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    • 5. 发明授权
    • Process for producing .alpha.-methyl styrene-methyl
methacrylate-acrylonitrile thermoplastic resin
    • 制备α-甲基苯乙烯 - 甲基丙烯酸甲酯 - 丙烯腈热塑性树脂的方法
    • US4448580A
    • 1984-05-15
    • US421777
    • 1982-09-23
    • Mitsuo AbeSyuji TsuchikawaTeizo FukutaTsugio Asakawa
    • Mitsuo AbeSyuji TsuchikawaTeizo FukutaTsugio Asakawa
    • C08F2/00C08F2/22C08F212/00C08F212/10C08F212/12C08L25/12C08L25/16C08L55/02C08F257/02C08L33/12
    • C08L25/12C08F212/12C08L25/16C08L55/02
    • A thermoplastic resin having an excellent thermal stability and a high heat resistance is prepared by initiating polymerization of 65-85 parts by weight of a monomer mixture (A) consisting of 50-85% by weight of .alpha.-methylstyrene, 3-20% by weight of methyl methacrylate, 2-20% by weight of acrylonitrile, and 0-25% by weight of an aromatic alkenyl compound other than .alpha.-methylstyrene, continuously or intermittently adding, on the way of the polymerization, 2-15 parts by weight of a monomer (B) consisting of acrylonitrile or a mixture thereof with an aromatic alkenyl compound other than .alpha.-methylstyrene to the polymerization system while continuing the polymerization, further adding to the polymerization system 5-25 parts by weight of a monomer (C) consisting of an aromatic alkenyl compound other than .alpha.-methylstyrene, or a mixture thereof with acrylonitrile, and continuing the polymerization to complete the polymerization, the total amount of monomers (A), (B), and (C) being 100 parts by weight. Further, a thermoplastic resin composition having an excellent thermal stability, a high heat resistance and a high impact strength is prepared by mixing the thermoplastic resin thus obtained with a graft copolymer obtained by grafting 60-30 parts by weight of a monomer mixture consisting of 65-80% by weight of an aromatic alkenyl compound and 35-20% by weight of acrylonitrile on 40-70 parts by weight of a diene rubbery polymer in such a proportion that the composition contains 10-30% by weight of the rubbery polymer.
    • 通过引发65-85重量份由50-85重量%的α-甲基苯乙烯,3-20重量%的α-甲基苯乙烯组成的单体混合物(A)的引发聚合来制备具有优异的热稳定性和高耐热性的热塑性树脂 重量的甲基丙烯酸甲酯,2-20重量%的丙烯腈和0-25重量%的除α-甲基苯乙烯之外的芳族烯基化合物,在聚合过程中连续或间歇地加入2-15重量份 由丙烯腈或其与α-甲基苯乙烯以外的芳族烯基化合物的混合物组成的单体(B),同时继续进行聚合,进一步向聚合体系中加入5-25重量份的单体(C) 由除α-甲基苯乙烯以外的芳族烯基化合物或其与丙烯腈的混合物组成,并继续聚合以完成聚合,单体(A),(B)和(C) ng 100重量份。 此外,通过将由此获得的热塑性树脂与通过接枝60-30重量份的由65重量份组成的单体混合物获得的接枝共聚物来制备具有优异的热稳定性,高耐热性和高冲击强度的热塑性树脂组合物 -80重量%的芳族链烯基化合物和35-20重量%的丙烯腈,40-70重量份的二烯橡胶状聚合物的比例为组合物含有10-30重量%的橡胶状聚合物。