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1. 发明授权

US09764169B2 UV filter combinations comprising benzylidene malonates 有权
公开(公告)号：US09764169B2
公开(公告)日：2017-09-19
申请号：US13381965
申请日：2010-06-29
申请人： Julie Grumelard , Thomas Ehlis , Markus Hansch , Myriam Sohn
发明人： Julie Grumelard , Thomas Ehlis , Markus Hansch , Myriam Sohn
IPC分类号： A61Q17/04 , A61K8/37
CPC分类号： A61Q17/04 , A61K8/37
摘要： Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone;(b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.

2. 发明申请

US20120128611A1 UV FILTER COMBINATIONS COMPRISING BENZYLIDENE MALONATES 有权
标题翻译：紫外线过滤器组合包含苄基胆碱酯
公开(公告)号：US20120128611A1
公开(公告)日：2012-05-24
申请号：US13381965
申请日：2010-06-29
申请人： Julie Grumelard , Thomas Ehlis , Paul Adriaan Van Der Schaaf , Markus Hansch , Myriam Sohn
发明人： Julie Grumelard , Thomas Ehlis , Paul Adriaan Van Der Schaaf , Markus Hansch , Myriam Sohn
IPC分类号： A61K8/37 , A61K8/49 , A61K8/58 , A61Q17/04
CPC分类号： A61Q17/04 , A61K8/37
摘要： Disclosed is the use of a UV filter combination, comprising (a) a first UV filter selected from benzylidene malonates of formula (1), wherein R1 methyl; ethyl; propyl; or n-butyl; if R1 is methyl, then R is tert. butyl; formula (II); formula (III); a radical of formula (1a); or a radical of formula (1b); wherein R2 and R3, independently from each other are hydrogen; or methyl; R4 is methyl; ethyl; or n-propyl; R5 and R6 independently from each other are hydrogen; or C1-C3alkyl; if R1 is ethyl; propyl; or n-butyl, then R is isopropyl; and (b) a second UV filter selected from (b1) Bis-Ethylhexyloxyphenol Methoxyphenyl Triazine; (b2) Butyl Methoxydibenzoylmethane; (b3)Diethylhexyl Butamido Triazone; (b4) Ethylhexyl Triazone; (b5) Diethylamino Hydroxy Benzoyl Hexyl Benzoate; (b6) Ethylhexyl Methoxycinnamate; (b7) Ethylhexyl Salicylate; (b8) Homosalate; (b9) Octocrylene; (b10) micronized Methylene Bis-Benzotriazolyl Tetramethylbutylphenol; (b11) Phenylbenzimidazole Sulfonic Acid; (b12) Titanium Dioxide; (b13) micronized Tris-Biphenyl Triazine; and (b14) micronized (2-{4-[2-(4-Diethylamino-2-hydroxy-benzoyl)-benzoyl]-piperazine-1-carbonyl}-phenyl)-(4-diethylamino-2-hydroxy-phenyl)-methanone; (b15) benzoicacid,4,4-[[3-[1,3,3,3-tetramethyl-1-[trimethylsilyl)oxy]-1-disiloxanyl]propyl]amino]-1,3,5-triazine-2,4-diyl]diimino]bis-, dibutyl ester wherein the UV filter combination comprises at least 2 UV filters of component (b1)-(b14); for the protection of human and animal hair and skin against UV radiation.
摘要翻译：公开了使用UV过滤器组合，其包含（a）选自式（1）的亚苄基丙二酸酯的第一UV过滤器，其中R 1甲基; 乙基; 丙基; 或正丁基; 如果R1是甲基，那么R是叔丁基。丁基; 式（II）; 式（III）; 式（1a）的基团; 或式（1b）的基团; 其中R2和R3彼此独立地是氢; 或甲基; R4是甲基; 乙基; 或正丙基; R5和R6彼此独立地是氢; 或C 1 -C 3烷基; 如果R1是乙基; 丙基; 或正丁基，那么R是异丙基; 和（b）选自（b1）双 - 乙基己氧基苯酚甲氧基苯基三嗪的第二UV过滤器; （b2）丁基甲氧基二苯甲酰甲烷; （b3）丁酰己二酸二乙基己酯; （b4）乙基己基三嗪酮; （b5）二乙基氨基羟基苯甲酰己基苯甲酸酯; （b6）甲氧基肉桂酸乙基己酯; （b7）水杨酸乙基己酯; （b8）均质酸; （b9）（b10）微米亚甲基双苯并三唑基四甲基丁基苯酚; （b11）苯基苯并咪唑磺酸; （b12）二氧化钛; （b13）微粉化的三联苯三嗪; 和（b14）微粉化（2- {4- [2-（4-二乙基氨基-2-羟基 - 苯甲酰基） - 苯甲酰基] - 哌嗪-1-羰基} - 苯基） - （4-二乙基氨基-2-羟基 - 苯基）甲酮（b15）苯甲酸，4,4 - [[3- [1,3,3,3-四甲基-1- [三甲基甲硅烷基]氧基] -1-二硅氧烷基]丙基]氨基] -1,3,5-三嗪-2 ，4-二基]二亚氨基]双 - 二丁酯，其中UV滤光器组合包含至少2个组分（b1） - （b14）的UV滤光剂; 用于保护人和动物的头发和皮肤免受紫外线辐射。

3. 发明申请

US20110033400A1 SUNSCREEN COMPOSITIONS COMPRISING COLOUR PIGMENTS 审中-公开
标题翻译：包含色素的SUNSCREEN组合物
公开(公告)号：US20110033400A1
公开(公告)日：2011-02-10
申请号：US12746186
申请日：2008-12-05
申请人： Thomas Ehlis , Myriam Sohn
发明人： Thomas Ehlis , Myriam Sohn
IPC分类号： A61K8/37 , A61K8/49 , A61Q17/04
CPC分类号： A61K8/4966 , A61K8/19 , A61K8/25 , A61K8/26 , A61K8/29 , A61K8/35 , A61K8/40 , A61K8/41 , A61K8/418 , A61K8/46 , A61K8/466 , A61K8/494 , A61K8/496 , A61K8/498 , A61K8/4986 , A61K8/987 , A61K2800/43 , A61K2800/621 , A61K2800/651 , A61Q1/02 , A61Q17/04 , A61Q19/08
摘要： Disclosed are cosmetic formulation comprising (a) particulates having an absorption in the range of 400 to 800 nm; and (b) UV filters selected from (b1) particulate organic UV-filters; and (b2) soluble organic UV filters.
摘要翻译：公开了化妆品制剂，其包含（a）吸收在400至800nm范围内的颗粒; 和（b）选自（b1）颗粒状有机UV-过滤器的UV过滤器; 和（b2）可溶性有机UV过滤器。

4. 发明授权

US09656103B2 Light protecting-effective cosmetic or dermatological preparations 有权
公开(公告)号：US09656103B2
公开(公告)日：2017-05-23
申请号：US11632686
申请日：2005-07-11
申请人： Stefan Müller , Thomas Ehlis , Jochen Giesinger , Gilbert Kreyer
发明人： Stefan Müller , Thomas Ehlis , Jochen Giesinger , Gilbert Kreyer
IPC分类号： A61Q17/04 , A61K8/02 , A61K9/107 , A61K8/06
CPC分类号： A61Q17/04 , A61K8/02 , A61K9/107 , A61K2800/412
摘要： Disclosed is the use of an insoluble or sparingly soluble micronized substance class which is not a cosmetic UV absorber and which is dispersed in the oil- or water-phase of a cosmetic or dermatological composition for the enhancement of light protecting action of this cosmetic or dermatological composition comprising at least one cosmetic UV filter which is soluble in the water- or oil-phase. The cosmetic preparation according to the invention shows a remarkable increase in SPF.

5. 发明授权

US08535648B2 Stabilization of UV-sensitive active ingredients 有权
标题翻译：紫外线敏感活性成分的稳定化
公开(公告)号：US08535648B2
公开(公告)日：2013-09-17
申请号：US12520880
申请日：2008-01-16
申请人： Barbara Wagner , Bernd Herzog , Stefan Müller , Thomas Ehlis
发明人： Barbara Wagner , Bernd Herzog , Stefan Müller , Thomas Ehlis
IPC分类号： A61K8/00
CPC分类号： A61K8/41 , A61K8/35 , A61K8/44 , A61K2800/52 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/12 , A61Q17/04 , A61Q19/004 , A61Q19/04
摘要： Disclosed is the use of merocyanine derivatives of formula (1) for stabilizing UV-sensitive active ingredients like dibenzoylmethane derivatives.
摘要翻译：公开了式（1）的部花青衍生物用于稳定紫外线敏感活性成分如二苯甲酰甲烷衍生物的用途。

6. 发明申请

US20100143274A1 USE OF AMINES AND AMIDES FOR THE STABILIZATION OF ORGANIC MICRONIZED UV ABSORBERS 审中-公开
标题翻译：用于有机微波紫外线吸收剂稳定化的氨基和氨基
公开(公告)号：US20100143274A1
公开(公告)日：2010-06-10
申请号：US12529573
申请日：2008-02-27
申请人： Cyrille Deshayes , Thomas Ehlis , Julie Grumelard
发明人： Cyrille Deshayes , Thomas Ehlis , Julie Grumelard
IPC分类号： A61K8/35 , A61Q17/04
CPC分类号： A61K8/41 , A61K8/35 , A61K8/494 , A61K2800/52 , A61Q17/04
摘要： Disclosed is the use of amines and amides for the stabilization of a cosmetic composition comprising: (a) an organic micronized UV absorber selected from a benzophenone derivative and (b) a dibenzoylmethane derivative. The use of the amines and amides results in the stabilization of the end-product formulations.
摘要翻译：公开了胺和酰胺用于稳定化妆品组合物的用途，包括：（a）选自二苯甲酮衍生物和（b）二苯甲酰甲烷衍生物的有机微粉化UV吸收剂。使用胺和酰胺导致最终产品配方的稳定化。

7. 发明申请

US20100104523A1 STABILIZATION OF UV-SENSITIVE ACTIVE INGREDIENTS 有权
标题翻译：紫外线敏感活性成分的稳定性
公开(公告)号：US20100104523A1
公开(公告)日：2010-04-29
申请号：US12520880
申请日：2008-01-16
申请人： Barbara Wagner , Bernd Herzog , Stefan Muller , Thomas Ehlis
发明人： Barbara Wagner , Bernd Herzog , Stefan Muller , Thomas Ehlis
IPC分类号： A61K8/41 , A61K8/40 , A61Q17/04
CPC分类号： A61K8/41 , A61K8/35 , A61K8/44 , A61K2800/52 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/12 , A61Q17/04 , A61Q19/004 , A61Q19/04
摘要： Disclosed is the use of merocyanine derivatives of formula (1) for stabilizing UV-sensitive active ingredients like dibenzoylmethane derivatives.
摘要翻译：公开了式（1）的部花青衍生物用于稳定紫外线敏感活性成分如二苯甲酰甲烷衍生物的用途。

8. 发明申请

US20090214453A1 Use of Transmission Dyes for Protecting Human Skin From Browning and Ageing 有权
标题翻译：使用透射染料保护人体皮肤免于褐变和老化
公开(公告)号：US20090214453A1
公开(公告)日：2009-08-27
申请号：US12086648
申请日：2006-12-11
申请人： Stefan Müller , Jurg Haase , Thomas Ehlis , Gilbert Kreyer , Jochen Giesinger , Martin Vogt
发明人： Stefan Müller , Jurg Haase , Thomas Ehlis , Gilbert Kreyer , Jochen Giesinger , Martin Vogt
IPC分类号： A61Q17/04 , C07D241/04
CPC分类号： C07D295/192 , A61K8/411 , A61K8/42 , A61K8/49 , A61K8/494 , A61K2800/43 , A61Q17/04
摘要： Disclosed is the use of an aqueous dispersion comprising (a) a micronized sparingly soluble organic compound which has a UV-Vis spectrum with a maximum from 380 to 420 nm; and (b) an anionic dispersing agent for protecting the human skin from browning and skin aging.
摘要翻译：公开了包含（a）微波化的微溶有机化合物的水分散体的使用，其具有最大值为380至420nm的UV-Vis光谱; 和（b）用于保护人体皮肤免于褐变和皮肤老化的阴离子分散剂。

9. 发明申请

US20090124576A1 Triazine Derivatives 有权
标题翻译：三嗪衍生物
公开(公告)号：US20090124576A1
公开(公告)日：2009-05-14
申请号：US12227042
申请日：2007-05-02
申请人： Thomas Ehlis , Elek Borsos
发明人： Thomas Ehlis , Elek Borsos
IPC分类号： A61K8/49 , C07D403/14 , C07D403/12 , A61K8/58
CPC分类号： C07D251/52 , C07D251/70
摘要： Disclosed are triazine derivatives of formula X1 is a bivalent radical of formula A and A′ independently from each other are unsubstituted or substituted, straight-chain or branched C1-C12alkylene, which is optionally interrupted by C5-C12cycloalkylene, N, O or S; C5-C12cycloalkylene; biphenylene; C6-C10arylene; or C5-C10arylene-(C1-C12alkylene); R1 is a radical of formula R2 and R3 independently from each other are hydrogen; C1-C12alkyl; OR7; NR7R8; C6-C10aryl; X2 is O, or NH; W1 is C1-C20alkyl; or a group Sp-Sil; Sp is a straight-chain or branched saturated or single or multiple unsaturated C3-C12 hydrocarbon; Sil is a silane; an oligosiloxane; or a polysiloxane moiety; and R4, R5 R6, R7, R8 and R9 independently from each other are hydrogen; C1-C12alkyl; or C3-C12cycloalkyl.
摘要翻译：公开了式X1的三嗪衍生物是式A的二价基团，A'彼此独立地是未取代或取代的直链或支链C 1 -C 12亚烷基，其任选被C 5 -C 12亚环烷基，N，O或S中断; C5-C12环亚烷基; 联苯; C6-C10亚芳基或C 5 -C 10亚芳基 - （C 1 -C 12亚烷基）; R1是式R2和R3的基团彼此独立地是氢; C 1 -C 12烷基; OR7; NR7R8; C6-C10芳基; X2是O或NH; W1是C1-C20烷基; 或一组Sp-Sil; Sp是直链或支链饱和或单或多不饱和C 3 -C 12烃; 硅是硅烷; 低聚硅氧烷; 或聚硅氧烷部分; R 4，R 5，R 6，R 7，R 8和R 9彼此独立地为氢; C 1 -C 12烷基; 或C 3 -C 12环烷基。

10. 发明授权

US07344706B2 UV absorber compositions comprising a hydroxyphenyltriazine compound 有权
标题翻译：包含羟基苯基三嗪化合物的紫外线吸收剂组合物
公开(公告)号：US07344706B2
公开(公告)日：2008-03-18
申请号：US10507295
申请日：2003-03-04
申请人： Jürg Haase , Thomas Ehlis , Elek Borsos , Dietmar Hüglin , Bernd Herzog
发明人： Jürg Haase , Thomas Ehlis , Elek Borsos , Dietmar Hüglin , Bernd Herzog
IPC分类号： A61Q17/00 , A61Q17/04 , A61Q19/00 , A61K8/02 , A61K31/53
CPC分类号： A61K8/4966 , A61Q17/04
摘要： UV absorber compositions are described, comprising (a) from 1 to 99% by weight of a hydroxyphenyltriazine compound of formula (I) wherein R1, R2 and R3 are each independently of the others C1-C18alkyl; C2-C10,alkenyl; or phenyl-C1-C4 alkyl; R4 is hydrogen; or C1-C5alkyl; and (b) from 99 to 1% by weight of a further UV absorber selected from the group of (b) hydroxyphenyltriazines that are different from component (a), (b2) benzotriazoles, (b3) dibenzoylmethane derivatives and (b4) camphor derivatives. The compositions are suitable as UV filters in cosmetic compositions
摘要翻译：描述了UV吸收剂组合物，其包含（a）1至99重量％的式（I）的羟基苯基三嗪化合物，其中R 1，R 2和R 2 > 3 各自独立地为C 1 -C 12烷基; C 2 -C 10，烯基; 或苯基-C 1 -C 4烷基; R 4是氢; 或C 1 -C 5烷基; （b）99〜1重量％的另外的紫外线吸收剂，其选自（b）不同于组分（a），（b-2）苯并三唑的（b）羟基苯基三嗪，（b < （3/4）二苯甲酰甲烷衍生物和（b 4 S）樟脑衍生物。该组合物适用于化妆品组合物中的UV过滤器

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