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    • 8. 发明授权
    • Polyether amide from polyalkylene glycol diamine and diacid mixture
    • 来自聚亚烷基二醇二胺和二酸混合物的聚醚酰胺
    • US5086162A
    • 1992-02-04
    • US506990
    • 1990-04-10
    • George P. SperanzaWei-Yang Su
    • George P. SperanzaWei-Yang Su
    • C08G69/26C08G69/28C08G69/40
    • C08G69/40
    • Novel polyether amides produced by reacting at least one polyalkylene glycol diamine with at least two dicarboxylic acids or esters thereof are described. The polyethylene glycol diamine has the formula NH.sub.2 --(CH.sub.2 CH.sub.2 O).sub.x --CH.sub.2 CH.sub.2 --NH.sub.2, where x ranges from 2 to 6, and at least one of the dicarboxylic acids is an aromatic discarboxylic acid. These novel polyether amides may have the formula: ##STR1## where each R and R' are independently an alkylene or arylene moiety having from 3 to 34 carbon atoms, where at least one R or R' is an arylene moiety, and where each x and y independently have the values noted. Suitable dicarboxylic acids include adipic acid, azelaic acid, sebacic acid, dodecanedioic acid, terephthalic acid, isophthalic acid, t-butyl isophthalic acid, and mixtures thereof. Suitable diamines include triethylene glycol diamine (JEFFAMINE.RTM. EDR-148 amine) and tetraethylene glycol diamine (JEFFAMINE.RTM. EDR-192 amine), among others. The resulting polyether amides are useful to make polymers, including fibers, with unusually good water absorbancy properties. The inventive methods successfully incorporate triethylene glycol diamine and aromatic dibasic acids, where this cannot be accomplished directly.
    • 描述了通过使至少一种聚亚烷基二醇二胺与至少两种二羧酸或其酯反应制备的新型聚醚酰胺。 聚乙二醇二胺具有式NH 2 - (CH 2 CH 2 O)x -CH 2 CH 2 -NH 2,其中x为2-6,并且至少一种二羧酸为芳族四羧酸。 这些新型聚醚酰胺可以具有下式:其中每个R和R'独立地是具有3至34个碳原子的亚烷基或亚芳基部分,其中至少一个R或R'是亚芳基部分 ,并且其中每个x和y独立地具有所述的值。 合适的二羧酸包括己二酸,壬二酸,癸二酸,十二烷二酸,对苯二甲酸,间苯二甲酸,叔丁基间苯二甲酸及其混合物。 合适的二胺包括三甘醇二胺(JEFFAMINE TM EDR-148胺)和四甘醇二胺(JEFFAMINE TM EDR-192胺)等。 所得聚醚酰胺可用于制备包括纤维在内的聚合物,具有非常好的吸水性。 本发明的方法成功地并入三甘醇二胺和芳族二元酸,其中这不能直接实现。