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1. 发明授权

US5389280A Stable and homogeneous aqueous formulations of surfactants 失效
标题翻译：表面活性剂的稳定且均匀的水性制剂
公开(公告)号：US5389280A
公开(公告)日：1995-02-14
申请号：US821682
申请日：1992-01-16
申请人： Thomas Martini , Karl-Heinz Keil , Ignaz Wimmer
发明人： Thomas Martini , Karl-Heinz Keil , Ignaz Wimmer
IPC分类号： B01F17/24 , B01F17/00 , B01J13/00 , C11D1/12 , C11D1/28 , C11D1/52 , C11D1/66 , C11D1/72 , C11D1/74 , C11D1/83 , C09D9/00 , C11D7/32 , C11D7/50
CPC分类号： B01F17/0085 , C11D1/12 , C11D1/83 , C11D1/28 , C11D1/526 , C11D1/667 , C11D1/72 , C11D1/74
摘要： Stable and homogeneous aqueous formulations of surfactantsStable and homogeneous aqueous formulations of surfactants having an HLB value of less than or equal to 13, which additionally contain a compound of the formula I ##STR1## in which R.sup.1 is C.sub.1 -C.sub.8 -alkyl, C.sub.1 -C.sub.8 -alkenyl, phenyl, alkylphenyl or phenalkyl having in each case 1 to 4 carbon atoms in the alkyl chain or cyclohexyl, R.sup.2 is hydrogen or one of the radicals mentioned for R.sup.1, or R.sup.1 and R.sup.2, together with the nitrogen atom, are a heterocyclic radical, M is an alkali metal cation, an ammonium cation or one equivalent of an alkaline earth metal or aluminium cation and m and n in each case independently of one another are numbers from 6 to 8.By the presence of the compounds of the formula I, it is possible to prepare stable and homogeneous aqueous formulations even from those surfactants which are otherwise only sparingly soluble or not soluble at all in water.
摘要翻译：稳定且均匀的表面活性剂水性制剂具有HLB值小于或等于13的表面活性剂的稳定且均匀的水性制剂，其另外含有式I化合物（I），其中R 1是C 1 -C 8 - 烷基，在烷基链或环己基中各自为1至4个碳原子的C1-C8-烯基，苯基，烷基苯基或苯烷基，R2为氢或R1或R1和R2所提及的一个基团，以及氮原子是杂环基，M是碱金属阳离子，铵阳离子或一当量的碱土金属或铝阳离子，m和n在每种情况下彼此独立地为6至8.通过存在式I的化合物，即使从那些仅在微溶于水或不溶于水的那些表面活性剂中，也可制备稳定和均匀的水性制剂。

2. 发明授权

US5230711A Dyeing of cellulose with soluble sulphur dyes without reducing agent 失效
标题翻译：不含还原剂的可溶性硫酸染料的纤维素染色
公开(公告)号：US5230711A
公开(公告)日：1993-07-27
申请号：US861604
申请日：1992-04-01
申请人： Karl-Heinz Keil , Thomas Martini
发明人： Karl-Heinz Keil , Thomas Martini
IPC分类号： C08F251/02 , C08F251/00 , D06M13/02 , D06M13/248 , D06M13/322 , D06M13/325 , D06M13/328 , D06M13/463 , D06M14/04 , D06M14/22 , D06M101/00 , D06M101/02 , D06M101/06 , D06M101/08 , D06P1/30 , D06P3/60 , D06P3/854 , D06P5/22
CPC分类号： D06M14/04 , D06M14/22 , D06P3/6025 , Y10S8/918
摘要： Water-soluble sulphur dyes can be applied to cellulose without reducing agents, without added salt and without oxidising agents if the cellulose has been grafted with a polymer obtained by polymerisation of at least one N-containing basic monomer.
摘要翻译：如果纤维素已经通过至少一种含N碱性单体的聚合而获得的聚合物接枝，则水溶性硫化染料可以不用还原剂施加到纤维素上，而不加入盐和不含氧化剂。

3. 发明授权

US5006129A Dyeing textile material with pigment dyes: pre-treatment with quaternary ally ammonium salt polymer 失效
标题翻译：染色纺织材料与颜料染料：预处理与季铵盐聚合物
公开(公告)号：US5006129A
公开(公告)日：1991-04-09
申请号：US459270
申请日：1989-12-29
申请人： Thomas Martini , Karl-Heinz Keil , Ulrich Karsunky , Klaus Sternberger
发明人： Thomas Martini , Karl-Heinz Keil , Ulrich Karsunky , Klaus Sternberger
IPC分类号： D06P1/54 , D06P1/44 , D06P1/52 , D06P1/66 , D06P5/00 , D06P5/22
CPC分类号： D06P1/66 , D06P1/44 , D06P1/525 , Y10S8/918
摘要： Process for dyeing textile material with pigment dyes, which comprises1. pretreating the textile material with a polymer which consists wholly or partly of monomeric units of the formula I ##STR1## where R.sup.1 and R.sup.2 are each hydrogen, (C.sub.1 -C.sub.22)alkyl which may be interrupted by --CO--NH-- or --NH--CO--, or C.sub.1 -C.sub.4 -hydroxyalkyl,R.sup.3 and R.sup.4 are each hydrogen or methyl, and Y.sup.- is a monovalent anion or one equivalent of a polyvalent anion,2. then dyeing with a pigment dye in the presence of a leveling or dispersing agent by the exhaust method and if necessary3. treating the dyeing in a liquor with a pigment binder and subsequently fixing it.This process makes it possible to dye textile material, in particular ready-made jeans garments, with pigment dyes by an exhaust method.
摘要翻译：用颜料染料染色纺织材料的方法，其包括1.用全部或部分由式I（I）的单体单元组成的聚合物预处理织物材料，其中R 1和R 2各自为氢，（C 1 -C 22 ）可被-CO-NH-或-NH-CO-或C 1 -C 4 - 羟烷基，R 3和R 4间隔的烷基，各自为氢或甲基，Y-为一价阴离子或一当量多价阴离子， 2.然后用流平剂或分散剂存在下用颜料染料通过排气法和必要时进行染色3.用颜料粘合剂处理在液体中的染色并随后固定。该方法使得可以通过排气法将纺织材料，特别是现成的牛仔服装染色成颜料染料。

4. 发明授权

US5131913A Production of pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents: cationization and oxidized in a pattern before dyeing 失效
标题翻译：在碱性或还原剂无法染色或印刷纺织材料时生产图案效果：染色前的图案和氧化
公开(公告)号：US5131913A
公开(公告)日：1992-07-21
申请号：US538102
申请日：1990-06-14
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： D06P1/52 , D06P3/60
CPC分类号： D06P3/60 , D06P1/5278 , Y10S8/918
摘要： Process for producing pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents, which comprises pretreating the textile material with a cationizing agent, drying, applying an oxidizing agent in the form of a pattern, drying and dyeing or printing with reactive, direct, acid, water-soluble sulfur dyes or pigment dyes in the absence of any alkali or reducing agent.
摘要翻译：在不存在碱或还原剂的情况下染色或印刷纺织品材料时产生图案效果的方法，其包括用阳离子化剂预处理织物材料，干燥，以图案形式施用氧化剂，干燥和染色或印刷，反应性，直接，酸性，水溶性硫化染料或颜料染料，不存在任何碱或还原剂。

5. 发明授权

US4814453A Naphthalimides containing sulfuric acid ester groups, a process for their preparation and their use 失效
标题翻译：含硫酸酯基的萘二酰亚胺，其制备方法及其应用
公开(公告)号：US4814453A
公开(公告)日：1989-03-21
申请号：US55904
申请日：1987-05-29
申请人： Erich Schinzel , Thomas Martini
发明人： Erich Schinzel , Thomas Martini
IPC分类号： C07D221/14 , C11D3/42 , D06L3/12
CPC分类号： C07D221/14
摘要： New optical brighteners of the general formula ##STR1## in which R denotes hydrogen, alkyl, alkoxyalkyl, cyclohexyl, methylcyclohexyl, benzyl, phenylethyl, phenyl, alkylphenyl or xylyl,X denotes a C.sub.2 -C.sub.7 -alkylene group or a bridge member of the formula --X.sup.1 --(OX.sup.2).sub.n -- in which X.sup.1 and X.sup.2 denote C.sub.2 H.sub.4 or C.sub.3 H.sub.7 and n denotes 1 or 2 and Me denotes a proton, an alkali metal cation or a cation NH.sub.2 R.sup.1 R.sup.2 in which R.sup.1 and R.sup.2 represent hydrogen, alkyl or hydroxyalkyl.
摘要翻译：新的通式的荧光增白剂，其中R表示氢，烷基，烷氧基烷基，环己基，甲基环己基，苄基，苯基乙基，苯基，烷基苯基或二甲苯基，X表示C 2 -C 7亚烷基或式 -X1-（OX2）n-，其中X1和X2表示C2H4或C3H7，n表示1或2，Me表示质子，碱金属阳离子或阳离子NH 2 R 1 R 2，其中R 1和R 2表示氢，烷基或羟烷基。

6. 发明授权

US4140699A Process for preparing perfluorinated vinyl ethers 失效
标题翻译：制备全氟化乙烯基醚的方法
公开(公告)号：US4140699A
公开(公告)日：1979-02-20
申请号：US743958
申请日：1976-11-22
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： C07D319/12 , H01B3/24 , C07D319/10
CPC分类号： C07D319/12 , H01B3/24 , C10M2211/042 , C10M2211/044 , C10M2211/06 , C10M2213/00 , C10M2213/04 , C10M2213/06
摘要： Perfluorinated vinyl ethers are prepared by reacting a fluorinated carboxylic acid fluoride with hexafluoropropylene epoxide in the presence of a catalyst and thereafter pyrolyzing the carboxylic acid fluoride containing ether linkages, optionally after having converted it into a salt of a monovalent metal.
摘要翻译：全氟化乙烯基醚通过氟化羧酸氟化物与六氟丙烯环氧化物在催化剂存在下反应，然后热解含羧酸氟醚的醚键，任选地在将其转化为一价金属盐后制备。

7. 发明授权

US4035388A Process for preparing perfluoro-alkoxy-propionic acid fluorides 失效
标题翻译：制备全氟烷氧基 - 丙酸氟化物的方法
公开(公告)号：US4035388A
公开(公告)日：1977-07-12
申请号：US643124
申请日：1975-12-22
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： C07C51/00 , C07C51/58 , C07C51/62 , C07C59/135 , C07C67/00 , C07D319/12
CPC分类号： C07D319/12 , C07C51/58 , C07C51/62
摘要： Perfluoro carbonyl compounds react with hexafluoro propene epoxide in the presence of dimethylamino-difluoro-phosphorane producing perfluorinated carboxylic acid fluorides with ether linkages. Among the carbonyl compounds which can be used are perfluorinated ketones, acid fluorides of the formulaR.sub.F -- COF and R.sub.F -- OCF(CF.sub.3) -- COF(r.sub.f being a perfluoro-alkyl radical having from 1 to 4 carbon atoms) and perfluoro-2-oxo-3,6-dimethyl-1,4-dioxane.
摘要翻译：全氟羰基化合物与六氟丙烯环氧化物在二甲基氨基 - 二氟 - 正膦产生的具有醚键的全氟化羧酸氟化物存在下反应。可以使用的羰基化合物是全氟化酮，式RF-COF和RF-OCF（CF 3）-COF（RF是具有1至4个碳原子的全氟烷基）的氟化氟和全氟-2- 氧代-3,6-二甲基-1,4-二恶烷。

8. 发明授权

US4447350A Mixtures of optical brighteners and their use 失效
标题翻译：荧光增白剂的混合物及其用途
公开(公告)号：US4447350A
公开(公告)日：1984-05-08
申请号：US532809
申请日：1983-09-15
申请人： Thomas Martini , Erich Schinzel , Hans Frischkorn , Herbert Friedrich , Heinz Probst
发明人： Thomas Martini , Erich Schinzel , Hans Frischkorn , Herbert Friedrich , Heinz Probst
IPC分类号： C09B57/00 , C09B67/22 , D06L3/12 , C11D7/26
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners consisting of 1 to 60% by weight of a brightener from the bisbenzoxazolylnaphthalene series and 99 to 40% by weight of one or more brighteners of the formulae 2 to 10 listed in the description.
摘要翻译：由1至60重量％的来自双苯并恶唑基萘系列的增白剂和99至40重量％的一种或多种本说明书所列的式2至10的增白剂组成的荧光增白剂的混合物。

9. 发明授权

US4416795A Mixtures of optical brighteners 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4416795A
公开(公告)日：1983-11-22
申请号：US346561
申请日：1982-02-08
申请人： Thomas Martini , Hans Frischkorn , Erich Schinzel , Heinz Probst
发明人： Thomas Martini , Hans Frischkorn , Erich Schinzel , Heinz Probst
IPC分类号： C09B67/22 , C09K11/06 , D06L3/12
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners composed of(a) 1 to 99% by weight of one or more compounds of the formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 can be identical or different and denote hydrogen, chlorine, C.sub.1 -C.sub.4 carbalkoxy, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and(b) 99 to 1% by weight of one or more compounds of the formulae ##STR2## in which n denotes 0 or 1, R.sub.7 and R.sub.8 denote identical or different radicals from the group comprising hydrogen, fluorine, chlorine, phenyl, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl, alkoxy, cyano, carboxyl, carboalkoxy, carboxamide or alkyl sulfonates, and two adjacent radicals R.sub.7 and R.sub.8 together can also represent a benzene ring, a lower alkylene group or a 1,3-dioxapropylene group, and B denotes a cyano group, a carboxylate group or a carboxamide group or a 1,2,4-oxadiazol-3-yl group, a 1,3,5-oxadiazol-2-yl group, a phenyl group or a 1,3,4-oxadiazol-2-yl group.
摘要翻译：由（a）1至99重量％的一种或多种式（1）化合物（1）组成的荧光增白剂的混合物其中R1，R2，R3，R4，R5和R6可以相同或不同，表示氢，氯，C 1 -C 4烷氧基，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，（b）99至1重量％的一种或多种下式的化合物：（IMAG）（2）（5）其中n表示0或1，R7和R8表示与氢，氟，氯，苯基，三氟甲基，C 1 -C 4 - 烷基，烷氧基中的基团相同或不同的基团，氰基，羧基，烷氧羰基，甲酰胺或烷基磺酸盐，两个相邻基团R7和R8一起也可以表示苯环，低级亚烷基或1,3-二氧亚丙基，B表示氰基，羧酸酯基或甲酰胺基或1,2,4-恶二唑-3-基，1,3,5-恶二唑-2-基，苯基或1,3,4-恶二唑-2-基。

10. 发明授权

US4271036A Colorless formulations of optical brighteners from the series of bis-triazinylamino-stilbene-disulfonic acid compounds 失效
标题翻译：来自该系列双 - 三嗪基 - 二苯乙烯 - 二磺酸化合物的荧光增白剂的无色配方
公开(公告)号：US4271036A
公开(公告)日：1981-06-02
申请号：US114665
申请日：1980-01-23
申请人： Klaus Uhl , Hans Frischkorn , Thomas Martini
发明人： Klaus Uhl , Hans Frischkorn , Thomas Martini
IPC分类号： C07D251/40 , C07D251/68 , D06L3/12 , C09K11/06
CPC分类号： D06L3/1264 , C07D251/40 , C07D251/68
摘要： Colorless formulations of optical brighteners from the 4,4'-bis-triazinylamino-stilbene-disulfonic acid series, which are obtained by heating the brightener together with an oxyalkylate.
摘要翻译：通过与烷氧基化物一起加热增白剂而获得的4,4'-双 - 三嗪基氨基 - 二苯乙烯 - 二磺酸系列的荧光增白剂的无色配方。

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