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1. 发明授权

US4477618A Aminoplast curable coating compositions containing sulfonic acid esters as latent acid catalysts 失效
标题翻译：含有磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
公开(公告)号：US4477618A
公开(公告)日：1984-10-16
申请号：US427402
申请日：1982-09-29
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson , Michael M. Chau , Wen-Hsuan Chang
IPC分类号： C08F8/36 , C08K5/42 , C09D161/20
CPC分类号： C07C309/00 , C08K5/42 , C09D161/20
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formula: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom; ##STR2## C.sub.3 -C.sub.20 cycloalkyl; and R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical. These groups can be particularly described as follows:R.sub.1 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.2 is hydrogen, carboalkoxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.3 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl;R.sub.4 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl, andR.sub.5 is hydrogen, carboalkoxy, acyloxy, N-alkylcarbamyloxy, N-arylcarbamyloxy, C.sub.3 -C.sub.20 alkyl, C.sub.6 -C.sub.18 aryl, or C.sub.3 -C.sub.20 cycloalkyl.
摘要翻译：能够进行酸催化交联的高固体，有机溶剂型可喷涂涂料组合物由含活性氢的树脂，在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成，以及催化量的磺酸的非离子酯。磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团通过碳原子连接到硫原子上; C3-C20环烷基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。这些基团可以特别描述如下：R 1是氢，烷氧羰基，C 3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基; R2是氢，烷氧羰基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R3是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基; R4是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3-C20烷基，C6-C18芳基或C3-C20环烷基，R5是氢，烷氧羰基，酰氧基，N-烷基氨基甲酰氧基，N-芳基氨基甲酰氧基，C3 -C 20烷基，C 6 -C 18芳基或C 3 -C 20环烷基。

2. 发明授权

US4454274A Aminoplast curable coating compositions containing cycloaliphatic sulfonic acid esters as latent acid catalysts 失效
标题翻译：含有脂环族磺酸酯作为潜酸催化剂的氨基塑料可固化涂料组合物
公开(公告)号：US4454274A
公开(公告)日：1984-06-12
申请号：US427400
申请日：1982-09-29
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , Roger M. Christenson
IPC分类号： C08F8/36 , C08K5/42
CPC分类号： C08K5/42 , C07C309/00
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin; and a catalytic amount of a non-ionic ester of a sulfonic acid. The sulfonic acid ester is represented by the following structural formulas: ##STR1## wherein: Z is a radical selected from the group consisting of amino and an organic radical, said organic radical being connected to the sulfur atom by a carbon atom;W is C.sub.1 -C.sub.18 alkylene, C.sub.2 -C.sub.18 alkenylene;V is C.sub.1 -C.sub.18 alkylene, C.sub.1 -C.sub.18 hydroxyl substituted alkylene, C.sub.2 -C.sub.18 alkenylene, C.sub.2 -C.sub.18 hydroxyl substituted alkenylene; andR.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 are independently hydrogen or an organic radical.
摘要翻译：能够进行酸催化交联的高固含量有机溶剂型可喷涂涂料组合物由含活性氢的树脂，外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂组成。和催化量的磺酸的非离子酯。磺酸酯由以下结构式表示：其中：Z是选自氨基和有机基团的基团，所述有机基团与硫连接原子由碳原子; W是C 1 -C 18亚烷基，C 2 -C 18亚烯基; V是C 1 -C 18亚烷基，C 1 -C 18羟基取代的亚烷基，C 2 -C 18亚烯基，C 2 -C 18羟基取代的亚烯基; 并且R 1，R 2，R 3，R 4，R 5独立地为氢或有机基团。

3. 发明授权

US4469832A Aminoplast curable coating compositions containing polycyclic esters of sulfonic acids as latent acid catalysts 失效
标题翻译：含有磺酸多环酯作为潜酸催化剂的氨基塑料固化涂料组合物
公开(公告)号：US4469832A
公开(公告)日：1984-09-04
申请号：US427399
申请日：1982-09-29
申请人： Debra L. Singer , Karl F. Schimmel , Rostyslaw Dowbenko , Michael M. Chau , Wen-Hsuan Chang
发明人： Debra L. Singer , Karl F. Schimmel , Rostyslaw Dowbenko , Michael M. Chau , Wen-Hsuan Chang
IPC分类号： C08F2/36 , C09D161/20 , C08F3/36
CPC分类号： C09D161/20
摘要： A high solids, organic solvent based, sprayable coating composition which is capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a non-ionic, saturated or unsaturated organic polycyclic ester of a sulfonic acid.
摘要翻译：能够进行酸催化交联的高固体，有机溶剂型可喷涂涂料组合物由含活性氢的树脂，在外部和/或内部作为含活性氢树脂的一部分存在的固化剂组成，以及催化量的磺酸的非离子，饱和或不饱和有机多环酯。

4. 发明授权

US4501854A Aminoplast curable compositions containing disulfonic acid esters as latent acid catalysts 失效
标题翻译：含有二磺酸酯作为潜酸催化剂的氨基塑料可固化组合物
公开(公告)号：US4501854A
公开(公告)日：1985-02-26
申请号：US551388
申请日：1983-11-14
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko
IPC分类号： C08F4/00 , C08K5/42 , C09D133/00 , C08L61/28
CPC分类号： C07C309/00 , C08K5/42
摘要： An improved curable composition capable of acid catalyzed crosslinking is composed of an active hydrogen-containing resin, a curing agent and a sulfonate as latent acid catalyst. The catalyst is represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, hydroxyl, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, and C.sub.6 to C.sub.18 aryl;R.sup.1 is independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, hydroxyalkyl, and hydroxycycloalkyl;y is an integer from 0 to 4,w is an integer from 0 to 2, andx is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 3.
摘要翻译：能够进行酸催化交联的改进的可固化组合物由含活性氢的树脂，固化剂和作为潜酸催化剂的磺酸盐组成。催化剂由以下结构式表示：其中：Z是独立地选自C 1至C 20烷基，C 3至C 20环烷基，C 6至C 18芳基，卤素，烷氧基，羟基和芳氧基的基团; R独立地选自氢，C1至C20烷基，C3至C20环烷基和C6至C18芳基; R 1独立地选自C 1至C 20烷基，C 3至C 20环烷基，羟基烷基和羟基环烷基; y是0至4的整数，w是0至2的整数，x是1至3的整数，条件是当w为0时，y为1至4的整数，x为整数 2〜3，y为0时，w为1〜2的整数，x为1〜3的整数。

5. 发明授权

US4500680A Aromatic acid catalysts providing improved humidity resistance 失效
标题翻译：提供改善的耐湿性的芳香族酸催化剂
公开(公告)号：US4500680A
公开(公告)日：1985-02-19
申请号：US551389
申请日：1983-11-14
申请人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , James B. O'Dwyer
发明人： Debra L. Singer , Gregory J. McCollum , Rostyslaw Dowbenko , James B. O'Dwyer
IPC分类号： C08K5/42 , C08L61/20 , C08L67/00 , C08L75/00
CPC分类号： C08K5/42
摘要： Curable compositions with improved humidity resistance are composed of an active hydrogen-containing resin which is essentially free of glycidyl groups, a curing agent present externally and/or internally as a part of the active hydrogen-containing resin, and a catalytic amount of a sulfonic acid having a molecular weight of less than 500 and represented by the following structural formula: ##STR1## wherein: Z is a radical independently selected from C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl, C.sub.6 to C.sub.18 aryl, halogen, alkoxy, and aryloxy;R is independently selected from hydrogen, C.sub.1 to C.sub.20 alkyl, C.sub.3 to C.sub.20 cycloalkyl and C.sub.6 to C.sub.18 aryl;y is an integer from 0 to 4; w is an integer from 0 to 2;x is an integer from 1 to 3, with the proviso that when w is 0, y is an integer from 1 to 4 and x is an integer from 2 to 3 and when y is 0, w is an integer from 1 to 2 and x is an integer from 1 to 2.
摘要翻译：具有改善的耐湿性的可固化组合物由基本上不含缩水甘油基的活性含氢树脂，外部存在和/或内部作为活性含氢树脂的一部分存在的固化剂和催化量的磺酸分子量小于500并由以下结构式表示的酸：其中：Z是独立地选自C 1至C 20烷基，C 3至C 20环烷基，C 6至C 18芳基，卤素，烷氧基和芳氧基 ; R独立地选自氢，C1至C20烷基，C3至C20环烷基和C6至C18芳基; y为0〜4的整数; w为0〜2的整数; x为1〜3的整数，条件是当w为0时，y为1〜4的整数，x为2〜3的整数，y为0时，w为1〜2的整数， x是1到2的整数。

6. 发明授权

US4681811A Color plus clear coatings employing polyepoxides and polyacid curing agents in the clear coat 失效
标题翻译：颜色加透明涂层，在透明涂层中使用聚环氧化物和多元酸固化剂
公开(公告)号：US4681811A
公开(公告)日：1987-07-21
申请号：US837118
申请日：1986-03-07
申请人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
发明人： Dennis A. Simpson , Debra L. Singer , Rostyslaw Dowbenko , William P. Blackburn , Charles M. Kania
IPC分类号： B05D7/00 , C09D163/00 , B05D1/36 , B32B15/08 , B32B27/38
CPC分类号： B05D7/536 , C09D163/00 , Y10T428/31511
摘要： A color-plus-clear coating system is disclosed. A pigmented or colored base coat is first applied to a substrate followed by the application of a transparent top coat to the base coat. The transparent top coat composition is a liquid crosslinkable composition comprising a polyepoxide and a polyacid curing agent. The polyepoxide-polyacid curing agent in the transparent top coat provides a composite coating with outstanding gloss and distinctness of image making the composite coating particularly useful as an automotive top coat.
摘要翻译：公开了一种彩色透明涂层系统。首先将着色或着色的底涂层施加到基材上，然后向基底涂层施加透明的顶涂层。透明面漆组合物是包含聚环氧化物和多元酸固化剂的液体可交联组合物。透明面漆中的聚环氧化物 - 多元酸固化剂提供了复合涂层，其具有优异的光泽度和独特的图像，使复合涂层特别适用于汽车顶涂层。

7. 发明授权

US4749803A Reaction products of mercapto-functional monohydric alcohols and vinyl silanes, and NCO-functional compounds therefrom 失效
标题翻译：巯基官能的一元醇和乙烯基硅烷的反应产物，以及由它们构成的NCO-官能的化合物
公开(公告)号：US4749803A
公开(公告)日：1988-06-07
申请号：US816078
申请日：1986-01-03
申请人： Rostyslaw Dowbenko , Debra L. Singer
发明人： Rostyslaw Dowbenko , Debra L. Singer
IPC分类号： C07F7/08 , C07F7/18 , C08G18/10 , C08G18/38 , C07F7/10
CPC分类号： C08G18/3893 , C07F7/182 , C08G18/10
摘要： Disclosed is an adduct of a mercapto-functional monohydric alcohol and a vinyl-type silane having at least one hydrolyzable group directly attached to a silicon atom, the adduct prepared by reacting the mercapto-functional monohydric alcohol and the vinyl-type silane in the presence of a free radical initiator.Also disclosed is an NCO-functional compound comprising the reaction product of: (A) the aforesaid adduct of a mercapto-functional monohydric alcohol and a vinyl-type silane having at least one hydrolyzable group directly attached to a silicon atom, and (B) an organic polyisocyanate.
摘要翻译：公开了一种巯基官能的一元醇和具有至少一个直接连接到硅原子上的可水解基团的乙烯基型硅烷的加合物，该加成物是通过巯基官能的一元醇和乙烯基型硅烷在存在下反应制备的的自由基引发剂。还公开了包含以下反应产物的NCO官能化合物：（A）上述巯基官能化一元醇的上述加成物和至少具有直接与硅原子连接的可水解基团的乙烯基型硅烷，（B）有机多异氰酸酯。

8. 发明授权

US4703101A Liquid crosslinkable compositions using polyepoxides and polyacids 失效
标题翻译：使用聚环氧化物和多元酸的液体可交联组合物
公开(公告)号：US4703101A
公开(公告)日：1987-10-27
申请号：US767019
申请日：1985-08-19
申请人： Debra L. Singer , Rostyslaw Dowbenko , Dennis A. Simpson
发明人： Debra L. Singer , Rostyslaw Dowbenko , Dennis A. Simpson
IPC分类号： B05D7/00 , C09D163/00 , C08G63/42
CPC分类号： B05D7/536 , C09D163/00
摘要： A crosslinkable composition comprising a polyepoxide and a polyacid which is the half-ester formed from reacting an acid anhydride with a polyol is disclosed. The compositions are useful as coatings, particularly as clear coats in color-plus-clear coatings.
摘要翻译：公开了一种包含聚环氧化物和多酸的可交联组合物，其是由酸酐与多元醇反应形成的半酯。该组合物可用作涂料，特别是作为透明涂料在彩色 - 透明涂料中。

9. 发明授权

US4690980A Acrylic modified polymers 失效
标题翻译：丙烯酸改性聚合物
公开(公告)号：US4690980A
公开(公告)日：1987-09-01
申请号：US864579
申请日：1986-05-20
申请人： Debra L. Singer , William J. Birkmeyer , Rostyslaw Dowbenko , Charles M. Kania
发明人： Debra L. Singer , William J. Birkmeyer , Rostyslaw Dowbenko , Charles M. Kania
IPC分类号： C08F8/14 , C08F291/06 , C08F265/02
CPC分类号： C08F8/14 , C08F291/06 , C08F2810/30
摘要： A liquid, ungelled composition of matter composed of a graft copolymer prepared by the free radical initiated polymerization in an organic medium of a vinyl monomer component which contains at least 0.5 weight percent of an epoxy group containing vinyl monomer in the presence of an acid group containing polymer having an acid value greater than 10 mg KOH/g. One means of graft formation is the condensation reaction between the acid groups of the acid group containing polymer and the epoxy groups of the vinyl monomer component.
摘要翻译：由在乙烯基单体组分的有机介质中通过自由基引发聚合制备的接枝共聚物的液体，未胶凝组合物，其含有至少0.5重量％的含环氧基的乙烯基单体在含酸基团的存在下聚合物的酸值大于10mg KOH / g。接枝形成的一种方法是含酸基聚合物的酸基与乙烯基单体组分的环氧基之间的缩合反应。

10. 发明授权

US4652664A Addition products prepared from mercapto-functional polyhydric alcohols and vinyl-type silanes containing hydrolyzable groups 失效
标题翻译：由巯基官能多元醇和含有可水解基团的乙烯基型硅烷制备的添加产物
公开(公告)号：US4652664A
公开(公告)日：1987-03-24
申请号：US816079
申请日：1986-01-03
申请人： Debra L. Singer , Rostyslaw Dowbenko
发明人： Debra L. Singer , Rostyslaw Dowbenko
IPC分类号： C07F7/18 , C08G18/38 , C07F7/08
CPC分类号： C07F7/1836 , C08G18/3893
摘要： Disclosed is a free-radical addition product of a mercapto-functional polyhydric alcohol and a vinyl-type silane having at least one hydrolyzable group directly attached to a silicon atom, the addition product prepared by reacting the mercapto-functional polyhydric alcohol and the vinyl-type silane in the presence of a free radical initiator. The addition product contains at least two hydroxyl groups bonded to carbon atoms and at least one silicon atom bonded to at least one hydrolyzable group.The resulting polyhydroxyl-functional addition products can be chain extended using organic polyisocyanates to produce isocyanate-terminated compounds which also contain silicon atoms directly bonded to hydrolyzable groups along the molecule chains.
摘要翻译：公开了一种巯基官能多元醇的自由基加成产物和具有至少一个直接连接到硅原子上的可水解基团的乙烯基型硅烷，该加成产物通过使巯基官能的多元醇与乙烯基 - 在自由基引发剂的存在下形成硅烷。加成产物含有至少两个与碳原子键合的羟基和至少一个与至少一个可水解基团键合的硅原子。所得的多羟基官能加成产物可以使用有机多异氰酸酯链延长以产生异氰酸酯封端的化合物，其也含有直接键合到可分子链的可水解基团的硅原子。

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