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1. 发明申请

US20230062627A1 ACETAL COMPOUNDS AND PROCESSES FOR PREPARING THEREOF, AND PROCESSES FOR PREPARING ALDEHYDE COMPOUNDS FROM THE ACETAL COMPOUNDS 有权
公开(公告)号：US20230062627A1
公开(公告)日：2023-03-02
申请号：US17861629
申请日：2022-07-11
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Takeru Watanabe , Takeshi Kinsho
IPC分类号： C07C45/51 , C07C41/48 , C07C43/305
摘要： The present invention relates to an acetal compound of the following general formula (1) and an acetal compound of the following general formula (2). The present invention relates to processes for preparing the acetal compound (2), comprising subjecting the acetal compound (1) to a hydrogenation reaction to form the acetal compound (2). The present invention provides a process for preparing 2,3,4,4-tetramethylcyclopentanecarbaldehyde of the following formula (3), comprising subjecting the acetal compound (2) to a hydrolysis reaction to form 2,3,4,4-tetramethylcyclopentanecarbaldehyde (3).

2. 发明申请

US20210395641A1 PERFUMING INGREDIENTS WITH LILY OF THE VALLEY NOTE 有权
公开(公告)号：US20210395641A1
公开(公告)日：2021-12-23
申请号：US17292836
申请日：2018-11-13
申请人： SYMRISE AG
发明人： Bernd HÖLSCHER , Vijayanand CHANDRASEKARAN , Eva KIERMASCH
IPC分类号： C11B9/00 , C07C45/51 , C07C67/343 , C07C67/31 , C07C45/65 , C07C41/48
摘要： The present invention primarily relates to the use of 3-(4-isobutyl-2-methyl-cyclohexyl)pro-panal, 3-(4-Isobutyl-6-methyl-cyclohexa-1,5-dien-1-yl)propanal, 3-(4-isobutyl-6-meth-ylene-cyclohexen-1-yl)propanal, or 3-(4-isobutyl-6-methyl-cyclohexen-1-yl)propanal as perfuming ingredients. Moreover, the present invention relates to perfume compositions and perfumed products comprising the before mentioned perfuming ingredients. Still more particularly, the invention relates to a method for producing said perfumed products and a method of imparting and/or increasing i) floral and/or ii) green and/or iii) lily of the valley odor characteristics to perfumed products. This invention also relates to 3-(4-isobutyl-2-methyl-cyclohexyl)propanal, 3-(4-Isobutyl-6-methyl-cyclohexa-1,5-dien-1-yl)propanal, 3-(4-isobutyl-6-methylene-cyclohexen-1-yl)propanal, or 3-(4-isobutyl-6-methyl-cyclohexen-yl)propanal and a process for the preparation of said compounds.

3. 发明授权

US10377689B2 Process for preparing polyoxymethylene dimethyl ethers from formaldehyde and methanol in aqueous solutions 有权
公开(公告)号：US10377689B2
公开(公告)日：2019-08-13
申请号：US15807092
申请日：2017-11-08
申请人： OME Technologies GmbH
发明人： Jakob Burger , Niklas Schmitz , Hans Hasse , Eckhard Stroefer
IPC分类号： C07C41/56 , C07C41/58 , C07C41/60 , B01D3/00 , B01D3/14 , C07C41/48 , C07C43/11
摘要： Process for preparing polyoxymethylene dimethyl ethers having ≥3 oxymethylene units (OMEn≥3), comprising the steps:(i) introduction of formaldehyde, methanol and water into a reactor R and reaction to give a reaction mixture containing formaldehyde, water, methylene glycol, polyoxymethylene glycols, methanol, hemiformals, methylal (OMEn=1) and polyoxymethylene dimethyl ethers (OMEn>1); (ii) introduction of the reaction mixture into a reactive distillation column K1 and separation into a low boiler fraction F1 containing formaldehyde, water, methylene glycol, polyoxymethylene glycols, methanol, hemiformals, methylal (OMEn=1) and polyoxymethylene dimethyl ethers having from 2 to 3 oxymethylene units (OMEn=2-3) and a high boiler fraction F2 containing polyoxymethylene dimethyl ethers having more than two oxymethylene units (OMEn≥3).

4. 发明授权

US09845304B2 Method for producing asymmetric conjugated diyne compound and method for producing Z,Z-conjugated diene compound using the same 有权
公开(公告)号：US09845304B2
公开(公告)日：2017-12-19
申请号：US15014598
申请日：2016-02-03
申请人： Shin-Etsu Chemical Co., Ltd.
发明人： Yuki Miyake , Takeshi Kinsho , Miyoshi Yamashita , Naoki Ishibashi , Yusuke Nagae , Akihiro Baba
IPC分类号： C07C17/266 , C07C17/269 , C07C2/86 , C07C29/10 , C07C29/32 , C07C41/48 , C07C45/26 , C07C45/51 , C07C67/08 , C07C67/40 , C07D309/12
CPC分类号： C07D309/12 , C07B2200/09 , C07C2/861 , C07C17/266 , C07C17/269 , C07C29/103 , C07C29/32 , C07C41/48 , C07C45/26 , C07C45/515 , C07C67/08 , C07C67/40 , C07C2527/122 , C07C33/04 , C07C21/22 , C07C43/303 , C07C43/30 , C07C47/21 , C07C33/02 , C07C69/145 , C07C11/22 , C07C2/32
摘要： Provided are a method for efficiently producing an asymmetric conjugated diyne from an inexpensive and safe alternative compound to hydroxylamine hydrochloride and a method for producing a Z,Z-conjugated diene compound from the asymmetric conjugated diyne compound thus obtained. More specifically, provided is a method for producing an asymmetric conjugated diyne compound comprising a step of subjecting a terminal alkyne compound (1): HC≡C—Z1—Y1 to a coupling reaction with an alkynyl halide (2): Y2—Z2—C≡C—X by using sodium borohydride in water and an organic solvent in the presence of a copper catalyst and a base to obtain the asymmetric conjugated diyne compound (3): Y2—Z2—C≡C—C≡C—Z1—Y1. In addition, provided is a method for producing a Z,Z-conjugated diene compound by reducing the resulting asymmetric conjugated diyne compound, or the like.

5. 发明申请

US20170297987A1 METHOD OF PRODUCING ALIPHATIC ALDEHYDE COMPOUND HAVING TERMINAL CONJUGATED DIENE STRUCTURE AND INTERMEDIATE THEREFOR 审中-公开
公开(公告)号：US20170297987A1
公开(公告)日：2017-10-19
申请号：US15473150
申请日：2017-03-29
申请人： SHIN-ETSU CHEMICAL CO., LTD.
发明人： Akihiro Baba , Yuki MIYAKE , Takeshi KINSHO
IPC分类号： C07C43/315 , C07C41/48
CPC分类号： C07C43/315 , C07C41/20 , C07C41/30 , C07C41/48 , C07C43/178 , C07C45/42 , C07C45/81 , C07C45/82 , C07C47/21 , C07C303/28 , C07C47/02 , C07C43/313 , C07C43/303 , C07C309/66
摘要： Provided are a method for producing a terminal conjugated dienal compound without an oxidation reaction and a terminal hydroxyacetal compound useful as an intermediate in the method. More specifically, provided are a method for producing an (E)-dienal compound comprising the steps of: a metalation reaction of an alkynal acetal compound (1) to obtain an organic metal compound (2), an addition reaction of (2) to ethylene oxide to obtain a hydroxyalkynal acetal compound (3), a reduction reaction of (3) to obtain an (E)-hydroxyalkenal acetal compound (4), a functional group conversion reaction of (4) to obtain an (E)-alkenal acetal compound (5) having a leaving group X, an elimination reaction of (5) to obtain an (E)-dienal acetal compound (6), and a hydrolysis reaction of (6) to obtain the (E)-dienal compound (7); and others.

6. 发明申请

US20160185683A1 PROCESS OF ASYMMETRIC HYDROGENATION OF KETALS AND ACETALS 有权
标题翻译：乙醇和乙酸盐的不对称加氢方法
公开(公告)号：US20160185683A1
公开(公告)日：2016-06-30
申请号：US14652562
申请日：2013-12-18
申请人： DSM IP ASSETS B.V.
发明人： Werner BONRATH , Thomas NETSCHER , Jonathan Alan MEDLOCK , Gerardus Karel Maria VERZIJL , Andreas Hendrikus Maria DE VRIES
IPC分类号： C07B35/02 , C07C41/48 , B01J31/18 , C07D317/12 , C07D319/06 , C07C41/56 , C07C41/58
CPC分类号： C07B35/02 , B01J31/189 , B01J2231/34 , B01J2531/827 , C07B53/00 , C07B2200/07 , C07B2200/09 , C07C41/48 , C07C41/56 , C07C41/58 , C07D311/72 , C07D317/12 , C07D319/06 , C07C43/303 , C07C43/313
摘要： The present invention relates to a process of the asymmetric hydrogenation of a ketal of an unsaturated ketone or an acetal of an unsaturated aldehyde by molecular hydrogen in the presence of at least one chiral iridium complex. This process yields chiral compounds in a very efficient way and is very advantageous in that the amount of iridium complex can be remarkably reduced.
摘要翻译：本发明涉及在至少一种手性铱络合物的存在下，通过分子氢在不饱和酮或不饱和醛的缩醛中缩酮的不对称氢化的方法。该方法以非常有效的方式产生手性化合物，并且非常有利的是铱络合物的量可以显着降低。

7. 发明申请

US20130053598A1 METHOD FOR PRODUCING A CROSS-COUPLING PRODUCT OF A BENZENOID DIAZONIUM SALT 审中-公开
公开(公告)号：US20130053598A1
公开(公告)日：2013-02-28
申请号：US13265736
申请日：2010-04-22
申请人： Nicolas Boege , Andreas Kreipl , Bernd Schmidt , Frank Hoelter , René Berger
发明人： Nicolas Boege , Andreas Kreipl , Bernd Schmidt , Frank Hoelter , René Berger
IPC分类号： C07C67/293 , C07C37/11 , C07C41/48 , C07C67/343 , C07C201/12
CPC分类号： C07C37/11 , C07C37/14 , C07C41/48 , C07C45/511 , C07C245/20 , Y02P20/55 , C07C39/15 , C07C39/19 , C07C47/27 , C07C43/307 , C07C43/315
摘要： The invention relates to a method for producing a cross-coupling product of a benzenoid dizonium salt according to the general formula (I), wherein the groups R1, R2, R3, R4, and R5 represent hydrogen, halogen, an alkyl, alkenyl, aryl, alkoxy, aryloxy, nitro, cyano, hydroxy, acetyl, and/or diazo groups independently of each, and X represents BF4, Cl, F, SO3CH3, CO2CH3, PF6, ClO2CH3, or CIO4, comprising the following steps: (a) providing a benzenoid amide, which with the exception of the diazo function has the same substituents R1, R2, R3, R4, and R5 as the benzenoid diazonium salt of the general formula (I), and hydrolytically cleaving the amide to form an amine or providing a corresponding amine, (b) diazotizing the amine thus obtained or provided with a nitrite, and (c) subsequently reacting the benzenoid diazonium salt with a coupling partner in the presence of a catalyst to form a cross-coupling product, wherein the coupling parter is represented by the general formula (II), R6, R7, and R8 are the same or different and represent hydrogen, carboxyalkyl groups, carboxyaryl groups, alkyl groups, aryl groups, alkoxy groups, aryloxy groups, wherein the groups can each contain Si, N, S, O, and or halogen atoms, or R6 and R7 with the double bound form an aromatic ring, which can be provided with R8 and one to four further substituents, independently of each other, selected from the group comprising a straight-chain or branched (C1-C6) alkyl group, a (C3-C7) cycloalkyl group, a straight-chain or branched (C1-C6) alkenyl group, a straight-chain or branched (C1-C6) alkyoxy group, halogen, the hydroxy group, an amino, di(C1-C6) alkylamino, nitro, acetyl, cyan, benzyl, 4-methoxybenzyl, 4-nitrobenzyl, phenyl, and 4-methoxyphenyl group and represents Y=H, —B(OR)2, —SnR3, —ZnR, —SiR3, or Mg (halogen), and wherein at least the steps (b) and (c) are performed without intermediate isolation of an intermediate product. According to said method, cross-couplings can be performed more simply and with improved yield without the hydroxyl group in aromatic reactants containing hydroxyl groups having to be provided with a protective group.

8. 发明授权

US06919480B2 Processes for the preparation of fluorinated acyl fluorides and fluorinated vinyl ethers 失效
标题翻译：氟化氟化物和氟化乙烯基醚的制备方法
公开(公告)号：US06919480B2
公开(公告)日：2005-07-19
申请号：US10727610
申请日：2003-12-05
申请人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Daisuke Shirakawa , Shin Tatematsu
发明人： Takashi Okazoe , Kunio Watanabe , Masahiro Ito , Daisuke Shirakawa , Shin Tatematsu
IPC分类号： C07C41/48 , C07C43/313 , C07C51/58 , C07D317/42 , C08F16/24 , C08F24/00 , C07C51/62
CPC分类号： C08F24/00 , C07C41/48 , C07C51/58 , C07D317/42 , C08F16/24 , C07C59/135 , C07C43/313
摘要： The present invention provides novel processes for preparing a fluorinated acyl fluoride and a fluorinated vinyl ether.Namely, it provides a process for preparing a fluorinated acyl fluoride (3), which comprises reacting a compound (1) having a fluorine content of 30 mass % or above with fluorine in a liquid phase to form a compound (2) and then dissociating the ester bond in the compound (2), and a process for preparing a fluorinated vinyl ether (10), which comprises pyrolyzing the fluorinated acyl fluoride: wherein RA and RB are alkyl groups or the like, or the combination RA and RB is an ethereal oxygen-containing alkylene group or the like, RC and RD are perfluoro(ethereal oxygen-containing alkyl) groups or the like, or the combination of RC and RD is a perfluoro(ethereal oxygen-containing alkylene) group or the like, X1, X2, X3, X4, X5 and X6 are hydrogen atoms, fluorine atoms or the like, RAF, RBF, RCF and RDF are groups derived respectively from RA, RB, RC and RD by replacing substantially all of the hydrogen atoms by fluorine atoms.
摘要翻译：本发明提供了制备氟化酰氟和氟化乙烯基醚的新方法。即，提供一种制备氟化酰基氟（3）的方法，其包括使氟含量为30质量％以上的化合物（1）与氟在液相中反应以形成化合物（2），然后解离化合物（2）中的酯键和制备氟化乙烯基醚（10）的方法，其包括热解氟化酰基氟：其中R A A和R B B >是烷基等，或者组合R A和B B是含醚的含氧亚烷基等，R 0 C >和R“D”是全氟（醚类含氧烷基）基团等，或者R 0和R D 2的组合是全氟（醚性亚烷基）亚烷基等，X 1，X 2，X 3，X 4， SUP>，X 5和X 6是氢原子，氟原子等，R AF，BF，BF >，R＆lt; CF＆gt;和R＆gt; DF 是分别由R A，R B，R C和R D D衍生的基团，用氟原子代替基本上所有的氢原子。

9. 发明授权

US5753776A Liquid-phase fluorination 失效
标题翻译：液相氟化
公开(公告)号：US5753776A
公开(公告)日：1998-05-19
申请号：US471031
申请日：1995-06-06
申请人： Thomas R. Bierschenk , Timothy J. Juhlke , Hajimu Kawa , Richard J. Lagow
发明人： Thomas R. Bierschenk , Timothy J. Juhlke , Hajimu Kawa , Richard J. Lagow
IPC分类号： C07B39/00 , C07C17/02 , C07C17/06 , C07C17/12 , C07C29/62 , C07C31/40 , C07C41/22 , C07C41/48 , C07C43/12 , C07C43/313 , C07C43/315 , C07C43/32 , C07C45/54 , C07C49/167 , C07C67/307 , C07C209/74 , C07C211/15 , C08G65/00 , C08G65/323 , C08G65/337 , C07C17/10
CPC分类号： C08G65/337 , C07B39/00 , C07C17/02 , C07C17/06 , C07C17/12 , C07C209/74 , C07C211/15 , C07C29/62 , C07C31/40 , C07C41/22 , C07C41/26 , C07C41/48 , C07C41/60 , C07C45/54 , C07C49/167 , C07C67/307 , C08G65/00 , C08G65/007 , C08G65/3236 , C07C2101/14 , C07C2103/26
摘要： This invention pertains to a method for liquid phase fluorination for perfluorination of a wide variety of hydrogen-containing compounds.
摘要翻译：本发明涉及用于全氟化各种含氢化合物的液相氟化方法。

10. 发明授权

US5557012A Fluorination of acetals, ketals and orthoesters 失效
公开(公告)号：US5557012A
公开(公告)日：1996-09-17
申请号：US461995
申请日：1995-06-05
申请人： Thomas R. Bierschenk , Timothy J. Juhlke , Hajimu Kawa , Richard J. Lagow
发明人： Thomas R. Bierschenk , Timothy J. Juhlke , Hajimu Kawa , Richard J. Lagow
IPC分类号： C07C41/48 , C07C41/60 , C07C43/313 , C07C43/315 , C08G2/30 , C08G4/00 , C08G65/00 , C08G65/30 , C08G65/323 , C08G65/34 , C08G65/46 , C07C59/245 , C07C43/30 , C07C43/32
CPC分类号： C07C41/48 , C07C41/60 , C07C43/313 , C07C43/315 , C08G2/30 , C08G4/00 , C08G65/007 , C08G65/30 , C08G65/3236 , C08G65/34 , C08G65/46
摘要： This invention pertains to perfluoropolyethers and perhalogenated chlorofluoroether polymers that can be prepared by fluorinating polymers made by the polymerization of acetals, ketals, polyacetals, polyketals and orthoesters with elemental fluorine.

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