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1. 发明申请

US20090117358A1 Extruded Polymer Foams Containing Brominated Fatty Acid-Based Flame Retardant Additives 失效
标题翻译：含有溴化脂肪酸阻燃添加剂的挤出聚合物泡沫
公开(公告)号：US20090117358A1
公开(公告)日：2009-05-07
申请号：US12247818
申请日：2008-10-08
申请人： William J. Kruper, JR. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
发明人： William J. Kruper, JR. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
IPC分类号： C08J9/06 , C08K5/095 , B32B5/20
CPC分类号： C08J9/0019 , C08J2201/03 , C08J2325/04 , C08K5/02 , C08K5/095 , Y10T82/16737 , Y10T82/16885 , Y10T82/2552 , Y10T82/2561 , Y10T82/2562 , C08L25/04
摘要： Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
摘要翻译：使用溴化脂肪酸，溴化脂肪酸的酯，酰胺或酯 - 酰胺，一种或多种溴化脂肪酸的甘油酯或作为FR添加剂的聚合的溴化脂肪酸制备挤出的聚合物泡沫。溴化FR添加剂在挤出温度下出人意料地稳定，并且对泡沫具有优异的阻燃性。

2. 发明申请

US20120077894A1 EXTRUDED POLYMER FOAMS CONTAINING BROMINATED FATTY ACID-BASED FLAME RETARDANT ADDITIVES 有权
标题翻译：含有基于脂肪酸的阻燃剂添加剂的挤出聚合物
公开(公告)号：US20120077894A1
公开(公告)日：2012-03-29
申请号：US13307728
申请日：2011-11-30
申请人： William J. Kruper, JR. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
发明人： William J. Kruper, JR. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
IPC分类号： C08K5/11 , C08K5/098
CPC分类号： C08J9/0019 , C08J2201/03 , C08J2325/04 , C08K5/02 , C08K5/095 , Y10T82/16737 , Y10T82/16885 , Y10T82/2552 , Y10T82/2561 , Y10T82/2562 , C08L25/04
摘要： Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
摘要翻译：使用溴化脂肪酸，溴化脂肪酸的酯，酰胺或酯 - 酰胺，一种或多种溴化脂肪酸的甘油酯或作为FR添加剂的聚合的溴化脂肪酸制备挤出的聚合物泡沫。溴化FR添加剂在挤出温度下出人意料地稳定，并且对泡沫具有优异的阻燃性。

3. 发明授权

US08080592B2 Extruded polymer foams containing brominated fatty acid-based flame retardant additives 失效
标题翻译：含有溴化脂肪酸类阻燃添加剂的挤出聚合物泡沫
公开(公告)号：US08080592B2
公开(公告)日：2011-12-20
申请号：US12247818
申请日：2008-10-08
申请人： William J. Kruper, Jr. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
发明人： William J. Kruper, Jr. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
IPC分类号： C08J9/06
CPC分类号： C08J9/0019 , C08J2201/03 , C08J2325/04 , C08K5/02 , C08K5/095 , Y10T82/16737 , Y10T82/16885 , Y10T82/2552 , Y10T82/2561 , Y10T82/2562 , C08L25/04
摘要： Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
摘要翻译：使用溴化脂肪酸，溴化脂肪酸的酯，酰胺或酯 - 酰胺，一种或多种溴化脂肪酸的甘油酯或作为FR添加剂的聚合的溴化脂肪酸制备挤出的聚合物泡沫。溴化FR添加剂在挤出温度下出人意料地稳定，并且对泡沫具有优异的阻燃性。

4. 发明授权

US08324288B2 Extruded polymer foams containing brominated fatty acid-based flame retardant additives 有权
标题翻译：含有溴化脂肪酸类阻燃添加剂的挤出聚合物泡沫
公开(公告)号：US08324288B2
公开(公告)日：2012-12-04
申请号：US13307728
申请日：2011-11-30
申请人： William J. Kruper, Jr. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
发明人： William J. Kruper, Jr. , David R. Arrowsmith , Duane R. Romer , Bruce M. Bell , William G. Stobby , Inken Beulich , Zenon Lysenko , John Gordon-Duffy , Chau V. Vo
IPC分类号： C08J9/06
CPC分类号： C08J9/0019 , C08J2201/03 , C08J2325/04 , C08K5/02 , C08K5/095 , Y10T82/16737 , Y10T82/16885 , Y10T82/2552 , Y10T82/2561 , Y10T82/2562 , C08L25/04
摘要： Extruded polymer foams are prepared using brominated fatty acids, an ester, amide or ester-amide of a brominated fatty acid, a glyceride of one or more brominated fatty acids, or a polymerized brominated fatty acid as an FR additive. The brominated FR additives unexpectedly are stable at the extrusion temperatures, and provide excellent flame retardancy to the foams.
摘要翻译：使用溴化脂肪酸，溴化脂肪酸的酯，酰胺或酯 - 酰胺，一种或多种溴化脂肪酸的甘油酯或作为FR添加剂的聚合的溴化脂肪酸制备挤出的聚合物泡沫。溴化FR添加剂在挤出温度下出人意料地稳定，并且对泡沫具有优异的阻燃性。

5. 发明申请

US20100292355A1 ALKENYL-AROMATIC FOAM HAVING GOOD SURFACE QUALITY, HIGH THERMAL INSULATING PROPERTIES AND LOW DENSITY 审中-公开
标题翻译：具有良好表面质量的ALKENYL-AROMATIC泡沫，高热绝缘性能和低密度
公开(公告)号：US20100292355A1
公开(公告)日：2010-11-18
申请号：US12596178
申请日：2008-04-18
申请人： Mark A. Barger , Charles A. Berglund , Clive P. Bosnyak , Stephanie A. Donati , John Gordon-Duffy , Warren H. Griffin , Ing-Feng Hu , Jean-Francois Koenig , Simon Lee , Creston D. Shmidt , Roy E. Smith , Chau V. Vo
发明人： Mark A. Barger , Charles A. Berglund , Clive P. Bosnyak , Stephanie A. Donati , John Gordon-Duffy , Warren H. Griffin , Ing-Feng Hu , Jean-Francois Koenig , Simon Lee , Creston D. Shmidt , Roy E. Smith , Chau V. Vo
IPC分类号： C08J9/04 , C08J9/00
CPC分类号： C08J9/146 , C08J9/149 , C08J2325/04
摘要： Prepare an alkenyl-aromatic foam having good surface quality, high thermal insulating properties and low density using an extrusion method by expanding a foamable polymer composition of an alkenyl-aromatic polymer composition containing less than 20 weight-percent covalently bonded halogens and having a polydispersity of less than 2.5 and a water solubility greater than 0.09 moles per kilogram and 2.2 moles per kilogram or less at 130 degrees Celsius and 101 kilopascals pressure and 0.8-2 moles per kilogram of a blowing agent containing 0.4 moles per kilogram or more of a chlorine-free fluorinated blowing agents and water at a concentration of at least 0.22 moles per kilogram; wherein moles per kilogram are relative to kilograms of alkenyl-aromatic polymer. The resulting foam has a density of 64 kilograms per cubic meter or less and a thermal conductivity of 32 milliwatts per meter-Kelvin or less after 180 days.
摘要翻译：使用挤出方法制备具有良好表面质量，高绝热性和低密度的烯基 - 芳族泡沫体，其通过使包含少于20重量％共价键合的卤素的烯基 - 芳族聚合物组合物的可发泡聚合物组合物膨胀并具有多分散性小于2.5，水溶解度大于0.09摩尔/千克，在130摄氏度和101千帕斯卡压力下为2.2摩尔/千克或更小，每千克含有0.4摩尔/千克或更多氯气的发泡剂为0.8-2摩尔，游离氟化发泡剂和浓度至少为0.22摩尔/千克的水; 其中每千克的摩尔数相对于千克的烯基 - 芳族聚合物。生成的泡沫体的密度为64千克/立方米或更小，并且180天后的热导率为32毫瓦/米 - 开尔文或更低。

6. 发明申请

US20110275730A1 POLYMER FOAM WITH LOW BROMINE CONTENT 有权
标题翻译：具有低溴含量的聚合物泡沫
公开(公告)号：US20110275730A1
公开(公告)日：2011-11-10
申请号：US13139406
申请日：2010-01-05
申请人： John Gordon-Duffy , David R. Arrowsmith , Simon P. Lee , Ralph Schmidt
发明人： John Gordon-Duffy , David R. Arrowsmith , Simon P. Lee , Ralph Schmidt
IPC分类号： C08J9/228 , C08L63/04
CPC分类号： C08J9/14 , C08J9/0019 , C08J9/0061 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/142 , C08J2325/02 , C08J2461/00
摘要： Prepare extruded polymer foam comprising at least 50 weight-percent alkenyl aromatic polymer, a brominated flame retardant providing 0.8 to 1.4 weight percent bromide, 0.05 to 0.5 weight-percent hydrobromic acid scavenger, at least 1.5 weight-percent graphite and less than 0.1 weight-percent C—C and O—O labile organic compounds using a blowing agent composition comprising at least 0.3 weight-parts per 100 weight parts polymer and that consists of blowing agents having an ozone depletion potential of zero and a global warming potential that is less than 1000.
摘要翻译：制备包含至少50重量％的链烯基芳族聚合物的挤出聚合物泡沫体，溴化阻燃剂，其提供0.8-1.4重量％的溴化物，0.05-0.5重量％的氢溴酸清除剂，至少1.5重量％的石墨和小于0.1重量％百分比C-C和O-O不稳定有机化合物，其使用包含至少0.3重量份/ 100重量份聚合物的发泡剂组合物，其由臭氧消耗潜能为零的发泡剂和小于 1000。

7. 发明授权

US09493624B2 Polymer foam with low bromine content 有权
标题翻译：低溴含量的聚合物泡沫
公开(公告)号：US09493624B2
公开(公告)日：2016-11-15
申请号：US13139406
申请日：2010-01-05
申请人： John Gordon-Duffy , David R. Arrowsmith , Simon P. Lee , Ralph Schmidt
发明人： John Gordon-Duffy , David R. Arrowsmith , Simon P. Lee , Ralph Schmidt
IPC分类号： C08J9/14 , C08J9/00
CPC分类号： C08J9/14 , C08J9/0019 , C08J9/0061 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/142 , C08J2325/02 , C08J2461/00
摘要： Prepare extruded polymer foam comprising at least 50 weight-percent alkenyl aromatic polymer, a brominated flame retardant providing 0.8 to 1.4 weight percent bromide, 0.05 to 0.5 weight-percent hydrobromic acid scavenger, at least 1.5 weight-percent graphite and less than 0.1 weight-percent C—C and O—O labile organic compounds using a blowing agent composition comprising at least 0.3 weight-parts per 100 weight parts polymer and that consists of blowing agents having an ozone depletion potential of zero and a global warming potential that is less than 1000.
摘要翻译：制备包含至少50重量％的链烯基芳族聚合物的挤出聚合物泡沫体，溴化阻燃剂，其提供0.8-1.4重量％的溴化物，0.05-0.5重量％的氢溴酸清除剂，至少1.5重量％的石墨和小于0.1重量％百分比C-C和O-O不稳定有机化合物，其使用包含至少0.3重量份/ 100重量份聚合物的发泡剂组合物，其由臭氧消耗潜能为零的发泡剂和小于 1000。

8. 发明授权

US08785510B2 Alkenyl aromatic foam with low solubility hydrofluorocarbon 有权
标题翻译：具有低溶解度氢氟碳化物的烯基芳香族泡沫
公开(公告)号：US08785510B2
公开(公告)日：2014-07-22
申请号：US12531518
申请日：2008-03-13
申请人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin , John Gordon-Duffy , Lawrence S. Hood , Roy E. Smith
发明人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin , John Gordon-Duffy , Lawrence S. Hood , Roy E. Smith
IPC分类号： C08J9/00 , C08J9/12 , C08J9/14
CPC分类号： C08J9/127 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/142 , C08J2203/144 , C08J2325/06 , C08J2325/08 , C08J2325/12
摘要： Prepare a closed-cell alkenyl aromatic polymer foam by an extrusion process using a blowing agent composition that contains at least 30 weight-percent of the chlorine-free hydrofluorocarbon blowing agent such that the foam has a density of 48 kilograms per cubic meter or less, contains more than 50 weight-percent styrene-acrylonitrile copolymer based on total polymer weight and at least eight weight-percent of a chlorine-free hydrofluorocarbon blowing agent that has a lower solubility in polystyrene than 1,1,2,2-tetrafluoroethane (HFC-134).
摘要翻译：通过使用包含至少30重量％的无氯氢氟烃发泡剂的发泡剂组合物的挤出方法制备闭孔烯基芳族聚合物泡沫体，使得泡沫体的密度为48千克/立方米或更小，含有基于总聚合物重量的超过50重量％的苯乙烯 - 丙烯腈共聚物和至少8重量％的无氯氢氟烃发泡剂，其在聚苯乙烯中的溶解度低于1,1,2,2-四氟乙烷（HFC -134）。

9. 发明申请

US20100099783A1 ALKENYL AROMATIC FOAM WITH LOW SOLUBILITY HYDROFLUOROCARBON 有权
标题翻译： ALKENYL具有低溶解度氢氟碳化合物的芳香泡沫
公开(公告)号：US20100099783A1
公开(公告)日：2010-04-22
申请号：US12531518
申请日：2008-03-13
申请人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin , John Gordon-Duffy , Lawrence S. Hood , Roy E. Smith
发明人： Van-Chau Vo , Richard T. Fox , Warren H. Griffin , John Gordon-Duffy , Lawrence S. Hood , Roy E. Smith
IPC分类号： C08J9/00
CPC分类号： C08J9/127 , C08J9/144 , C08J9/146 , C08J9/149 , C08J2201/03 , C08J2203/06 , C08J2203/14 , C08J2203/142 , C08J2203/144 , C08J2325/06 , C08J2325/08 , C08J2325/12
摘要： Prepare a closed-cell alkenyl aromatic polymer foam by an extrusion process using a blowing agent composition that contains at least 30 weight-percent of the chlorine-free hydrofluorocarbon blowing agent such that the foam has a density of 48 kilograms per cubic meter or less, contains more than 50 weight-percent styrene-acrylonitrile copolymer based on total polymer weight and at least eight weight-percent of a chlorine-free hydrofluorocarbon blowing agent that has a lower solubility in polystyrene than 1,1,2,2-tetrafluoroethane (HFC-134).
摘要翻译：通过使用含有至少30重量％的无氯氢氟烃发泡剂的发泡剂组合物的挤出方法制备闭孔烯基芳族聚合物泡沫体，使得泡沫体的密度为48千克/立方米或更小，含有基于总聚合物重量的超过50重量％的苯乙烯 - 丙烯腈共聚物和至少8重量％的无氯氢氟烃发泡剂，其在聚苯乙烯中的溶解度低于1,1,2,2-四氟乙烷（HFC -134）。

10. 发明申请

US20120074347A1 INFRARED ATTENUATED POLYMERIC FOAM INSULATION WITH FLAME RETARDANT PERFORMANCE 审中-公开
标题翻译：具有阻燃性能的红外衰减聚合物泡沫绝缘
公开(公告)号：US20120074347A1
公开(公告)日：2012-03-29
申请号：US13318365
申请日：2010-06-01
申请人： John Gordon-Duffy
发明人： John Gordon-Duffy
IPC分类号： E04B1/78 , C08J9/35
CPC分类号： C08J9/0019 , C08J9/0023 , C08J9/0066 , C08J9/127 , C08J2201/03 , C08J2203/06 , C08J2203/12 , C08J2203/14 , C08J2325/04
摘要： Prepare a polymer foam by extrusion foaming a foamable thermoplastic polymer composition using a blowing agent containing 3 to 5 weight-percent (wt %) carbon dioxide, up to 5 wt % alcohol having 2-3 carbons, up to 0.7 wt % water and up to 2.5 weight-percent iso-butane; wherein the blowing agent comprises at least 0.1 wt % of water and/or alcohol having 2-3 carbons; two to five wt % infrared attenuating agent selected from petcokes and 100-700 nanometers size carbon black; 2.5 to 3.5 wt % brominated flame retardant; and at least 0.1 wt % of epoxy stabilizer wherein the resulting polymeric foam is characterized by having a density in a range of 30 to 37 kilograms per cubic meter, a unimodal cell size distribution, an average cell size of 0.15 to 0.4 millimeters, a thermal conductivity in a range of 28 to 35 milliwatts per meter*Kelvin and that passes the German B2 fire test.
摘要翻译：通过使用含有3至5重量百分比（wt％）二氧化碳，至多5重量％的具有2-3个碳原子的醇，至多0.7重量％的水及以上的发泡剂将发泡性热塑性聚合物组合物挤出发泡来制备聚合物泡沫体至2.5重量％的异丁烷; 其中所述发泡剂包含至少0.1重量％的具有2-3个碳原子的水和/或醇; 二至五重量％的红外衰减剂，选自petcoke和100-700纳米尺寸的炭黑; 2.5〜3.5wt％溴化阻燃剂; 和至少0.1重量％的环氧稳定剂，其中所得聚合物泡沫的特征在于密度在30至37千克/立方米的范围内，单峰电池尺寸分布，平均电池尺寸为0.15至0.4毫米，热电导率在28至35毫瓦每米*开尔文，并通过德国B2火测试。

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