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1. 发明授权

US6149880A Method and apparatus for treating aqueous medium containing organic matter 失效
标题翻译：用于处理含有机物的含水介质的方法和装置
公开(公告)号：US6149880A
公开(公告)日：2000-11-21
申请号：US102620
申请日：1998-06-23
申请人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
发明人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
IPC分类号： B09B3/00 , B01J3/00 , B01J3/04 , B01J19/00 , C02F1/72 , C02F1/78 , C02F3/08 , C02F11/08 , C02F11/10 , C02F11/18 , F23K1/02 , F23G7/04 , F28D21/00 , G05D9/00 , G05D16/00
CPC分类号： B01J3/00 , B01J3/04 , C02F1/025 , C02F11/08 , C02F11/18 , F23K1/02 , B01J2219/00087 , B01J2219/00162 , B01J2219/00182 , C02F1/722 , C02F1/78 , C02F11/083 , Y10S210/908
摘要： A hydrothermal reaction is performed on an aqueous medium without adding an oxidizing agent, and then another hydrothermal reaction is performed in the presence of an oxidizing agent, thereby reducing a chemical oxygen demand of the aqueous medium. An apparatus for performing a hydrothermal reaction has a fluid inlet being capable of introducing an oxidizing agent in a fluid form during a hydrothermal reaction.
摘要翻译：在水性介质中进行水热反应而不添加氧化剂，然后在氧化剂的存在下进行另一次水热反应，从而降低水性介质的化学需氧量。进行水热反应的装置具有在水热反应期间能够以流体形式引入氧化剂的流体入口。

2. 发明授权

US5997751A Method and apparatus for treating aqueous medium containing organic matter 失效
公开(公告)号：US5997751A
公开(公告)日：1999-12-07
申请号：US867824
申请日：1997-06-03
申请人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
发明人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
IPC分类号： B09B3/00 , B01J3/00 , B01J3/04 , B01J19/00 , C02F1/72 , C02F1/78 , C02F3/08 , C02F11/08 , C02F11/10 , C02F11/18 , F23K1/02
CPC分类号： B01J3/00 , B01J3/04 , C02F1/025 , C02F11/08 , C02F11/18 , F23K1/02 , B01J2219/00087 , B01J2219/00162 , B01J2219/00182 , C02F1/722 , C02F1/78 , C02F11/083 , Y10S210/908
摘要： A hydrothermal reaction is performed on an aqueous medium without adding an oxidizing agent, and then another hydrothermal reaction is performed in the presence of an oxidizing agent, thereby reducing a chemical oxygen demand of the aqueous medium. An apparatus for performing a hydrothermal reaction has a fluid inlet being capable of introducing an oxidizing agent in a fluid form during a hydrothermal reaction.

3. 发明授权

US5976387A Method for feeding wastes into a boiler 失效
标题翻译：将废物送入锅炉的方法
公开(公告)号：US5976387A
公开(公告)日：1999-11-02
申请号：US819936
申请日：1997-03-18
申请人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
发明人： Tsutomu Higo , Roberto Masahiro Serikawa , Kazuhiro Kondo
IPC分类号： F23G5/02 , B09B3/00 , B09C1/06 , C02F11/10 , C02F11/18 , F23K1/02 , C02F1/02
CPC分类号： C02F11/18 , B09B3/00 , B09C1/06 , C02F11/10 , Y02W10/40 , Y10S210/919
摘要： A waste containing organic solids is fed into a boiler after it has been subjected to a hydrothermal reaction treatment in the presence of water. A slurry containing the waste is held under high-temperature and high-pressure conditions to cause a hydrothermal reaction such that an acidic slurry is formed during part of or throughout the process of the hydrothermal reaction. Thereby the content of oxygen in the waste relative to carbon atoms in building molecules of the waste is reduced. This concurrently causes removal of halogens in said building molecule and transferring the halogens into the slurry. The slurry then is cooled and dewatered and fed into a combustion section of the boiler. The waste slurry to be subjected to the hydrothermal reaction can be sorted into two portions for separate storage. One portion is a waste slurry the pH of which will increase as a result of the hydrothermal reaction. The other portion is a waste slurry the pH of which will decrease during the hydrothermal reaction. The two slurries are combined together and subjected to the hydrothermal reaction, with their relative amounts of supply being adjusted such as to form an acidic slurry either during part of or throughout the process of the hydrothermal reaction. Wastes can be supplied as a mass of high heat value into the boiler in such a manner that organic matter is transferred by a smaller amount into the aqueous phase during the hydrothermal reaction, and there is no scale deposit on the surfaces of those areas of the system components in contact with the liquid.
摘要翻译：将含有有机固体的废物在水的存在下进行水热反应处理后，进入锅炉。将含有废物的浆料保持在高温高压条件下进行水热反应，使得在水热反应的一部分或整个过程中形成酸性浆料。因此，废物中的氧相对于碳原子在废物构建分子中的含量降低。这同时导致去除所述构建分子中的卤素并将卤素转移到浆料中。然后将浆料冷却并脱水并进料到锅炉的燃烧部分。要进行水热反应的废浆料可以分成两部分分开储存。一部分是由于水热反应而使其pH值增加的废浆料。另一部分是在水热反应期间其pH将降低的废浆料。将两种浆料组合在一起并进行水热反应，在水热反应的一部分或整个过程的一部分或整个过程中调节其相对供应量以形成酸性浆料。可以将废弃物以大量的高热量供给到锅炉中，使得在水热反应期间将有机物质转移到水相中较少量，并且在这些区域的表面上没有结垢系统组件与液体接触。

4. 发明授权

US5791566A Method and apparatus for submerged grinding of wastes 失效
标题翻译：废物淹没研磨的方法和装置
公开(公告)号：US5791566A
公开(公告)日：1998-08-11
申请号：US812130
申请日：1997-03-05
申请人： Tsutomu Higo , Kazuhiro Kondo , Roberto Masahiro Serikawa
发明人： Tsutomu Higo , Kazuhiro Kondo , Roberto Masahiro Serikawa
IPC分类号： B09B3/00 , C02F11/00 , C10L1/32 , B02C19/12 , B02C23/18
CPC分类号： C10L1/326 , Y02E50/30
摘要： An improved apparatus for submerged grinding of wastes includes a vessel that is filled with an alkaline liquid and which has a mechanism for grinding a feed waste containing organic solids, a feeding mechanism for charging the feed waste into the vessel, a primary screening mechanism for filtering the liquid being discharged from the grinding mechanism and a secondary screening mechanism by which the waste/liquid mixture that has been filtered by the primary classification mechanism is freed of the liquid fraction such that the waste is converted into a slurry. The apparatus further includes a line by which the filtrate from the secondary classification mechanism is returned to the liquid with which the vessel is filled, a mechanism for adding an alkaline aqueous solution and/or particulate matter into the liquid with which the vessel is filled, a mechanism for detecting the pH of the liquid with which the vessel is filled, and a mechanism for adjusting the amount of addition of the alkaline aqueous solution and/or particulate matter into the liquid with the vessel is filled on the basis of the value detected by the pH detecting mechanism in order to ensure that the liquid with which the vessel is filled is maintained in an alkaline condition. Using this apparatus, submerged grinding of wastes can be accomplished over an extended period with the progress of putrefaction being retarded and the emission of malodor being suppressed with the resulting advantage of facilitated liquid maintenance.
摘要翻译：一种废弃物浸没式研磨的改进装置包括：填充有碱性液体的容器，其具有用于研磨含有有机固体的废料的机构，用于将进料废料装入容器的进料机构，用于过滤的原料筛选机构从研磨机构排出的液体和二级筛分机构，由初级分级机构过滤的废液/液体混合物不含液体馏分，从而将废物转化为浆料。该设备还包括一条线，其中来自次级分级机构的滤液返回到容器所填充的液体中，用于将碱性水溶液和/或颗粒物质添加到容器所填充的液体中的机构，用于检测填充容器的液体的pH的机构，并且基于检测到的值填充用于将容器中的碱性水溶液和/或颗粒物质添加到液体中的量的调节机构通过pH检测机构，以确保容器填充的液体保持在碱性条件下。使用这种装置，可以在延长的时间内完成废弃物的浸没研磨，同时抑制腐败的进展并抑制恶臭的排放，从而有利于液体维持。

5. 发明授权

US06939458B1 Apparatus and method for hydrothermal electrolysis 失效
标题翻译：水热电解装置及方法
公开(公告)号：US06939458B1
公开(公告)日：2005-09-06
申请号：US09890871
申请日：2000-02-10
申请人： Tatsuya Nishimura , Roberto Masahiro Serikawa , Qingquan Su , Masahiro Isaka
发明人： Tatsuya Nishimura , Roberto Masahiro Serikawa , Qingquan Su , Masahiro Isaka
IPC分类号： B01D53/32 , B01D53/77 , B01J3/04 , B01J10/00 , B01J19/00 , B01J19/18 , B01J19/26 , C02F1/02 , C02F1/461 , C02F1/467 , C02F1/74
CPC分类号： C02F1/4672 , B01D53/32 , B01D53/77 , B01J3/04 , B01J10/00 , B01J19/18 , B01J19/26 , B01J2219/00054 , B01J2219/00058 , B01J2219/00063 , B01J2219/00069 , B01J2219/00087 , B01J2219/00099 , B01J2219/00103 , B01J2219/00132 , B01J2219/00135 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , B01J2219/00182 , B01J2219/083 , B01J2219/0884 , B01J2219/185 , B01J2219/30207 , B01J2219/30223 , C02F1/02 , C02F1/025 , C02F1/461 , C02F1/46104 , C02F1/46114 , C02F1/467 , C02F1/74 , C02F2001/46133 , C02F2101/36 , C02F2103/18 , C02F2103/28 , C02F2201/4612 , C02F2201/46155 , C02F2301/066 , C02F2301/08
摘要： A hydrothermal electrolytic apparatus comprises a reaction cell for electrolyzing influent at high temperature and high pressure, wherein an overall surface area of a pair of electrodes located in the reaction cell per 1 m3 of the volume of the influent is 0.05 m2 or more. The hydrothermal electrolytic apparatus has two or more tubular reaction cells each having a metal inner wall serving as a cathode, and an anode is provided in each of the reaction cells. A hydrothermal electrolytic process comprises incorporating conductive particles into an influent to substantially increase a surface area of electrodes during hydrothermal electrolysis.
摘要翻译：水热电解装置包括用于在高温高压下电解流入物的反应池，其中位于反应池中的一对电极的总表面积每流入体积的1m 3以上是0.05m 2以上。水热电解装置具有两个以上的管状反应池，每个管状反应池均具有金属内壁作为阴极，在每个反应池中设置阳极。水热电解方法包括将导电颗粒结合到流入物中，以在水热电解期间显着增加电极的表面积。

6. 发明授权

US06572759B1 Method and apparatus for treating aqueous medium 失效
标题翻译：水介质处理方法和装置
公开(公告)号：US06572759B1
公开(公告)日：2003-06-03
申请号：US09913028
申请日：2001-08-09
申请人： Tatsuya Nishimura , Roberto Masahiro Serikawa , Oingquan Su , Masahiro Isaka , Takashi Usui
发明人： Tatsuya Nishimura , Roberto Masahiro Serikawa , Oingquan Su , Masahiro Isaka , Takashi Usui
IPC分类号： C02F1461
CPC分类号： C02F1/4672 , B01D53/32 , B01D53/77 , B01J3/04 , B01J10/00 , B01J19/18 , B01J19/26 , B01J2219/00054 , B01J2219/00058 , B01J2219/00063 , B01J2219/00069 , B01J2219/00087 , B01J2219/00099 , B01J2219/00103 , B01J2219/00132 , B01J2219/00135 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , B01J2219/00182 , B01J2219/083 , B01J2219/0884 , B01J2219/185 , B01J2219/30207 , B01J2219/30223 , C02F1/02 , C02F1/025 , C02F1/461 , C02F1/46104 , C02F1/46114 , C02F1/467 , C02F1/74 , C02F2001/46133 , C02F2101/36 , C02F2103/18 , C02F2103/28 , C02F2201/4612 , C02F2201/46155 , C02F2301/066 , C02F2301/08
摘要： An object of the present invention is to provide a process and an apparatus for treating an aqueous medium at low running costs with a decreased electricity required for hydrothermal electrolytic reaction. The present invention proposes a two-step process comprising a first step of performing a conventional hydrothermal reaction or a conventional electrolytic reaction prior to hydrothermal electrolytic reaction to degrade readily degradable substances or ammonia or various electrolytically degradable organics and then a second step of performing hydrothermal electrolytic reaction to degrade the remaining organics, whereby the electricity consumed by hydrothermal electrolytic reaction in the second step can be greatly reduced.
摘要翻译：本发明的目的是提供一种以低运行成本处理水性介质的方法和装置，其中水热电解反应所需的电量降低。本发明提出了一种两步法，其包括在水热电解反应之前进行常规水热反应或常规电解反应以降解易降解物质或氨或各种电解可降解有机物的第一步骤，然后进行水热电解使其余的有机物发生反应，可以大大降低第二工序中的水热电解反应消耗的电量。

7. 发明授权

US06348143B1 Hydrothermal electrolysis method and apparatus 失效
标题翻译：水热电解方法及装置
公开(公告)号：US06348143B1
公开(公告)日：2002-02-19
申请号：US09485519
申请日：2000-02-11
申请人： Roberto Masahiro Serikawa , Qingquan Su , Akira Watanabe
发明人： Roberto Masahiro Serikawa , Qingquan Su , Akira Watanabe
IPC分类号： C02F1461
CPC分类号： C02F1/4672 , B01J3/04 , C02F1/02 , C02F1/025 , C02F1/46104 , C02F1/4674 , C02F2001/46138 , C02F2001/46152 , C02F2101/16 , C02F2101/163 , C02F2101/166 , C02F2101/18 , C02F2101/30 , C02F2101/32 , C02F2101/36 , C02F2101/38 , C02F2201/4613 , C02F2201/46155 , C02F2201/4617 , C02F2201/4619 , C02F2301/066
摘要： A method and apparatus for simultaneously performing hydrothermal reaction and electrolysis in the presence of a strongly acidic ion such as halide ions. A reactor internally has a pair of electrodes. An oxidizing agent such as an oxygen gas may be added. Even low-molecular weight compounds such as acetic acid and ammonia can be readily decomposed.
摘要翻译：在存在强酸性离子如卤离子的情况下同时进行水热反应和电解的方法和装置。反应器内部具有一对电极。可以加入氧气如氧气。甚至低分子量的化合物，如乙酸和氨也很容易分解。

8. 发明授权

US06585882B1 Method and apparatus for treatment of gas by hydrothermal electrolysis 失效
标题翻译：通过水热电解处理气体的方法和装置
公开(公告)号：US06585882B1
公开(公告)日：2003-07-01
申请号：US09913264
申请日：2001-08-10
申请人： Qingquan Su , Roberto Masahiro Serikawa , Masahiro Isaka , Tatsuya Nishimura , Yoko Kubota
发明人： Qingquan Su , Roberto Masahiro Serikawa , Masahiro Isaka , Tatsuya Nishimura , Yoko Kubota
IPC分类号： C02F1461
CPC分类号： C02F1/4672 , B01D53/32 , B01D53/77 , B01J3/04 , B01J10/00 , B01J19/18 , B01J19/26 , B01J2219/00054 , B01J2219/00058 , B01J2219/00063 , B01J2219/00069 , B01J2219/00087 , B01J2219/00099 , B01J2219/00103 , B01J2219/00132 , B01J2219/00135 , B01J2219/00155 , B01J2219/00157 , B01J2219/00159 , B01J2219/00162 , B01J2219/00164 , B01J2219/00182 , B01J2219/083 , B01J2219/0884 , B01J2219/185 , B01J2219/30207 , B01J2219/30223 , C02F1/02 , C02F1/025 , C02F1/461 , C02F1/46104 , C02F1/46114 , C02F1/467 , C02F1/74 , C02F2001/46133 , C02F2101/36 , C02F2103/18 , C02F2103/28 , C02F2201/4612 , C02F2201/46155 , C02F2301/066 , C02F2301/08
摘要： An object of the present invention is to provide a process and an apparatus for treating a gas containing reducing substances to efficiently degrade and remove the reducing substances. As a means to achieve this object, the present invention provides a process for treating a gas containing reducing substances by hydrothermal electrolysis, comprising supplying a gas containing reducing substances into a reactor charged with an aqueous medium containing a halide ion under application of a direct current at a temperature of 100° C. or more but the critical temperature of said aqueous medium or less and at a pressure that allows said aqueous medium to be kept in the liquid phase.
摘要翻译：本发明的目的是提供一种用于处理含有还原物质的气体以有效降解还原物质的方法和装置。作为实现该目的的手段，本发明提供了一种通过水热电解处理含有还原物质的气体的方法，包括在含有还原物质的气体的情况下，在装有含有卤化物离子的水性介质的反应器中，在100℃或更高的温度下，所述水性介质的临界温度或更低的压力和允许所述水性介质保持在液相中的压力。

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