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1. 发明授权

US4560791A Synthesis of triconjugated dienones and intermediates used in said process 失效
标题翻译：在所述方法中使用的三氯联二烯酮和中间体的合成
公开(公告)号：US4560791A
公开(公告)日：1985-12-24
申请号：US551480
申请日：1983-11-14
申请人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
发明人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
IPC分类号： C07C45/67 , C07C49/203 , C07C69/157 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07C45/673 , C07C45/676 , C07C49/203 , C07C67/293 , C07C67/297 , C07C69/63 , C11B9/0015 , C11B9/0061
摘要： Described is a process for preparing triconjugated dienones defined according to the structure: ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.8 alkyl, phenyl or phenyl methyl and wherein R.sub.2 represents hydrogen or C.sub.1 -C.sub.5 lower alkyl; and wherein the wavy lines are indicative of a "cis" or a "trans" juxtaposition of the R.sub.2, methyl, acyl or vinyl moieties about one or both of the carbon-carbon double bonds which process involves the reaction of an acyl halide having the structure: ##STR2## (wherein X represents chloro) with a substituted or unsubstituted prenyl ester having the structure: ##STR3## wherein R.sub.3 represents C.sub.1 -C.sub.5 alkyl in the presence of an aluminum chloride catalyst and a methylene dichloride solvent in order to form the novel intermediate genus defined according to the structure: ##STR4## then dehydrohalogenating the compound defined according to the structure: ##STR5## using an alkali metal carbonate and a dimethylformamide solvent in order to form the novel compound genus having the structure: ##STR6## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; and then dehydroacyloxylating the compound having the structure: ##STR7## in order to form the compound having the structure: ##STR8## the dehydroacyloxylation step taking place in the presence of an akali metal carbonate and dimethylformamide solvent.
摘要翻译：描述了根据以下结构定义的三结合双酮的方法：其中R 1表示C 1 -C 8烷基，苯基或苯基甲基，并且其中R 2表示氢或C 1 -C 5低级烷基; 并且其中波浪线表示R2，甲基，酰基或乙烯基部分在一个或两个碳 - 碳双键上的“顺式”或“反式”并置，该方法涉及具有结构：其中X表示氯，具有以下结构的取代或未取代的异戊二烯基酯：其中R 3表示C 1 -C 5烷基，在氯化铝催化剂和二氯甲烷溶剂的存在下，形成根据以下结构定义的新型中间体：然后使用碱金属碳酸盐和二甲基甲酰胺溶剂将根据结构定义的化合物脱卤化氢，以形成具有以下结构的新颖化合物：其中虚线中的一条代表碳 - 碳双键，另一条虚线表示碳 - 碳单键; 然后将具有以下结构的化合物脱氢酰化氧化：为了形成具有以下结构的化合物：在碱金属碳酸盐和二甲基甲酰胺溶剂存在下进行脱氢甲酰氧基化步骤。

2. 发明授权

US4467820A Synthesis of triconjugated dienones and novel intermediates used in said process 失效
标题翻译：三氯联二烯酮的合成和所述方法中使用的新型中间体
公开(公告)号：US4467820A
公开(公告)日：1984-08-28
申请号：US551551
申请日：1983-11-14
申请人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
发明人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
IPC分类号： C07C45/67 , C07C49/203 , C11B9/00 , C11D3/50 , A24B3/12
CPC分类号： C11D3/50 , C07C45/673 , C07C45/676 , C07C49/203 , C07C67/293 , C07C67/297 , C11B9/0015 , C11B9/0061
摘要： Described is a process for preparing triconjugated dienones defined according to the structure: ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.8 alkyl, phenyl or phenyl methyl and wherein R.sub.2 represents hydrogen or C.sub.1 -C.sub.5 lower alkyl; and wherein the wavy lines are indicative of a "Cis" or a "trans" juxtaposition of the R.sub.2, methyl, acyl or vinyl moieties about one or both of the carbon-carbon double bonds which process involves the reaction of an acyl halide having the structure: ##STR2## with a substituted or unsubstituted prenyl ester having the structure: ##STR3## wherein R.sub.3 represents C.sub.1 -C.sub.5 alkyl in the presence of an aluminum chloride catalyst and a methylene dichloride solvent in order to form the novel intermediate genus defined according to the structure: ##STR4## then dehydrohalogenating the compound defined according to the structure: ##STR5## using an alkali metal carbonate and a dimethylformamide solvent in order to form the novel compound genus having the structure: ##STR6## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; and then dehydroacyloxylating the compound having the structure: ##STR7## in order to form the compound having the structure: ##STR8## the dehydroacyloxylation step taking place in the presence of an alkali metal carbonate and dimethylformamide solvent.
摘要翻译：描述了根据以下结构定义的三结合双酮的方法：其中R 1表示C 1 -C 8烷基，苯基或苯基甲基，并且其中R 2表示氢或C 1 -C 5低级烷基; 并且其中波浪线表示R2，甲基，酰基或乙烯基部分在碳 - 碳双键中的一个或两个上的“Cis”或“反式”并置，该方法涉及具有结构：具有以下结构的取代或未取代的异戊二烯基酯：其中R 3在氯化铝催化剂和二氯甲烷溶剂的存在下代表C 1 -C 5烷基，以形成根据结构：然后使用碱金属碳酸盐和二甲基甲酰胺溶剂将根据结构定义的化合物脱卤化氢，以形成具有以下结构的新型化合物：其中虚线之一代表碳 - 碳双键，虚线中的另一个代表碳 - 碳单键; 然后将具有以下结构的化合物脱氢酰化氧化：为了形成具有以下结构的化合物：在碱金属碳酸盐和二甲基甲酰胺溶剂的存在下进行脱氢甲酰氧基化步骤。

3. 发明授权

US4560802A Synthesis of triconjugated dienones and novel intermediates used in said process 失效
标题翻译：三氯联二烯酮的合成和所述方法中使用的新型中间体
公开(公告)号：US4560802A
公开(公告)日：1985-12-24
申请号：US620086
申请日：1984-06-13
申请人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
发明人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
IPC分类号： C07C45/67 , C07C49/203 , C11B9/00 , C11D3/50 , C07C45/65
CPC分类号： C11D3/50 , C07C45/673 , C07C45/676 , C07C49/203 , C07C67/293 , C07C67/297 , C11B9/0015 , C11B9/0061
摘要： Described is a process for preparing triconjugated dienones defined according to the structure: ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.8 alkyl, phenyl or phenyl methyl and wherein R.sub.2 represents hydrogen or C.sub.1 -C.sub.5 lower alkyl; and wherein the wavy lines are indicative of a "cis" or a "trans" juxtaposition of the R.sub.2, methyl, acyl or vinyl moieties about one or both of the carbon-carbon double bonds which process involves the reaction of an acyl halide having the structure: ##STR2## (wherein X represents chloro) with a substituted or unsubstituted prenyl ester having the structure: ##STR3## wherein R.sub.3 represents C.sub.1 -C.sub.5 alkyl in the presence of an aluminum chloride catalyst and a methylene dichloride solvent in order to form the novel intermediate genus defined according to the structure: ##STR4## then dehydrohalogenating the compound defined according to the structure: ##STR5## using an alkali metal carbonate and a dimethylformamide solvent in order to form the novel compound genus having the structure: ##STR6## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; and then dehydrocyloxylating the compound having the structure: ##STR7## in order to form the compound having the structure: ##STR8## the dehydroacyloxylation step taking place in the presence of an alkali metal carbonate and dimethylformamide solvent.
摘要翻译：描述了根据以下结构定义的三结合双酮的方法：其中R 1表示C 1 -C 8烷基，苯基或苯基甲基，并且其中R 2表示氢或C 1 -C 5低级烷基; 并且其中波浪线表示R2，甲基，酰基或乙烯基部分在一个或两个碳 - 碳双键上的“顺式”或“反式”并置，该方法涉及具有结构：其中X表示氯，具有以下结构的取代或未取代的异戊二烯基酯：其中R 3表示C 1 -C 5烷基，在氯化铝催化剂和二氯甲烷溶剂的存在下，形成根据以下结构定义的新型中间体：然后使用碱金属碳酸盐和二甲基甲酰胺溶剂将根据结构定义的化合物脱卤化氢，以形成具有以下结构的新颖化合物：其中虚线中的一条代表碳 - 碳双键，另一条虚线表示碳 - 碳单键; 然后脱氢甲基化具有以下结构的化合物：以形成具有以下结构的化合物：在碱金属碳酸盐和二甲基甲酰胺溶剂的存在下进行脱氢甲酰化步骤。

4. 发明授权

US4623749A Synthesis of triconjugated dienones and novel intermediates used in said process 失效
标题翻译：三氯联二烯酮的合成和所述方法中使用的新型中间体
公开(公告)号：US4623749A
公开(公告)日：1986-11-18
申请号：US620163
申请日：1984-08-17
申请人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
发明人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
IPC分类号： C07C45/67 , C07C49/203 , C07C69/145 , C07C69/157 , C11B9/00 , C11D3/50
CPC分类号： C11D3/50 , C07C45/673 , C07C45/676 , C07C49/203 , C07C67/293 , C11B9/0015 , C11B9/0061
摘要： Described is a process for preparing triconjugated dienones defined according to the structure: ##STR1## wherein R.sub.1 represents C.sub.1 -C.sub.8 alkyl, phenyl or phenyl methyl and wherein R.sub.2 represents hydrogen or C.sub.1 -C.sub.5 lower alkyl; and wherein the wavy lines are indicative of a "cis" or a "trans" juxtaposition of the R.sub.2, methyl, acyl or vinyl moieties about one or both of the carbon-carbon double bonds which process involves the reaction of an acyl halide with a substituted or unsubstituted prenyl ester having the structure: ##STR2## wherein R.sub.3 represents C.sub.1 -C.sub.5 alkyl in the presence of an aluminum chloride catalyst and a methylene dichloride solvent in order to form a halogen-ester intermediate defined according to the structure: ##STR3## then dehydrohalogenating said halogen-ester intermediate using an alkali metal carbonate and a dimethylformamide solvent in order to form a ketoester having the structure: ##STR4## wherein one of the dashed lines represents a carbon-carbon double bond and the other of the dashed lines represents a carbon-carbon single bond; and then dehydroacyloxylating the ketoester in the presence of an alkali metal carbonate and dimethylformamide solvent in order to form the triconjugated dienone.
摘要翻译：描述了根据以下结构定义的三结合双酮的方法：其中R 1表示C 1 -C 8烷基，苯基或苯基甲基，并且其中R 2表示氢或C 1 -C 5低级烷基; 并且其中波浪线表示R2，甲基，酰基或乙烯基部分在一个或两个碳 - 碳双键上的“顺式”或“反式”并置，该方法涉及酰卤与具有以下结构的取代或未取代的异戊二烯基酯：其中R 3在氯化铝催化剂和二氯甲烷溶剂的存在下代表C 1 -C 5烷基，以形成根据以下结构定义的卤素 - 酯中间体：然后使用碱金属碳酸盐和二甲基甲酰胺溶剂将所述卤代酯中间体脱卤化氢，以形成具有以下结构的酮酯：其中虚线中的一条代表碳 - 碳双键，另一条虚线表示碳 - 碳单键; 然后在碱金属碳酸盐和二甲基甲酰胺溶剂的存在下，使酮酯脱羟基酰化，以形成三羟甲基封端的二烯酮。

5. 发明授权

US4504398A Process for augmenting or enhancing the aroma of perfumed articles by adding thereto triconjugated dienones 失效
标题翻译：通过向其中加入三环酮二烯酮来增强或增强香料制品香气的方法
公开(公告)号：US4504398A
公开(公告)日：1985-03-12
申请号：US551482
申请日：1983-11-14
申请人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
发明人： William J. Evers , Gilbert Stork , Braja D. Mookherjee , Howard H. Heinsohn, Jr.
IPC分类号： C07C45/67 , C07C49/203 , C11B9/00 , C11D3/50 , D06M13/20
CPC分类号： C11D3/50 , C07C45/673 , C07C45/676 , C07C49/203 , C07C67/293 , C07C67/297 , C11B9/0015 , C11B9/0061
摘要： Described is a process for augmenting or enhancing the aroma of a perfumed article which is a solid or liquid anionic, cationic, nonionic or zwitterionic detergent or a fabric softener composition or a dryer-added fabric softener article comprising the step of adding to said perfumed article at least one compound having a structure selected from the group consisting of: ##STR1##
摘要翻译：描述了一种用于增强或增强作为固体或液体阴离子，阳离子，非离子或两性离子洗涤剂或织物柔软剂组合物或干衣剂添加的织物柔软剂制品的香料的香气的方法，其包括将所述香料至少一种具有选自以下的结构的化合物：（i）和（iii）（ii）

6. 发明授权

US4255293A 2,6,6-Trimethyl-.alpha.-(iso-propenyl-1-cyclohexene-1-methanol and 1,3 cyclohexadiene-1-methanol 失效
标题翻译： 2,6,6-三甲基-α-（异丙烯基-1-环己烯-1-甲醇和1,3环己二烯-1-甲醇
公开(公告)号：US4255293A
公开(公告)日：1981-03-10
申请号：US119859
申请日：1980-02-08
申请人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
发明人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
IPC分类号： A23L27/20 , A23L27/29 , A24B15/34 , C07C29/40 , C07C33/14 , C07C403/00 , C11B9/00
CPC分类号： C11B9/0034 , A23L27/203 , A23L27/29 , A24B15/34 , C07C29/40 , C07C33/14 , C07C403/08 , C07C2101/16
摘要： Described are processes for augmenting or enhancing the aroma of perfume compositions or colognes, comprising the step of adding in an aroma augmenting or enhancing quantity to a perfume base or a cologne base, one or more compounds defined according to the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 are hydrogen; wherein the dashed line represents a carbon-carbon double bond or a carbon-carbon single bond with the proviso that when R.sub.1 is hydrogen, the dashed line represents a carbon-carbon double bond.
摘要翻译：描述了用于增强或增强香料组合物或古龙水香气的方法，其包括将香味增强或增强量添加到香料基料或古龙水碱中的步骤，一种或多种根据通用结构定义的化合物：其中R 1，R 2或R 3中的一个为甲基，R 1，R 2和R 3中的另外两个为氢; 其中虚线表示碳 - 碳双键或碳 - 碳单键，条件是当R1为氢时，虚线表示碳 - 碳双键。

7. 发明授权

US4278098A 2,6,6-Trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols and -1,3-cyclohexadiene-1-methanols and organoleptic uses thereof 失效
标题翻译： 2,6,6-三甲基-α-（异）丙烯-1-环己烯-1-甲醇和1,3-环己二烯-1-甲醇及其感官用途
公开(公告)号：US4278098A
公开(公告)日：1981-07-14
申请号：US119858
申请日：1980-02-08
申请人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
发明人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
IPC分类号： A24B15/30 , A24B15/34 , C07C29/09 , C07C29/40 , C07C29/68 , C07C33/14 , C11B9/00 , A24B3/12 , A24B15/36
CPC分类号： C11B9/0034 , A24B15/34 , C07C29/09 , C07C29/40 , C07C29/68 , C07C33/14 , C07C403/08 , C07B2200/09 , C07C2101/16
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.Addition of one or more of the 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanols or -1,3-cyclohexadiene-1-methanols of our invention to consumable materials is indicated to produce:A. In foodstuffs, chewing gums, toothpastes and medicinal products, sweet, camphoraceous, damascenone, raspberry-like, raspberry juice-like, rosey, woody/ionone-like, oriental, tobacco-like, tea-like, grape-like, fruity and ionone-like aromas and flavor notes;B. In perfumes, colognes and perfumed articles, leathery, hay, woody, mustard, minty, spicey (clove) and pulegone-like aromas and hay/tobacco and honey ionone-like topnotes with safronal-like nuances; andC. In tobaccos and tobacco flavors, a sweet-musty, hay-tobacco-like, fruity-raspberry, ionone-like aroma prior to smoking and a fruity tobacco-like, Virginia tobacco-like aroma on smoking both in the main stream and in the side stream.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品风味和香气，吸烟烟草风味和香气以及香料和香料制品香气增强，增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-（异）丙烯基-1-环己烯-1-甲醇的食品，口香糖，牙膏，药用产品，吸烟烟草，香料和香料制品香气和/或调味材料，以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种：其中R 1，R 2或R 3中的一个为甲基，R 1，R 2和R 3中的另外两个为表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时，虚线是碳 - 碳双键。将本发明的一种或多种2,6,6-三甲基-α-（异）丙烯-1-环己烯-1-甲醇或-1,3-环己二烯-1-甲醇添加到消耗材料中被指示产生：A.在食品，口香糖，牙膏和药用产品中，甜，樟脑，大马士革，覆盆子样，覆盆子汁，玫瑰，木/紫罗兰酮样，东方，烟草状，茶状，葡萄状，水果和紫罗兰酮样香气和风味香气; B.香水，古龙水和香水制品，革质，干草，木质，芥末，小茴香，香料（丁香）和香菇样香气和干草/烟草和蜂蜜类似紫罗兰酮的顶峰，具有丰富的细微差别; 在烟草和烟草香料中，在吸烟之前是一种甜味，干草烟样，果香 - 覆盆子，类胡萝卜素的香气，并且在主流中吸烟时具有类似烟草般的弗吉尼亚烟草样香气并在旁边的流。

8. 发明授权

US4275087A Flavoring with 2,6,6-trimethyl-.alpha.-propenyl-1,3-cyclohexadiene-1-methanol substances 失效
标题翻译：用2,6,6-三甲基-α-丙烯基-1,3-环己二烯-1-甲醇物质调味
公开(公告)号：US4275087A
公开(公告)日：1981-06-23
申请号：US120102
申请日：1980-02-08
申请人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
发明人： Richard A. Wilson , William L. Schreiber , Braja D. Mookherjee , Jacob Kiwala , Joaquin F. Vinals , Manfred H. Vock , Gilbert Stork , Frederick L. Schmitt
IPC分类号： A23L27/20 , A24B15/34 , C07C29/09 , C07C29/40 , C07C29/68 , C07C33/14 , C11B9/00 , A23L1/226 , A23L1/235
CPC分类号： C11B9/0034 , A24B15/34 , C07C29/09 , C07C29/40 , C07C29/68 , C07C33/14 , C07C403/08 , C07B2200/09 , C07C2101/16
摘要： Processes and compositions are described for use in foodstuff, chewing gum, toothpaste and medicinal product flavor and aroma, smoking tobacco flavor and aroma and perfume and perfumed article aroma augmenting, enhancing and imparting compositions; and as foodstuff, chewing gum, toothpaste, medicinal product, smoking tobacco, perfume and perfumed article aroma and/or flavor imparting materials of 2,6,6-trimethyl-.alpha.-(iso)propenyl-1-cyclohexene-1-methanol and -1,3-cyclohexadiene-1-methanol derivatives or one or more of their geometric or stereoisomers as defined by the generic structure: ##STR1## wherein one of R.sub.1, R.sub.2 or R.sub.3 is methyl and the other two of R.sub.1, R.sub.2 and R.sub.3 represents hydrogen; the dashed line is a carbon-carbon double bond or a carbon-carbon single bond; with the proviso that when R.sub.1 is hydrogen, the dashed line is a carbon-carbon double bond.
摘要翻译：描述了用于食品，口香糖，牙膏和药用产品风味和香气，吸烟烟草风味和香气以及香料和香料制品香气增强，增强和赋予组合物的方法和组合物; 以及2,6,6-三甲基-α-（异）丙烯基-1-环己烯-1-甲醇的食品，口香糖，牙膏，药用产品，吸烟烟草，香料和香料制品香气和/或调味材料，以及 -1,3-环己二烯-1-甲醇衍生物或其一般结构定义的其几何或立体异构体中的一种或多种：其中R 1，R 2或R 3中的一个为甲基，R 1，R 2和R 3中的另外两个为表示氢; 虚线是碳 - 碳双键或碳 - 碳单键; 条件是当R1是氢时，虚线是碳 - 碳双键。

9. 发明授权

US4224352A Pear flavoring containing a mixture of 2- and 3-cyclotetradecen-1-ones 失效
标题翻译：含有2-和3-环十四碳烯-1-酮的混合物的梨调味剂
公开(公告)号：US4224352A
公开(公告)日：1980-09-23
申请号：US52829
申请日：1979-06-27
申请人： Braja D. Mookherjee , Robert W. Trenkle , Manfred H. Vock , Domenick Luccarelli, Jr. , Frederick L. Schmitt , Gilbert Stork , Timothy MacDonald , Arthur L. Liberman
发明人： Braja D. Mookherjee , Robert W. Trenkle , Manfred H. Vock , Domenick Luccarelli, Jr. , Frederick L. Schmitt , Gilbert Stork , Timothy MacDonald , Arthur L. Liberman
IPC分类号： A23L27/20 , A23L27/29 , C07C45/56 , C07C49/587 , C11B9/00 , A23L1/235
CPC分类号： C11B9/0038 , A23L27/203 , A23L27/29 , C07C45/562 , C07C49/587
摘要： Described is a pear flavoring containing isomer mixtures of 2- and 3-cyclotetradecen-1-ones having the structures: ##STR1##
摘要翻译：描述了含有具有以下结构的2-和3-环十四碳烯-1-酮的异构体混合物的梨调味剂：

10. 发明授权

US4183965A 2- and 3-Cyclotetradecen-1-ones as bitterness depressants 失效
标题翻译： 2-和3-环十四碳烯-1-酮作为苦味抑制剂
公开(公告)号：US4183965A
公开(公告)日：1980-01-15
申请号：US973093
申请日：1978-12-26
申请人： Braja D. Mookherjee , Robert W. Trenkle , Manfred H. Vock , Domenick Luccarelli, Jr. , Frederick L. Schmitt , Gilbert Stork , Timothy MacDonald , Arthur L. Liberman
发明人： Braja D. Mookherjee , Robert W. Trenkle , Manfred H. Vock , Domenick Luccarelli, Jr. , Frederick L. Schmitt , Gilbert Stork , Timothy MacDonald , Arthur L. Liberman
IPC分类号： A23F5/46 , A23G3/00 , A23G3/36 , A23L27/20 , A23L27/30 , C07C45/56 , C07C49/587 , C11B9/00 , A23F1/04 , A23L1/22 , A23L1/226 , C12C3/00
CPC分类号： A23G3/36 , A23F5/465 , A23L27/203 , A23L27/30 , C07C45/562 , C07C49/587 , C11B9/0038
摘要： Processes and compositions are described for the use in foodstuff flavor and aroma and perfume and perfumed article aroma augmenting, modifying, altering and enhancing compositions and as foodstuffs, chewing gum, toothpaste, medicinal product, perfume and perfumed article aroma imparting materials of specific isomer and isomer mixtures of 2- and 3-cyclotetradecen-1-ones having the structures: ##STR1## or mixtures of same or mixtures of such 2- and 3-cyclotetradecen-1-ones with cyclotetradecanone having the structure: ##STR2## or cyclododecanone having the structure: ##STR3## Addition of said 2- and 3-cyclotetradecen-1-ones or mixtures is indicated to produce:(a) In food flavorings, a sweet, brown sugar and musky aroma and sweet and musky flavor characteristics (useful for flavor augmentation or enhancement in pear, blackberry, apricot and peach flavors and as a bitterness depressant for such foodstuffs, flavor adjuvants and beverages as black coffee; and(b) In perfumes and perfumed articles, a sweet, musk aroma and exaltone-like, scorched linen, waxy and rooty nuances.
摘要翻译：描述了用于食品香料和香料和香料和香料制品香气增强，改性，改变和增强组合物以及作为食品，口香糖，牙膏，药用产品，香料和香料赋予特定异构体的芳香赋予材料的方法和组合物，具有以下结构的2-和3-环十四碳烯-1-酮的异构体混合物：或其混合物或这些2-和3-环十四碳烯-1-酮与环十四烷酮的混合物，其具有以下结构：具有以下结构：结构：所述2-和3-环十四碳烯-1-酮或其混合物的添加表明产生：（a）在食品香料中，甜味，红糖和麝香的香气和甜味和麝香风味特征（可用于梨，黑莓，杏子和桃子香味的香味增强或增强，以及作为黑咖啡的这类食品，风味佐剂和饮料的苦味抑制剂;和（b）在香水和香料中一种甜美的麝香，麝香香气和高雅的香味，烧焦的亚麻，蜡质和根深蒂固的细微差别。

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