L29/165H01L29/7834H01L29/7848
    • Methods for formation and treatment of epitaxial layers containing silicon and carbon are disclosed. Treatment converts interstitial carbon to substitutional carbon in the epitaxial layer, according to one or more embodiments. Specific embodiments pertain to the formation and treatment of epitaxial layers in semiconductor devices, for example, Metal Oxide Semiconductor Field Effect Transistor (MOSFET) devices. In specific embodiments, the treatment of the epitaxial layer involves annealing for short periods of time, for example, by laser annealing, millisecond annealing, rapid thermal annealing, spike annealing and combinations thereof. Embodiments include amorphization of at least a portion of the epitaxial layer containing silicon and carbon.
    • 公开了用于形成和处理含有硅和碳的外延层的方法。 根据一个或多个实施方案,处理将间隙碳转化成外延层中的替代碳。 具体实施例涉及半导体器件中的外延层的形成和处理,例如金属氧化物半导体场效应晶体管(MOSFET)器件。 在具体实施例中,外延层的处理包括退火短时间,例如通过激光退火,毫秒退火,快速热退火,尖峰退火及其组合。 实施例包括至少部分含有硅和碳的外延层的非晶化。
    • 5. 发明授权
    • Carbon addition for low resistivity in situ doped silicon epitaxy
    • 用于低电阻率原位掺杂硅外延的碳添加
    • US09012328B2
    • 2015-04-21
    • US13193566
    • 2011-07-28
    • Zhiyuan YeXuebin LiSaurabh ChopraYihwan Kim
    • Zhiyuan YeXuebin LiSaurabh ChopraYihwan Kim
    • H01L21/311H01L21/02H01L29/66H01L29/78H01L21/8238
    • H01L29/36H01L21/0245H01L21/02529H01L21/02532H01L21/02573H01L21/02664H01L21/823814H01L29/167H01L29/66628H01L29/66636H01L29/7834
    • Embodiments of the present invention generally relate to methods of forming epitaxial layers and devices having epitaxial layers. The methods generally include forming a first epitaxial layer including phosphorus and carbon on a substrate, and then forming a second epitaxial layer including phosphorus and carbon on the first epitaxial layer. The second epitaxial layer has a lower phosphorus concentration than the first epitaxial layer, which allows for selective etching of the second epitaxial layer and undesired amorphous silicon or polysilicon deposited during the depositions. The substrate is then exposed to an etchant to remove the second epitaxial layer and undesired amorphous silicon or polysilicon. The carbon present in the first and second epitaxial layers reduces phosphorus diffusion, which allows for higher phosphorus doping concentrations. The increased phosphorus concentrations reduce the resistivity of the final device. The devices include epitaxial layers having a resistivity of less than about 0.381 milliohm-centimeters.
    • 本发明的实施例一般涉及形成外延层的方法和具有外延层的器件。 所述方法通常包括在衬底上形成包括磷和碳的第一外延层,然后在第一外延层上形成包括磷和碳的第二外延层。 第二外延层具有比第一外延层更低的磷浓度,其允许在沉积期间沉积的第二外延层和不期望的非晶硅或多晶硅的选择性蚀刻。 然后将衬底暴露于蚀刻剂以除去第二外延层和不期望的非晶硅或多晶硅。 存在于第一和第二外延层中的碳减少了磷扩散,这允许更高的磷掺杂浓度。 增加的磷浓度降低了最终装置的电阻率。 这些器件包括具有小于约0.381毫欧姆厘米的电阻率的外延层。