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    • 2. 发明申请
    • PROCESS FOR PRODUCING LITHIUM VANADIUM PHOSPHATE-CARBON COMPOSITE
    • 用于生产磷酸氢钙 - 碳复合材料的方法
    • US20130214462A1
    • 2013-08-22
    • US13823612
    • 2011-09-22
    • Tsutomu KikuchiKazuki TakimotoHideo Yanagita
    • Tsutomu KikuchiKazuki TakimotoHideo Yanagita
    • H01M4/1397
    • H01M4/1397C01B25/45H01M4/04H01M4/13H01M4/136H01M4/5825H01M4/625H01M10/0525Y02E60/122Y02P70/54Y02T10/7011
    • A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
    • 一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤,其包括在水性溶剂中将锂源,四价或五价钒化合物,磷源和通过热解产生碳的导电碳材料源混合至 制备原料混合物,第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物,第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨 研磨以获得包括研磨颗粒的浆料,第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体,第五步包括在600至1300℃下煅烧反应前体, 惰性气体气氛或还原气氛。 通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能(例如,高放电容量)的锂二次电池。
    • 4. 发明授权
    • Process for producing lithium vanadium phosphate-carbon composite
    • 生产锂钒磷酸盐 - 碳复合材料的方法
    • US09437866B2
    • 2016-09-06
    • US13823612
    • 2011-09-22
    • Tsutomu KikuchiKazuki TakimotoHideo Yanagita
    • Tsutomu KikuchiKazuki TakimotoHideo Yanagita
    • H01M4/1397H01M4/13H01M4/58C01B25/45H01M4/04H01M4/136H01M10/0525H01M4/62
    • H01M4/1397C01B25/45H01M4/04H01M4/13H01M4/136H01M4/5825H01M4/625H01M10/0525Y02E60/122Y02P70/54Y02T10/7011
    • A process for producing a lithium vanadium phosphate-carbon composite includes a first step that includes mixing a lithium source, a tetravalent or pentavalent vanadium compound, a phosphorus source, and a conductive carbon material source that produces carbon through pyrolysis, in an aqueous solvent to prepare a raw material mixture, a second step that includes heating the raw material mixture to effect a precipitation reaction to obtain a reaction mixture that includes a precipitate, a third step that includes subjecting the reaction mixture that includes the precipitate to wet grinding using a media mill to obtain a slurry that includes ground particles, a fourth step that includes spray-drying the slurry that includes the ground particles to obtain a reaction precursor, and a fifth step that includes calcining the reaction precursor at 600 to 1300° C. in an inert gas atmosphere or a reducing atmosphere. A lithium vanadium phosphate-carbon composite produced by the process may provide a lithium secondary battery with excellent battery performance (e.g., high discharge capacity) when used as a cathode active material.
    • 一种制备锂钒磷酸盐 - 碳复合材料的方法包括第一步骤,其包括在水性溶剂中将锂源,四价或五价钒化合物,磷源和通过热解产生碳的导电碳材料源混合至 制备原料混合物,第二步骤包括加热原料混合物进行沉淀反应以获得包含沉淀物的反应混合物,第三步骤包括使用介质对含有沉淀物的反应混合物进行湿磨研磨 研磨以获得包括研磨颗粒的浆料,第四步骤包括喷雾干燥包含研磨颗粒的浆料以获得反应前体,第五步包括在600至1300℃下煅烧反应前体, 惰性气体气氛或还原气氛。 通过该方法生产的锂钒磷酸铁复合物可以提供当用作阴极活性材料时具有优异的电池性能(例如,高放电容量)的锂二次电池。
    • 8. 发明授权
    • Gas analyzing apparatus
    • 气体分析仪
    • US06397660B1
    • 2002-06-04
    • US09774730
    • 2001-01-31
    • Tsutomu KikuchiAkira NishinaTetsuya Kimijima
    • Tsutomu KikuchiAkira NishinaTetsuya Kimijima
    • G01N3004
    • G01N30/7206G01N2030/201G01N2030/8886
    • There is provided a gas analyzing apparatus capable of minimizing gas remaining by integrating gas switching apparatuses into one and capable of analyzing impurities of ppb level to sub-ppb level contained in various kinds of high-purity gases efficiently and accurately. The gas analyzing apparatus comprises an analyzer introduction passage 22 for introducing a sample gas supplied from a sample gas source 11 into an analyzer 12 via an analyzer introduction valve 22V; a separator introduction passage 23 diverging from a first side passage of the analyzer introduction valve 22V for introducing a sample gas into a separator 13 via a separator introduction valve 23V; a separator flowing out passage 24 for introducing the sample gas flowing out from the separator 13 into a second side passage of the analyzer introduction valve 22V via a separator flowing-out valve 24V; and a gas switching apparatus to be such formed that when the analyzer introduction valve 22V is opened, the separator introduction valve 23V and the separator flowing-out valve 24V are connectively operated to be closed, and when the analyzer introduction valve 22V is closed, the separator introduction valve 23V and the separator flowing-out valve 24V are connectively operated to be opened.
    • 提供一种气体分析装置,其能够通过将气体切换装置集成为一体而使气体残留最小化,并且能够高效且准确地分析各种高纯度气体中所含的ppb等级和亚ppb等级的杂质。 气体分析装置包括分析器引入通道22,用于经由分析器引入阀22V将从样品气体源11供给的样品气体引入分析器12; 从分析器引入阀22V的第一侧通道分离出的分离器引入通道23,用于经由分离器引入阀23V将样品气体引入隔板13; 分离器流出通道24,用于将从分离器13流出的样品气体经由分离器流出阀24V引入分析器导入阀22V的第二侧通道; 以及气体切换装置,其形成为当分析器导入阀22V打开时,分离器导入阀23V和分离器流出阀24V连接动作关闭,当分析器导入阀22V关闭时, 分离器引入阀23V和分离器流出阀24V被连接操作以打开。