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1. 发明授权

US4743702A Preparation of aliphatic dinitriles 失效
标题翻译：脂肪族二腈的制备
公开(公告)号：US4743702A
公开(公告)日：1988-05-10
申请号：US839161
申请日：1986-03-13
申请人： Wolfgang Hoelderich , Hubert Lendle , Peter Magnussen , Hans Leitner , Jost H. Manegold , Wolfgang Leitenberger
发明人： Wolfgang Hoelderich , Hubert Lendle , Peter Magnussen , Hans Leitner , Jost H. Manegold , Wolfgang Leitenberger
IPC分类号： C07B61/00 , B01J27/00 , B01J29/04 , C07C67/00 , C07C253/00 , C07C253/22 , C07C255/04 , C07C120/08
CPC分类号： C07C253/22
摘要： Aliphatic dinitriles are prepared by reacting aliphatic dicarboxylic acids with ammonia in excess at from 200.degree. to 500.degree. C. in the presence of zeolites as catalysts.
摘要翻译：在沸石作为催化剂存在下，在200-500℃下使脂族二羧酸与氨过量反应制备脂族二腈。

2. 发明授权

US5616784A Thermal cleavage of carbamic esters 失效
标题翻译：氨基甲酸酯的热裂解
公开(公告)号：US5616784A
公开(公告)日：1997-04-01
申请号：US570250
申请日：1995-12-11
申请人： Hans V. Schwarz , Andreas Otterbach , Otto Mattner , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Roland Minges
发明人： Hans V. Schwarz , Andreas Otterbach , Otto Mattner , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Roland Minges
IPC分类号： B01J6/00 , C07C263/04 , C07C265/00 , C07C271/06 , C07C45/00
CPC分类号： C07C263/04
摘要： In a reactor for the thermal cleavage of mono- and polyfunctional carbamic esters into the corresponding isocyanates and the hydroxyl component in the liquid phase, the geometry of the reactor, defined by the degassing area in relation to the volume and the arrangement of the heating surfaces, permits cleavage in a two-phase mixture which has a volumetric gas content of more than 50%.
摘要翻译：在用于将单官能和多官能的氨基甲酸酯热裂解成相应的异氰酸酯和液相中的羟基组分的反应器中，由相对于体积的排气面积和加热表面的排列限定的反应器的几何形状允许在体积气体含量大于50％的两相混合物中断裂。

3. 发明授权

US4360695A Continuous preparation of adiptic acid 失效
标题翻译：连续制备二十二酸
公开(公告)号：US4360695A
公开(公告)日：1982-11-23
申请号：US337684
申请日：1982-01-07
申请人： Peter Magnussen , Volker Schumacher , Wolfgang Gebert , Heinrich Reitz , Werner Praetorius
发明人： Peter Magnussen , Volker Schumacher , Wolfgang Gebert , Heinrich Reitz , Werner Praetorius
IPC分类号： C07C55/14 , B01J31/00 , B01J31/10 , C07B61/00 , C07C27/02 , C07C51/00 , C07C51/09 , C07C67/00 , B01D3/14
CPC分类号： C07C51/09 , Y10S203/20
摘要： In a process for the continuous preparation of adipic acid by hydrolysis of C.sub.1 -C.sub.4 -alkyl adipates with water at an elevated temperature in the presence of a strongly acidic ion exchanger, the improvement that the esters and excess water are fed to the middle section of a column, reaction mixture is taken off at a plurality of trays of the column below the feed point, passed over a strongly acidic ion exchanger and recycled, alkanols or alkanol/water mixtures are taken off at the top of the column and an aqueous solution of adipic acid is taken off at the bottom of the column.
摘要翻译：在强酸性离子交换剂存在下，通过在高温下水解C1-C4烷基己二酸酯连续制备己二酸的方法中，将酯和过量的水加入到中间部分柱子，反应混合物在进料点下方的塔的多个塔板中取出，通过强酸性离子交换剂并再循环，链烷醇或链烷醇/水混合物在塔顶馏去，水溶液的己二酸在塔的底部取出。

4. 发明授权

US4298748A Preparation of 2-imidazolines 失效
标题翻译： 2-咪唑啉的制备
公开(公告)号：US4298748A
公开(公告)日：1981-11-03
申请号：US97814
申请日：1979-11-27
申请人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius , Hans J. Szymanski
发明人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius , Hans J. Szymanski
IPC分类号： C07D233/06 , C07D233/08 , C07D233/10
CPC分类号： C07D233/10 , C07D233/06
摘要： A novel process for the preparation of 2-imidazolines by reacting 1,2-diamines with nitriles or carbonyl compounds in the gas phase at from 200.degree. to 450.degree. C. in the presence of an oxide or phosphate of a metal of group 3 or 4 of the periodic table and/or in the presence of silicon dioxide.The 2-imidazolines obtainable by the process of the invention are valuable starting materials for the preparation of dyes, crop protection agents and drugs.
摘要翻译：一种新型的制备2-咪唑啉的方法，该方法是在200-350℃的气相中，在二氧化碳或磷酸三烷基酯存在下，使1,2-二胺与腈或羰基化合物反应， 4和/或在二氧化硅存在下。通过本发明的方法可获得的2-咪唑啉是制备染料，作物保护剂和药物的有价值的起始原料。

5. 发明授权

US4163027A Working-up of reaction mixtures containing cyclohexanol and cyclohexanone 失效
标题翻译：含有环己醇和环己酮的反应混合物的处理
公开(公告)号：US4163027A
公开(公告)日：1979-07-31
申请号：US844985
申请日：1977-10-25
申请人： Peter Magnussen , Guenter Herrmann , Elmar Frommer
发明人： Peter Magnussen , Guenter Herrmann , Elmar Frommer
IPC分类号： C07C20060101 , C07C27/12 , C07C27/26 , C07C35/08 , C07C49/303 , C07C49/403 , C07C29/24 , C07C45/24
摘要： A process for working up reaction mixtures containing cyclohexanol and cyclohexanone, which have been obtained by oxidizing cyclohexane with molecular oxygen or gases containing molecular oxygen, in the liquid phase, at from 130.degree. to 200.degree. C. under a pressure of from 5 to 25 bars, working-up being effected by treatment with aqueous solutions of an alkali metal hydroxide and/or alkali metal carbonate in two stages, the fresh aqueous alkali metal hydroxide and/or alkali metal carbonate solution being fed to the second stage and the separated-off spent alkali being brought into contact with fresh reaction mixture in the first stage. The treatment in the first stage is carried out in the presence of inert gases and the inert gases are separated off before the second stage.
摘要翻译：在液相中在130〜200℃下，在5〜25的压力下，通过用分子氧或含有分子氧的气体氧化环己烷而得到的含有环己醇和环己酮的反应混合物的方法通过两步处理碱金属氢氧化物和/或碱金属碳酸盐的水溶液进行后处理，将新鲜的碱金属氢氧化物和/或碱金属碳酸盐水溶液进料到第二阶段，在第一阶段使废碱与新鲜的反应混合物接触。第一阶段的处理是在惰性气体的存在下进行的，惰性气体在第二阶段之前被分离出来。

6. 发明授权

US5386053A Multistep, continuous preparation of organic polyisocyanates 失效
标题翻译：多步连续制备有机多异氰酸酯
公开(公告)号：US5386053A
公开(公告)日：1995-01-31
申请号：US28009
申请日：1993-03-08
申请人： Andreas Otterbach , Hans V. Schwarz , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Otto Mattner
发明人： Andreas Otterbach , Hans V. Schwarz , Franz Merger , Wolfgang Schwarz , Eckhardt Brandt , Peter Magnussen , Otto Mattner
IPC分类号： C08G18/72 , C07C263/00 , C07C263/04 , C07C263/20 , C07C265/00 , C07C265/04 , C07C265/10 , C07C265/14 , C08G71/00 , C08G71/04 , C07C263/06
CPC分类号： C07C263/04 , C07C2101/14 , Y02P20/582
摘要： A multistep process for the continuous preparation of organic polyisocyanates, preferably aliphatic or cycloaliphatic diisocyanates, by reacting the corresponding organic polyamines with carbonic acid derivatives and alcohols to give monomeric polyurethanes and pyrolyzing the latter involves separating the resultant polyisocyanates and worthless residues in certain reaction steps and recycling the reusable by-products into earlier steps.
摘要翻译：通过使相应的有机多胺与碳酸衍生物和醇反应得到单体聚氨酯并热解后者，连续制备有机多异氰酸酯，优选脂族或环脂族二异氰酸酯的多步骤方法包括在某些反应步骤中分离得到的多异氰酸酯和无价值残基，将可重复使用的副产品回收到早期步骤中。

7. 发明授权

US4340744A Preparation of imidazoles 失效
标题翻译：咪唑的制备
公开(公告)号：US4340744A
公开(公告)日：1982-07-20
申请号：US242012
申请日：1981-03-09
申请人： Helmut Schwarz , Toni Dockner , Uwe Kempe , Herbert Krug , Werner Praetorius , Peter Magnussen , Ewald Gallei , Erich Fehr
发明人： Helmut Schwarz , Toni Dockner , Uwe Kempe , Herbert Krug , Werner Praetorius , Peter Magnussen , Ewald Gallei , Erich Fehr
IPC分类号： B01J23/00 , B01J27/00 , B01J27/19 , C07B61/00 , C07D233/54 , C07D233/56 , C07D233/58 , C07D231/12
CPC分类号： C07D233/54
摘要： Imidazoles are prepared by reacting 2-imidazolines at from 250.degree. to 500.degree. C. in the presence of molybdenum oxide and nickel oxide and/or cobalt oxide and aluminum oxide, silicon dioxide and/or silicates as catalysts.The imidazoles obtainable by the process according to the invention are valuable starting materials for the preparation of dyes, crop protection agents, textile auxiliaries, catalysts for polyurethanes and epoxy resins, surfactants and drugs, for example the corresponding nitroimidazoles.
摘要翻译：在氧化钼和氧化镍和/或氧化钴和氧化铝，二氧化硅和/或硅酸盐作为催化剂的存在下，在250-500℃下使2-咪唑啉反应制备咪唑。通过本发明的方法可获得的咪唑是用于制备染料，作物保护剂，纺织助剂，聚氨酯和环氧树脂的催化剂，表面活性剂和药物，例如相应的硝基咪唑的有价值的起始材料。

8. 发明授权

US4861895A Treatment of aqueous solutions obtained in the carbalkoxylation of olefinically unsaturated compounds 失效
标题翻译：处理在烯属不饱和化合物的碳烷基化反应中获得的水溶液
公开(公告)号：US4861895A
公开(公告)日：1989-08-29
申请号：US77630
申请日：1987-07-24
申请人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
发明人： Werner Bertleff , Robert Maerkl , Peter Magnussen , Gebhard Kuehn , Peter Stops
IPC分类号： C07C67/38 , C07C67/00 , C07C67/48 , C07C67/54 , C07C67/60 , C07C69/02 , C07C69/34 , C07C69/44 , C07C69/533 , C07D211/70 , C07D213/06
CPC分类号： C07C67/38 , C07C67/60
摘要： Aqueous solutions which are obtained in the carbalkoxylation of olefinically unsaturated compounds and contain heterocyclic aromatic nitrogen bases, their transformation products and lower fatty acids and/or their salts are treated by a process in which (a) the aqueous solution is heated to 150.degree.-300.degree. C. under from 10 to 300 bar and (b) heterocyclic aromatic nitrogen bases which are formed again from the transformation products are then separated off.
摘要翻译：通过以下方法处理在烯属不饱和化合物的碳烷基氧化中含有杂环芳族氮碱，它们的转化产物和低级脂肪酸和/或其盐的水溶液，其中（a）将水溶液加热至150℃， 300℃，10-300巴，（b）从转化产物再次形成的杂环芳基氮碱分离出来。

9. 发明授权

US4340745A Preparation of 2-imidazolines 失效
标题翻译： 2-咪唑啉的制备
公开(公告)号：US4340745A
公开(公告)日：1982-07-20
申请号：US242011
申请日：1981-03-09
申请人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius
发明人： Toni Dockner , Uwe Kempe , Herbert Krug , Peter Magnussen , Werner Praetorius
IPC分类号： B01J23/00 , C07D233/06 , C07D231/06
CPC分类号： C07D233/06
摘要： 2-Imidazolines are prepared by reacting N,N'-diformyl-1,2-diamines in the gas phase at 200.degree.-350.degree. C., in the presence of certain amounts of an inert gas, over zinc oxide of a particular structure or over a mixture of this zinc oxide and aluminum oxide, as the catalyst.The 2-imidazolines obtainable by the process according to the invention are valuable starting materials for the preparation of dyes, crop protection agents and drugs.
摘要翻译： 2-甲苯胺是通过使N，N'-二甲酰基-1,2-二胺在气相中在200-350℃下，在特定结构的氧化锌存在下，在一定量的惰性气体存在下，或者该氧化锌和氧化铝的混合物，作为催化剂。通过根据本发明的方法可获得的2-咪唑啉是制备染料，作物保护剂和药物的有价值的原料。

10. 发明授权

US4171451A Manufacture of butanedicarboxylic acid esters 失效
标题翻译：丁二羧酸酯的制造
公开(公告)号：US4171451A
公开(公告)日：1979-10-16
申请号：US883216
申请日：1978-03-03
申请人： Rudolf Kummer , Heinz-Walter Schneider , Rolf Platz , Peter Magnussen , Franz-Josef Weiss
发明人： Rudolf Kummer , Heinz-Walter Schneider , Rolf Platz , Peter Magnussen , Franz-Josef Weiss
IPC分类号： C07C69/44 , B01J31/00 , C07B61/00 , C07C67/38 , C07C69/34
CPC分类号： C07C69/34 , C07C67/38
摘要： A process for the manufacture of butanedicarboxylic acid esters, wherein(a) an aqueous cobalt salt solution is treated, at from 50.degree. to 200.degree. C. and under a pressure of from 50 to 500 bars, with excess carbon monoxide and hydrogen in the presence of active charcoal laden with cobalt carbonyl,(b) the resulting aqueous solution of cobalt carbonyl hydride is extracted with butadiene or with a hydrocarbon mixture containing butadiene and the aqueous phase is separated off,(c) the butadiene, or butadiene-hydrocarbon mixture, containing cobalt carbonyl hydride, cobalt carbonyl and butenyl-cobalt tricarbonyl is reacted with carbon monoxide and an excess of an alkanol of 1 to 4 carbon atoms in the presence of from 0.5 to 2 moles, per mole of butadiene, of a tertiary nitrogen base having a pK.sub.a of from 3 to 11, at from 80.degree. to 150.degree. C. under a pressure of from 300 to 2,000 bars, and(d) the resulting reaction mixture is freed from the tertiary nitrogen base contained therein, except for from 0.1 to 0.3 mole per mole of pentenoic acid ester, and from excess hydrocarbons, the pentenoic acid ester remaining in the reaction mixture is reacted with carbon monoxide and an excess of an alkanol of 1 to 4 carbon atoms at from 140.degree. to 200.degree. C. and under pressures of from 100 to 400 bars in the presence of the amounts of cobalt carbonyl and tertiary nitrogen base contained in the reaction mixture, and excess alkanol and free nitrogen base are then distilled off, and(e) the reaction mixture which remains, and which contains cobalt catalyst, the butanedicarboxylic acid ester and by-products is treated with an oxidizing agent in an aqueous acid medium and the mixture is separated into an organic phase, from which the butanedicarboxylic acid ester is isolated by distillation, and into an aqueous phase containing cobalt salts.Butanedicarboxylic acid esters may be used for the manufacture of adipic acid and of nylons.
摘要翻译：一种制备丁烷二羧酸酯的方法，其中（A）在50至200℃和50至500巴的压力下处理苛性钴盐溶液，其中过量的一氧化碳和氢气在（B）碳酸氢盐的结晶水溶液是用丁二烯或含有二丁烯和水相的烃混合物分离的，（C）丁二烯或二苯乙烯混合物，含有碳酸氢二乙酯，碳酸氢钾和二苯乙酮三溴化硼与一氧化碳反应，另有1至4个碳原子的碱金属在0.5至2摩尔浓度范围内反应，每次可以达到丁二烯，碱性氮在300至2,000巴的压力下具有3至11，80至150℃的PKa，以及（D）结合反应混合物来自含有其的碱性氮碱，除F 或从0.1至0.3毫升的硝酸酯和超级碳氢化合物，反应混合物中的硝酸酯反应在一氧化碳和超过1至4个碳原子的碱性物质在140°至200°的条件下反应在反应混合物中所含的羰基钴和叔氮碱的量存在下，在100-400巴的压力下，然后蒸出过量的链烷醇和游离氮碱，和（E）反应混合物剩余的，其中含有钴催化剂，溴化苹果酸酯和副产物与氧化剂在酸性介质中进行处理，并且混合物分离成有机相，其中通过蒸馏分离所述溴化乙酸酯，和进入含有钴酸盐的水相。

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