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    • 3. 发明申请
    • Negative electrode material for lithium ion secondary battery
    • 锂离子二次电池用负极材料
    • US20050158550A1
    • 2005-07-21
    • US10501333
    • 2003-01-24
    • Naoto OhtaKatsuhide NagaokaKazuhito HoshiHidehiko NozakiTatsuro TojoToshiaki Sogabe
    • Naoto OhtaKatsuhide NagaokaKazuhito HoshiHidehiko NozakiTatsuro TojoToshiaki Sogabe
    • H01M4/36B32B27/00H01M4/133H01M4/583H01M4/587H01M10/0525H01M4/58
    • H01M4/133H01M4/366H01M4/587H01M10/0525H01M2004/021Y10T428/2998
    • The invention provides an anode material for lithium ion secondary battery using a coated graphite powder as a raw material. The coated graphite powder is coated with carbonized material of thermoplastic resin of a carbonization yield of not more than 20 wt % in a proportion of not more than 10 parts by weight the carbonized material per 100 parts by weight graphite powder. The graphite powder as coated with thermoplastic resin increases 5% or more in accumulative pore volume of the graphite powder having a pore size of 0.012 μm to 40 μm as measured by a mercury porosimeter method, as compared with the graphite powder before coated with the thermoplastic resin. The coated graphite powder has a mesopore volume defined by IUPAC of 0.01 cc/g or less as calculated with the BJH method as viewed from desorption isotherm, which is also equal to 60% or less of the pore volume of the graphite powder before coated with the thermoplastic resin, an average particle size ranging from 10 μm to 50 μm, as measured by a laser-scattering-particle-size-distribution measuring device, and a ratio of standard deviation to the average particle size (σ/D) of 0.02 or less.
    • 本发明提供一种使用涂覆石墨粉作为原料的锂离子二次电池的负极材料。 涂覆的石墨粉末以每100重量份石墨粉末碳化材料不超过10重量份的比例涂覆碳化产率为20重量%以下的热塑性树脂碳化材料。 与热塑性树脂一起涂覆的石墨粉末,与用热塑性树脂涂覆之前的石墨粉末相比,通过水银孔率计法测量,孔径为0.012μm至40μm的石墨粉末的累积孔体积增加5%或更多 树脂。 涂覆的石墨粉末具有由解吸等温线观察时用BJH法计算的0.01cc / g以下的由IUPAC定义的中孔体积,其等于涂布前的石墨粉末的孔体积的60%以下 热塑性树脂,通过激光散射 - 粒度分布测量装置测量的平均粒度为10〜50μm,标准偏差与平均粒径(sigma / D)的比值为0.02 或更少。
    • 4. 发明授权
    • Anode material for lithium ion secondary battery
    • 锂离子二次电池用阳极材料
    • US07816037B2
    • 2010-10-19
    • US10501333
    • 2003-01-24
    • Naoto OhtaKatsuhide NagaokaKazuhito HoshiHidehiko NozakiTetsuro TojoToshiaki Sogabe
    • Naoto OhtaKatsuhide NagaokaKazuhito HoshiHidehiko NozakiTetsuro TojoToshiaki Sogabe
    • H01M4/58
    • H01M4/133H01M4/366H01M4/587H01M10/0525H01M2004/021Y10T428/2998
    • The invention provides an anode material for lithium ion secondary battery using a coated graphite powder as a raw material, which is coated thermoplastic resin of a carbonization yield of ≦20 wt % in a proportion of ≦10 parts by weight the carbonized material per 100 parts by weight graphite powder. Coating with thermoplastic resin increases the accumulative pore volume by ≦5%, relative to the uncoated powder, and results in pore sizes of 0.012-40 μm via mercury porosimeter method. Calculated with the BJH method as viewed from desorption isotherm, the coated graphite powder has a mesopore volume ≦0.01 cc/g or ≦60% of the pore volume of the uncoated graphite powder. This coated powder also has an average particle size ranging from 10-50 μm measured by a laser-scattering-particle-size-distribution measuring device, and a standard deviation to the average particle size (σ/D) ratio of ≦0.02.
    • 本发明提供一种使用涂覆石墨粉末作为原料的锂离子二次电池的负极材料,其为碳化产率为< nEE的涂层热塑性树脂;以< NEE为20重量%; 10重量份碳化材料 100重量份石墨粉。 用热塑性树脂涂层,相对于未涂覆的粉末,累积孔体积增加了±10%; 5%,通过汞孔率计法得到0.012-40μm的孔径。 用解吸等温线观察的BJH方法计算,涂覆的石墨粉末的中孔体积为0.01cc / g或者nlE;未涂覆石墨粉末的孔体积的60%。 该涂覆粉末还具有通过激光散射 - 粒度分布测量装置测量的10-50μm的平均粒径,并且与平均粒径(& Gr / D)比率&n1E的标准偏差为0.02 。