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    • 2. 发明授权
    • Process for fabricating a high-endurance non-volatile memory device
    • 制造高耐久性非易失性存储器件的方法
    • US06255169B1
    • 2001-07-03
    • US09255053
    • 1999-02-22
    • Xiao-Yu LiQi XiangSunil D. Mehta
    • Xiao-Yu LiQi XiangSunil D. Mehta
    • H01L218247
    • H01L27/11521H01L27/11558
    • A process for fabricating a non-volatile memory device includes the step of forming a nitrogen region in a semiconductor substrate prior to carrying out a thermal oxidation process to form a tunnel oxide layer. In a preferred process, nitrogen atoms are ion implanted into a silicon substrate to form a nitrogen region at the substrate surface. Then, a thermal oxidation process is carried out to grow a thin tunnel oxide layer overlying the surface of the nitrogen region. During the oxidation process, nitrogen is incorporated into the growing tunnel oxide layer. A floating-gate electrode is formed overlying the tunnel oxide layer and receives electrical charge transferred from a charge control region of the substrate through the tunnel oxide layer. The tunnel oxide layer is capable of undergoing repeated programming and erasing operations while exhibiting reduced effects from stress induced current leakage. In another aspect of the invention, an MOS transistor having enhanced carrier mobility is obtained by forming a gate oxide layer over a nitrogen region of a silicon substrate. The thermal oxidation process of the invention also provides both tunnel oxide layers and gate oxide layers having a reduced thickness for a given set of thermal oxidation conditions.
    • 一种用于制造非易失性存储器件的方法包括在进行热氧化工艺以形成隧道氧化物层之前在半导体衬底中形成氮区的步骤。 在优选的方法中,将氮原子离子注入到硅衬底中以在衬底表面形成氮区。 然后,进行热氧化处理,以生长覆盖在氮区域的表面上的薄的隧道氧化物层。 在氧化过程中,将氮气掺入生长的隧道氧化物层中。 在隧道氧化物层上形成浮栅电极,并接收通过隧道氧化物层从衬底的电荷控制区转移的电荷。 隧道氧化物层能够经受重复的编程和擦除操作,同时表现出应力感应电流泄漏的减小的影响。 在本发明的另一方面,通过在硅衬底的氮区上形成栅极氧化层,获得具有增强的载流子迁移率的MOS晶体管。 本发明的热氧化方法还为给定的一组热氧化条件提供具有减小的厚度的隧道氧化物层和栅极氧化物层。
    • 7. 发明授权
    • Non-volatile memory device having a high-reliability composite insulation layer
    • 具有高可靠性复合绝缘层的非易失性存储器件
    • US06207989B1
    • 2001-03-27
    • US09268897
    • 1999-03-16
    • Xiao-Yu LiSunil D. Mehta
    • Xiao-Yu LiSunil D. Mehta
    • H01L2976
    • H01L27/11521H01L27/115H01L27/11558
    • A non-volatile memory device includes a floating-gate electrode overlying a tunnel oxide layer. A portion of the floating-gate electrode forms the control gate electrode for a sense transistor that is used to determine the presence of charge on the floating-gate electrode. A composite insulation layer overlies the floating-gate electrode. The composite insulation layer includes a dielectric layer, a doped insulating layer overlying the dielectric layer, and a planarization layer overlying the doped insulating layer. The thicknesses of the dielectric layer and the doped insulating layer are precisely determined, such that the doped insulating layer getters mobile ions, such as hydrogen ions, away from the floating-gate electrode, while not capacitively coupling with the floating-gate electrode. In a preferred embodiment of the invention, the dielectric layer has a thickness of about 450 to about 550 Å, and the doped insulating layer has a thickness of about 2900 to about 3100 Å, and the planarization layer has a thickness of about 6000 to 8000 Å.
    • 非易失性存储器件包括覆盖隧道氧化物层的浮栅电极。 浮栅电极的一部分形成用于确定浮栅电极上电荷存在的读出晶体管的控制栅电极。 复合绝缘层覆盖浮栅电极。 复合绝缘层包括电介质层,覆盖电介质层的掺杂绝缘层和覆盖掺杂绝缘层的平坦化层。 电介质层和掺杂绝缘层的厚度被精确地确定,使得掺杂的绝缘层在不与浮栅电极电容耦合的同时将诸如氢离子的移动离子吸引到浮栅电极。 在本发明的优选实施例中,电介质层的厚度为约450至约550,掺杂绝缘层的厚度为约2900至约3100,平坦化层的厚度为约6000至8000 一个。