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1. 发明申请

US20090291031A1 Integrated Hydrocarbon Cracking and Product Olefin Cracking 有权
标题翻译：综合烃裂解和产品烯烃裂化
公开(公告)号：US20090291031A1
公开(公告)日：2009-11-26
申请号：US12512202
申请日：2009-07-30
申请人： Joseph E. Zimmermann , Charles P. Luebke , John B. Baker
发明人： Joseph E. Zimmermann , Charles P. Luebke , John B. Baker
IPC分类号： B01J8/18
CPC分类号： B01J8/18 , C10G35/14 , C10G47/00 , C10G51/04 , C10G2400/20
摘要： Processing scheme and arrangement for increasing the relative yield of light olefins involves integration of the cracking a heavy hydrocarbon feedstock to produce an effluent comprising a range of hydrocarbon products including C4-C7 olefins and the subsequent cracking at least a portion of the C4-C7 olefins to produce additional light olefins.
摘要翻译：用于提高轻质烯烃的相对产率的加工方案和布置涉及将重质烃原料开裂整合以产生包含一系列烃产物（包括C 4 -C 7烯烃）的流出物，随后开裂至少一部分C 4 -C 7烯烃以产生另外的轻质烯烃。

2. 发明授权

US07528290B2 Apparatuses and methods for separating butene-1 from a mixed C4 feed 有权
标题翻译：从混合C4进料中分离丁烯-1的装置和方法
公开(公告)号：US07528290B2
公开(公告)日：2009-05-05
申请号：US11617069
申请日：2006-12-28
申请人： Joseph E. Zimmermann , Dennis E. O'Brien
发明人： Joseph E. Zimmermann , Dennis E. O'Brien
IPC分类号： C07C7/00 , B01D3/14
CPC分类号： B01D3/32 , B01D1/007 , B01D3/14 , B01D3/141 , C07C7/04 , C07C11/08
摘要： A process is disclosed for recovering 1-butene from a feed steam comprising n-butane, isobutane and butene isomers using a single, divided wall distillation column. The disclosed process includes introducing the feed steam into an inlet of a first side of a distillation column, wherein the distillation column comprises a top, a bottom and a center dividing wall extending between the bottom and the top of the column and dividing the column into the first side and a second side. The process includes taking off an isobutane stream from the top of the second side of column, taking off a 1-butene stream as a bottoms stream from the second side of the column, and taking off a combination 2-butene and n-butane stream as a bottom stream from the first side of column.
摘要翻译：公开了一种用于使用单分隔壁蒸馏塔从包含正丁烷，异丁烷和丁烯异构体的进料蒸汽中回收1-丁烯的方法。所公开的方法包括将进料蒸汽引入蒸馏塔的第一侧的入口，其中蒸馏塔包括在塔的底部和顶部之间延伸的顶部，底部和中心分隔壁，并将塔分成第一面和第二面。该方法包括从塔的第二侧的顶部除去异丁烷料流，从塔的第二侧排出作为塔底物流的1-丁烯物流，并取出2-丁烯和正丁烷流的组合作为从塔的第一侧的底部流。

3. 发明申请

US20080161618A1 Apparatus and Methods for Separating Butene-1 from a Mixed C4 Feed 有权
标题翻译：从混合C4进料分离丁烯-1的装置和方法
公开(公告)号：US20080161618A1
公开(公告)日：2008-07-03
申请号：US11617069
申请日：2006-12-28
申请人： Joseph E. Zimmermann , Dennis E. O'Brien
发明人： Joseph E. Zimmermann , Dennis E. O'Brien
IPC分类号： C07C11/08 , B01D3/14
CPC分类号： B01D3/32 , B01D1/007 , B01D3/14 , B01D3/141 , C07C7/04 , C07C11/08
摘要： A process is disclosed for recovering 1-butene from a feed steam comprising n-butane, isobutane and butene isomers using a single, divided wall distillation column. The disclosed process includes introducing the feed steam into an inlet of a first side of a distillation column, wherein the distillation column comprises a top, a bottom and a center dividing wall extending between the bottom and the top of the column and dividing the column into the first side and a second side. The process includes taking off an isobutane stream from the top of the second side of column, taking off a 1-butene stream as a bottoms stream from the second side of the column, and taking off a combination 2-butene and n-butane stream as a bottom stream from the first side of column.
摘要翻译：公开了一种用于使用单分隔壁蒸馏塔从包含正丁烷，异丁烷和丁烯异构体的进料蒸汽中回收1-丁烯的方法。所公开的方法包括将进料蒸汽引入蒸馏塔的第一侧的入口，其中蒸馏塔包括在塔的底部和顶部之间延伸的顶部，底部和中心分隔壁，并将塔分成第一面和第二面。该方法包括从塔的第二侧的顶部除去异丁烷料流，从塔的第二侧排出作为塔底物流的1-丁烯物流，并取出2-丁烯和正丁烷流的组合作为从塔的第一侧的底部流。

4. 发明授权

US07268265B1 Apparatus and process for light olefin recovery 有权
标题翻译：轻烯烃回收的设备和工艺
公开(公告)号：US07268265B1
公开(公告)日：2007-09-11
申请号：US10882531
申请日：2004-06-30
申请人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
发明人： Douglas G. Stewart , Joseph E. Zimmermann , Angelo P. Furfaro , Bipin V. Vora
IPC分类号： C07C1/00 , C07C1/20
CPC分类号： C07C4/06 , C07C7/163 , C10G2400/20 , Y02P30/42 , C07C11/04 , C07C11/06 , C07C11/02
摘要： The present invention relates to a process and apparatus for the production of light olefins comprising olefins having from 2 to 3 carbon atoms per molecule from a feedstock containing heavier olefins. An intermediate cut from a fractionation column is used as olefinic feed to an olefin cracking process preferably after undergoing selective hydrogenation of diolefins. In one embodiment, a liquid side draw from a fractionation column is selectively hydrogenated and then returned to the fractionation column from which a vapor side draw containing olefins is cracked in the olefin cracking reactor.
摘要翻译：本发明涉及一种用于生产轻质烯烃的方法和设备，其包含每分子含有2至3个碳原子的烯烃，其含有较重的烯烃的原料。来自分馏塔的中间馏分用作烯烃裂化方法的烯烃进料，优选在进行二烯烃的选择性氢化之后。在一个实施方案中，从分馏塔抽出的液体侧被选择性氢化，然后返回到在烯烃裂解反应器中含有烯烃的蒸汽侧馏分从其分馏的分馏塔。

5. 发明授权

US06969496B2 Apparatus with increased yield and selectivity using side-by-side reaction zones 失效
标题翻译：使用并排反应区增加产率和选择性的装置
公开(公告)号：US06969496B2
公开(公告)日：2005-11-29
申请号：US10180832
申请日：2002-06-24
申请人： Michael J. Vetter , Paul R. Cottrell , Joseph E. Zimmermann
发明人： Michael J. Vetter , Paul R. Cottrell , Joseph E. Zimmermann
IPC分类号： C07C5/32 , B01J8/02 , C07C5/333
CPC分类号： C07C5/321
摘要： An apparatus provides for increased feed throughput without loss of conversion or selectivity by increasing the catalyst volume in a final reactor of at least three reaction zones. The catalyst volume of the final reactor may be larger because the inner and outer screens that define a radial flow bed are extended. A low LHSV is maintained by increasing the catalyst volume in the final reactor.
摘要翻译：一种装置通过增加至少三个反应区的最终反应器中的催化剂体积来提供增加的进料通量而不损失转化率或选择性。最终反应器的催化剂体积可能较大，因为限定径向流动床的内部和外部筛网延伸。通过增加最终反应器中的催化剂体积来维持低LHSV。

6. 发明授权

US06472577B1 Process for increasing the yield and selectivity of a dehydrogenation process using side-by-side reaction zones 失效
标题翻译：使用并排反应区提高脱氢工艺的产率和选择性的方法
公开(公告)号：US06472577B1
公开(公告)日：2002-10-29
申请号：US09458854
申请日：1999-12-10
申请人： Joseph E. Zimmermann , Paul R. Cottrell , Michael J. Vetter
发明人： Joseph E. Zimmermann , Paul R. Cottrell , Michael J. Vetter
IPC分类号： C07C5333
CPC分类号： C07C5/321
摘要： A method increases the feed throughput for a process of dehydrogenating light hydrocarbons without loss of conversion or selectivity by increasing the catalyst volume in only the final reactor of at least three reaction zones. The catalyst volume of the final reactor may be increased relative to the other reactors by extending the inner and outer screens that define a radial flow bed therein. Maintaining a low LHSV by increasing the catalyst volume in only the final reactor greatly reduces the expense of improving the capacity and yield of such a process. This method provides the most benefit to moving bed reactor systems since modifications are limited to the last reactor. A further benefit is derived from the simplified method of raising only a section of the last reactor to increase the catalyst volume.
摘要翻译：一种方法通过仅在至少三个反应区的最终反应器中增加催化剂体积来增加轻烃脱氢过程而不损失转化率或选择性的进料通量。最终反应器的催化剂体积可以相对于其它反应器通过在其中限定径向流动床的内部和外部筛网延伸来增加。通过仅在最终反应器中增加催化剂体积来维持低的LHSV大大降低了提高这种方法的能力和产率的费用。这种方法为移动床反应器系统提供了最大的益处，因为修改限于最后一个反应器。进一步的益处来自于仅提高最后一个反应器的一部分以增加催化剂体积的简化方法。

7. 发明授权

US5300696A C4 rejection for etherification and isomerization process 失效
标题翻译： C4排除醚化和异构化过程
公开(公告)号：US5300696A
公开(公告)日：1994-04-05
申请号：US998177
申请日：1992-12-29
申请人： Charles P. Luebke , Srikantiah Raghuram , Joseph E. Zimmermann
发明人： Charles P. Luebke , Srikantiah Raghuram , Joseph E. Zimmermann
IPC分类号： C07C41/06 , C07C5/22
CPC分类号： C07C41/06
摘要： A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses an adsorptive separation zone that receives an effluent fraction from the etherification reaction zone and separates the fraction at low efficiency to produce an isomerization feed stream comprising normal butenes and butanes, and a butane stream that is rejected from the process. The rejection of butanes at low efficiency reduces or eliminates the loss of butenes with the rejection of butane. A low efficiency adsorptive separation to reject butanes also benefits the isomerization process by inhibiting coking.
摘要翻译：醚化方法和将线性烯烃异构化为异烯烃的方法的组合使用吸附分离区，其接收来自醚化反应区的流出物部分并以低效率分离馏分以产生包含正丁烯和丁烷的异构化进料流，以及从流程中拒绝的丁烷流。以低效率排斥丁烷可以降低或消除丁烷的排斥与丁烷的排斥。抑制焦炭的低效吸附分离也有利于异构化过程。

8. 发明授权

US5283373A Etherification with skeletal olefin isomerization 失效
标题翻译：醚化与骨架烯烃异构化
公开(公告)号：US5283373A
公开(公告)日：1994-02-01
申请号：US997461
申请日：1992-12-28
申请人： Charles P. Luebke , Bipin V. Vora , David A. Wegerer , Joseph E. Zimmermann
发明人： Charles P. Luebke , Bipin V. Vora , David A. Wegerer , Joseph E. Zimmermann
IPC分类号： B01D3/00 , C07C41/06 , C07C41/42 , C07C5/22
CPC分类号： B01D3/009 , C07C41/06 , C07C41/42 , Y02P20/127
摘要： A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses a separation zone that receives an effluent stream from the etherification reaction zone and separates it into a high boiling stream, a low boiling stream and an intermediate boiling stream in order to reduce the mass flow of reactants through the isomerization and etherification reaction zones. The separation zone includes at least one distillation column. The distillation column can provide a distillation function only, or can also provide a reactive distillation zone. The intermediate boiling stream leaves a two column separation zone as a bottoms stream from a second column or in a single column separation zone as a sidecut which in the case of reactive distillation is taken from the point above a bed of catalyst within the column. Taking the sidecut stream substantially eliminates the circulation of isoalkane hydrocarbons through the etherification and isomerization zone and maintains normal alkanes at an acceptable equilibrium level. The effluent from the isomerization zone may enter the first in a series of etherification zones or may enter a second etherification zone having higher capacity.
摘要翻译：醚化方法和将线性烯烃异构化成异烯烃的方法的组合使用分离区，其接收来自醚化反应区的流出物流，并将其分离成高沸点流，低沸点流和中间沸腾流以减少反应物通过异构化和醚化反应区的质量流动。分离区包括至少一个蒸馏塔。蒸馏塔只能提供蒸馏功能，也可以提供反应蒸馏区。中间沸腾物流作为来自第二塔或单塔分离区的塔底物流离开两塔分离区，作为反应蒸馏的情况，其从塔内的催化剂床上方取出。采取旁路基本上消除了通过醚化和异构化区域的异烷烃的循环，并将正常烷烃保持在可接受的平衡水平。来自异构化区的流出物可以在一系列醚化区中进入第一个或者可以进入具有较高容量的第二醚化区。

9. 发明申请

US20100331589A1 INTEGRATED PROCESSES FOR PROPYLENE PRODUCTION AND RECOVERY 有权
标题翻译：用于丙烯生产和回收的综合方法
公开(公告)号：US20100331589A1
公开(公告)日：2010-12-30
申请号：US12493374
申请日：2009-06-29
申请人： Joseph E. ZIMMERMANN , Larry C. Erickson , Gregory J. Nedohin
发明人： Joseph E. ZIMMERMANN , Larry C. Erickson , Gregory J. Nedohin
IPC分类号： C07C5/333
CPC分类号： C07C7/04 , C07C5/05 , C07C5/09 , C07C5/333 , C07C5/3337 , C07C7/09 , C07C2521/04 , C07C2523/42 , C07C2523/755 , C07C2527/02 , C10G2400/20 , Y02P20/125 , C07C11/06
摘要： Processes utilizing the integration of (i) processes and the associated equipment used to purify and recover propylene from propane- and/or C4+-containing refinery hydrocarbon streams, with (ii) catalytic dehydrogenation are disclosed. This integration allows for elimination of some or all of the conventional fractionation section of the dehydrogenation process, normally used to purify propylene from unconverted propane in the reactor effluent. Significant capital and utility savings are therefore attained.
摘要翻译：公开了利用（i）工艺和用于从具有（ii）催化脱氢的丙烷和/或含C4 +的炼油厂烃流中纯化和回收丙烯的方法和相关设备的整合的方法。该整合允许消除通常用于在反应器流出物中从未转化的丙烷纯化丙烯的脱氢过程的一些或全部常规分馏部分。因此，实现了大量的资本和效用节省。

10. 发明申请

US20100158765A1 SCREENLESS INTERNALS FOR RADIAL FLOW REACTORS 有权
标题翻译：径流式反应器的无缝内部
公开(公告)号：US20100158765A1
公开(公告)日：2010-06-24
申请号：US12711278
申请日：2010-02-24
申请人： Bryan K. Glover , Guy B. Woodle , Joseph E. Zimmermann , John J. Senetar
发明人： Bryan K. Glover , Guy B. Woodle , Joseph E. Zimmermann , John J. Senetar
IPC分类号： B01J8/18 , B01J8/44 , B01D53/02
CPC分类号： B01J8/12 , B01J8/008 , B01J8/085
摘要： An apparatus for contacting a bed of particulate material with a cross flowing fluid, which maintains the bed of particulate material within a retention volume. The apparatus includes partitions for retaining particles, with apertures disposed within the partitions. The apertures are covered by louvers that extend above the edges of the apertures to prevent solid particles from spilling through inlet apertures.
摘要翻译：用于使颗粒材料床与交叉流动流体接触的装置，其将颗粒材料床保持在保持体积内。该装置包括用于保持颗粒的分隔物，孔中设置在隔板内。这些孔由在孔的边缘上方延伸的百叶窗覆盖以防止固体颗粒溢出入口孔。

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