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1. 发明授权

US4430445A Novel basic imidazolylmethylstyrene compound, its polymer, a process for the preparation thereof and a use as ion exchange resin 失效
标题翻译：新的基本咪唑基甲基苯乙烯化合物，其聚合物，其制备方法和用作离子交换树脂
公开(公告)号：US4430445A
公开(公告)日：1984-02-07
申请号：US335943
申请日：1981-12-30
申请人： Tetsuya Miyake , Kunihiko Takeda , Keishi Tada
发明人： Tetsuya Miyake , Kunihiko Takeda , Keishi Tada
IPC分类号： C07D233/54 , C07D233/92 , C07D521/00 , C08F12/32 , B01J39/20 , C08F26/06
CPC分类号： C07D233/56 , C07D231/12 , C07D233/92 , C07D249/08 , C08F12/32
摘要： Novel imidazolylmethylstyrene compounds which are basic compounds and have excellent resistance to oxidation and high polymerizability are disclosed. The basic compound of the present invention is prepared by reacting a halogenomethyl-styrene with an imidazole compound, and can be used, for example, as a curing agent for epoxy resins. The imidazolymethylstyrene compounds are readily homopolymerized or copolymerized to provide linear homopolymers, linear copolymers or cross-linked copolymers having pendant imidazolylmethylphenyl groups. These polymers have greater resistance to oxidation than the homologues, and are useful as an ion exchange resin, extractant of metals, sizing agent and antistatic agent.
摘要翻译：公开了作为碱性化合物并且具有优异的抗氧化性和高聚合性的新型咪唑基甲基苯乙烯化合物。本发明的碱性化合物是通过卤甲基苯乙烯与咪唑化合物的反应来制备的，可用作例如环氧树脂的固化剂。咪唑聚甲基苯乙烯化合物容易均聚或共聚以提供具有侧链咪唑基甲基苯基的线性均聚物，线性共聚物或交联共聚物。这些聚合物比同系物具有更大的抗氧化性，并且可用作离子交换树脂，金属萃取剂，上浆剂和抗静电剂。

2. 发明授权

US4394353A Separation of rare earth metals using a cation exchanger 失效
标题翻译：使用阳离子交换器分离稀土金属
公开(公告)号：US4394353A
公开(公告)日：1983-07-19
申请号：US213110
申请日：1980-12-04
申请人： Tetsuya Miyake , Kunihiko Takeda , Hatsuki Onitsuka , Kazuo Okuyama , Yasuki Shimamura
发明人： Tetsuya Miyake , Kunihiko Takeda , Hatsuki Onitsuka , Kazuo Okuyama , Yasuki Shimamura
IPC分类号： B01D15/42 , B01J39/26 , C01F17/00 , C22B3/32 , G01N30/02
CPC分类号： C22B3/0024 , B01D15/422 , B01J39/26 , C01F17/0006 , C22B3/24 , C22B3/42 , G01N30/02 , Y02P10/234
摘要： A process for the separation of one rare earth metal from another in a mixture of rare earth metals by chromatographic displacement using a complexing agent and a cation exchanger, which process comprises using a cation exchanger having a micro-void volume void ratio of 0.5 to 0.95, preferably 0.5 to 0.88.
摘要翻译：一种通过使用络合剂和阳离子交换剂的色谱置换在稀土金属混合物中分离一种稀土金属的方法，该方法包括使用具有微孔隙体积空隙率为0.5至0.95的阳离子交换剂，优选为0.5〜0.88。

3. 发明授权

US4280984A Isotope separation 失效
标题翻译：同位素分离
公开(公告)号：US4280984A
公开(公告)日：1981-07-28
申请号：US941505
申请日：1978-09-11
申请人： Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
发明人： Tetsuya Miyake , Norito Ogawa , Kohji Inada , Kunihiko Takeda
IPC分类号： B01D15/00 , B01D59/30 , C01G56/00 , B01J39/00 , B01J41/00 , B01J47/00
CPC分类号： B01D59/30 , Y10S422/903
摘要： An isotope separation apparatus comprises a plurality of independent developing units, each comprising 2 to 20 adsorbent-packed columns forming a continuous developing circuit or passageway, and the developing units are connected to at least one common main pipe for supplying an isotope mixture solution, a regenerating agent solution, or an eluent solution. Also, in a further embodiment the developing units are connected to common liquid-discharge main pipes.The separation or concentration of isotopes such as uranium isotopes, nitrogen isotopes, boron isotopes, etc., is performed by continuously developing the isotope mixture solution passed through the individual adsorbent-packed columns successively in each developing units.
摘要翻译：同位素分离装置包括多个独立的显影单元，每个显影单元包括形成连续显影回路或通道的2至20个吸附剂填充柱，显影单元连接至至少一个用于提供同位素混合溶液的公共主管，再生剂溶液或洗脱液。此外，在另一实施例中，显影单元连接到共同的排液主管。通过在每个显影单元中连续地开发通过单独的吸附剂填充塔的同位素混合物溶液来进行同位素如铀同位素，氮同位素，硼同位素等的分离或浓缩。

4. 发明授权

US4246351A Protein adsorbent 失效
标题翻译：蛋白质吸附剂
公开(公告)号：US4246351A
公开(公告)日：1981-01-20
申请号：US088927
申请日：1979-10-29
申请人： Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Masayuki Mizuno
发明人： Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Masayuki Mizuno
IPC分类号： B01J20/22 , C07K1/16 , C08J9/28 , C12H1/056 , C12N11/08 , C08J9/00
CPC分类号： C12N11/08 , B01J20/22 , C07K1/16 , C08J9/286 , C12H1/0424 , Y10S210/905 , Y10S435/815 , Y10S530/806
摘要： A novel protein adsorbent consisting essentially of a porous copolymer obtained by copolymerizing a monomer mixture comprising at least one cyano group-containing monomer and at least one cross-linkable monomer, said copolymer having an average pore diameter (d) of from 40 A to 9,000 A and a total pore volume of from 0.05.sqroot.X ml to 1.5.sqroot.X ml per gram of the copolymer in a dry state, in which X designates the weight proportion of said cross-linkable monomer expressed in terms of the percent by weight based on the total monomers. The present porous copolymer adsorbent has a remarkably high protein adsorbing capacity. The adorbent can advantageously be used for various purposes such as purification and separation of proteins, and removal of proteins. Copolymer-protein composites obtained by adsorption of proteins on the present porous copolymer also are industrially useful and have a wide variety of applications.
摘要翻译：一种新型蛋白质吸附剂，其基本上由多孔共聚物组成，所述多孔共聚物通过使包含至少一个含氰基单体和至少一种可交联单体的单体混合物共聚而获得，所述共聚物的平均孔径（d）为40〜9,000 A，并且在干燥状态下每克共聚物的总孔体积为0.05×2×UV×1.5×2××××X，其中X表示所述可交联单体的重量比例，以基于总单体。本发明的多孔共聚物吸附剂具有非常高的蛋白质吸附能力。该助剂可有利地用于各种目的，例如蛋白质的纯化和分离以及蛋白质的去除。通过在本发明的多孔共聚物上吸附蛋白获得的共聚物 - 蛋白质复合物在工业上也是有用的并且具有广泛的应用。

5. 发明授权

US4406870A Method for the separation of carbon isotopes by chemical exchange method 失效
标题翻译：通过化学交换法分离碳同位素的方法
公开(公告)号：US4406870A
公开(公告)日：1983-09-27
申请号：US293220
申请日：1981-08-10
申请人： Tetsuya Miyake , Kunihiko Takeda , Heiichiro Obanawa
发明人： Tetsuya Miyake , Kunihiko Takeda , Heiichiro Obanawa
IPC分类号： B01D59/30 , C01B31/00
CPC分类号： B01D59/30 , Y10S423/07
摘要： A method for the separation of the isotopes of carbon comprising contacting an aqueous solution containing an acid-dissociated type chemical species of a carbon-containing acid and a non-dissociated type chemical species of said acid with an anion exchange resin as a solid phase, thereby to allow an isotope exchange reaction with respect to carbon to proceed between said acid-dissociated type chemical species and said non-dissociated type chemical species and, concurrently, to adsorb said acid-dissociated type chemical species on said anion exchange resin, and separate C.sup.12 and C.sup.13 respectively into a solution phase and the solid phase or the solid phase and a solution phase, whereby C.sup.13 is concentrated. This method can be practised at an extremely favorable efficiency and inexpensive cost, as compared with the prior art method for the separation utilizing a distillation method or a chemical exchange method between gas--liquid phases, gas--solution phases, solution--solution phases and the like.
摘要翻译： PCT No.PCT / JP80 / 00326 Sec。 371日期1981年8月10日 102（e）日期1981年8月10日PCT提交1980年12月2日PCT公布。出版物WO81 / 01802 日本1981年7月9日。一种用于分离碳同位素的方法，包括使含有酸的酸的解离型化学物质和所述酸的非离解型化学物质的水溶液与阴离子交换树脂作为固相，从而允许在所述酸解离型化学物质和所述非解离型化学物质之间进行相对于碳的同位素交换反应，并且同时将所述酸解离型化学物质吸附在所述阴离子交换树脂，并将C12和C13分别分离成溶液相和固相或固相和溶液相，由此C13浓缩。与现有技术的分离方法相比，可以以非常有利的效率和廉价的成本实现该方法，其中使用蒸气法或气 - 液相，气溶相，溶液相之间的化学交换方法喜欢。

6. 发明授权

US4137054A Purification of formaldehyde by separation 失效
标题翻译：通过分离纯化甲醛
公开(公告)号：US4137054A
公开(公告)日：1979-01-30
申请号：US760218
申请日：1977-01-17
申请人： Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
发明人： Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
IPC分类号： C07C47/058 , B01J20/18 , C07C45/00 , C07C45/78 , C07C67/00 , B01D53/04 , B01D53/28
CPC分类号： C07C45/79 , Y10S95/902
摘要： A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要翻译：通过与元素周期表第IA（4）至（6）或IIA（6）或其组合的元素的交换阳离子的特定A型沸石的吸附剂接触，可以有效地分离含甲醛和水的混合物。

7. 发明授权

US4285811A Purification of formaldehyde by separation 失效
标题翻译：通过分离纯化甲醛
公开(公告)号：US4285811A
公开(公告)日：1981-08-25
申请号：US7527
申请日：1979-01-29
申请人： Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
发明人： Tetsuya Miyake , Kunihiko Takeda , Naoki Miyata , Tatsushi Saeki , Maomi Seko
IPC分类号： C07C47/058 , B01J20/18 , C07C45/00 , C07C45/78 , C07C67/00 , B01D15/00
CPC分类号： C07C45/79 , Y10S95/902
摘要： A mixture containing formaldehyde and water is separated effectively by contacting with adsorbents of specific type A zeolites containing exchanged cations of the elements from Group IA (4) to (6) or Group IIA (6) or mixture thereof of the Periodic Table of Elements.
摘要翻译：通过与元素周期表第IA（4）至（6）或IIA（6）或其组合的元素的交换阳离子的特定A型沸石的吸附剂接触，可以有效地分离含甲醛和水的混合物。

8. 发明授权

US4124770A Separation of xylenols from cresols with adsorbent 失效
标题翻译：用吸附剂从甲酚中分离二甲苯酚
公开(公告)号：US4124770A
公开(公告)日：1978-11-07
申请号：US764129
申请日：1977-01-31
申请人： Tetsuya Miyake , Kunihiko Takeda
发明人： Tetsuya Miyake , Kunihiko Takeda
IPC分类号： C07C37/82 , C07C37/24
CPC分类号： C07C37/82
摘要： A mixture of xylenols and cresols is contacted with a zeolite with aperture of 5.5 A or more containing at least one cations selected from lithium, potassium, cesium, rubidium, calcium, barium, strontium, cadmium, chromium, molybdenum, manganese, iron, nickel, cobalt, and ammonium to separate xylenols from cresols.
摘要翻译：将二甲苯酚和甲酚的混合物与含有至少一种选自锂，钾，铯，铷，钙，钡，锶，镉，铬，钼，锰，铁，镍的至少一种阳离子的沸点接触的沸石，钴和铵，以将二甲苯酚与甲酚分离。

9. 发明授权

US4118457A Redox uranium isotope separation using anion exchangers 失效
标题翻译：使用阴离子交换剂的氧化还原铀同位素分离
公开(公告)号：US4118457A
公开(公告)日：1978-10-03
申请号：US687844
申请日：1976-05-19
申请人： Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人： Maomi Seko , Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
IPC分类号： C22B60/02 , B01D15/00 , B01D59/30 , B01J41/14 , B01J41/20 , C08F212/08 , C08F226/06
CPC分类号： B01D59/30 , B01J41/14
摘要： An anion exchange resin particle provided with specific structure as well as specific functional groups is found to be suitable for uranium technology, especially for separation of uranium isotopes.
摘要翻译：发现具有特定结构和特定官能团的阴离子交换树脂颗粒适用于铀技术，特别是用于分离铀同位素。

10. 发明授权

US4093570A Production of porous polymers 失效
标题翻译：生产多孔聚合物
公开(公告)号：US4093570A
公开(公告)日：1978-06-06
申请号：US677120
申请日：1976-04-14
申请人： Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
发明人： Tetsuya Miyake , Kunihiko Takeda , Akihiko Ikeda , Kazuo Imamura
IPC分类号： C08F2/00 , C08F2/06 , C08F2/14 , C08F2/16 , C08F2/18 , C08F236/04 , C08J9/28 , C08J9/00
CPC分类号： C08J9/286 , C08F2/06 , C08F2/16 , C08F236/04
摘要： A method of producing a polar, porous polymer comprising polymerizing a monomer mixture comprising:(A) about 2 to about 98 percent by weight of at least one cross-linkable monomer having a plurality of CH.sub.2 .dbd.C
摘要翻译：一种制备极性多孔聚合物的方法，包括聚合单体混合物，其包括：

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