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1. 发明授权

US5750800A Process for producing diisopropyl ether from propane 失效
标题翻译：从丙烷生产二异丙醚的方法
公开(公告)号：US5750800A
公开(公告)日：1998-05-12
申请号：US556117
申请日：1995-11-09
申请人： Terry L. Marker , Brian S. Muldoon , Bryan K. Glover , Bipin V. Vora
发明人： Terry L. Marker , Brian S. Muldoon , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C5/333 , C07C41/05 , C07C41/00
CPC分类号： C07C41/05 , C07C5/333 , Y02P20/125
摘要： An integrated process to produce diisopropyl ether from propane has been developed. In a first reaction zone the propane in a feedstock, after any hydrocarbons containing four or more carbon atoms are removed from the feedstock via fractionation, is dehydrogenated in the presence of a dehydrogenation catalyst to form propylene. After removing hydrogen, the propane and propylene mixture generated in the first reaction zone is separated into a propane enriched stream and a propylene enriched stream where the propylene enriched stream contains at least 65 mass % propylene. The propane enriched stream is recycled to the feedstock fractionation unit, and the propylene of the propylene enriched stream is reacted with water in a second reaction zone in the presence of an acidic catalyst to form isopropyl alcohol which is concurrently reacted with propylene to produce diisopropyl ether. A portion of the second reaction zone effluent is recycled to the second reaction zone, and the remainder may be collected or further separated to provide a high purity diisopropyl ether product. A variant to produce high purity propylene as well as diisopropyl ether is also discussed.
摘要翻译：已经开发了从丙烷生产二异丙醚的综合方法。在第一反应区中，原料中的丙烷在含有四个或更多个碳原子的烃通过分馏从原料中除去后，在脱氢催化剂存在下脱氢形成丙烯。除去氢气后，在第一反应区产生的丙烷和丙烯混合物分离成富丙烷流和富丙烯流，其中富含丙烯的料流含有至少65质量％的丙烯。将富丙烷流再循环至原料分馏装置，在酸性催化剂存在下，使丙烯富集物流的丙烯与第二反应区中的水反应形成异丙醇，同时与丙烯反应产生二异丙醚。第二反应区流出物的一部分再循环至第二反应区，其余部分可以被收集或进一步分离以提供高纯度的二异丙醚产物。还讨论了生产高纯度丙烯以及二异丙基醚的变体。

2. 发明授权

US6049017A Enhanced light olefin production 失效
标题翻译：增强轻烯烃生产
公开(公告)号：US6049017A
公开(公告)日：2000-04-11
申请号：US59906
申请日：1998-04-13
申请人： Bipin V. Vora , Terry L. Marker , Paul T. Barger
发明人： Bipin V. Vora , Terry L. Marker , Paul T. Barger
IPC分类号： C07C11/04 , C07C11/06 , C07C1/00 , C07C1/20 , C07C4/06
CPC分类号： C07C4/06 , B01J21/16 , B01J29/005 , B01J29/035 , B01J29/85 , B01J37/0045 , C07C1/20 , C07C7/14891 , C07C7/163 , C10G11/05 , C10G11/18 , C10G27/00 , C10G51/026 , C10G55/06 , B01J2229/42 , C07C2529/65 , C07C2529/84 , C07C2529/85 , C10G2400/20 , Y02P20/52 , Y02P30/42
摘要： A process is disclosed for enhancing the production of light olefins with a catalytic reaction zone containing small pore zeolitic and non-zeolitic catalysts which can significantly improve the yield of ethylene and propylene in a process for the conversion of light olefins having four carbon atoms per molecule and heavier. Specifically, a C.sub.4 olefin stream from an ethylene production complex is converted in a reaction zone over a non-zeolitic catalyst at effective conditions to produce a product mixture containing ethylene and propylene. Ethylene and propylene are separated from the product mixture and recovered. A portion of the remaining heavy hydrocarbons and paraffins may be recycled to the reaction zone for further conversion, or oligomerized to produce valuable downstream products. The additional step of removing iso-olefins from the recycle stream provided significant advantages. The process of the present invention may be applied in commercial ethylene plants, in petroleum refining catalytic cracking operations, and in processes for the conversion of oxygenates such as methanol-to-olefins to enhance the production of ethylene and propylene.
摘要翻译：公开了一种利用含有小孔沸石和非沸石催化剂的催化反应区增强轻质烯烃生产的方法，该催化反应区可在每分子具有四个碳原子的轻质烯烃转化方法中显着提高乙烯和丙烯的产率更重具体地说，来自乙烯生成络合物的C 4烯烃流在有效条件下在非沸石催化剂的反应区中被转化，以产生含有乙烯和丙烯的产物混合物。将乙烯和丙烯与产物混合物分离并回收。剩余的重质烃和链烷烃的一部分可以再循环到反应区进行进一步的转化，或被低聚制成有价值的下游产物。从循环流中除去异烯烃的附加步骤提供了显着的优点。本发明的方法可以应用于商业乙烯装置，石油精炼催化裂化操作，以及用于转化含氧化合物如甲醇至烯烃的方法中以增加乙烯和丙烯的生产。

3. 发明授权

US5714662A Process for producing light olefins from crude methanol 失效
标题翻译：从粗甲醇生产轻质烯烃的方法
公开(公告)号：US5714662A
公开(公告)日：1998-02-03
申请号：US513242
申请日：1995-08-10
申请人： Bipin V. Vora , Terry L. Marker , Henning R. Nilsen
发明人： Bipin V. Vora , Terry L. Marker , Henning R. Nilsen
IPC分类号： C10C1/02 , C07C1/20 , C07C11/02 , C07C41/05 , C07C41/06 , C08F210/16 , C07C1/24
CPC分类号： C07C1/20 , C07C11/02 , C07C41/05 , C07C41/06 , C08F210/16 , C07C2529/85 , Y02P20/52 , Y02P30/42
摘要： A process is disclosed for the production of light olefins from a hydrocarbon gas stream by a combination of reforming, oxygenate production, and oxygenate conversion wherein a crude methanol stream--produced in the production of oxygenates and comprising methanol, light ends, and heavier alcohols--is passed directly to the oxygenate conversion zone for the production of light olefins. Furthermore, the combination provides the synergy for increased catalyst life and reduced water treatment costs by recycling by-product water produced in the oxygenate conversion zone to provide water to the syngas production zone. The advantage of this integration is the elimination of costly methanol separation and purification steps which result in the overall reduction in the costs of producing the light olefins. Other advantages include the reduction in catalyst cost in the oxygenate production zone by the reduction in the catalyst selectivity by the extension of catalyst life in the oxygenate production zone. In addition, a portion of the by-product water can be combined with a propylene stream to provide a high octane blending component for gasoline. The propylene and butylene fractions produced by the above integrated scheme are further converted to high octane ether and other high value products.
摘要翻译：公开了一种通过重整，含氧化合物生产和含氧化合物转化的组合从烃类气体流中生产轻质烯烃的方法，其中在生产含氧化合物并且包含甲醇，轻馏分和较重的醇 - 直接通入含氧化合物转化区用于生产轻质烯烃。此外，该组合通过再循环在含氧化合物转化区产生的副产物水以向合成气生产区提供水，提供了增加催化剂寿命和降低水处理成本的协同作用。这种整合的优点是消除了昂贵的甲醇分离和纯化步骤，导致轻质烯烃的生产成本的总体降低。其他优点包括通过在含氧化合物生产区延长催化剂寿命，催化剂选择性降低，从而降低含氧化合物生产区的催化剂成本。此外，一部分副产物水可以与丙烯流混合以提供用于汽油的高辛烷值混合组分。由上述集成方案制备的丙烯和丁烯馏分进一步转化成高辛烷值和其它高价值产物。

4. 发明授权

US07368618B2 Process for removal of oxygenates from a paraffin stream 有权
标题翻译：从石蜡流中除去含氧化合物的方法
公开(公告)号：US07368618B2
公开(公告)日：2008-05-06
申请号：US11457889
申请日：2006-07-17
申请人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
发明人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C5/327
CPC分类号： C07C5/333 , C07C2/66 , C07C7/12 , C07C7/13 , C07C15/107 , C07C9/14 , C07C11/02
摘要： The present invention comprises a process for removal of oxygenates from a paraffin-rich or olefin-rich paraffin stream which comprises passing a feed stream, comprising one or more C10 to C15 feed paraffins or C10 to C15 olefin-rich paraffin stream and one or more oxygenates through an adsorbent bed comprising one or more adsorbents selected from silica gel, activated alumina and sodium x zeolites to remove essentially all of said oxygenates; and recovering said paraffins. A second adsorbent bed may be employed to more thoroughly remove these oxygenates.
摘要翻译：本发明包括从富含链烷烃或富烯烃的石蜡流中除去含氧化合物的方法，该方法包括将含有一个或多个C 10的进料流送入C 15 通过吸附床将含有一种或多种选自硅胶，活性氧化铝和吸附剂的吸附剂的烷烃或C 10向富含C 15的富烯烃链烷烃流和一种或多种含氧化合物进料，钠x沸石以除去基本上所有的含氧化合物; 并回收所述石蜡。可以使用第二吸附剂床来更彻底地除去这些含氧化合物。

5. 发明授权

US07408092B2 Selective conversion of oxygenate to propylene using moving bed technology and a hydrothermally stabilized dual-function catalyst 有权
标题翻译：使用移动床技术和水热稳定的双功能催化剂选择性地将含氧化合物转化为丙烯
公开(公告)号：US07408092B2
公开(公告)日：2008-08-05
申请号：US10988136
申请日：2004-11-12
申请人： Bryan K. Glover , John Q. Chen , Peter R. Pujado , Bipin V. Vora
发明人： Bryan K. Glover , John Q. Chen , Peter R. Pujado , Bipin V. Vora
IPC分类号： C07C1/00
CPC分类号： C07C11/06 , B01J8/082 , B01J8/085 , B01J8/12 , B01J2208/00274 , B01J2208/00283 , B01J2208/00292 , C07C1/20 , C07C2521/04 , C07C2529/40 , C07C2529/84 , C07C2529/85 , Y02P20/52
摘要： The average propylene cycle selectivity of an oxygenate to propylene (OTP) process using a dual-function oxygenate conversion catalyst is substantially enhanced by the use of a combination of: 1) moving bed reactor technology in the hydrocarbon synthesis portion of the OTP flow scheme in lieu of the fixed bed technology of the prior art; 2) a hydrothermally stabilized and dual-functional catalyst system comprising a molecular sieve having dual-function capability dispersed in a phosphorus-modified alumina matrix containing labile phosphorus and/or aluminum anions; and 3) a catalyst on-stream cycle time of 400 hours or less. These provisions stabilize the catalyst against hydrothermal deactivation and hold the build-up of coke deposits on the catalyst to a level which does not substantially degrade dual-function catalyst activity, oxygenate conversion and propylene selectivity, thereby enabling maintenance of average propylene cycle yield near or at essentially start-of-cycle levels.
摘要翻译：使用双功能含氧化合物转化催化剂的含氧化合物对丙烯（OTP）方法的平均丙烯循环选择性通过使用以下组合来显着增强：1）OTP流程图的烃合成部分中的移动床反应器技术现有技术的固定床技术的代替; 2）水热稳定和双功能催化剂体系，其包含具有分散在含有不稳定磷和/或铝阴离子的磷改性氧化铝基质中的双功能能力的分子筛; 和3）催化剂在流循环时间为400小时以下。这些规定稳定催化剂以防止水热失活，并将催化剂上焦炭沉积物的积聚保持在基本上不降低双功能催化剂活性，含氧化合物转化率和丙烯选择性的水平，从而使维持平均丙烯循环产率接近或基本上是循环周期的水平。

6. 发明授权

US07102044B1 Process for removal of oxygenates from a paraffin stream 有权
标题翻译：从石蜡流中除去含氧化合物的方法
公开(公告)号：US07102044B1
公开(公告)日：2006-09-05
申请号：US10882887
申请日：2004-06-30
申请人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
发明人： Santi Kulprathipanja , James W. Priegnitz , Stephen W. Sohn , Bryan K. Glover , Bipin V. Vora
IPC分类号： C07C2/64
CPC分类号： C07C5/333 , C07C2/66 , C07C7/12 , C07C7/13 , C07C15/107 , C07C9/14 , C07C11/02
摘要： The present invention comprises a process for removal of oxygenates from a paraffin-rich or olefin-rich paraffin stream which comprises passing a feed stream, comprising one or more C10 to C15 feed paraffins or C10 to C15 olefin-rich paraffin stream and one or more oxygenates through an adsorbent bed comprising one or more adsorbents selected from silica gel, activated alumina and sodium x zeolites to remove essentially all of said oxygenates; and recovering said paraffins. A second adsorbent bed may be employed to more thoroughly remove these oxygenates.
摘要翻译：本发明包括从富含链烷烃或富烯烃的石蜡流中除去含氧化合物的方法，该方法包括将含有一个或多个C 10的进料流通入C 15 通过吸附床将含有一种或多种选自硅胶，活性氧化铝和吸附剂的吸附剂的烷烃或C 10向富含C 15的富烯烃链烷烃流和一种或多种含氧化合物进料，钠x沸石以除去基本上所有的含氧化合物; 并回收所述石蜡。可以使用第二吸附剂床来更彻底地除去这些含氧化合物。

7. 发明申请

US20100240941A1 New Catalyst for Higher Production Rates in Hydrocarbon Dehydrogenation 失效
标题翻译：用于烃脱氢的更高生产率的新催化剂
公开(公告)号：US20100240941A1
公开(公告)日：2010-09-23
申请号：US12406522
申请日：2009-03-18
申请人： Mark G. Riley , Bipin V. Vora
发明人： Mark G. Riley , Bipin V. Vora
IPC分类号： C07C5/333
CPC分类号： C07C5/3335 , C10G2400/20 , C10G2400/22
摘要： A process is presented for the dehydrogenation of hydrocarbons in a radial flow reactor. The process includes the continuous feeding of catalyst into the reactor and the continuous withdrawal of catalyst from the reactor, where the catalyst is modified to increase the increased density. The catalyst is a layered structure with a dense core and an active catalytic outer layer.
摘要翻译：提出了一种用于在径向流动反应器中烃的脱氢的方法。该方法包括将催化剂连续进料到反应器中，以及催化剂从反应器中连续排出，其中催化剂被改性以增加密度。催化剂是具有致密核心和活性催化外层的层状结构。

8. 发明授权

US07268265B1 Apparatus and process for light olefin recovery 有权
标题翻译：轻烯烃回收的设备和工艺
公开(公告)号：US07268265B1
公开(公告)日：2007-09-11
申请号：US10882531
申请日：2004-06-30
申请人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
发明人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： C07C4/06 , C07C7/163 , C10G2400/20 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/02
摘要： The present invention relates to a process and apparatus for the production of light olefins comprising olefins having from 2 to 3 carbon atoms per molecule from a feedstock containing heavier olefins. An intermediate cut from a fractionation column is used as olefinic feed to an olefin cracking process preferably after undergoing selective hydrogenation of diolefins. In one embodiment, a liquid side draw from a fractionation column is selectively hydrogenated and then returned to the fractionation column from which a vapor side draw containing olefins is cracked in the olefin cracking reactor.
摘要翻译：本发明涉及一种用于生产轻质烯烃的方法和设备，其包含每分子含有2至3个碳原子的烯烃，其含有较重的烯烃的原料。来自分馏塔的中间馏分用作烯烃裂化方法的烯烃进料，优选在进行二烯烃的选择性氢化之后。在一个实施方案中，从分馏塔抽出的液体侧被选择性氢化，然后返回到在烯烃裂解反应器中含有烯烃的蒸汽侧馏分从其分馏的分馏塔。

9. 发明授权

US07189885B1 Staged process for producing linear 2-phenyl-alkanes 有权
标题翻译：生产线性2-苯基烷烃的分阶段方法
公开(公告)号：US07189885B1
公开(公告)日：2007-03-13
申请号：US10680683
申请日：2003-10-07
申请人： Andrea G. Bozzano , R. Joe Lawson , Paul T. Barger , Bipin V. Vora , Kurt A. Detrick
发明人： Andrea G. Bozzano , R. Joe Lawson , Paul T. Barger , Bipin V. Vora , Kurt A. Detrick
IPC分类号： C07C2/64 , C07C2/66
CPC分类号： C07C2/66 , B01J21/12 , B01J29/18 , B01J35/0006 , B01J37/26 , B01J2229/42 , C07C2/68 , C07C2521/12 , C07C2527/12 , C07C2529/18 , C07C15/107
摘要： The process disclosed herein is a process for producing phenyl-alkanes by alkylation of an aryl compound with an olefinic compound and which uses a mordenite catalyst and a silica-alumina catalyst. The selectivity of the process to 2-phenyl-alkanes can be varied over a wide range.
摘要翻译：本文公开的方法是通过用烯烃化合物烷基化芳基化合物并使用丝光沸石催化剂和二氧化硅 - 氧化铝催化剂来生产苯基烷烃的方法。该方法对2-苯基 - 烷烃的选择性可以在很宽的范围内变化。

10. 发明授权

US06156947A Process for the production of butene-1 from a mixture of C.sub.4 olefins 有权
标题翻译：从C4烯烃混合物生产丁烯-1的方法
公开(公告)号：US06156947A
公开(公告)日：2000-12-05
申请号：US340622
申请日：1999-06-28
申请人： Bipin V. Vora
发明人： Bipin V. Vora
IPC分类号： C07C11/08 , C07C41/06 , C07C41/42 , C07C1/00
CPC分类号： C07C11/08 , C07C41/06 , C07C41/42 , C07C2529/85 , Y02P20/127
摘要： A simplified process for jointly producing butene-1 and ether in a catalytic distillation column which comprises an upper catalytic zone for etherification and a lower catalytic zone for isomerization of C.sub.4 plus olefins and conversion of butadiene. The process is especially useful when combined with a process for the production of light olefins including ethylene and propylene from methanol. According to the invention, the produced butene-1 stream is combined with ethylene to produce polyethylene.
摘要翻译：在催化蒸馏塔中共同生产丁烯-1和醚的简化方法，其包括用于醚化的上部催化区和用于C4加烯烃异构化的较低催化区和丁二烯的转化。当与用于从甲醇生产包括乙烯和丙烯的轻质烯烃的方法组合时，该方法是特别有用的。根据本发明，将生产的丁烯-1流与乙烯混合以制备聚乙烯。

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