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1. 发明授权

US4055607A Acrylic coating compositions 失效
标题翻译：丙烯酸涂料组合物
公开(公告)号：US4055607A
公开(公告)日：1977-10-25
申请号：US602857
申请日：1975-08-07
申请人： Thomas R. Sullivan , Roger M. Christenson , Suryya K. Das , Rostyslaw Dowbenko
发明人： Thomas R. Sullivan , Roger M. Christenson , Suryya K. Das , Rostyslaw Dowbenko
IPC分类号： C08L33/06 , C08L57/00 , C08L61/20 , C09D133/06 , C09D157/10 , C08L61/28 , C08K5/01 , C08L51/08
CPC分类号： C09D157/10 , C08L57/00 , C09D133/066 , C08L2205/02 , C08L2205/18 , C08L33/066 , C08L61/20
摘要： Insoluble microgel particles are added to solutions of polymerized ethylenically unsaturated monomers containing hydroxyl groups. The solutions may be spray coated onto various substrates in two coat applications to form coatings having improved gloss, film build and pattern control. The coatings are especially useful as automotive finishes.
摘要翻译：将不溶性微凝胶颗粒加入到含有羟基的聚合的烯属不饱和单体的溶液中。溶液可以在两个涂层应用中喷涂到各种基材上，以形成具有改善的光泽，成膜和图案控制的涂层。涂料特别适用于汽车涂料。

2. 发明授权

US4380601A Thermosetting catonic acrylic latices and their use in coating compositions 失效
标题翻译：热固性聚氨酯胶乳及其在涂料组合物中的应用
公开(公告)号：US4380601A
公开(公告)日：1983-04-19
申请号：US305585
申请日：1981-09-25
申请人： David A. Welsh , Rostyslaw Dowbenko , Suryya K. Das , Charles M. Kania , Roger M. Christenson
发明人： David A. Welsh , Rostyslaw Dowbenko , Suryya K. Das , Charles M. Kania , Roger M. Christenson
IPC分类号： C08F2/00 , C08F2/22 , C08F2/24 , C08F2/28 , C08F220/00 , C08F220/04 , C08G18/00 , C08G18/62 , C08L75/00 , C08L75/04 , C09D133/06 , C09D175/04 , C08L75/12 , C08L33/12
CPC分类号： C08F2/28 , C09D133/066 , C08L75/04 , Y10T428/31605
摘要： A cationic thermosetting latex, coating compositions prepared therefrom, and the process for providing a protective coating are disclosed. The thermosetting latex comprises a blocked isocyanate curing agent and a cationic acrylic latex which is prepared by copolymerizing ethylenically unsaturated monomers, at least one of which contains an active hydrogen group, in an acidic medium in the presence of a cationic surfactant, of which the gegen-ion is derived from certain phosphorous-containing acids. Such latices, when formulated into coating compositions, provide corrosion-resistant coatings.
摘要翻译：公开了阳离子热固性胶乳，由其制备的涂料组合物和提供保护涂层的方法。热固性胶乳包括封端的异氰酸酯固化剂和阳离子丙烯酸胶乳，其通过在阳离子表面活性剂的存在下在酸性介质中共聚烯键式不饱和单体（其中至少一种含有活性氢基团）衍生自某些含磷酸。当制成涂料组合物时，这种胶乳提供耐腐蚀涂层。

3. 发明授权

US4327008A Urethane rheology modifiers and coating compositions containing same 失效
标题翻译：聚氨酯流变改性剂和含有它们的涂料组合物
公开(公告)号：US4327008A
公开(公告)日：1982-04-27
申请号：US221146
申请日：1980-12-29
申请人： Karl F. Schimmel , Jerome A. Seiner , Roger M. Christenson , Rostyslaw Dowbenko
发明人： Karl F. Schimmel , Jerome A. Seiner , Roger M. Christenson , Rostyslaw Dowbenko
IPC分类号： C08G18/28 , C08G18/30 , C08G18/66 , C08G18/71 , C08G18/72 , C09D7/00 , C08G18/12 , C08G18/48
CPC分类号： C08G18/6666 , C08G18/2805 , C08G18/302 , C08G18/6677 , C08G18/71 , C08G18/721 , C09D7/002 , C08L75/04
摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate, water and a monofunctional active hydrogen-containing compound or monoisocyanate. The modifiers are characterized by having a branched structure, urea linkages and terminal hydrophobic groups.
摘要翻译：可用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯，水和单官能活性氢化合物或单异氰酸酯的反应。改性剂的特征在于具有支链结构，脲键和末端疏水基团。

4. 发明授权

US4298511A Urethane rheology modifiers and compositions containing same 失效
标题翻译：聚氨酯流变改性剂和含有它的组合物
公开(公告)号：US4298511A
公开(公告)日：1981-11-03
申请号：US174479
申请日：1980-08-01
申请人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C09K3/00 , B01F17/52 , C08G18/00 , C08G18/30 , C08G18/65 , C08G18/66 , C08G18/72 , C09D7/00 , C09D7/12 , C08G18/48
CPC分类号： C09D7/002 , C08G18/302 , C08G18/6666 , C08G18/6677 , C08G18/721 , C08L75/04
摘要： Rheology modifiers useful in water-and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
摘要翻译：用于水和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能物质，二异氰酸酯和水的反应。改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

5. 发明授权

US4252935A Esters of diglycidyl polyethers of hydrogenated phenols and coating compositions containing same 失效
标题翻译：氢化苯酚的二缩水甘油醚聚醚和含有它们的涂料组合物的酯
公开(公告)号：US4252935A
公开(公告)日：1981-02-24
申请号：US62589
申请日：1979-07-31
申请人： Carl C. Anderson , William J. Birkmeyer , Roger M. Christenson , Rostyslaw Dowbenko , Ronald J. Lewarchik
发明人： Carl C. Anderson , William J. Birkmeyer , Roger M. Christenson , Rostyslaw Dowbenko , Ronald J. Lewarchik
IPC分类号： C08G59/00 , C08G18/48 , C08G18/58 , C08G18/64 , C08G59/06 , C08G59/16 , C08G59/24 , C08G59/62 , C09D163/00 , C09D175/00
CPC分类号： C08G59/625 , C08G18/4875 , C08G18/58 , C08G18/581 , C08G18/6407 , C08G59/1455 , C08G59/24 , C09D163/00
摘要： Esters of glycidyl polyethers of saturated phenols are especially useful in coating compositions having a low organic solvent content. The esters are the reaction products of from about 0.5 to about 1.5 equivalents of a saturated monocarboxylic acid with each epoxy group in a diglycidyl polyether of phenols where the aromatic rings of the phenols are saturated.
摘要翻译：饱和酚的缩水甘油聚醚的酯特别可用于具有低有机溶剂含量的涂料组合物。酯是在酚的二环氧甘油基聚醚中酚基饱和的约0.5至约1.5当量的饱和一元羧酸与每个环氧基的反应产物。

6. 发明授权

US4454274A Aminoplast curable coating compositions containing cycloaliphatic sulfonic acid esters as latent acid catalysts 失效
标题翻译：含有脂环族磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
公开(公告)号：US4454274A
公开(公告)日：1984-06-12
申请号：US427400
申请日：1982-09-29
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08F8/36 , C08K5/42
CPC分类号： C08K5/42 , C07C309/00
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin; and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formulas: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom;W is C.sub.1 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkenylene;V is C.sub.1 -C.sub.18 alkylene, C.sub.1 -C.sub.18 hydroxyl substituted alkylene, C.sub.2 -C.sub.18 alkenylene, C.sub.2 -C.sub.18 hydroxyl substituted alkenylene; andR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical.
摘要翻译：能够进行酸催化交联的高固含量有机溶剂型可喷涂涂料组合物由含活性氢的树脂，外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂组成。和催化量的磺酸的非离子酯。磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团与硫连接原子由碳原子; W是C 1 -C 18亚烷基，C 2 -C 18亚烯基; V是C 1 -C 18亚烷基，C 1 -C 18羟基取代的亚烷基，C 2 -C 18亚烯基，C 2 -C 18羟基取代的亚烯基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。

7. 发明授权

US4029621A Reaction products of a polyepoxide with a thiol having a group hydroyzable to carboxyl, and aqueous solubilized products 失效
标题翻译：聚环氧化物与具有可水解羧基的硫醇的反应产物和水溶性产物
公开(公告)号：US4029621A
公开(公告)日：1977-06-14
申请号：US680935
申请日：1976-04-28
申请人： Marvis E. Hartman , Thomas R. Hockswender , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Marvis E. Hartman , Thomas R. Hockswender , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08G59/14 , C08G59/42 , C08G59/66 , C08G59/16
CPC分类号： C08G59/66 , C08G59/1483 , C08G59/4207
摘要： Aqueous coating compositions which may be applied by conventional coating techniques as well as by electrodeposition are provided by reacting an epoxy-containing organic material with a compound containing a mercaptan group and at least one group hydrolyzable to a carboxyl group. Examples of such hydrolyzable groups include ester groups, amide groups and nitrile groups. The resultant product is then hydrolyzed and solubilized using hydrolyzing agents such as aqueous alkali metal hydroxides and aqueous solutions of various amines.
摘要翻译：可以通过常规涂布技术和电沉积施用的水性涂料组合物通过使含环氧基的有机材料与含有硫醇基团的化合物和至少一个可水解成羧基的基团反应来提供。这些可水解基团的实例包括酯基，酰胺基和腈基。然后使用水解剂如碱金属氢氧化物水溶液和各种胺的水溶液将所得产物水解和溶解。

8. 发明授权

US4591518A Acrylic functional urethane alkyd resin coating compositions 失效
标题翻译：丙烯酸官能氨基甲酸酯醇酸树脂涂料组合物
公开(公告)号：US4591518A
公开(公告)日：1986-05-27
申请号：US639874
申请日：1984-08-13
申请人： William J. Schillinger , J. Alden Erikson , Rostyslaw Dowbenko , Roger M. Christenson
发明人： William J. Schillinger , J. Alden Erikson , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C09D175/14 , C08G18/42 , C08G18/81 , C09D175/16 , B05D3/02 , C08F20/00 , C08G63/76
CPC分类号： C09D175/16 , C08G18/4288 , C08G18/8108 , C08G18/8158
摘要： An air oxidizable coating composition is disclosed comprising an ungelled urethane modified alkyd resin containing pendant polymerizable unsaturated groups attached to the alkyd through urethane linkages. The ungelled urethane modified alkyd is the reaction product of components comprising a hydroxyl containing, air oxidizable alkyd resin having an oil length of between about 20 percent and about 70 percent and an isocyanate-functional ethylenically unsaturated compound. Also disclosed are a process for coating the substrate with the coating composition and certain ungelled urethane modified alkyd resins.
摘要翻译：公开了一种空气可氧化涂料组合物，其包含含有通过氨基甲酸酯键连接到醇酸树脂上的侧基聚合不饱和基团的未凝胶化的聚氨酯改性醇酸树脂。未凝胶化的氨基甲酸酯改性醇酸树脂是包含具有约20％至约70％的油长度的含羟基的可空气可氧化醇酸树脂和异氰酸酯官能的烯属不饱和化合物的组分的反应产物。还公开了用涂料组合物和某些未凝胶化的氨基甲酸酯改性醇酸树脂涂覆基材的方法。

9. 发明授权

US4477618A Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
标题翻译：含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
公开(公告)号：US4477618A
公开(公告)日：1984-10-16
申请号：US427402
申请日：1982-09-29
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
IPC分类号： C08F8/36 , C08K5/42 , C09D161/20
CPC分类号： C07C309/00 , C08K5/42 , C09D161/20
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.
摘要翻译：能够进行酸催化交联的高固体，有机溶剂型可喷涂涂料组合物由含活性氢的树脂，在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成，以及催化量的磺酸的非离子酯。磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。这些基团可以特别描述如下：R 1是氢，烷氧羰基，C 3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢，烷氧羰基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R3是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R4是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基，R5是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基。

10. 发明授权

US4337184A Urethane rheology modifiers substantially free of terminal hydrophobic groups and compositions containing same 失效
标题翻译：基本上不含末端疏水基团的聚氨酯流变改性剂和含有它们的组合物
公开(公告)号：US4337184A
公开(公告)日：1982-06-29
申请号：US220617
申请日：1980-12-29
申请人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Karl F. Schimmel , Jerome A. Seiner , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08G18/30 , C08G18/66 , C08G18/72 , C09D7/00 , C08K5/29
CPC分类号： C08G18/6677 , C08G18/302 , C08G18/6666 , C08G18/721 , C09D7/002 , C08L75/04
摘要： Rheology modifiers useful in water-based and organic solvent-based compositions are derived from the reaction of polyalkylene oxide, polyfunctional material, diisocyanate and little or no water. The modifiers are characterized by having a branched structure and containing substantially no terminal hydrophobic groups.
摘要翻译：用于水基和有机溶剂基组合物的流变改性剂衍生自聚环氧烷，多官能材料，二异氰酸酯和少量或不含水的反应。改性剂的特征在于具有支链结构并且基本上不含末端疏水基团。

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