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1. 发明申请

US20100104523A1 STABILIZATION OF UV-SENSITIVE ACTIVE INGREDIENTS 有权
标题翻译：紫外线敏感活性成分的稳定性
公开(公告)号：US20100104523A1
公开(公告)日：2010-04-29
申请号：US12520880
申请日：2008-01-16
申请人： Barbara Wagner , Bernd Herzog , Stefan Muller , Thomas Ehlis
发明人： Barbara Wagner , Bernd Herzog , Stefan Muller , Thomas Ehlis
IPC分类号： A61K8/41 , A61K8/40 , A61Q17/04
CPC分类号： A61K8/41 , A61K8/35 , A61K8/44 , A61K2800/52 , A61Q5/00 , A61Q5/02 , A61Q5/04 , A61Q5/06 , A61Q5/12 , A61Q17/04 , A61Q19/004 , A61Q19/04
摘要： Disclosed is the use of merocyanine derivatives of formula (1) for stabilizing UV-sensitive active ingredients like dibenzoylmethane derivatives.
摘要翻译：公开了式（1）的部花青衍生物用于稳定紫外线敏感活性成分如二苯甲酰甲烷衍生物的用途。

2. 发明申请

US20090175809A1 Merocyanine derivatives for cosmetic use 有权
标题翻译：用于化妆品使用的花青衍生物
公开(公告)号：US20090175809A1
公开(公告)日：2009-07-09
申请号：US12378566
申请日：2009-02-17
申请人： Barbara Wagner , Thomas Ehlis , Stefan Muller
发明人： Barbara Wagner , Thomas Ehlis , Stefan Muller
IPC分类号： A61K8/37 , C07C255/31 , C07C229/46 , C07D295/14 , C07D413/12 , C07D401/12 , C07D403/12 , A61Q17/04
CPC分类号： C07D295/116 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/494 , A61K8/81 , A61Q17/00 , A61Q17/02 , C07C225/20 , C07C229/46 , C07C255/31 , C07C317/48 , C07C2601/14 , C07C2601/16 , C07D295/155
摘要： Described are merocyanine derivatives of formula wherein R2 is hydrogen; C1-C22alkyl; cyclo-C3-C8alkyl; unsubstituted or C1-C6alkyl- or C1-C6alkoxy-substituted C6-C20aryl; a cyano group; or R1 and R2 together with the nitrogen atom linking them form a —(CH2)m— ring which is optionally interrupted by —O— or by —NR7—; R4 is a cyano group; or -Q1-R5; Q1 is —COO—; —CONH—; —CO—; —SO2—; or —CONR6—; R5 is C1-C22alkyl; cyclo-C3-C8alkyl; or unsubstituted or C1-C6alkyl-substituted C6-C20aryl; R6 is hydrogen; C1-C22alkyl; cyclo-C3-C8alkyl; unsubstituted or C1-C6alkyl- or C1-C6alkoxy-substituted C6-C20aryl; R7 is hydrogen; C1-C22alkyl; cyclo-C3-C8alkyl; unsubstituted or C1-C6alkyl- or C1-C6alkoxy-substituted C6-C20aryl; the cyclohexene radical C is not substituted or substituted by one or more C1-C5alkyl; m is from 3 to 7; n is from 2 to 4; and o is from 2 to 4. Said merocyanine derivatives are useful in protecting human and animal hair and skin from UV radiation and to cosmetic compositions comprising said derivatives.
摘要翻译：描述的是下式的部花青衍生物其中R2是氢; C 1 -C 22烷基; 环-C 3 -C 8烷基; 未取代的或C 1 -C 6烷基 - 或C 1 -C 6烷氧基取代的C 6 -C 20芳基; 氰基; 或R 1和R 2与连接它们的氮原子一起形成 - （CH 2）m - 环，其任选被-O-或-NR 7 - 间隔; R4是氰基; 或-Q1-R5; Q1是-COO-; -CONH-; -CO-; -SO2-; 或-CONR6-; R5是C1-C22烷基; 环-C 3 -C 8烷基; 或未取代的或C 1 -C 6烷基取代的C 6 -C 20芳基; R6是氢; C 1 -C 22烷基; 环-C 3 -C 8烷基; 未取代的或C 1 -C 6烷基 - 或C 1 -C 6烷氧基取代的C 6 -C 20芳基; R7是氢; C 1 -C 22烷基; 环-C 3 -C 8烷基; 未取代的或C 1 -C 6烷基 - 或C 1 -C 6烷氧基取代的C 6 -C 20芳基; 环己烯基C不被一个或多个C 1 -C 5烷基取代或取代; m为3〜7; n为2〜4; 和o为2至4.所述的部花青衍生物可用于保护人和动物毛发和皮肤免受紫外线辐射和包含所述衍生物的化妆品组合物。

3. 发明申请

US20080124285A1 Merocyanine Derivatives for Cosmetic Use 有权
标题翻译：用于化妆品使用的花青衍生物
公开(公告)号：US20080124285A1
公开(公告)日：2008-05-29
申请号：US10582748
申请日：2004-12-08
申请人： Barbara Wagner , Thomas Ehlis , Stefan Muller
发明人： Barbara Wagner , Thomas Ehlis , Stefan Muller
IPC分类号： A61K8/41 , A61Q17/04 , C07C233/11 , A61K31/165 , C07C211/26 , A61K31/137 , C07C229/40 , A61K31/216 , C07C211/54 , A61K31/136
CPC分类号： C07D295/116 , A61K8/41 , A61K8/44 , A61K8/46 , A61K8/494 , A61K8/81 , A61Q17/00 , A61Q17/02 , C07C225/20 , C07C229/46 , C07C255/31 , C07C317/48 , C07C2601/14 , C07C2601/16 , C07D295/155
摘要： Described are merocyanine derivatives of formula (1a) or (1b) wherein n and o are integers from 2 to 4 and aminocyclohexenone intermediates. They are used in protecting human and animal hair and skin from UV radiation.
摘要翻译：描述的是式（1a）或（1b）的部花青衍生物，其中n和o是2-4的整数和氨基环己烯酮中间体。它们用于保护人体和动物的毛发和皮肤免受紫外线辐射。

4. 发明申请

US20080075746A1 Light Protecting-Effective Cosmetic or Dermatological Preparations 有权
标题翻译：光保护有效的化妆品或皮肤病学制剂
公开(公告)号：US20080075746A1
公开(公告)日：2008-03-27
申请号：US11632686
申请日：2005-07-11
申请人： Stefan Muller , Thomas Ehlis , Jochen Giesinger , Gilbert Kreyer
发明人： Stefan Muller , Thomas Ehlis , Jochen Giesinger , Gilbert Kreyer
IPC分类号： A61K8/02 , A61K8/00 , A61Q17/04
CPC分类号： A61Q17/04 , A61K8/02 , A61K9/107 , A61K2800/412
摘要： Disclosed is the use of an insoluble or sparingly soluble micronized substance class which is not a cosmetic UV absorber and which is dispersed in the oil- or water-phase of a cosmetic or dermatological composition for the enhancement of light protecting action of this cosmetic or dermatological composition comprising at least one cosmetic UV filter which is soluble in the water- or oil-phase. The cosmetic preparation according to the invention shows a remarkable increase in SPF.
摘要翻译：公开了使用不是化妆品UV吸收剂并且分散在化妆品或皮肤病学组合物的油相或水相中的不溶性或微溶的微粉化物质类，以增强该化妆品或皮肤病学的光保护作用组合物，其包含至少一种可溶于水相或油相的化妆品UV过滤器。根据本发明的化妆品显示出SPF的显着增加。

5. 发明申请

US20100193614A1 PREPARATION OF NANOSCALAR UV ABSORBERS 有权
标题翻译：纳米紫外线吸收剂的制备
公开(公告)号：US20100193614A1
公开(公告)日：2010-08-05
申请号：US12664429
申请日：2008-06-27
申请人： Stefan Muller , Bernd Herzog
发明人： Stefan Muller , Bernd Herzog
IPC分类号： B02C23/06 , C07D251/24
CPC分类号： C07D251/24 , A61K8/4966 , A61K2800/412 , A61K2800/413 , A61Q17/04 , B82Y5/00
摘要： Disclosed is a method of preparing a composition, comprising a micronised insoluble organic UV absorber, which method comprises grinding the insoluble organic UV absorber, in coarse particle form, in a grinding apparatus comprising yttrium-stabilized zirconium oxide grinding beads, in the presence of alkyl polyglucoside having the formula CnH2n+1O(C6H10O5)xH, in which n is an integer ranging from 8 to 16 and x is the mean polymerisation level of the glucoside moiety (C6H10O5) and ranges from 1.4 to 1.6, or an ester thereof and in the presence of an antifoam agent as dispersingagent auxiliary.
摘要翻译：公开了一种制备组合物的方法，所述组合物包含微粉化的不溶性有机UV吸收剂，该方法包括在包含钇稳定的氧化锆研磨珠的研磨装置中，在烷基存在下，以粗颗粒形式研磨不溶性有机UV吸收剂具有式C n H 2n + 10（C 6 H 10 O 5）x H的聚葡萄糖苷，其中n是8至16的整数，x是葡萄糖苷部分（C 6 H 10 O 5）的平均聚合水平，范围为1.4至1.6，或其酯，消泡剂作为分散助剂的存在。

6. 发明申请

US20060018846A1 Animo substituted hydroxyphenyl benzophenone derivatives 有权
标题翻译： Animo取代的羟基苯基二苯甲酮衍生物
公开(公告)号：US20060018846A1
公开(公告)日：2006-01-26
申请号：US10537940
申请日：2003-12-03
申请人： Jurg Haase , Thomas Ehlis , Elek Borsos , Stefan Muller
发明人： Jurg Haase , Thomas Ehlis , Elek Borsos , Stefan Muller
IPC分类号： C07D417/02 , C07D405/02 , A61K8/49
CPC分类号： C07D295/192 , A61K8/42 , A61K8/44 , A61K8/49 , A61K8/4973 , A61Q17/04 , C07C229/52 , C07C237/32 , C07C237/34 , C07C237/40 , C07C237/42 , C07D277/46 , C07D277/66 , C07D313/12
摘要： Described are amino substituted hydroxyphenyl benzophenone derivatives of formula (I), wherein R1, and R2 independently from each other are; C1-C20alkyl; C2-C20-alkenyl; C3-C10cycloalkyl; C3-C10cycloalkenyl; or R1, and R2 together with the linking nitrogen atom form a 5- or 6-membered heterocyclic ring; n1 is a number from 1 to 4; when n1=1, R3 is a saturated or unsaturated heterocyclic radical; hydroxy-C1-C5alkyl; cyclohexyl optionally substituted with one or more C1-C5alkyl; phenyl optionally substituted with a heterocyclic radical, aminocarbonyl or C1-C5alkylcarboxy; when n1 is 2, R3 is an alkylene-, cycloalkylene- or alkenylene radical which is optionally substituted by a carbonyl- or carboxy group; o R3 together with A forms a bivalent radical of the formula (Ia), wherein n2 is a number from 1 to 3; when n1 is 3, R3 is an alkanetriyl radical; when n1 is 4, R3 is an alkanetetrayl radical; A is —O—; or —N(R5)—; and R5 is hydrogen; C1-C5alkyl; or hydroxy-C1-C5alkyl. The compounds are useful as UV filters in sunscreen applications.
摘要翻译：描述了式（I）的氨基取代的羟基苯基二苯甲酮衍生物，其中R 1和R 2彼此独立地为： C 1 -C 20烷基; C 1 -C 20烷基; C 2 -C 20 - 烯基; C 3 -C 10环烷基; C 3 -C 10环烯基; 或R 1和R 2与连接氮原子一起形成5-或6-元杂环; n 1是1至4的数; 当n 1 = 1时，R 3 3是饱和或不饱和杂环基; 羟基-C 1 -C 5烷基; 任选被一个或多个C 1 -C 5烷基取代的环己基; 任选被杂环基取代的苯基，氨基羰基或C 1 -C 5烷基羧基; 当n 1是2时，R 3是任选被羰基或羧基取代的亚烷基 - 亚环烷基 - 或亚烯基; R 3与A一起形成式（Ia）的二价基团，其中n 2是1至3的数; 当n 1为3时，R 3为烷三基; 当n 1为4时，R 3为烷基乙酰基; A为-O- 或-N（R 5） - ; 并且R 5是氢; C 1 -C 5烷基; 或羟基-C 1 -C 5烷基。这些化合物可用作防晒霜中的紫外线过滤器。

7. 发明授权

US08940060B2 Methods and apparatuses for forming low-metal biomass-derived pyrolysis oil 有权
标题翻译：用于形成低金属生物质衍生的热解油的方法和装置
公开(公告)号：US08940060B2
公开(公告)日：2015-01-27
申请号：US13327525
申请日：2011-12-15
申请人： Lance Awender Baird , Stefan Muller , Barry A. Freel
发明人： Lance Awender Baird , Stefan Muller , Barry A. Freel
IPC分类号： C10L1/00
CPC分类号： C10C5/00 , C10B49/16 , C10B53/02 , C10B57/08 , C10G2300/1014 , C10K1/08 , C10K1/10 , Y02E50/14 , Y02P30/20
摘要： Methods and apparatuses for forming a low-metal biomass-derived pyrolysis oil are provided. In an embodiment, a method for forming a low-metal biomass-derived pyrolysis oil includes washing biomass comprising a water-soluble metal component therein with wash water that is substantially free of water-soluble metals. The washed biomass and water containing water-soluble metal are separated after washing the biomass. The washed biomass is pyrolyzed in a pyrolysis process to form a pyrolysis vapor stream. A portion of the pyrolysis vapor stream is condensed to form a condensate. The wash water is derived from the washed biomass. In an embodiment of an apparatus, the apparatus comprises a washing stage, a biomass dryer, a pyrolysis reactor, a quenching system comprising a primary condenser and a secondary condenser, and a return line that connects the quenching system to the washing stage.
摘要翻译：提供了形成低金属生物质衍生的裂解油的方法和装置。在一个实施方案中，用于形成低金属生物质衍生的热解油的方法包括用基本上不含水溶性金属的洗涤水洗涤其中包含水溶性金属组分的生物质。在洗涤生物质后，分离经洗涤的生物质和含水溶性金属的水分。洗涤的生物质在热解过程中热解，形成热解蒸汽流。一部分热解蒸汽流被冷凝以形成冷凝物。洗涤水源自洗涤的生物质。在装置的一个实施方案中，该装置包括洗涤阶段，生物质干燥器，热解反应器，包括初级冷凝器和次级冷凝器的淬火系统，以及将淬火系统连接到洗涤阶段的返回管线。

8. 发明授权

US07601730B2 Carboxylic acid derivatives, their preparation and use 失效
公开(公告)号：US07601730B2
公开(公告)日：2009-10-13
申请号：US11502293
申请日：2006-08-10
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Josef Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： A61P7/02
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.

9. 发明申请

US20070203338A1 Novel carboxylic acid derivatives, their preparation and use 失效
标题翻译：新型羧酸衍生物，其制备和用途
公开(公告)号：US20070203338A1
公开(公告)日：2007-08-30
申请号：US11789630
申请日：2007-04-25
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： C07D251/22 , C07D207/00 , C07D233/22 , C07D303/48 , C07D257/06 , C07D239/24
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R—R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R 6，X，Y和Z具有说明书中所述含义及其制备的羧酸衍生物。新型化合物适用于控制疾病。

10. 发明申请

US20060276474A1 Novel carboxylic acid derivatives, their preparation and use 失效
标题翻译：新型羧酸衍生物，其制备和用途
公开(公告)号：US20060276474A1
公开(公告)日：2006-12-07
申请号：US11502293
申请日：2006-08-10
申请人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
发明人： Hartmut Riechers , Dagmar Klinge , Wilhelm Amberg , Andreas Kling , Stefan Muller , Ernst Baumann , Joachim Rheinheimer , Uwe Vogelbacher , Wolfgang Wernet , Liliane Unger , Manfred Raschack
IPC分类号： C07D251/48 , A61K31/53 , A61K31/513
CPC分类号： C07D495/04 , C07D239/34 , C07D239/48 , C07D239/52 , C07D239/60 , C07D239/70 , C07D239/96 , C07D251/20 , C07D251/26 , C07D251/52 , C07D403/06 , C07D403/12 , C07D405/12 , C07D405/14 , C07D413/12 , C07D417/12 , C07D487/04 , C07D491/04 , C07D491/048
摘要： Carboxylic acid derivatives where R-R6, X, Y and Z have the meanings stated in the description, and the preparation thereof, are described. The novel compounds are suitable for controlling diseases.
摘要翻译：其中R-R 6，X，Y和Z具有说明书中所述含义及其制备的羧酸衍生物。新型化合物适用于控制疾病。

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