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    • 1. 发明申请
    • METHOD FOR PRODUCING SMALL SIZE TITANIUM OXIDE PARTICLES
    • 生产小尺寸氧化钛颗粒的方法
    • US20140044876A1
    • 2014-02-13
    • US13988477
    • 2011-11-21
    • Asher VitnerMatti Ben-MosheMubeen Baidossi
    • Asher VitnerMatti Ben-MosheMubeen Baidossi
    • C01G23/053
    • C01G23/053B82Y30/00C01G23/0532C01G23/0536C01P2002/60C01P2004/64C01P2006/12
    • The present invention provides a method for the production of small-size titanium oxide particles, comprising the steps of: e) providing a solid containing titanic acid; f) contacting the solid with an acidic aqueous medium thereby forming an aqueous precursor solution at given conditions of temperature lower than 100° C., Titanium cation concentration lower than 20 wt % and higher than 0.1 wt %, pH lower than 1 and strong acid concentration higher than 2.5% and lower than 30%; g) optionally, adding one or more capping agents to the aqueous precursor solution; and h) modifying at least one of the conditions of the aqueous precursor and maintaining the aqueous precursor at the modified conditions, whereupon precipitation of a precipitate comprising small-size titanium oxide particles takes place, the modifications being selected from at least one of temperature elevation by at least 5° C. and pH elevation by at least 0.1 pH units.
    • 本发明提供一种生产小尺寸氧化钛颗粒的方法,包括以下步骤:e)提供含有钛酸的固体; f)使固体与酸性水性介质接触,从而在温度低于100℃的规定条件下形成水性前体溶液,钛阳离子浓度低于20wt%且高于0.1wt%,pH低于1,强酸 浓度高于2.5%,低于30%; g)任选地,向前体水溶液中加入一种或多种封端剂; 和h)修饰水性前体的至少一种条件并将水性前体保持在改性条件下,由此发生包含小尺寸氧化钛颗粒的沉淀物,所述修饰选自温度升高中的至少一种 至少5℃,pH升高至少0.1个pH单位。