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1. 发明授权

US4440960A Continuous preparation of 3-alkyl-buten-1-als 失效
标题翻译：连续制备3-烷基 - 丁烯-1-醛
公开(公告)号：US4440960A
公开(公告)日：1984-04-03
申请号：US330024
申请日：1981-12-11
申请人： Wolfgang Sauer , Werner Aquila , Wolfgang Hoffmann , Karl Brenner , Klaus Halbritter
发明人： Wolfgang Sauer , Werner Aquila , Wolfgang Hoffmann , Karl Brenner , Klaus Halbritter
IPC分类号： C07C47/21 , B01J23/00 , C07B61/00 , C07C45/00 , C07C45/38 , C07C45/81 , C07C67/00 , C07C45/29
CPC分类号： C07C45/38 , C07C45/81
摘要： A process for the continuous preparation of 3-alkyl-buten-1-als by oxidative dehydrogenation of 3-alkyl-buten-1-ols at from 320.degree. to 650.degree. C. with oxygen over a catalyst containing copper and/or silver, wherein, within one second after contact with the catalyst, the vaporous reaction mixture, which is at from 320.degree. to 650.degree. C., is brought into contact with a liquid comprising water and/or the condensed reaction mixture at from -20.degree. to 50.degree. C., and the 3-alkyl-buten-1-als are separated off from the resulting condensate.
摘要翻译： 3-烷基 - 丁烯-1-醇的连续制备方法，其通过在含有铜和/或银的催化剂上，在320℃至650℃下用氧氧化脱氢3-烷基 - 丁烯-1-醇，其中在与催化剂接触后一秒钟内，将在320℃至650℃的气态反应混合物与包含水和/或冷凝的反应混合物的液体在-20℃至 50℃，从所得的冷凝物中分离出3-烷基 - 丁烯-1-醇。

2. 发明授权

US5149884A Tube bundle reactor, use thereof in exothermic organic reactions, and preparation of ketones and aldehydes using same 失效
标题翻译：管组件反应器，在有机有机反应中使用，以及使用其制备酮和醛
公开(公告)号：US5149884A
公开(公告)日：1992-09-22
申请号：US680631
申请日：1991-04-01
申请人： Karl Brenner , Wilhelm Ruppel , Otto Woerz , Klaus Halbritter , Hans-Juergen Scheiper , Werner Aquila , Hartwig Fuchs
发明人： Karl Brenner , Wilhelm Ruppel , Otto Woerz , Klaus Halbritter , Hans-Juergen Scheiper , Werner Aquila , Hartwig Fuchs
IPC分类号： B01J8/06 , C07B61/00 , C07C45/00 , C07C45/38 , C07C45/39 , C07C47/21 , C07C67/00
CPC分类号： B01J8/067 , C07C45/38 , C07C45/39 , B01J2208/00212 , B01J2208/0053
摘要： In a tube bundle reactor for carrying out catalytic organic reactions in the gas phase, comprising reaction tubes (A) arranged between tubesheets (B), the reaction tubes have an inside diameter ranging from 0.5 to 3 cm, the ratio of reaction tube length to inside diameter ranges from 2 to 10, and the reaction tubes (A) are surrounded by a fluid heat transport medium flowing in the crosswise direction; said tube bundle reactor is useful in particular in exothermic organic reactions.
摘要翻译：在用于在气相中进行催化有机反应的管束反应器中，包括布置在管板（B）之间的反应管（A），反应管的内径范围为0.5至3cm，反应管长度与内径为2〜10，反应管（A）由沿横向流动的流体传热介质包围; 所述管束反应器尤其可用于放热有机反应中。

3. 发明授权

US4940805A Preparation of 1,4-butanediol or tetrahydrofuran or both 失效
标题翻译： 1,4-丁二醇或四氢呋喃或二者的制备
公开(公告)号：US4940805A
公开(公告)日：1990-07-10
申请号：US230015
申请日：1988-08-08
申请人： Rolf Fischer , Hans-Juergen Gosch , Wolfgang Harder , Klaus-Dieter Malsch , Manfred Eggersdorfer , Lothar Franz , Horst Zimmermann , Karl Brenner , Klaus Halbritter , Wolfgang Sauer , Hans-Juergen Scheiper
发明人： Rolf Fischer , Hans-Juergen Gosch , Wolfgang Harder , Klaus-Dieter Malsch , Manfred Eggersdorfer , Lothar Franz , Horst Zimmermann , Karl Brenner , Klaus Halbritter , Wolfgang Sauer , Hans-Juergen Scheiper
IPC分类号： B01J27/18 , B01J27/19 , C07B61/00 , C07C27/00 , C07C29/136 , C07C29/147 , C07C29/149 , C07C29/17 , C07C29/56 , C07C31/20 , C07C67/00 , C07D307/08
CPC分类号： C07D307/08 , C07C29/177
摘要： Process for the preparation of 1,4-butanediol or tetrahydrofuran or both by the catalytic hydrogenation of maleic anhydride, succinic anhydride, maleic acid, succinic acid, fumaric acid, or the alkyl esters of these acids at temperatures of from 100.degree. C. to 350.degree. C. and pressures of from 50 bar to 350 bar over a catalyst containing cobalt as the active metal and one or both of the elements copper and phosphorus, if necessary in the presence of an aliphatic alcohol.
摘要翻译：通过马来酸酐，琥珀酸酐，马来酸，琥珀酸，富马酸或这些酸的烷基酯的催化氢化制备1,4-丁二醇或四氢呋喃或二者的方法，温度为100℃至 350℃，并且在含有钴作为活性金属的催化剂和一种或两种元素铜和磷的催化剂中，如果需要，在脂族醇的存在下，压力为50巴至350巴。

4. 发明授权

US6013843A Continuous industrial production of unsaturated aliphatic aldehydes in a tube bundle reactor 失效
标题翻译：在管束反应器中连续工业生产不饱和脂族醛
公开(公告)号：US6013843A
公开(公告)日：2000-01-11
申请号：US85836
申请日：1998-05-28
申请人： Werner Aquila , Hartwig Fuchs , Otto Worz , Wilhelm Ruppel , Klaus Halbritter
发明人： Werner Aquila , Hartwig Fuchs , Otto Worz , Wilhelm Ruppel , Klaus Halbritter
IPC分类号： B01J23/52 , B01J8/02 , B01J8/08 , C07B61/00 , C07C45/38 , C07C45/67 , C07C47/21 , C07C47/22 , C07C45/00
CPC分类号： C07C45/38 , B01J8/0242 , B01J8/087 , C07C45/67 , B01J2208/00212
摘要： A process for continuous industrial production of unsaturated aliphatic aldehydes having a boiling range from 95 to 136.degree. C. by oxidative dehydrogenation of the corresponding alcohols with an oxygen-comprising gas over a supported catalyst consisting of copper, silver and/or gold on an inert support in a tube bundle reactor, rapid cooling of the reaction gases and removal of the aldehydes from the resulting condensate with recycling of the unconverted alcohols comprisesa) vaporizing the alcohol,b) admixing the alcohol vapor with an oxygen-comprising gas,c) initially passing the resulting oxygen-comprising alcohol vapor at above the dew point of the alcohol but below the commencement temperature of the reaction through a layer of one of the abovementioned supported catalysts which is at least 0.5 cm in thickness and only thend) reacting the oxygen-comprising alcohol vapor at from 300 to 600.degree. C. in a sufficient number, for the desired capacity, of parallel reaction tubes surrounded by a fluidic heat transfer medium, packed with the supported catalyst and having an internal diameter D of from about 0.5 to 3 cm and a length of at least 5 cm, to form the corresponding aldehyde.
摘要翻译：通过相对应的醇与含氧气体在由铜，银和/或金组成的负载型催化剂上惰性惰性的连续工业生产不饱和脂族醛的方法，其沸程为95至136℃ 在管束反应器中的支撑，反应气体的快速冷却以及未转化的醇的再循环从所得冷凝物中除去醛包括a）蒸发醇，b）将醇蒸气与含氧气体混合，c）首先将所得的含氧醇醇蒸气在醇的露点以上但低于反应开始温度的上述负载型催化剂层中的至少0.5cm厚度，然后d）使含氧的醇蒸气在300-600℃下以足够的数量容纳所需的并联反应管由流体传热介质引入，填充有负载的催化剂并且具有约0.5至3cm的内径D和至少5cm的长度以形成相应的醛。

5. 发明授权

US4503261A Preparation of glyoxal 失效
标题翻译：乙二醛的制备
公开(公告)号：US4503261A
公开(公告)日：1985-03-05
申请号：US400690
申请日：1982-07-22
申请人： Wolfgang Sauer , Klaus Halbritter , Heinz Engelbach
发明人： Wolfgang Sauer , Klaus Halbritter , Heinz Engelbach
IPC分类号： C07C45/38
CPC分类号： C07C45/38
摘要： A process for the continuous preparation of glyoxal by oxidation of ethylene glycol, in which the ethylene glycol, oxygen and an inert gas are passed, at from 450.degree. to 800.degree. C., over a catalyst consisting of one or more layers of copper crystals and one or more layers of silver crystals, the copper and silver crystals having a particle size of from 0.1 to 2.5 mm.
摘要翻译：通过氧化乙二醇（其中乙二醇，氧气和惰性气体）在450℃至800℃下通过由一层或多层铜晶体组成的催化剂连续制备乙二醛的方法和一层或多层银晶，铜和银晶体的粒径为0.1至2.5mm。

6. 发明授权

US06888021B2 Hydrogenation of benzenepolycarboxylic acids or derivatives thereof using a catalyst containing macropores 有权
标题翻译：使用含有大孔的催化剂氢化苯多元羧酸或其衍生物
公开(公告)号：US06888021B2
公开(公告)日：2005-05-03
申请号：US09879456
申请日：2001-06-13
申请人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
发明人： Melanie Brunner , Arnd Böttcher , Boris Breitscheidel , Klaus Halbritter , Jochem Henkelmann , Lucien Thil , Rolf Pinkos
IPC分类号： B01J23/46 , C07B61/00 , C07C51/36 , C07C61/08 , C07C61/09 , C07C67/303 , C07C69/75 , C08K5/12 , C07C69/74 , C07C69/66 , C08K5/09
CPC分类号： C08K5/12 , C07C51/36 , C07C67/303 , C07C69/75 , C07C2601/14 , C07C61/09
摘要： A process for producing plasticizers in which a phthalic acid having the CAS Nos. 111381-89-6, 111381-90-9, 111381-91-0, 68515-44-6, 68515-45-7 and 3648-20-7, the formed plasticizers and a method of increasing the plasticity of a plastic product.
摘要翻译：一种生产增塑剂的方法，其中具有CAS号111381-89-6,111381-90-9,111381-91-0,68515-44-6,68515-45-7和3648-20-7的邻苯二甲酸，形成的增塑剂和增加塑料制品的可塑性的方法。

7. 发明授权

US06042799A Coproduction of acetylene and hydrocyanic acid from acrylonitrile 失效
标题翻译：从丙烯腈生产乙炔和氢氰酸
公开(公告)号：US06042799A
公开(公告)日：2000-03-28
申请号：US34274
申请日：1998-03-04
申请人： Klaus Halbritter , Michael Henningsen , Manfred Julius , Wolf Stegmaier
发明人： Klaus Halbritter , Michael Henningsen , Manfred Julius , Wolf Stegmaier
IPC分类号： C01C3/02 , C07C1/32 , C01C3/08 , C07C2/00 , C07C2/02
CPC分类号： C01C3/0245 , C07C1/323
摘要： In the process for preparing acetylene and hydrocyanic acid by pyrolyzing acrylonitrile in a reactor, the gaseous reaction products of the pyrolysis are quenched down to less than 100.degree. C. immediately, advantageously within seconds, preferably within .ltoreq.1 s, of leaving the pyrolysis zone.
摘要翻译：在通过在反应器中热解丙烯腈制备乙炔和氢氰酸的方法中，将热分解的气态反应产物立即下降至小于100℃，有利地在几秒钟内，优选在<1s内离开热解区。

8. 发明授权

US4806670A Preparation of .alpha.-substituted .beta.-dicarbonyl and .beta.-cyanocarbonyl compounds 失效
标题翻译： α-取代的β-二羰基和β-氰基羰基化合物的制备
公开(公告)号：US4806670A
公开(公告)日：1989-02-21
申请号：US45420
申请日：1987-05-04
申请人： Walter Gramlich , Klaus Halbritter , Gerd Heilen
发明人： Walter Gramlich , Klaus Halbritter , Gerd Heilen
IPC分类号： C07C69/34 , B01J23/00 , B01J27/00 , C07B31/00 , C07B37/00 , C07B37/04 , C07B61/00 , C07C45/00 , C07C45/48 , C07C45/73 , C07C49/12 , C07C49/403 , C07C67/00 , C07C69/38 , C07C69/716 , C07C253/00 , C07C255/04 , C07C255/17 , C07C255/19 , C07C255/32 , C07C255/45 , C07C255/46 , C07C120/00
CPC分类号： C07C255/00 , C07C45/73 , C07C49/12 , C07C49/403
摘要： .beta.-Dicarbonyl and .beta.-cyanocarbonyl compounds ##STR1## where R.sup.1 is alkyl of 1-20 carbons, X is --COR.sup.2, Y is --COOR.sup.3, --COR.sup.3 or --CN, and R.sup.2 and R.sup.3 are each C.sub.1 -C.sub.10 -alkyl, are prepared from R.sup.1 --CHO (II) and X--CH.sub.2 --Y (III) by reaction in the presence of a condensation catalyst, hydrogen and a hydrogenation catalyst, using an oxide or phosphate of Mg, Al, Ti, Zn or a rare earth metal as the condensation catalyst.
摘要翻译： β-二羰基和β-氰基羰基化合物其中R 1是1-20个碳的烷基，X是-COR 2，Y是-COOR 3，-COR 3或-CN，R 2和R 3各自是C 1 -C 10 - 烷基，通过使用Mg，Al，Ti，Zn或稀有金属的氧化物或磷酸盐在缩合催化剂，氢气和氢化催化剂的存在下反应，由R1-CHO（II）和X-CH2-Y（III）地球金属作为缩合催化剂。

9. 发明授权

US4521602A Preparation of pyridines or pyrroles from .alpha.,.omega.-dinitriles 失效
标题翻译：从α，ω-二腈制备吡啶或吡咯
公开(公告)号：US4521602A
公开(公告)日：1985-06-04
申请号：US502522
申请日：1983-06-09
申请人： Walter Rebafka , Gerd Heilen , Klaus Halbritter , Wolfgang Franzischka
发明人： Walter Rebafka , Gerd Heilen , Klaus Halbritter , Wolfgang Franzischka
IPC分类号： C07D211/12 , B01J23/00 , B01J27/00 , C07D207/32 , C07D207/323 , C07D213/08 , C07D211/10
CPC分类号： C07D207/323 , C07D213/08
摘要： A pyridine or a pyrrole is obtained in a one-stage process directly from an .alpha.,.omega.-dinitrile of appropriate carbon skeleton when the dinitrile is reacted in the gas phase with hydrogen, over a hydrogenation catalyst.
摘要翻译：当二腈在气相中与氢气在氢化催化剂上反应时，直接从适当碳骨架的α，ω-二腈一步法获得吡啶或吡咯。

10. 发明授权

US4831166A Preparation of alpha-substituted upsilon-butyrolactones 失效
标题翻译：制备α-取代的上升 - 丁内酯
公开(公告)号：US4831166A
公开(公告)日：1989-05-16
申请号：US47131
申请日：1987-05-08
申请人： Heinz Eckhardt , Walter Gramlich , Walter Best , Klaus Halbritter
发明人： Heinz Eckhardt , Walter Gramlich , Walter Best , Klaus Halbritter
IPC分类号： B01J27/10 , B01J27/18 , B01J27/232 , B01J31/02 , C07B61/00 , C07D307/33 , C07D315/00
CPC分类号： C07D307/33 , C07D315/00
摘要： .gamma.-butyrolactones of the general formula I ##STR1## where R.sup.1 is hydrogen or alkyl of 1 to 4 carbon atoms which may be substituted by lower alkoxy or acyloxy and R.sup.2 is hydrogen or straight-chain or branched alkyl which is unsubstituted or substituted by a functional group or is aryl, are prepared by reacting an alkylene oxide of the general formula II ##STR2## with an acylacetate of the general formla III ##STR3## where R.sup.1 and R.sup.2 have the above meanings and R.sup.3 and R.sup.4 are each alkyl of 1 to 6 carbon atoms or aryl, and R.sup.4 may furthermore be hydrogen, in the presence of a catalyst at elevated temperatures, by a process in which the reaction is carried out in the presence of an alkali metal halide, of an ammonium halide, preferably a quaternary ammonium halide, of a phosphonium halide, of an alkali metal phosphate or of an alkali metal carbonate at from 20.degree. to 200.degree. C. and under from 1 to 50 bar.
摘要翻译：通式I（I）的γ-丁内酯，其中R 1是氢或可以被低级烷氧基或酰氧基取代的具有1至4个碳原子的烷基，R 2是氢或未被取代的直链或支链烷基，被官能团取代或是芳基，通过使通式II（II）的烯化氧与一般形式III（III）的酰基乙酸酯反应制备，其中R 1和R 2具有上述含义， R 3和R 4各自为1至6个碳原子的烷基或芳基，并且R 4还可以在催化剂存在下在升高的温度下通过其中反应在碱金属卤化物卤化铵，碱金属磷酸盐或碱金属碳酸盐的卤化铵，优选季铵卤化物，在20至200℃和1至50巴之间。

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