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1. 发明授权

US5714457A 2-hydroxypropanediamine derivative and detergent composition containing the same 失效
标题翻译： 2-羟基丙二胺衍生物和含有它们的洗涤剂组合物
公开(公告)号：US5714457A
公开(公告)日：1998-02-03
申请号：US569128
申请日：1996-01-11
申请人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
发明人： Tomohito Kitsuki , Mitsuru Uno , Katsumi Kita , Yoshiaki Fujikura , Akiko Nakano , Masaki Tosaka , Kazuyuki Yahagi , Shigeru Tamura , Kazunari Maruta
IPC分类号： A61K8/41 , A61K8/44 , A61K8/68 , A61Q5/00 , A61Q5/02 , A61Q19/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/13 , C07C309/14 , C07C309/17 , C11D1/02 , C11D1/10 , C11D1/28 , C11D1/92
CPC分类号： A61Q19/00 , A61K8/41 , A61K8/416 , A61K8/44 , A61K8/68 , A61Q5/00 , C07C229/12 , C07C229/16 , C07C233/18 , C07C233/20 , C07C233/36 , C07C233/38 , C07C235/08 , C07C235/10 , C07C305/06 , C07C309/14 , C07C309/17 , C11D1/10 , C11D1/28 , C11D3/0094 , A61K2800/75 , A61Q19/10 , A61Q5/02
摘要： The present invention relates to a 2-hydroxypropanediamine derivative represented by the following general formula (1): ##STR1## wherein R.sup.1 and R.sup.2 mean individually a linear or branched C.sub.6 -C.sub.36 alkyl or alkenyl group, X denotes a C.sub.1 -C.sub.6 alkylene or alkenylene group which may be substituted by at least one hydroxyl, sulfonic or carboxyl group and has 1-6 carbon atoms, y.sup.1 is a sulfonic group, a sulfuric acid residue or a carboxyl group, y.sup.2 means a hydroxyl group, a sulfuric acid residue or ##STR2## and n stands for 0 or 1, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01129 Sec。 371日期1996年1月11日 102（e）日期1996年1月11日PCT提交1994年7月11日PCT公布。出版物WO95 / 01955 日本1 9月19日本发明涉及由以下通式（1）表示的2-羟基丙二胺衍生物：其中R 1和R 2分别表示直链或支链C 6 -C 36烷基或链烯基，X 表示可以被至少一个羟基，磺酸或羧基取代并具有1-6个碳原子的C1-C6亚烷基或亚烯基，y1是磺酸基，硫酸残基或羧基，y2表示羟基基团，硫酸残基或，n表示0或1，或其盐或季铵化物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

2. 发明授权

US5409705A Phosphobetaine and detergent and cosmetic containing the same 失效
标题翻译：磷酸甜菜碱和洗涤剂和化妆品含有相同的含量
公开(公告)号：US5409705A
公开(公告)日：1995-04-25
申请号：US796337
申请日：1991-11-22
申请人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
发明人： Katsumi Kita , Mitsuru Uno , Hiroshi Kamitani , Yoshiaki Fujikura , Nobutaka Horinishi , Tomohito Kitsuki , Kazuyasu Imai , Yasushi Kajihara
IPC分类号： C07F9/09 , C07F9/655 , C07H11/04 , C07H15/04 , C08B31/06 , C11D1/88 , C11D3/22 , C11D3/36 , C07C69/76 , A61K7/06 , C07H15/00
CPC分类号： C11D3/364 , A61K8/55 , A61Q19/00 , C07F9/091 , C07F9/65515 , C07H11/04 , C07H15/04 , C08B31/066 , C11D1/886 , C11D3/228 , A61Q19/10 , A61Q5/00 , A61Q5/006 , A61Q5/02
摘要： A novel phosphobetaine is disclosed. This compound is very excellence in that it exerts a conditioning effect of imparting a good feel to the skin or hair, is excellent in humidifying properties, is available at a low price, and thus it is highly usable in detergents, cosmetics, a bathing preparation and the like. A detergent composition, a cosmetic, and a bathing preparation each containing the phosphobetaine are also disclosed.
摘要翻译：公开了一种新的磷酸甜菜碱。该化合物非常优异地发挥赋予皮肤或毛发良好感觉的调理效果，加湿性优异，可以低价位获得，因此其可用于洗涤剂，化妆品，洗浴用品等等。还公开了含有磷酸甜菜碱的洗涤剂组合物，化妆品和洗浴剂。

3. 发明授权

US5136112A Process for preparing 2-hydroxy-2 5, 5, 9-tetramethyldecalyl ethanol 失效
标题翻译：制备2-羟基-5,5,9-四甲基乙基醚的方法
公开(公告)号：US5136112A
公开(公告)日：1992-08-04
申请号：US736927
申请日：1991-07-29
申请人： Tomohito Kitsuki , Yoshiaki Fujikura
发明人： Tomohito Kitsuki , Yoshiaki Fujikura
IPC分类号： C07C29/149 , C07C29/147 , C07C29/94 , C07C35/23 , C07C35/36
CPC分类号： C07C35/36 , C07C29/147 , C07C2102/28
摘要： A process for preparing 2-hydroxy-2, 5, 5, 9-tetramethyldecalyl ethanol of formula (II): ##STR1## which comprises reducing 3a, 6, 6, 9a-tetramethyldecahydro-naphto[2, 1-b]furan-2(1H)-one of formula (I): ##STR2## with an alkali metal boron hydride in the presence of a hydroxyl ether compound.

4. 发明授权

US5929283A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5929283A
公开(公告)日：1999-07-27
申请号：US935539
申请日：1997-09-23
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C215/06
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译：本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可具有-OH并且具有1-24个碳原子的烷基或烯基，A表示亚烷基或亚烯基，可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子，y1是-COOH，-SO3H或-OSO3H，y2表示-OH，-OSO3H或-OCO-A-COOH，n表示 0或1的数，p为1-8的整数，或其盐或季铵化产物，以及含有这种化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉快的感觉。

5. 发明授权

US4839340A Bornane-3-spiro-1'-cyclopentane derivatives and perfumery compositions containing them 失效
标题翻译：戊烷-3-螺-1'-环戊烷衍生物和含有它们的香料组合物
公开(公告)号：US4839340A
公开(公告)日：1989-06-13
申请号：US213151
申请日：1988-06-29
申请人： Yoshiaki Fujikura , Tomohito Kitsuki , Manabu Fujita , Nao Toi
发明人： Yoshiaki Fujikura , Tomohito Kitsuki , Manabu Fujita , Nao Toi
IPC分类号： A61L9/01 , A61K8/33 , A61K8/34 , A61K8/37 , A61Q13/00 , C07C27/00 , C07C35/30 , C07C35/37 , C07C41/00 , C07C43/18 , C07C67/00 , C07C69/013 , C07C69/02 , C11B9/00 , C11D3/50 , C11D9/44
CPC分类号： C07C35/30 , C07C43/18 , C11B9/0057
摘要： The invention provides derivatives of bornane-3-spiro-1'-cyclopentane with woody note scent useful as a base component in perfumery formulations which comprises those having a substituting group selected from a methoxyl, ethoxyl, formyloxyl and acetoxyl groups or two of substituting groups being either a hydroxyl group and a methyl group or a hydroxyl group and an ethyl group at the 2-position synthesized by any of the reactions of borane-3-spiro-1'-cyclopentan-2--ol or bornane-3-spiro-1'-cyclopentan-2-one with any of the reagents selected in accordance with the substituting group(s) to be introduced.The invention also provides perfumery compositions containing the above.

6. 发明授权

US5801270A Amine derivative and detergent composition containing the same 失效
标题翻译：胺衍生物和含有它的洗涤剂组合物
公开(公告)号：US5801270A
公开(公告)日：1998-09-01
申请号：US646338
申请日：1996-06-13
申请人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
发明人： Mitsuru Uno , Tomohito Kitsuki , Katsumi Kita , Yoshiaki Fujikura , Akiko Okutsu
IPC分类号： A61K8/00 , A61K8/40 , A61K8/42 , A61K8/44 , A61K8/46 , A61Q5/02 , A61Q5/12 , A61Q19/10 , C07C215/18 , C07C229/16 , C07C233/36 , C07C305/06 , C07C309/14 , C07C309/17 , C10M133/08 , C10N30/04 , C10N40/25 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90 , C11D1/92 , C07C229/00 , C11D1/04 , C11D1/46
CPC分类号： C11D1/92 , A61K8/44 , A61K8/463 , A61K8/466 , A61Q19/10 , A61Q5/02 , A61Q5/12 , C07C215/18 , C07C233/36 , C07C305/06 , C07C309/17 , C11D1/10 , C11D1/18 , C11D1/28 , C11D1/42 , C11D1/90
摘要： The present invention relates to an amine derivative represented by the following general formula (1): ##STR1## wherein R.sup.2 and R.sup.3 mean individually an alkyl or alkenyl group which may have --OH and has 1-24 carbon atoms, A denotes an alkylene or alkenylene group which may have at least one --OH, --COOH or --SO.sub.3 H and has 1-6 carbon atoms, Y.sup.1 is --COOH, --SO.sub.3 H or --OSO.sub.3 H, Y.sup.2 means --OH, --OSO.sub.3 H or --OCO--A--COOH, n stands for a number of 0 or 1, and p is an integer of 1-8, or a salt or quaternized product thereof, and a detergent composition containing such a compound. This compound is low in irritativeness to the skin and hair and excellent in foamability, and can give a pleasant feeling to the user's skin and the like.
摘要翻译： PCT No.PCT / JP94 / 01923 Sec。 371日期：1996年6月13日 102（e）1996年6月13日PCT 1994年11月14日PCT PCT。出版物WO95 / 16664 日期：1995年6月22日本发明涉及由以下通式（1）表示的胺衍生物：其中R2和R3分别表示可以具有-OH并具有1-24的烷基或烯基碳原子，A表示可以具有至少一个-OH，-COOH或-SO 3 H并且具有1-6个碳原子的亚烷基或亚烯基，Y 1是-COOH，-SO 3 H或-OSO 3 H，Y 2表示-OH，-OSO 3 H 或-OCO-A-COOH，n表示0或1的数，p表示1-8的整数，或其盐或季铵化产物，以及含有该化合物的洗涤剂组合物。该化合物对皮肤和头发的刺激性低，起泡性优异，并且可以给使用者的皮肤等提供愉悦的感觉。

7. 发明授权

US5196601A Process for producing alcohol or amine 失效
标题翻译：生产醇或胺的方法
公开(公告)号：US5196601A
公开(公告)日：1993-03-23
申请号：US899951
申请日：1992-06-17
申请人： Tomohito Kitsuki , Yoshiaki Fujikura
发明人： Tomohito Kitsuki , Yoshiaki Fujikura
IPC分类号： C07C29/132 , C07C29/143 , C07C29/147 , C07C35/29 , C07C209/48 , C07C209/50
CPC分类号： C07C209/48 , C07C209/50 , C07C29/132 , C07C29/143 , C07C29/147 , C07C35/29 , C07C2101/14 , C07C2103/94
摘要： Disclosed herein is a process for producing an alcohol or an amine by reducing a compound having a formyl, keto, nitro, oxirane, ester, nitrile, amide or halogenated carboxyl group with an alkali metal boro-hydride in the presence of a compound having a hydroxyl group and ether linkage. According to the present invention, a functional group having a great steric hindrance can be reduced, and a corresponding alcohol or amine can efficiently be produced under very mild conditions on an industrial scale.
摘要翻译：本文公开了一种通过在具有甲酰基，酮基，硝基，环氧乙烷，酯，腈，酰胺或卤代羧基的化合物与碱金属硼氢化物的存在下还原具有甲酰基，酮基，硝基，环氧乙烷，羟基和醚键。根据本发明，可以降低具有大的空间位阻的官能团，并且在非常温和的条件下可以在工业规模上有效地生产相应的醇或胺。

8. 发明授权

US5872272A Polyvalent metal salts of phosphoric diester and organo(poly)siloxanes modified with polyvalent metal salt of phosphoric diester 失效
标题翻译：磷酸二酯的多价金属盐和用磷酸二酯的多价金属盐改性的有机（聚）硅氧烷
公开(公告)号：US5872272A
公开(公告)日：1999-02-16
申请号：US454181
申请日：1995-06-15
申请人： Shinji Yano , Junichi Fukasawa , Hironori Kawasaki , Munehisa Okutsu , Takeshi Ihara , Katsumi Kita , Yoshiaki Fujikura , Akira Akaogi
发明人： Shinji Yano , Junichi Fukasawa , Hironori Kawasaki , Munehisa Okutsu , Takeshi Ihara , Katsumi Kita , Yoshiaki Fujikura , Akira Akaogi
IPC分类号： A61K8/55 , A61K8/893 , A61K8/896 , A61Q1/02 , A61Q17/04 , A61Q19/00 , A61Q19/10 , C07F7/08 , C07F9/09 , C07F9/6596 , C08G77/30 , C08G77/395 , C08G77/48 , C08G79/04
CPC分类号： C08G77/48 , A61K8/55 , A61K8/896 , A61Q19/00 , C07F9/091 , C07F9/092 , C07F9/6596 , C08G77/395 , A61Q1/02 , A61Q17/04
摘要： The present invention relates to polyvalent metal salts of a phosphoric diester represented by formula (1) and organo(poly)siloxanes modified with a polyvalent metal salt of a phosphoric diester having the structural units represented by formulae (9) and (10): ##STR1## wherein R.sup.1 represents a C1 to C20 linear or branched alkyl group, R.sup.2 and R.sup.4 are the same or different and independently represent a C2 to C3 linear or branched alkylene group, R.sup.3 represents a C3 to C20 linear or C5 to C20 branched alkylene group, A represents a group --COO-- or --O--, x and y are the same or different from each other and independently represent an integer of 0 to 10, L represents a C1 to C40 linear or branched alkyl group or a group, R.sup.1 --(OR.sup.2).sub.x --A--R.sup.3 (OR.sup.4).sub.y -- wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, A, x and y have the same meaning as defined herein before, M represents a divalent or polyvalent metal atom, and m represents the same value as the valence of M.
摘要翻译： PCT No.PCT / JP93 / 01924 Sec。 371日期：1995年6月15日 102（e）日期1995年6月15日PCT 1993年12月28日PCT PCT。公开号WO94 / 14822 日期：1994年7月7日本发明涉及由式（1）表示的磷酸二酯的多价金属盐和由具有式（9）所示的结构单元的磷酸二酯的多价金属盐改性的有机（聚）硅氧烷，（10）：其中R1表示C1〜C20直链或支链烷基，R2和R4相同或不同，并且独立地表示C2〜C3直链或支链亚烷基，R3表示C3〜C20 线性或C5至C20支链亚烷基，A表示基团-COO-或-O-，x和y彼此相同或不同，并且独立地表示0至10的整数，L表示C1至C40直链或支化烷基或基团，R1-（OR2）xA-R3（OR4）y-，其中R1，R2，R3，R4，A，x和y具有如前所定义的相同含义，M表示二价或多价金属原子，m表示与M的化合价相同的值。

9. 发明授权

US5457222A Process for producing nitrile 失效
标题翻译：制备腈的方法
公开(公告)号：US5457222A
公开(公告)日：1995-10-10
申请号：US396586
申请日：1995-03-01
申请人： Masayuki Oku , Yoshiaki Fujikura
发明人： Masayuki Oku , Yoshiaki Fujikura
IPC分类号： C07C253/00
CPC分类号： C07C253/00
摘要： The present invention provides a process for producing a nitrile represented by the general formula (1):RC.ident.N (1)wherein R is alkyl, alkenyl, aralkyl or aryl, each may have a substituent, characterized by heating an aldoxime represented by the general formula (2):RCH=NOH (2)wherein R is as defined above, in the presence of one or more catalysts selected from hydroxides of alkali metals, alcoholates of alkali metals, hydroxides of alkaline earth metals and alcoholates of alkaline earth metals, and distilling off water formed in the course of the reaction from the reaction system. The process according to the present invention can produce a nitrile which is useful as a perfume or as a starting material for the organic synthesis of perfumes, medicines and so on in high yields and advantageously from the viewpoint of production economy.
摘要翻译：本发明提供一种制备由通式（1）表示的腈的方法：RC = N（1）其中R是烷基，烯基，芳烷基或芳基，各自可以具有取代基，其特征在于加热由在一种或多种选自碱金属的氢氧化物，碱金属的醇化物，碱土金属的氢氧化物和碱土金属的醇化物的催化剂的存在下，通式（2）：RCH = NOH（2）其中R的定义同上，并从反应体系中蒸馏出在反应过程中形成的水。根据本发明的方法可以产生腈，其可以作为香料或用作有机合成香料，药物等的高产率的有机合成起始材料，并且从生产经济性的观点来看是有利的。

10. 发明授权

US5446208A Process for producing ether alcohols by hydrogenolysis of cyclic ketal 失效
标题翻译：通过环状缩酮氢解生产醚醇的方法
公开(公告)号：US5446208A
公开(公告)日：1995-08-29
申请号：US209277
申请日：1994-03-14
申请人： Junji Koshino , Hajime Miyabe , Yoshiaki Fujikura
发明人： Junji Koshino , Hajime Miyabe , Yoshiaki Fujikura
IPC分类号： B01J23/44 , B01J23/46 , B01J23/89 , C07B61/00 , C07C41/28 , C07C43/196 , C07C41/48
CPC分类号： C07C41/28 , C07C2101/14
摘要： A process for the production of an ether alcohol is disclosed, which comprises subjecting a cyclic ketal to hydrogenolysis in the presence of a catalyst containing palladium in an amount of from 50 to 100% by weight, based on the total active catalytic component present. According to the inventive process, ether alcohols which are useful as perfumes or raw materials for perfumes can be produced easily with low cost and high yield.
摘要翻译：公开了一种制备醚醇的方法，其包括在存在钯的催化剂的存在下，以存在的总活性催化剂成分为50-100重量％的量使环状缩酮进行氢解。根据本发明的方法，可以容易地以低成本和高产率生产用作香料或香料原料的醚醇。

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