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    • 3. 发明申请
    • METHOD FOR PRODUCING SMALL SIZE TITANIUM OXIDE PARTICLES
    • 生产小尺寸氧化钛颗粒的方法
    • US20140044876A1
    • 2014-02-13
    • US13988477
    • 2011-11-21
    • Asher VitnerMatti Ben-MosheMubeen Baidossi
    • Asher VitnerMatti Ben-MosheMubeen Baidossi
    • C01G23/053
    • C01G23/053B82Y30/00C01G23/0532C01G23/0536C01P2002/60C01P2004/64C01P2006/12
    • The present invention provides a method for the production of small-size titanium oxide particles, comprising the steps of: e) providing a solid containing titanic acid; f) contacting the solid with an acidic aqueous medium thereby forming an aqueous precursor solution at given conditions of temperature lower than 100° C., Titanium cation concentration lower than 20 wt % and higher than 0.1 wt %, pH lower than 1 and strong acid concentration higher than 2.5% and lower than 30%; g) optionally, adding one or more capping agents to the aqueous precursor solution; and h) modifying at least one of the conditions of the aqueous precursor and maintaining the aqueous precursor at the modified conditions, whereupon precipitation of a precipitate comprising small-size titanium oxide particles takes place, the modifications being selected from at least one of temperature elevation by at least 5° C. and pH elevation by at least 0.1 pH units.
    • 本发明提供一种生产小尺寸氧化钛颗粒的方法,包括以下步骤:e)提供含有钛酸的固体; f)使固体与酸性水性介质接触,从而在温度低于100℃的规定条件下形成水性前体溶液,钛阳离子浓度低于20wt%且高于0.1wt%,pH低于1,强酸 浓度高于2.5%,低于30%; g)任选地,向前体水溶液中加入一种或多种封端剂; 和h)修饰水性前体的至少一种条件并将水性前体保持在改性条件下,由此发生包含小尺寸氧化钛颗粒的沉淀物,所述修饰选自温度升高中的至少一种 至少5℃,pH升高至少0.1个pH单位。
    • 6. 发明授权
    • Process for producing 1, 3-propanediol
    • 1,3-丙二醇生产方法
    • US07056439B2
    • 2006-06-06
    • US10430498
    • 2003-05-06
    • Avraham M. BanielRobert P. JansenAsher VitnerAnthony Baiada
    • Avraham M. BanielRobert P. JansenAsher VitnerAnthony Baiada
    • B01D11/00C07C7/10
    • C07C29/86B01D11/0446B01D11/0488B01D11/0492C02F1/26C07C31/205
    • Disclosed herein are processes for the recovery of 1,3-propanediol from an aqueous feed stream. The present invention involves contacting an aqueous feed stream that comprises water, 1,3-propanediol, and at least one contaminant with at least one solvent extractant to form a mixture. The mixture is separated into a first phase and a second phase. The second phase comprises a majority of the water from the aqueous feed stream. The first phase comprises solvent extractant and at least some of the 1,3-propanediol that was present in the aqueous feed stream. The weight ratio in the first phase of 1,3-propanediol to any one contaminant present is greater than the weight ratio of 1,3-propanediol to the same contaminant in the aqueous feed stream prior to the aqueous feed stream being contacted with the solvent extractant. The first phase can be removed from the separated second phase in order to recover the 1,3-propanediol.
    • 本文公开了从含水原料流中回收1,3-丙二醇的方法。 本发明涉及将包含水,1,3-丙二醇和至少一种污染物的含水进料流与至少一种溶剂萃取剂接触以形成混合物。 将混合物分离成第一相和第二相。 第二相包含来自含水进料流的大部分水。 第一阶段包括溶剂萃取剂和存在于含水进料流中的至少一些1,3-丙二醇。 在水性进料流与溶剂接触之前,1,3-丙二醇与任何一种污染物的第一相中的重量比大于1,3-丙二醇与含水进料流中相同污染物的重量比 萃取剂。 为了回收1,3-丙二醇,可以将第一相从分离的第二相中除去。
    • 8. 发明授权
    • Process for producing 1,3-propanediol
    • 1,3-丙二醇生产工艺
    • US07572376B2
    • 2009-08-11
    • US11352593
    • 2006-02-13
    • Avraham M. BanielRobert P. JansenAsher VitnerAnthony Baiada
    • Avraham M. BanielRobert P. JansenAsher VitnerAnthony Baiada
    • B01D11/00C07C31/18
    • C07C29/86B01D11/0446B01D11/0488B01D11/0492C02F1/26C07C31/205
    • Disclosed herein are processes for the recovery of 1,3-propanediol from an aqueous feed stream. The present invention involves contacting an aqueous feed stream that comprises water, 1,3-propanediol, and at least one contaminant with at least one solvent extractant to form a mixture. The mixture is separated into a first phase and a second phase. The second phase comprises a majority of the water from the aqueous feed stream. The first phase comprises solvent extractant and at least some of the 1,3-propanediol that was present in the aqueous feed stream. The weight ratio in the first phase of 1,3-propanediol to any one contaminant present is greater than the weight ratio of 1,3-propanediol to the same contaminant in the aqueous feed stream prior to the aqueous feed stream being contacted with the solvent extractant. The first phase can be removed from the separated second phase in order to recover the 1,3-propanediol.
    • 本文公开了从含水原料流中回收1,3-丙二醇的方法。 本发明涉及将包含水,1,3-丙二醇和至少一种污染物的含水进料流与至少一种溶剂萃取剂接触以形成混合物。 将混合物分离成第一相和第二相。 第二相包含来自含水进料流的大部分水。 第一阶段包括溶剂萃取剂和存在于含水进料流中的至少一些1,3-丙二醇。 在水性进料流与溶剂接触之前,1,3-丙二醇与任何一种污染物的第一相中的重量比大于1,3-丙二醇与含水进料流中相同污染物的重量比 萃取剂。 为了回收1,3-丙二醇,可以将第一相从分离的第二相中除去。
    • 9. 发明申请
    • Process for the recovery of citric acid
    • 回收柠檬酸的方法
    • US20060247468A1
    • 2006-11-02
    • US10548171
    • 2004-03-03
    • Avraham BanielAsher VitnerDavid GonenDavid Heidel
    • Avraham BanielAsher VitnerDavid GonenDavid Heidel
    • C07C59/265
    • C07C51/43C07C51/48C07C59/265
    • The invention provides a process for the recovery of citric acid from an aqueous solution feed stream originating in fermentation of carbohydrates and utilizing an amine solvent extraction step for separation of impurities comprising: subjecting said aqueous solution feed stream A to a treatment for partial recovery of citric acid, wherein said treatment is other than amine solvent extraction, to form a first portion of purified citric acid B and a secondary feed stream F; subjecting at least a portion G of said secondary feed stream F to a treatment consisting of amine solvent extraction to form a second portion of purified citric acid solution and to reject substantial of impurities initially present in said portion of said secondary feed stream; subjecting said second portion of purified citric acid solution to crystallization; and recycling mother liquor from said crystallization.
    • 本发明提供了一种从源于碳水化合物发酵的水溶液进料流中回收柠檬酸的方法,并利用胺溶剂萃取步骤分离杂质,其包括:使所述水溶液进料流A处理部分回收柠檬酸 酸,其中所述处理不是胺溶剂萃取,以形成纯化柠檬酸B的第一部分和第二进料流F; 使至少一部分G的所述二次进料流F经受由胺溶剂萃取组成的处理以形成第二部分纯化的柠檬酸溶液并且排除最初存在于所述第二进料流的所述部分中的大量杂质; 对所述第二部分纯化柠檬酸溶液进行结晶; 并从所述结晶中回收母液。