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    • 6. 发明申请
    • METHOD AND PLANT FOR THE WET-ROUTE OXIDATION TREATMENT OF HAZARDOUS ORGANIC WASTE, NOTABLY RADIOACTIVE WASTE, CONTAINING MINERAL FILLERS
    • 含有有机废物的湿式氧化处理方法和装置,含有矿物填料的不可渗透废物
    • US20160141059A1
    • 2016-05-19
    • US14897930
    • 2014-06-12
    • GRANIT TECHNOLOGIES S.A.
    • Boris CORREAOlivier MERCIER
    • G21F9/30
    • G21F9/30B01D1/0047C02F1/04C02F1/66C02F11/008C02F11/08C02F2101/006G21F9/08G21F9/165G21F9/304
    • A method and plant for wet-route oxidation treatment of hazardous organic waste products, notably radioactive wastes, which may contain mineral fillers, the waste products being treated in a secure environment. The plant comprises a closed space, with a mechanism for bringing a volume of hazardous organic waste products containing mineral fillers, adding a given quantity of water mixed with a base to the predetermined volume in order to adjust the pH to a determined value so as to make a solution and/or a liquid suspension, with a pressure reactor and with mechanism for transferring the solution and/or liquid suspension into the pressure reactor, and a device for introducing an oxygen atmosphere into the pressure reactor and for pressurizing the atmosphere. A heating mechanism is provided for subjecting the contents of the pressure reactor to heat treatment at a temperature between 150 and 350° C. to complete the wet-route oxidation.
    • 用于湿路线氧化处理有害有机废物的方法和设备,特别是可能含有矿物填料的放射性废物,废物在安全的环境中进行处理。 该植物包括封闭空间,其具有用于使大量含有矿物填料的有害有机废物产生的机构,将一定量的与基料混合的水添加至预定体积,以便将pH调节至确定值,以便 用压力反应器和用于将溶液和/或液体悬浮液转移到压力反应器中的机构制备溶液和/或液体悬浮液,以及用于将氧气氛引入压力反应器并对气氛加压的装置。 提供一种加热机构,用于使压力反应器的内容物在150-350℃的温度下进行热处理,以完成湿路径氧化。
    • 9. 发明申请
    • Supercritical water oxidation treatment system for organic wastewater with high salinity
    • 高盐度有机废水超临界水氧化处理系统
    • US20150128642A1
    • 2015-05-14
    • US14396732
    • 2012-12-05
    • XI'AN JIAOTONG UNIVERSITY
    • Shuzhong WangDonghal XuXingying TangYanmeng GongJie ZhangYuzhen Wang
    • F25J1/00
    • C02F11/086C02F1/20C02F1/385C02F5/00C02F9/00C02F11/08C02F2001/5218F25J1/0002
    • A supercritical water oxidation treatment system for organic wastewater with a high salinity crystallizes high-salinity wastewater by a low temperature of liquid oxygen, and decreases an inorganic salt content in the wastewater. Under supercritical water conditions, a hydrocyclone (4) separates most precipitated solid salts in the wastewater, so effectively prevents pipes and the tubular reactor (22) after the hydrocyclone (4) from plugging. Inorganic salts are able to be continuously separated from the system by the hydrocyclone (4) at the bottom of a desalination device, In addition, excess oxygen and gaseous products CO2 are recovered by a separation recovery part. The reaction time and the reaction temperature of supercritical water oxidation reaction are lowered due to the installation of a simple post-treatment unit (37). Moreover, the heat of the reactor effluent with a high temperature is recovered in the system, so operation cost of the system is reduced evidently.
    • 高盐度有机废水的超临界水氧化处理系统通过液氧低温结晶高盐度废水,降低废水中的无机盐含量。 在超临界水条件下,水力旋流器(4)分离废水中大部分沉淀固体盐,从而有效地防止水力旋流器(4)堵塞后的管道和管式反应器(22)。 无机盐能够通过脱盐装置底部的水力旋流器(4)与系统连续分离。此外,过量的氧气和气态产物CO 2通过分离回收部分回收。 由于安装简单的后处理单元(37),超临界水氧化反应的反应时间和反应温度降低。 此外,系统中回收了具有高温的反应器流出物的热量,因此系统的运行成本明显降低。