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1. 发明授权

US06723292B2 Stripper and a stripping process for removing the flue gas carried by regenerated catalyst 有权
标题翻译：汽提器和用于除去由再生催化剂携带的烟道气的汽提过程
公开(公告)号：US06723292B2
公开(公告)日：2004-04-20
申请号：US09795496
申请日：2001-03-01
申请人： Weimin Lu , Xieqing Wang , Xiaoxiang Zhong , Songnian Li
发明人： Weimin Lu , Xieqing Wang , Xiaoxiang Zhong , Songnian Li
IPC分类号： B01J818
CPC分类号： B01D3/24 , B01D3/38 , B01J8/085 , B01J8/125 , B01J2208/0084
摘要： A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom. The removed flue gas and the excessive steam enter the degassing pipe through the opening part of the degassing pipe under each set of inner annular baffles and leave the stripper from the top under the action of steam or air from the horizontal pipe. Using this stripper can minimize the amount of the flue gas carried by regenerated catalyst.
摘要翻译：汽提器和汽提过程，用于除去由再生催化剂携带的烟气。圆柱形汽提器主要包括在纵向轴线处的脱气管，与脱气管的下端连接的水平管，沿着垂直方向排列配置的几组内环形挡板和外环形挡板。内环形挡板固定在脱气管上，外环形挡板固定在气缸内壁上。脱气管在每组内环形挡板下面都有孔。再生催化剂从上部进入汽提器，与来自环形蒸汽导管的蒸汽进行逆流和交叉接触，汽提的再生催化剂从底部离开汽提塔。去除的烟气和过量蒸汽通过每组内环形挡板下的脱气管的开口部分进入脱气管，并在蒸汽或空气的作用下从顶部离开脱水器。使用该汽提器可以使再生催化剂携带的烟道气的量最小化。

2. 发明授权

US06939823B2 Stripper and a stripping process for removing the flue gas carried by regenerated catalyst 有权
标题翻译：汽提器和用于除去由再生催化剂携带的烟道气的汽提过程
公开(公告)号：US06939823B2
公开(公告)日：2005-09-06
申请号：US10767361
申请日：2004-01-29
申请人： Weimin Lu , Xieqing Wang , Xiaoxiang Zhong , Songnian Li
发明人： Weimin Lu , Xieqing Wang , Xiaoxiang Zhong , Songnian Li
IPC分类号： B01D3/24 , B01D3/38 , B01J8/08 , B01J8/12 , C10G11/18 , B01J8/18 , B01J8/34 , B01J38/06 , B01J38/12
CPC分类号： B01D3/24 , B01D3/38 , B01J8/085 , B01J8/125 , B01J2208/0084
摘要： A stripper and a stripping process for removing the flue gas carried by regenerated catalyst. A cylindrical stripper mainly comprises a degassing pipe at the longitudinal axis, a horizontal pipe connected with the lower end of the degassing pipe, several sets of inner annular baffles and outer annular baffles arranged in alternative arrangement along the vertical direction. Inner annular baffles are fixed on the degassing pipe, outer annular baffles are fixed on the inner wall of the cylinder. The degassing pipe has holes below each set of the inner annular baffles. The regenerated catalyst enters the stripper from the upper part, comes into a countercurrent and crosscurrent contact with steam from the annular steam conduit, and the stripped regenerated catalyst leaves the stripper from the bottom. The removed flue gas and the excessive steam enter the degassing pipe through the opening part of the degassing pipe under each set of inner annular baffles and leave the stripper from the top under the action of steam or air from the horizontal pipe. Using this stripper can minimize the amount of the flue gas carried by regenerated catalyst.
摘要翻译：汽提器和汽提过程，用于除去由再生催化剂携带的烟气。圆柱形汽提器主要包括在纵向轴线处的脱气管，与脱气管的下端连接的水平管，沿着垂直方向排列配置的几组内环形挡板和外环形挡板。内环形挡板固定在脱气管上，外环形挡板固定在气缸内壁上。脱气管在每组内环形挡板下面都有孔。再生催化剂从上部进入汽提器，与来自环形蒸汽导管的蒸汽进行逆流和交叉接触，汽提的再生催化剂从底部离开汽提塔。去除的烟气和过量蒸汽通过每组内环形挡板下的脱气管的开口部分进入脱气管，并在蒸汽或空气的作用下从顶部离开脱水器。使用该汽提器可以使再生催化剂携带的烟道气的量最小化。

3. 发明授权

US08778170B2 Process for producing light olefins and aromatics 有权
标题翻译：轻质烯烃和芳族化合物的制备方法
公开(公告)号：US08778170B2
公开(公告)日：2014-07-15
申请号：US10592166
申请日：2005-03-08
申请人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
发明人： Jun Long , Zhijian Da , Dadong Li , Xieqing Wang , Xingtian Shu , Jiushun Zhang , Hong Nie , Chaogang Xie , Zhigang Zhang , Wei Wang
IPC分类号： C10G51/02 , C10G51/04
CPC分类号： C10G69/04 , C07C4/06 , C07C5/05 , C07C5/11 , C10G11/18 , C10G69/02 , C10G69/06 , C10G69/14 , C10G2300/1044 , C10G2300/1055 , C10G2300/107 , C10G2300/1074 , C10G2300/1077 , C10G2300/301 , C10G2300/4006 , C10G2300/4018 , C10G2300/4093 , C10G2300/44 , C10G2300/807 , C10G2400/20 , C10G2400/30
摘要： A process for producing light olefins and aromatics, which comprises reacting a feedstock with a catalytic cracking catalyst in at least two reaction zones, wherein the reaction temperature of at least one reaction zone downstream of the first reaction zone is higher than that of the first reaction zone and its weight hourly space velocity is lower than that of the first reaction zone. The spent catalyst is separated, from the reaction product vapor, regenerated, and then returned to the reactor. The reaction product vapor is separated to obtain the desired products, light olefins and aromatics. This process efficiently produces light olefins such as propylene, ethylene, etc from heavy feedstocks, wherein the yield of propylene exceeds 20% by weight, and produces aromatics such as toluene, xylene, etc at the same time.
摘要翻译：一种用于生产轻质烯烃和芳族化合物的方法，其包括在至少两个反应区中使原料与催化裂化催化剂反应，其中第一反应区下游的至少一个反应区的反应温度高于第一反应的反应温度其重量时空速度低于第一反应区。将废催化剂与反应产物蒸气分离，再生，然后返回反应器。将反应产物蒸气分离以获得所需产物，轻质烯烃和芳族化合物。该方法从重质原料中有效地生产轻质烯烃如丙烯，乙烯等，其中丙烯的产率超过20重量％，同时产生芳烃如甲苯，二甲苯等。

4. 发明授权

US06261538B1 Series of water-insoluble polymeric quaternary phosphonium salt used for bactericides 有权
标题翻译：一系列用于杀菌剂的水不溶性聚合季鏻盐
公开(公告)号：US06261538B1
公开(公告)日：2001-07-17
申请号：US09179965
申请日：1998-10-28
申请人： Yongjun Chen , Xieqing Wang , Bengao Li
发明人： Yongjun Chen , Xieqing Wang , Bengao Li
IPC分类号： A61L904
CPC分类号： A01N57/34
摘要： Disclosed is a series of the water-insoluble polymeric quaternary phosphonium salt-type bactericides, which consists of as active bactericidal components an amino quaternary phosphonium salt, a quaternary ammonium group-containing quaternary phosphonium salt, an amino quaternary phosphonium salt-quaternay ammonium salt, or a quaternary ammonium salt-containing quaternary phosphonium salt and quaternary ammonium salt carried on a resin carrier which can be chloromethylated. Said bactericide series has rapid and highly effective bactericidal activity, and can be used repeatedly, and used widely for sterilizing and disinfecting various fluid media such as different industrial and domestic water and the like.
摘要翻译：公开了一系列水不溶性聚合季鏻盐型杀菌剂，其由作为活性杀菌成分的氨基季鏻盐，含季铵基季鏻盐，氨基季鏻盐 - 季铵盐，或含有季铵盐的季鏻盐和季铵盐，其载带在可被氯甲基化的树脂载体上。所述杀菌剂系列具有快速高效的杀菌活性，可重复使用，广泛用于各种流体介质如不同工业和家用水等的消毒和消毒。

5. 发明授权

US06342153B1 Pillared clay catalysts for heavy oil catalytic pyrolisis process and the preparation method thereof 有权
标题翻译：用于重油催化热解法的悬浮粘土催化剂及其制备方法
公开(公告)号：US06342153B1
公开(公告)日：2002-01-29
申请号：US09219119
申请日：1998-12-23
申请人： Jingjie Guan , Xieqing Wang , Zhiqing Yu , Zhengyu Chen , Qinglin Liu , Yi Liao
发明人： Jingjie Guan , Xieqing Wang , Zhiqing Yu , Zhengyu Chen , Qinglin Liu , Yi Liao
IPC分类号： C10G1102
CPC分类号： C10G11/04 , B01J20/10 , B01J20/12 , B01J29/005 , B01J29/049 , B01J29/084 , B01J29/40 , B01J2229/186 , B01J2229/42
摘要： Pillared clay catalysts for converting heavy oil or residual feedstock into maximum ethylene, propylene and butylene products comprises 30-75 wt % special pillared clays prepared by aluminum pillaring agents of high alkaline degree, 10-40 wt % inorganic oxide bonding agents, 0-30 wt % ZRP series high silicon zeolites with pentasil structure or Y-type zeolites, 0-10 wt % modified compositions of Mg, Al, K, P, Sn and polyethylene gycol, or 0-50 wt % Kaolinite matrix. The catalysts are prepared by mixing slurries, spray drying to form microspheric shapes, pillaring reaction and adding modified components. The catalysts have high catalytic activities, good light olefin selectivities and attrition resistance index. The products are suitable to be used as catalysts for hydrocarbon conversion, including CPP-catalyst for catalytic pyrolysis processes to convert heavy oil into ethylene and propylene, MIO-catalyst for yielding more isobutene and isoamylene products, and FCC-catalyst for yielding more gasoline and light cycle oil from heavy oil or residual feedstock, and also as adsorbents or catalyst carriers.
摘要翻译：用于将重油或残余原料转化为最大乙烯，丙烯和丁烯产品的柱状粘土催化剂包含由高碱度，10-40重量％无机氧化物粘合剂，0-30重量％的铝支撑剂制备的30-75重量％的特殊柱状粘土 wt％的具有pentasil结构的ZRP系列高硅沸石或Y型沸石，0-10wt％的Mg，Al，K，P，Sn和聚乙烯gycol的改性组合物，或0-50wt％的高岭石基质。催化剂通过混合浆料，喷雾干燥以形成微球形状，柱反应和加入改性成分来制备。催化剂具有高催化活性，良好的轻烯烃选择性和耐磨指数。该产品适用于烃转化催化剂，包括用于将重油转化为乙烯和丙烯的催化裂解方法的CPP催化剂，用于产生更多异丁烯和异戊烯产物的MIO催化剂，以及用于产生更多汽油的FCC催化剂来自重油或残余原料的轻循环油，以及作为吸附剂或催化剂载体。

6. 发明申请

US20050020867A1 Catalytic conversion process for producing light olefins with a high yield from petroleum hydrocarbons 有权
标题翻译：用于从石油烃生产高产率的轻质烯烃的催化转化方法
公开(公告)号：US20050020867A1
公开(公告)日：2005-01-27
申请号：US10878187
申请日：2004-06-29
申请人： Chaogang Xie , Jun Long , Jiushun Zhang , Zaiting Li , Xieqing Wang
发明人： Chaogang Xie , Jun Long , Jiushun Zhang , Zaiting Li , Xieqing Wang
IPC分类号： C07C4/06 , C10G11/18 , C07C4/02
CPC分类号： C07C4/06 , C07C2523/745 , C07C2523/755 , C07C2523/83 , C10G2400/20 , Y02P20/52 , Y02P20/584 , Y02P30/446 , C07C11/04 , C07C11/06
摘要： A catalytic conversion process for producing light olefins with a high yield from petroleum hydrocarbons, which comprises the steps of contacting a pre-heated petroleum hydrocarbons feedstock with a catalyst which comprises phosphorus and transition metal modified silica rich zeolite having a structure of pentasil in a riser or a fluidized bed reactor, and converting under the catalytic conversion conditions to produce reaction effluent and a spent catalyst, separating the resulted reaction effluent and spent catalyst, further separating said reaction effluent into liquid products and gaseous products comprising ethylene and propylene; stripping the spent catalyst by steam; regenerating the stripped catalyst by contacting the spent catalyst with oxygen-containing gas and burning off coke; and recycling the regenerated catalyst to reactor for reuse.
摘要翻译：一种用于从石油烃生产高产率的轻质烯烃的催化转化方法，其包括以下步骤：使预热的石油烃原料与催化剂接触，所述催化剂包含在提升管中具有pentasil结构的磷和过渡金属改性的富硅沸石或流化床反应器，并在催化转化条件下转化以产生反应流出物和废催化剂，分离所得反应流出物和废催化剂，进一步将所述反应流出物分离成液体产物和包含乙烯和丙烯的气态产物; 通过蒸汽汽提废催化剂; 通过使废催化剂与含氧气体接触并将焦炭烧掉来再生汽提催化剂; 并将再生的催化剂再循环到反应器中以便再利用。

7. 发明授权

US06495028B1 Catalytic conversion process for producing isobutane and isoparaffin-enriched gasoline 有权
标题翻译：用于生产异丁烷和富含异构烷烃的汽油的催化转化方法
公开(公告)号：US06495028B1
公开(公告)日：2002-12-17
申请号：US09556079
申请日：2000-04-21
申请人： Youhao Xu , Jiushun Zhang , Yinan Yang , Jun Long , Xieqing Wang , Zaiting Li , Raichi Zhang
发明人： Youhao Xu , Jiushun Zhang , Yinan Yang , Jun Long , Xieqing Wang , Zaiting Li , Raichi Zhang
IPC分类号： C10G5700
CPC分类号： C10G11/18
摘要： A process for catalytic conversion of hydrocarbon feedstock to produce isobutane and isoparaffin-enriched gasoline which comprises two different reactions, the preheated feedstock is contacted with hot regenerated catalyst in the lower part of a reactor with the result that catalytic cracking reaction takes place, and the mixture of vapors and the coke deposited catalyst are up-flowed and enter into a suitable reaction environment with the result that isomerization and hydrogen transfer reaction take place. The produced LPG has an isobutane content of about 20 wt % to about 40 wt % and the produced gasoline contains isoparaffin content of about 30 wt % to about 45 wt % and olefin content of less than 30 wt %. RON and MON of the gasoline are 90˜93 and 80˜84 respectively.
摘要翻译：催化转化烃原料以生产异丁烷和富含异构烷烃的汽油的方法，其包括两个不同的反应，预热的原料与反应器下部的热再生催化剂接触，结果发生催化裂化反应，蒸汽和焦炭沉积催化剂的混合物向上流动并进入合适的反应环境，结果发生异构化和氢转移反应。生产的LPG具有约20重量％至约40重量％的异丁烷含量，并且所生产的汽油含有约30重量％至约45重量％的异链烷烃含量和小于30重量％的烯烃含量。汽油的RON和MON分别为90〜93和80〜84。

8. 发明授权

US08349756B2 Noble metal-containing titanosilicate material and its preparation method 有权
标题翻译：贵金属含钛硅酸盐材料及其制备方法
公开(公告)号：US08349756B2
公开(公告)日：2013-01-08
申请号：US12594008
申请日：2008-03-27
申请人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
发明人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
IPC分类号： B01J29/89
CPC分类号： B01J35/002 , B01J23/38 , B01J23/40 , B01J23/44 , B01J29/89 , B01J35/0046 , B01J35/006 , B01J2229/20 , C07D301/08 , Y02P20/52
摘要： A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z
摘要翻译：一种含贵金属的钛硅酸盐材料，其特征在于，所述材料用xTiO2.1··O·SiO 2·yO·m·zE的氧化物形式表示，其中x为0.001-50.0; （y + z）为0.0001〜20.0，y / z <5。 E表示选自Ru，Rh，Pd，Re，Os，Ir，Pt，Ag和Au中的一种或多种贵金属; m是满足E的氧化态的数。所述材料的晶粒含有中空结构或下垂结构。在所述材料中，增强了贵金属和钛硅酸盐之间的协同效应。与现有技术相比，在氧化反应中，反应产物的选择性，催化活性和稳定性明显增加。通过丙烯环氧化制备环氧丙烷的反应。

9. 发明申请

US20100105542A1 NOBLE METAL-CONTAINING TITANOSILICATE MATERIAL AND ITS PREPARATION METHOD 有权
标题翻译：含金属的钛酸盐材料及其制备方法
公开(公告)号：US20100105542A1
公开(公告)日：2010-04-29
申请号：US12594008
申请日：2008-03-27
申请人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
发明人： Min Lin , Chunfeng Shi , Jun Long , Bin Zhu , Xingtian Shu , Xuhong Mu , Yibin Luo , Xieqing Wang , Yingchun Ru
IPC分类号： B01J29/068
CPC分类号： B01J35/002 , B01J23/38 , B01J23/40 , B01J23/44 , B01J29/89 , B01J35/0046 , B01J35/006 , B01J2229/20 , C07D301/08 , Y02P20/52
摘要： A noble metal-containing titanosilicate material, characterized in that said material is represented with the oxide form of xTiO2.100SiO2.yEOm.zE, wherein x ranges from 0.001 to 50.0; (y+z) ranges from 0.0001 to 20.0 and y/z
摘要翻译：一种含贵金属的钛硅酸盐材料，其特征在于，所述材料用xTiO2.1··O·SiO 2·yO·m·zE的氧化物形式表示，其中x为0.001-50.0; （y + z）为0.0001〜20.0，y / z <5。 E表示选自Ru，Rh，Pd，Re，Os，Ir，Pt，Ag和Au中的一种或多种贵金属; m是满足E的氧化态的数。所述材料的晶粒含有中空结构或下垂结构。在所述材料中，增强了贵金属和钛硅酸盐之间的协同效应。与现有技术相比，在氧化反应中，反应产物的选择性，催化活性和稳定性明显增加。通过丙烯环氧化制备环氧丙烷的反应。

10. 发明授权

US06475465B2 Titanium-silicalite molecular sieve and the method for its preparation 有权
标题翻译：钛 - 硅沸石分子筛及其制备方法
公开(公告)号：US06475465B2
公开(公告)日：2002-11-05
申请号：US09732100
申请日：2000-12-06
申请人： Min Lin , Xingtian Shu , Xieqing Wang , Bin Zhu
发明人： Min Lin , Xingtian Shu , Xieqing Wang , Bin Zhu
IPC分类号： C01B3700
CPC分类号： C01B37/005 , Y10S423/22
摘要： The present invention relates to a titanium-silicalite (TS-1) molecular sieve and the method for preparation of the same, wherein each crystallite of said titanium-silicalite molecular sieve has a hollow cavity with a radial length of 5-300 nm. The benzene adsorption capacity of the molecular sieve determined at 25° C. and P/P0=0.10 for 1 hour is at least 70 mg/g; and the method for preparation of said molecular sieve comprises an acid-treatment and then an organic-base treatment of the synthesized TS-1 molecular sieve, or only an organic-base treatment. The TS-1 molecular sieve of the present invention has a relatively high reactivity and activity stability in the catalytic oxidation.
摘要翻译：本发明涉及钛 - 硅沸石（TS-1）分子筛及其制备方法，其中所述钛 - 硅沸石分子筛的每个微晶具有径向长度为5-300nm的中空腔。在25℃和P / P0 = 0.10下测定1小时的分子筛的苯吸附能力为至少70mg / g; 并且所述分子筛的制备方法包括对所合成的TS-1分子筛进行酸处理，然后进行有机碱处理，或仅进行有机碱处理。本发明的TS-1分子筛在催化氧化中具有较高的反应活性和活性稳定性。

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