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    • 1. 发明授权
    • MOCVD of tungsten nitride thin films using W(CO)6 and NH3 for copper barrier applications
    • 使用W(CO)6和NH3作为铜屏障应用的氮化钨薄膜的MOCVD
    • US07094691B2
    • 2006-08-22
    • US10410029
    • 2003-04-09
    • Wei PanRobert BarrowcliffDavid R. EvansSheng Teng Hsu
    • Wei PanRobert BarrowcliffDavid R. EvansSheng Teng Hsu
    • H01L21/44
    • H01L21/76841C23C16/34
    • A method of forming a tungsten nitride thin film in an integrated circuit includes preparing a silicon substrate on a silicon wafer and placing the silicon wafer in a heatable chuck in a CVD vacuum chamber; placing a known quantity of a tungsten source in a variable-temperature bubbler to provide a gaseous tungsten source; setting the variable-temperature bubbler to a predetermined temperature; passing a carrier gas through the variable-temperature bubbler and carrying the gaseous tungsten source with the carrier gas into the CVD vacuum chamber; introducing a nitrogen-containing reactant gas into the CVD vacuum chamber; reacting the gaseous tungsten source and the nitrogen-containing reactant gas above the surface of the silicon wafer in a deposition process to deposit a WxNy thin film on the surface of the silicon wafer; and completing the integrated circuit containing the WxNy thin film.
    • 在集成电路中形成氮化钨薄膜的方法包括在硅晶片上制备硅衬底,并将硅晶片放置在CVD真空室中的可加热卡盘中; 将已知量的钨源放置在可变温度起泡器中以提供气态钨源; 将可变温度起泡器设定到预定温度; 使载气通过可变温度起泡器并将载气的气态钨源运送到CVD真空室中; 将含氮反应气体引入CVD真空室中; 在沉积过程中使气态钨源和硅晶片表面上方的含氮反应物气体反应,以沉积W 1 / N 2 N 2 O 3 硅晶片; 并完成包含W< N> N> Y<<<<薄膜的集成电路。
    • 5. 发明授权
    • Memory cell with an asymmetric crystalline structure
    • 具有不对称晶体结构的记忆单元
    • US07214583B2
    • 2007-05-08
    • US11130983
    • 2005-05-16
    • Sheng Teng HsuTingkai LiDavid R. EvansWei-Wei ZhuangWei Pan
    • Sheng Teng HsuTingkai LiDavid R. EvansWei-Wei ZhuangWei Pan
    • H01L21/8242
    • G11C13/0007G11C2213/31H01L45/04H01L45/1233H01L45/147H01L45/1608H01L45/1625
    • Asymmetrically structured memory cells and a fabrication method are provided. The method comprises: forming a bottom electrode; forming an electrical pulse various resistance (EPVR) first layer having a polycrystalline structure over the bottom electrode; forming an EPVR second layer adjacent the first layer, with a nano-crystalline or amorphous structure; and, forming a top electrode overlying the first and second EPVR layers. EPVR materials include CMR, high temperature super conductor (HTSC), or perovskite metal oxide materials. In one aspect, the EPVR first layer is deposited with a metalorganic spin coat (MOD) process at a temperature in the range between 550 and 700 degrees C. The EPVR second layer is formed at a temperature less than, or equal to the deposition temperature of the first layer. After a step of removing solvents, the MOD deposited EPVR second layer is formed at a temperature less than, or equal to the 550 degrees C.
    • 提供了非对称结构的存储单元和制造方法。 该方法包括:形成底部电极; 在底部电极上形成具有多晶结构的电脉冲各种电阻(EPVR)第一层; 用纳米结晶或无定形结构形成邻近第一层的EPVR第二层; 并且形成覆盖在第一和第二EPVR层上的顶部电极。 EPVR材料包括CMR,高温超导体(HTSC)或钙钛矿金属氧化物材料。 在一个方面,EPVR第一层在550-700℃的温度范围内用金属有机旋涂(MOD)工艺沉积.EPVR第二层是在小于或等于沉积温度 的第一层。 在除去溶剂的步骤之后,将MOD沉积的EPVR第二层在小于或等于550℃的温度下形成。
    • 10. 发明授权
    • Multilayered barrier metal thin-films
    • 多层阻隔金属薄膜
    • US08264081B2
    • 2012-09-11
    • US11311546
    • 2005-12-19
    • Wei PanYoshi OnoDavid R. EvansSheng Teng Hsu
    • Wei PanYoshi OnoDavid R. EvansSheng Teng Hsu
    • H01L23/48H01L23/52
    • H01L21/28562H01L21/76841H01L2221/1078
    • A multi-layered barrier metal thin film is deposited on a substrate by atomic layer chemical vapor deposition (ALCVD). The multi-layer film may comprise several different layers of a single chemical species, or several layers each of distinct or alternating chemical species. In a preferred embodiment, the multi-layer barrier thin film comprises a Tantalum Nitride layer on a substrate, with a Titanium Nitride layer deposited thereon. The thickness of the entire multi-layer film may be approximately fifty Angstroms. The film has superior film characteristics, such as anti-diffusion capability, low resistivity, high density, and step coverage, when compared to films deposited by conventional chemical vapor deposition (CVD). The multi-layered barrier metal thin film of the present invention has improved adhesion characteristics and is particularly suited for metallization of a Copper film thereon.
    • 通过原子层化学气相沉积(ALCVD)将多层阻挡金属薄膜沉积在衬底上。 多层膜可以包括单个化学物质的几个不同层,或者各个不同的或交替的化学物质的几个层。 在优选实施例中,多层阻挡薄膜包括在衬底上的氮化钽层,其上沉积有氮化钛层。 整个多层膜的厚度可以是大约50埃。 当与通过常规化学气相沉积(CVD)沉积的膜相比时,该膜具有优异的膜特性,例如抗扩散能力,低电阻率,高密度和台阶覆盖。 本发明的多层阻挡金属薄膜具有改善的粘合特性,特别适用于其上的铜膜的金属化。