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1. 发明申请

US20050080196A1 Carbamate functional addition polymers and method for their preparation 失效
标题翻译：氨基甲酸酯官能加成聚合物及其制备方法
公开(公告)号：US20050080196A1
公开(公告)日：2005-04-14
申请号：US10957556
申请日：2004-10-01
申请人： Swaminathan Ramesh , Paul Harris , Walter Ohrbom , Donald Campbell , Donald St. Aubin , Ulrike Rockrath
发明人： Swaminathan Ramesh , Paul Harris , Walter Ohrbom , Donald Campbell , Donald St. Aubin , Ulrike Rockrath
IPC分类号： C08F8/14 , C08F8/30 , C08F222/20 , C08F222/22 , C09D201/02 , C08L29/00
CPC分类号： C08F220/06 , C08F8/00 , C08F8/14 , C08F220/08 , C08F222/20 , C08F222/22 , C08L2312/00 , C09D133/14 , C09D201/025 , C08F265/06
摘要： Disclosed is a method for making nongelled addition polymers, especially carbamate functional additional polymers from linear unsaturated anhydrides. The method comprises reacting an unsaturated linear anhydride with an active hydrogen compound to provide two monomers comprising polymerizable C═C bonds, at least one of said monomers comprising an acid functional group; polymerizing the polymerizable C═C bonds of the two monomers to provide an acid functional polymerization product; and reacting the acid functional polymerization product with an epoxy functional compound to provide a nongelled addition polymer, wherein the disclosed method does not include a step comprising the physical removal of any acid functional monomers or polymerization products. Also disclosed is a curable coating composition containing the resulting carbamate functional polymer, as well as a coated substrate comprising a cured film resulting from the application and curing of the disclosed curable coating composition.
摘要翻译：公开了一种用于制备非线性加成聚合物，特别是来自线性不饱和酸酐的氨基甲酸酯官能的另外的聚合物的方法。该方法包括使不饱和直链酸酐与活性氢化合物反应以提供包含可聚合C = C键的两种单体，至少一种所述单体包含酸官能团; 聚合两种单体的可聚合C = C键以提供酸官能聚合产物; 并使酸官能聚合产物与环氧官能化合物反应以提供不通电的加成聚合物，其中所公开的方法不包括物理除去任何酸官能单体或聚合产物的步骤。还公开了含有所得氨基甲酸酯官能聚合物的可固化涂料组合物，以及包含由所公开的可固化涂料组合物的施用和固化产生的固化膜的涂布基材。

2. 发明申请

US20050079362A1 Functional addition polymers and a method for their preparation 有权
标题翻译：官能加成聚合物及其制备方法
公开(公告)号：US20050079362A1
公开(公告)日：2005-04-14
申请号：US10957568
申请日：2004-10-01
申请人： Walter Ohrbom , Donald Campbell , Donald St. Aubin , Swaminathan Ramesh , Paul Harris , Ulrike Rockrath
发明人： Walter Ohrbom , Donald Campbell , Donald St. Aubin , Swaminathan Ramesh , Paul Harris , Ulrike Rockrath
IPC分类号： C08F8/14 , C08F8/30 , C08F222/20 , C08F222/22 , C09D201/02 , B32B27/38
CPC分类号： C08F222/20 , C08F8/14 , C08F220/06 , C08F220/08 , C08F222/22 , C08G18/00 , C09D201/025 , Y10T428/31511 , C08F265/06
摘要： Disclosed is a method for making nongelled functional addition polymers from linear unsaturated anhydrides. The method subjects a linear unsaturated anhydride compound, an active hydrogen compound, and an epoxide compound to reaction conditions such that each of the following three reactions occur: (i) polymerization of polymerizable C═C bonds, (ii) ring opening of an anhydride functional group of the linear unsaturated anhydride compound by the active hydrogen compound to create an acid functional group, and (iii) reaction of the acid functional group resulting from the anhydride ring opening with the epoxide compound. At the time of reaction (iii), the acid functional group resulting from the anhydride ring opening may be selected from an ethylenically unsaturated monomer, a polymer, or both. In one embodiment, the method does not include the physical removal of any acid functional monomers or polymerization products. Also disclosed are a curable coating composition and a coated substrate.
摘要翻译：公开了一种从线性不饱和酸酐制造非功能性加成聚合物的方法。该方法使线性不饱和酸酐化合物，活性氢化合物和环氧化合物进行反应，使得发生以下三个反应中的每一个：（i）可聚合的C = C键的聚合，（ii）酸酐的开环通过活性氢化合物的线性不饱和酸酐化合物的官能团，以产生酸官能团，和（iii）由酸酐开环产生的酸官能团与环氧化合物的反应。在反应（iii）时，由酸酐开环产生的酸官能团可以选自烯属不饱和单体，聚合物或两者。在一个实施方案中，该方法不包括物理去除任何酸官能单体或聚合产物。还公开了可固化涂料组合物和涂布的基材。

3. 发明申请

US20080249250A1 Copolymers Containing Lateral Carbamate Groups And Groups Which Can Be Activated With Actinic Radiation, Processes For Preparing Them, And Their Use 审中-公开
标题翻译：含有侧链氨基甲酸酯基团和可以用光化学辐射活化的基团的共聚物，用于制备它们的方法及其用途
公开(公告)号：US20080249250A1
公开(公告)日：2008-10-09
申请号：US11995839
申请日：2006-07-18
申请人： Heinz-Peter Rink , Wilma Nimz , Ulrike Rockrath , Eva Wagner , Swaminathan Ramesh , Paul J. Harris
发明人： Heinz-Peter Rink , Wilma Nimz , Ulrike Rockrath , Eva Wagner , Swaminathan Ramesh , Paul J. Harris
IPC分类号： C08G69/08 , C08G12/00 , C08G18/00 , C08F226/00
CPC分类号： C08F8/14 , C08F220/14 , C08F220/28 , C08F220/32 , C08F220/36 , C08F2800/20 , C08F2810/30 , C08J3/243 , C08J2333/06 , C09D133/14 , C08F2220/325 , C08F2220/346 , C08F212/08 , C08F2220/1825 , C08F220/20
摘要： Copolymers (A) containing lateral, primary and/or secondary carbamate groups (a12) and groups (a31) which can be activated with actinic radiation, preparable byI. in a first process step copolymerizing (a1) a monomer containing (a11) a group of the general formula I: CH2═C(R)C(O)—O—, (I) in which the variable R is a hydrogen atom, a halogen atom, a nitrile group or an alkyl group having 1 to 10 carbon atoms, and (a12) a primary and/or secondary carbamate group, and (a2) a monomer containing (a21) a free-radically or ironically polymerizable, olefinically unsaturated double bond and (a22) a reactive functional group which is not reactive with the carbamate groups (a12) and is not polymerizable with the double bond (a21), to give the copolymer (a1/a2), and II. in a further process step, reacting the copolymer (a1/a2) with (a3) a compound containing (a31) a group which can be activated with actinic radiation and (a32) a reactive functional group complementary to the reactive functional group (a22), to give the copolymer (A); processes for preparing them, and their use.
摘要翻译：共聚物（A）含有侧链，伯胺和/或仲氨基甲酸酯基团（a12）和可以用光化辐射活化的基团（a31），其可由I制备，在第一工艺步骤中，共聚（a1）含（a11）通式I的基团：<？in-line-formula description =“In-line formula”end =“lead”？> CH 2 -C（R）C（O）-O- ，（I）<？in-line-formula description =“In-line formula”end =“tail”？>其中变量R是氢原子，卤素原子，腈基或具有1〜 10个碳原子和（a12）伯和/或仲氨基甲酸酯基团，和（a2）含有（a21）自由基或可讽刺可聚合的烯属不饱和双键的单体和（a22）不是与氨基甲酸酯基（a12）反应，与双键（a21）不可聚合，得到共聚物（a1 / a2），和II。在另一工艺步骤中，使共聚物（a1 / a2）与（a3）含有（a31）可以用光化辐射活化的基团的化合物和（a32）与反应性官能团（a22）互补的反应性官能团，得到共聚物（A）; 制备它们的过程及其用途。

4. 发明申请

US20050131134A1 Use of urea crystals for non-polymeric coatings 有权
标题翻译：尿素晶体用于非聚合物涂层
公开(公告)号：US20050131134A1
公开(公告)日：2005-06-16
申请号：US10732850
申请日：2003-12-10
申请人： Marvin Green , Swaminathan Ramesh , Walter Ohrbom
发明人： Marvin Green , Swaminathan Ramesh , Walter Ohrbom
IPC分类号： B05D7/24 , C08G18/28 , C08G18/46 , C08G18/80 , C09D4/00 , C09D161/20 , C09D175/02 , C09D175/04 , C09D201/02 , C08K3/34 , C08K3/00
CPC分类号： C09D175/02 , C08G18/2865 , C08G18/4615 , C09D201/025
摘要： The thermosetting, non-polymeric coating composition includes at least one monomeric material having a plurality of carbamate and/or urea groups, at least one crosslinker reactive with the at least one monomeric material, and a sag control agent that is a crystalline reaction product of an amine and an isocyanate.
摘要翻译：热固性非聚合物涂料组合物包括至少一种具有多个氨基甲酸酯和/或脲基团的单体材料，至少一种与至少一种单体材料反应的交联剂，以及一种下垂控制剂，其为下列物质的结晶反应产物：胺和异氰酸酯。

5. 发明申请

US20060128901A1 Clearcoat paint composition 有权
标题翻译：清漆涂料组成
公开(公告)号：US20060128901A1
公开(公告)日：2006-06-15
申请号：US11227868
申请日：2005-09-15
申请人： Swaminathan Ramesh , Donald Campbell , Marvin Green , Heinz-Peter Rink
发明人： Swaminathan Ramesh , Donald Campbell , Marvin Green , Heinz-Peter Rink
IPC分类号： C08F120/08
CPC分类号： C09D133/06 , C08F8/14 , C08F220/06 , C08F220/18 , C08F220/32 , C08F220/36 , C09D4/00 , C09D133/062 , C09D201/025 , C08L2666/02
摘要： A coating composition including a copolymerization product of a mixture of monomers including one or more carbamate-functional monomers and (meth)acrylic monomers, some having carboxylic acid-functionality. The monomer mixture is essentially free of hydroxyl monomers. The coating composition may be a solvent-borne clearcoat coating composition, preferably an automotive clearcoat coating composition, that may be applied over a water-borne basecoat coating composition.
摘要翻译：一种涂料组合物，其包含包含一种或多种氨基甲酸酯官能单体和（甲基）丙烯酸单体的单体混合物的共聚产物，一些具有羧酸官能团。单体混合物基本上不含羟基单体。涂料组合物可以是可涂覆在水性底涂层组合物上的溶剂型透明涂料涂料组合物，优选汽车透明涂料涂料组合物。

6. 发明授权

US07005473B2 Polymeric pigment dispersant utilized as a grind resin for pigments in solventborne pigment dispersions and method of preparing the same 失效
公开(公告)号：US07005473B2
公开(公告)日：2006-02-28
申请号：US10122509
申请日：2002-04-16
申请人： Swaminathan Ramesh , Paul Harris
发明人： Swaminathan Ramesh , Paul Harris
IPC分类号： C08K3/00
CPC分类号： B01F17/005 , C01P2004/61 , C01P2006/22 , C08G63/42 , C08G63/58 , C08G63/6854 , C08G83/005 , C09B67/009 , C09C1/3676 , C09C3/08 , C09C3/10
摘要： The present invention is directed to a polyester polycarbamate polymeric pigment dispersant to be used as a grind resin to incorporate pigment into pigment dispersions for coating compositions. The pigment dispersant is the reaction product of a first compound having a plurality of hydroxyl groups, a carboxylic acid anhydride, a second compound having at least one epoxy group, and a carbamate compound. The present invention is also directed to a method of preparing the pigment dispersant.

7. 发明授权

US06881791B2 Poly-electrolyte free block copolymers and their use in crosslinking coatings applications 失效
标题翻译：多电解质自由基嵌段共聚物及其在交联涂料中的应用
公开(公告)号：US06881791B2
公开(公告)日：2005-04-19
申请号：US10455066
申请日：2003-06-05
申请人： Swaminathan Ramesh , Paul Harris , Wolfgang Bremser , Walter H. Ohrbom
发明人： Swaminathan Ramesh , Paul Harris , Wolfgang Bremser , Walter H. Ohrbom
IPC分类号： C08F8/00 , C08F8/30 , C08F212/32 , C08F293/00 , C08K5/17 , C08L53/00 , C09D151/00 , C09D153/00 , C08J3/26
CPC分类号： C08F212/32 , C08F8/30 , C08F293/005 , C08F2810/20 , C08K5/17 , C08L53/00 , C09D151/003 , C09D153/00 , C08L2666/02
摘要： A curable, water-based coating composition comprising a reaction product of: a copolymer comprising a free-radical polymerization product of: a first block comprising a reaction product of: a plurality of ethylenically unsaturated monomers, and a vinyl aromatic hydrocarbon monomer, wherein at least one monomer of the plurality of ethylenically unsaturated monomers includes a functional group that can react with a water-dispersible cross-linking agent, and at least one monomer of the plurality of ethylenically unsaturated monomers is present in an amount such that it can render the copolymer water dispersible, and a second block comprising a reaction product of at least one ethylenically unsaturated monomer, wherein at least a portion of which are non-functional, and a water-dispersible cross-linking agent, wherein the water-based copolymer is free of salt structures.
摘要翻译：一种可固化的水性涂料组合物，其包含以下反应产物的反应产物：包含自由基聚合产物的共聚物，该自由基聚合产物包含：包含多个烯属不饱和单体和乙烯基芳族烃单体的反应产物的第一嵌段，其中在多个烯属不饱和单体中的至少一个单体包括可与水分散性交联剂反应的官能团，并且多个烯键式不饱和单体中的至少一种单体的存在量可以使得共聚物水分散体，和包含至少一种烯属不饱和单体的反应产物的第二嵌段，其中至少一部分是非官能的，和水分散性交联剂，其中所述水基共聚物是游离的的盐结构。

8. 发明申请

US20130317238A1 DEPOLYMERIZATION PROCESSES, APPARATUSES AND CATALYSTS FOR USE IN CONNECTION THEREWITH 有权
标题翻译：分解方法，装置和催化剂用于其中
公开(公告)号：US20130317238A1
公开(公告)日：2013-11-28
申请号：US13992617
申请日：2011-12-08
申请人： Pravansu S. Mohanty , Swaminathan Ramesh
发明人： Pravansu S. Mohanty , Swaminathan Ramesh
IPC分类号： C08J11/16
CPC分类号： B01J19/12 , B01J8/003 , B01J8/087 , B01J8/10 , B01J19/088 , B01J23/34 , B01J23/466 , B01J2219/00033 , B01J2219/0854 , B01J2219/0879 , B01J2219/0892 , B01J2219/0894 , C07C4/22 , C08J11/10 , C08J11/16 , C08J2300/00 , Y02P20/52 , Y02W30/705 , C07C11/04 , C07C11/06
摘要： The present disclosure generally relates to processes, apparatuses and custom catalysts designed to depolymerize a polymer. In one embodiment, the present invention relates to a de-polymerizing apparatus, catalysts and reaction schemes to obtain useful monomers including fuel products by “in situ” reactions using coupled electromagnetic induction.
摘要翻译：本公开一般涉及设计用于解聚聚合物的方法，装置和定制催化剂。在一个实施方案中，本发明涉及通过使用耦合电磁感应“原位”反应获得包括燃料产物的有用单体的脱聚装置，催化剂和反应方案。

9. 发明授权

US07531703B2 Method of recycling a recyclable plastic 有权
标题翻译：循环再造塑料的方法
公开(公告)号：US07531703B2
公开(公告)日：2009-05-12
申请号：US11539395
申请日：2006-10-06
申请人： Swaminathan Ramesh , Joel Sibul
发明人： Swaminathan Ramesh , Joel Sibul
IPC分类号： C10G1/10
CPC分类号： C08F8/50 , C08J11/16 , C08J2323/06 , C10G1/10 , Y02W30/705
摘要： The present invention provides a method of recycling a plastic thereby forming a narrow spectrum of hydrocarbons having from 4 to 14 carbon atoms that can be directly used as gasoline without additional processing or refining. The method includes the step of feeding the plastic, selected from the group of polyethylene, polypropylene, polystyrene, and combinations thereof, into a heated vessel for melting. The method also includes the step of decomposing the plastic at a temperature of from 400° C. to 500° C. in the presence of a metallocene catalyst and a zeolitic catalyst thereby forming the hydrocarbons having from 4 to 14 carbon atoms. The metallocene catalyst includes dichlorobis(2-methylindenyl)zirconium (IV). The zeolitic catalyst includes ammonium Y zeolite and has a pore size of from 1 to 4 Angstroms.
摘要翻译：本发明提供一种回收塑料的方法，从而形成具有4至14个碳原子的窄谱的烃，其可直接用作汽油而无需额外的加工或精炼。该方法包括将选自聚乙烯，聚丙烯，聚苯乙烯及其组合的塑料进料到加热的容器中进行熔化的步骤。该方法还包括在茂金属催化剂和沸石催化剂存在下，在400℃至500℃的温度下分解塑料的步骤，从而形成具有4至14个碳原子的烃。茂金属催化剂包括二氯双（2-甲基茚基）锆（IV）。沸石催化剂包括铵Y沸石，孔径为1至4埃。

10. 发明授权

US07226971B2 Polyester resin with carbamate functionality, a method of preparing the resin, and a coating composition utilizing the resin 有权
标题翻译：具有氨基甲酸酯官能团的聚酯树脂，制备树脂的方法和使用该树脂的涂料组合物
公开(公告)号：US07226971B2
公开(公告)日：2007-06-05
申请号：US10206418
申请日：2002-07-26
申请人： Swaminathan Ramesh , Marvin L Green
发明人： Swaminathan Ramesh , Marvin L Green
IPC分类号： C08G69/44
CPC分类号： B01F17/005 , C01P2004/61 , C01P2006/22 , C08G63/42 , C08G63/58 , C08G63/664 , C08G63/6854 , C09B67/009 , C09C1/3676 , C09C3/08 , C09C3/10 , C09D167/04 , C09D201/005 , C09D201/025
摘要： The present invention is directed to a polyester resin for use in a coating composition. The polyester resin is the reaction product of a first compound comprising a plurality of hydroxyl groups, a lactone compound, a carboxylic acid anhydride, an epoxy compound having at least one epoxy group, and a carbamate compound. The present invention is also directed to a coating composition including the polyester resin and to a method of preparing the resin.
摘要翻译：本发明涉及一种用于涂料组合物的聚酯树脂。聚酯树脂是包含多个羟基的第一化合物，内酯化合物，羧酸酐，具有至少一个环氧基的环氧化合物和氨基甲酸酯化合物的反应产物。本发明还涉及包含聚酯树脂的涂料组合物和制备树脂的方法。

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