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1. 发明授权

US4814453A Naphthalimides containing sulfuric acid ester groups, a process for their preparation and their use 失效
标题翻译：含硫酸酯基的萘二酰亚胺，其制备方法及其应用
公开(公告)号：US4814453A
公开(公告)日：1989-03-21
申请号：US55904
申请日：1987-05-29
申请人： Erich Schinzel , Thomas Martini
发明人： Erich Schinzel , Thomas Martini
IPC分类号： C07D221/14 , C11D3/42 , D06L3/12
CPC分类号： C07D221/14
摘要： New optical brighteners of the general formula ##STR1## in which R denotes hydrogen, alkyl, alkoxyalkyl, cyclohexyl, methylcyclohexyl, benzyl, phenylethyl, phenyl, alkylphenyl or xylyl,X denotes a C.sub.2 -C.sub.7 -alkylene group or a bridge member of the formula --X.sup.1 --(OX.sup.2).sub.n -- in which X.sup.1 and X.sup.2 denote C.sub.2 H.sub.4 or C.sub.3 H.sub.7 and n denotes 1 or 2 and Me denotes a proton, an alkali metal cation or a cation NH.sub.2 R.sup.1 R.sup.2 in which R.sup.1 and R.sup.2 represent hydrogen, alkyl or hydroxyalkyl.
摘要翻译：新的通式的荧光增白剂，其中R表示氢，烷基，烷氧基烷基，环己基，甲基环己基，苄基，苯基乙基，苯基，烷基苯基或二甲苯基，X表示C 2 -C 7亚烷基或式 -X1-（OX2）n-，其中X1和X2表示C2H4或C3H7，n表示1或2，Me表示质子，碱金属阳离子或阳离子NH 2 R 1 R 2，其中R 1和R 2表示氢，烷基或羟烷基。

2. 发明授权

US4595756A Cationic compounds of the naphthalimide series, process for their preparation and their use 失效
标题翻译：萘酰亚胺系列的阳离子化合物，其制备方法及其用途
公开(公告)号：US4595756A
公开(公告)日：1986-06-17
申请号：US613461
申请日：1984-05-24
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C07D221/14 , C09B17/04 , D06P1/649
CPC分类号： C07D221/14
摘要： Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion, process for their manufacture and their use.
摘要翻译：式（1）的阳离子化合物其中R表示烷基，羟烷基，烷氧基烷基，苯基烷基或苯氧基烷基，R'表示烷基，羟基烷基，苄基或烯丙基，X（ - ）表示无色阴离子，其制造及其使用过程。

3. 发明授权

US4246403A 1,3,4-Oxadiazolone-(2) compounds and process for their manufacture 失效
标题翻译： 1,3,4-恶二酮 - （2）化合物及其制备方法
公开(公告)号：US4246403A
公开(公告)日：1981-01-20
申请号：US60823
申请日：1979-07-25
申请人： Gunter Prossel , Erich Schinzel , Norbert Schonberger , Thomas Martini , Gunter Rosch
发明人： Gunter Prossel , Erich Schinzel , Norbert Schonberger , Thomas Martini , Gunter Rosch
IPC分类号： C09B57/00 , C07D271/10 , C07D271/113 , C07F9/653 , C07D413/10 , C07D413/14
CPC分类号： C07D271/113 , C07F9/65312
摘要： Novel 1,3,4-oxadiazolone-(2) compounds of the formula ##STR1## wherein Y denotes carboxy optionally functionally modified or optionally substituted phenyl or a five-membered heterocycle optionally substituted and selected from the group consisting of: furan, thiophen, oxazole, imidazole, oxadiazole, oxadiazolone, triazole, benzofuran, thionaphthalene, benzoxazole, benzimidazole, and benzotriazole, R denotes hydrogen, alkyl or optionally substituted phenyl, n denotes 0 and 1 and the rings A and B carry optionally further non-chromophoric substituents. These compounds may be used as optical brighteners.
摘要翻译：式（1）的新的1,3,4-恶二酮 - （2）化合物，其中Y表示任选官能修饰的或任选取代的苯基或任选取代并选自以下的五元杂环：呋喃，噻吩，恶唑，咪唑，恶二唑，恶二唑酮，三唑，苯并呋喃，噻二唑，苯并恶唑，苯并咪唑和苯并三唑，R表示氢，烷基或任选取代的苯基，n表示0和1，环A和B任选进一步携带非 - 发色取代基。这些化合物可以用作荧光增白剂。

4. 发明授权

US4447350A Mixtures of optical brighteners and their use 失效
标题翻译：荧光增白剂的混合物及其用途
公开(公告)号：US4447350A
公开(公告)日：1984-05-08
申请号：US532809
申请日：1983-09-15
申请人： Thomas Martini , Erich Schinzel , Hans Frischkorn , Herbert Friedrich , Heinz Probst
发明人： Thomas Martini , Erich Schinzel , Hans Frischkorn , Herbert Friedrich , Heinz Probst
IPC分类号： C09B57/00 , C09B67/22 , D06L3/12 , C11D7/26
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners consisting of 1 to 60% by weight of a brightener from the bisbenzoxazolylnaphthalene series and 99 to 40% by weight of one or more brighteners of the formulae 2 to 10 listed in the description.
摘要翻译：由1至60重量％的来自双苯并恶唑基萘系列的增白剂和99至40重量％的一种或多种本说明书所列的式2至10的增白剂组成的荧光增白剂的混合物。

5. 发明授权

US4416795A Mixtures of optical brighteners 失效
标题翻译：荧光增白剂的混合物
公开(公告)号：US4416795A
公开(公告)日：1983-11-22
申请号：US346561
申请日：1982-02-08
申请人： Thomas Martini , Hans Frischkorn , Erich Schinzel , Heinz Probst
发明人： Thomas Martini , Hans Frischkorn , Erich Schinzel , Heinz Probst
IPC分类号： C09B67/22 , C09K11/06 , D06L3/12
CPC分类号： D06L3/125
摘要： Mixtures of optical brighteners composed of(a) 1 to 99% by weight of one or more compounds of the formula (1) ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4, R.sub.5 and R.sub.6 can be identical or different and denote hydrogen, chlorine, C.sub.1 -C.sub.4 carbalkoxy, C.sub.1 -C.sub.4 -alkyl or C.sub.1 -C.sub.4 -alkoxy and(b) 99 to 1% by weight of one or more compounds of the formulae ##STR2## in which n denotes 0 or 1, R.sub.7 and R.sub.8 denote identical or different radicals from the group comprising hydrogen, fluorine, chlorine, phenyl, trifluoromethyl, C.sub.1 -C.sub.4 -alkyl, alkoxy, cyano, carboxyl, carboalkoxy, carboxamide or alkyl sulfonates, and two adjacent radicals R.sub.7 and R.sub.8 together can also represent a benzene ring, a lower alkylene group or a 1,3-dioxapropylene group, and B denotes a cyano group, a carboxylate group or a carboxamide group or a 1,2,4-oxadiazol-3-yl group, a 1,3,5-oxadiazol-2-yl group, a phenyl group or a 1,3,4-oxadiazol-2-yl group.
摘要翻译：由（a）1至99重量％的一种或多种式（1）化合物（1）组成的荧光增白剂的混合物其中R1，R2，R3，R4，R5和R6可以相同或不同，表示氢，氯，C 1 -C 4烷氧基，C 1 -C 4烷基或C 1 -C 4 - 烷氧基，（b）99至1重量％的一种或多种下式的化合物：（IMAG）（2）（5）其中n表示0或1，R7和R8表示与氢，氟，氯，苯基，三氟甲基，C 1 -C 4 - 烷基，烷氧基中的基团相同或不同的基团，氰基，羧基，烷氧羰基，甲酰胺或烷基磺酸盐，两个相邻基团R7和R8一起也可以表示苯环，低级亚烷基或1,3-二氧亚丙基，B表示氰基，羧酸酯基或甲酰胺基或1,2,4-恶二唑-3-基，1,3,5-恶二唑-2-基，苯基或1,3,4-恶二唑-2-基。

6. 发明授权

US4309551A Quaternized, bridged benzimidazolylbenzimidazoles, processes for their preparation and their use 失效
标题翻译：季铵化的桥联苯并咪唑基苯并咪唑，其制备方法及其用途
公开(公告)号：US4309551A
公开(公告)日：1982-01-05
申请号：US191709
申请日：1980-09-29
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C09B57/00 , C07D235/02 , C07D235/20 , C07D235/24 , C07D487/14 , C07D235/30 , C07D235/04
CPC分类号： C07D235/02 , C07D235/20 , C07D235/24 , C07D487/14
摘要： Compounds of the general formula (1) ##STR1## wherein R.sub.1 denotes hydrogen, halogen, alkyl, alkoxy or, conjointly with R.sub.2, a fused benzo ring, R.sub.2 denotes hydrogen, alkyl, alkoxy, halogen, phenyl, cyano, carboalkoxy, carboxyl, carbonamido, monoalkylcarbonamido, dialkylcarbonamido, sulfo, alkylsulfonyl, alkyloxysulfonyl, sulfonamido, monoalkylsulfonamido or dialkylsulfonamido or, conjointly with R.sub.3, a fused benzo ring, R.sub.3 has the same meaning as R.sub.2, R.sub.4 denotes hydrogen, alkyl, alkoxy, halogen or, conjointly with R.sub.3, a fused benzo ring, R.sub.5 denotes alkyl, hydroxyalkyl, alkoxyalkyl, optionally substituted aralkyl, cyanoethyl, cycloalkyl or a group of the formulae --CH.sub.2 CN, --CH.sub.2 CONH.sub.2 or --CH.sub.2 COO--alkyl, A denotes a group of the formulae ##STR2## or--(CH.sub.2).sub.4 --R.sub.6 denotes hydrogen, alkyl, hydroxyalkyl, alkoxyalkyl, aralkyl or optionally substituted phenyl, n denotes 1, 2 or 3 and X.sup.(-) denotes a halide, alkylsulfonate, alkylsulfate, alkylphenylsulfonate or phenylsulfonate ion, and processes for their preparation and their use as optical brighteners.
摘要翻译：通式（1）的化合物其中R1表示氢，卤素，烷基，烷氧基或与R2稠合的苯并环，R2表示氢，烷基，烷氧基，卤素，苯基，氰基，烷氧羰基，羧基，碳酰氨基，单烷基碳酰氨基，二烷基碳酰氨基，磺基，烷基磺酰基，烷氧基磺酰基，亚磺酰氨基，烷基磺酰氨基或二烷基磺酰氨基，或与R3稠合的苯并环，R3与R2相同，R4表示氢，烷基，烷氧基，卤素或 R 3表示烷基，羟基烷基，烷氧基烷基，任选取代的芳烷基，氰基乙基，环烷基或式-CH 2 CN，-CH 2 CONH 2或-CH 2 COO - 烷基的基团，A表示式或 - （CH 2）4 -R 6表示氢，烷基，羟基烷基，烷氧基烷基，芳烷基或任选取代的苯基，n表示1,2或3，X（ - ）表示卤素，烷基磺酸酯，烷基硫酸酯，烷基苯基磺酸酯或苯基磺酸根离子，过程为制备及其作为荧光增白剂的用途。

7. 发明授权

US4791205A Bisbenzoxazolylnaphthalenes containing sulfonate or sulfonamide groups, a process for their preparation and their use 失效
标题翻译：含有磺酸盐或磺酰胺基团的二苯并恶唑基萘，其制备方法及其应用
公开(公告)号：US4791205A
公开(公告)日：1988-12-13
申请号：US52783
申请日：1987-05-21
申请人： Erich Schinzel , Hans Frischkorn , Thomas Martini
发明人： Erich Schinzel , Hans Frischkorn , Thomas Martini
IPC分类号： C07D263/62 , C07D263/64 , C07D263/56
CPC分类号： C07D263/64
摘要： Compounds of the general formula ##STR1## in which n denotes 1 or 2,X denotes an OMe group,Me denotes a proton, an alkali metal cation or an optionally substituted ammonium cation,R denotes hydrogen, a lower alkyl group or halogen, and, in the event thatn is 1,X also denotes an --NR.sup.1 R.sup.2 group in which R.sup.1 and R.sup.2 represent hydrogen or a lower alkyl group,a process for their preparation and their use as optical brighteners, especially for polyamide fibers and wool.
摘要翻译：通式（1）的化合物，其中n表示1或2，X表示OMe基团，Me表示质子，碱金属阳离子或任选取代的铵阳离子，R表示氢，低级烷基或卤素，并且在n为1的情况下，X还表示-NR 1 R 2基团，其中R 1和R 2表示氢或低级烷基，其制备方法及其作为荧光增白剂的用途，特别是用于聚酰胺纤维和羊毛。

8. 发明授权

US4508900A Cationic compounds of the naphthalimide series, process for their preparation and their use 失效
公开(公告)号：US4508900A
公开(公告)日：1985-04-02
申请号：US417052
申请日：1982-09-13
申请人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
发明人： Norbert Schonberger , Erich Schinzel , Thomas Martini , Gunter Rosch
IPC分类号： C07D221/14 , C09B17/04 , D06P1/649
CPC分类号： C07D221/14
摘要： Cationic compounds of the formula (1) ##STR1## in which R denotes alkyl, hydroxyalkyl, alkoxyalkyl, phenylalkyl, or phenoxyalkyl,R' denotes alkyl, hydroxyalkyl, benzyl, or allyl andX.sup.(-) denotes a colorless anion,process for their manufacture and their use.

9. 发明授权

US5131913A Production of pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents: cationization and oxidized in a pattern before dyeing 失效
标题翻译：在碱性或还原剂无法染色或印刷纺织材料时生产图案效果：染色前的图案和氧化
公开(公告)号：US5131913A
公开(公告)日：1992-07-21
申请号：US538102
申请日：1990-06-14
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： D06P1/52 , D06P3/60
CPC分类号： D06P3/60 , D06P1/5278 , Y10S8/918
摘要： Process for producing pattern effects when dyeing or printing textile material in the absence of alkali or reducing agents, which comprises pretreating the textile material with a cationizing agent, drying, applying an oxidizing agent in the form of a pattern, drying and dyeing or printing with reactive, direct, acid, water-soluble sulfur dyes or pigment dyes in the absence of any alkali or reducing agent.
摘要翻译：在不存在碱或还原剂的情况下染色或印刷纺织品材料时产生图案效果的方法，其包括用阳离子化剂预处理织物材料，干燥，以图案形式施用氧化剂，干燥和染色或印刷，反应性，直接，酸性，水溶性硫化染料或颜料染料，不存在任何碱或还原剂。

10. 发明授权

US4140699A Process for preparing perfluorinated vinyl ethers 失效
标题翻译：制备全氟化乙烯基醚的方法
公开(公告)号：US4140699A
公开(公告)日：1979-02-20
申请号：US743958
申请日：1976-11-22
申请人： Thomas Martini
发明人： Thomas Martini
IPC分类号： C07D319/12 , H01B3/24 , C07D319/10
CPC分类号： C07D319/12 , H01B3/24 , C10M2211/042 , C10M2211/044 , C10M2211/06 , C10M2213/00 , C10M2213/04 , C10M2213/06
摘要： Perfluorinated vinyl ethers are prepared by reacting a fluorinated carboxylic acid fluoride with hexafluoropropylene epoxide in the presence of a catalyst and thereafter pyrolyzing the carboxylic acid fluoride containing ether linkages, optionally after having converted it into a salt of a monovalent metal.
摘要翻译：全氟化乙烯基醚通过氟化羧酸氟化物与六氟丙烯环氧化物在催化剂存在下反应，然后热解含羧酸氟醚的醚键，任选地在将其转化为一价金属盐后制备。

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