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1. 发明授权

US09150465B2 Integration of cyclic dehydrogenation process with FCC for dehydrogenation of refinery paraffins 有权
标题翻译：循环脱氢工艺与FCC脱氢炼油石蜡的整合
公开(公告)号：US09150465B2
公开(公告)日：2015-10-06
申请号：US12886966
申请日：2010-09-21
申请人： Bryan K. Glover
发明人： Bryan K. Glover
IPC分类号： C07C4/06 , C07C2/56 , C07C5/333 , C07C6/04 , C10G11/18 , C10G57/00 , C10G70/00
CPC分类号： C07C4/06 , C07C2/56 , C07C5/3335 , C07C5/3337 , C07C6/04 , C07C2521/06 , C07C2523/26 , C07C2523/42 , C10G11/18 , C10G57/00 , C10G57/005 , C10G70/00 , C10G2400/20 , Y02P20/52 , C07C11/06 , C07C11/04
摘要： A process for increasing light olefin yields from the fluidized catalytic cracking process. The process combines small units to treat the paraffinic components in the product streams from the fluidized cracking process. The paraffins are dehydrogenated and light olefins are separated. Heavier olefins are passed to an olefin cracking unit for increasing the yields of ethylene and propylene.
摘要翻译：一种从流化催化裂化过程中提高轻质烯烃产率的方法。该方法结合了小单位来处理来自流化裂解过程的产物流中的链烷烃组分。链烷烃脱氢，轻质烯烃分离。较重的烯烃被传递到烯烃裂解装置以提高乙烯和丙烯的产率。

2. 发明授权

US08282886B2 Fluidized bed reactor with back-mixing for dehydrogenation of light paraffins 有权
标题翻译：具有反混合的流化床反应器用于轻链烷烃的脱氢
公开(公告)号：US08282886B2
公开(公告)日：2012-10-09
申请号：US13013399
申请日：2011-01-25
申请人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
发明人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
IPC分类号： B01J8/18 , F27B15/08
CPC分类号： C07C5/324 , C07C5/325 , C07C2521/04 , C07C2521/08 , C07C2521/16 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/745 , C07C2523/75 , C07C2523/755 , Y02P20/584 , C07C11/02
摘要： An improved process and system for the endothermic dehydrogenation of an alkane stream is described. The process and system for catalytic dehydrogenation comprise a back-mixed fluidized bed reactor. The alkane stream is dehydrogenated in a single reactor stage by contacting the alkane stream with a back-mixed fluidized bed of catalyst. Deactivated catalyst is withdrawn from the back-mixed fluidized reactor and heated to produce hot regenerated catalyst. The hot regenerated catalyst is returned to the back-mixed fluidized bed reactor at a rate sufficient to maintain the back-mixed fluidized bed reactor at substantially isothermal conditions.
摘要翻译：描述了用于烷烃流的吸热脱氢的改进方法和系统。用于催化脱氢的方法和系统包括反混流化床反应器。通过使烷烃流与催化剂的反混合流化床接触，在单个反应器阶段使烷烃流脱氢。将脱活催化剂从反混合流化反应器中取出并加热以产生热再生催化剂。热再生催化剂以足以将反混流化床反应器保持在基本等温条件的速率返回到反混流化床反应器。

3. 发明授权

US08052938B2 Aromatics co-production in a methanol-to-propylene unit 有权
公开(公告)号：US08052938B2
公开(公告)日：2011-11-08
申请号：US12902462
申请日：2010-10-12
申请人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
发明人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
IPC分类号： B01J8/00 , B01J8/02 , B01J35/02 , B01J19/00 , C07C2/00 , C07C2/42 , C07C6/00
CPC分类号： C07C2/66 , C07C1/24 , C07C2/864 , C07C6/126 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C15/08
摘要： The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.

4. 发明授权

US07951984B2 Aromatics co-production in a methanol-to-propylene unit 有权
标题翻译：在甲醇 - 丙烯单元中的芳烃共生产
公开(公告)号：US07951984B2
公开(公告)日：2011-05-31
申请号：US12902492
申请日：2010-10-12
申请人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
发明人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
IPC分类号： C07C2/66
CPC分类号： C07C2/66 , C07C1/24 , C07C2/864 , C07C6/126 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C15/08
摘要： The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.
摘要翻译：本发明提供了一种反应器系统，其具有：（1）第一反应器，其接收含氧化合物组分和烃组分，并且能够将含氧化合物组分转化为轻质烯烃并将烃组分转化为烷基芳族化合物; （2）用于提供含有C 3烯烃的第一产物流，含有C 7芳族化合物的第二料流和含有C 8芳族化合物的第三料流的分离器系统; （3）将分离器连接到第一反应器的入口的第一管线，用于将第二流输送到第一反应器; （4）与用于将C3烯烃输送到丙烯回收单元的分离器系统流体连通的第二管线，和（4）与分离器系统流体连通以将C8芳族化合物输送到二甲苯回收单元的第三管线。

5. 发明申请

US20110116978A1 Fluidized Bed Reactor with Back-Mixing for Dehydrogenation of Light Paraffins 有权
标题翻译：流化床反应器，用于轻质石蜡脱氢反向混合
公开(公告)号：US20110116978A1
公开(公告)日：2011-05-19
申请号：US13013399
申请日：2011-01-25
申请人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
发明人： Bryan K. Glover , Julie A. Zarraga , Michael A. Schultz
IPC分类号： B01J8/18
CPC分类号： C07C5/324 , C07C5/325 , C07C2521/04 , C07C2521/08 , C07C2521/16 , C07C2523/26 , C07C2523/28 , C07C2523/30 , C07C2523/36 , C07C2523/42 , C07C2523/44 , C07C2523/745 , C07C2523/75 , C07C2523/755 , Y02P20/584 , C07C11/02
摘要： An improved process and system for the endothermic dehydrogenation of an alkane stream is described. The process and system of the present invention comprise a back-mixed fluidized bed reactor. The alkane stream is dehydrogenated in a single reactor stage by contacting the alkane stream with a back-mixed fluidized bed of catalyst. Deactivated catalyst is withdrawn from the back-mixed fluidized reactor and heated to produce hot regenerated catalyst. The hot regenerated catalyst is returned to the back-mixed fluidized bed reactor at a rate sufficient to maintain the back-mixed fluidized bed reactor at substantially isothermal conditions.
摘要翻译：描述了用于烷烃流的吸热脱氢的改进方法和系统。本发明的方法和系统包括反混流化床反应器。通过使烷烃流与催化剂的反混合流化床接触，在单个反应器阶段使烷烃流脱氢。将脱活催化剂从反混合流化反应器中取出并加热以产生热再生催化剂。热再生催化剂以足以将反混流化床反应器保持在基本等温条件的速率返回到反混流化床反应器。

6. 发明授权

US07897829B2 Olefinic feedstock treatment processes 有权
标题翻译：烯烃原料处理工艺
公开(公告)号：US07897829B2
公开(公告)日：2011-03-01
申请号：US12785994
申请日：2010-05-24
申请人： Bryan K. Glover , Andrea G. Bozzano , Antoine Negiz
发明人： Bryan K. Glover , Andrea G. Bozzano , Antoine Negiz
IPC分类号： C07C7/12 , C07C7/13
CPC分类号： C07C15/107 , C07C2/66
摘要： Aromatic by-products are sorbed from mono-olefin-containing feedstocks of olefins having from about 6 to 22 carbon atoms per molecule that contain aromatic by-products having from 7 to 22 carbon atoms per molecule. A benzene-containing regenerant displaces and desorbs the aromatic by-products from the sorbent and a regeneration effluent is provided. The regeneration effluent is treated in a regeneration effluent distillation system to provide a benzene-rich stream and an aromatic by-products-containing stream. The latter is subjected to benzene-forming conditions and recycled to the regeneration effluent distillation system where benzene is recovered.
摘要翻译：芳族副产物被从每分子含有约6至22个碳原子的含单烯烃的原料中吸收，每分子含有7至22个碳原子的芳族副产物。含苯的再生剂从吸附剂中取代并解吸芳族副产物，并提供再生流出物。再生流出物在再生流出物蒸馏系统中处理以提供富含苯的流和含芳香族副产物的流。后者经受苯形成条件并再循环至回收苯的再生流出物蒸馏系统。

7. 发明授权

US07834227B2 Aromatics co-production in a methanol-to-propylene unit 有权
标题翻译：在甲醇 - 丙烯单元中的芳烃共生产
公开(公告)号：US07834227B2
公开(公告)日：2010-11-16
申请号：US11955610
申请日：2007-12-13
申请人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
发明人： Andrea G. Bozzano , Timur V. Voskoboynikov , Tom N. Kalnes , Paul T. Barger , Gavin P. Towler , Bryan K. Glover
IPC分类号： C07C6/12 , C07C2/64 , C07C2/66
CPC分类号： C07C2/66 , C07C1/24 , C07C2/864 , C07C6/126 , C07C2529/40 , Y02P20/52 , Y02P30/42 , C07C11/06 , C07C15/08
摘要： The present invention provides a reactor system having: (1) a first reactor receiving an oxygenate component and a hydrocarbon component and capable of converting the oxygenate component into a light olefin and the hydrocarbon component into alkyl aromatic compounds; (2) a separator system for providing a first product stream containing a C3 olefin, a second stream containing a C7 aromatic, and a third stream containing C8 aromatic compounds; (3) a first line connecting the separator to the inlet of the first reactor for conveying the second stream to the first reactor; (4) a second line in fluid communication with the separator system for conveying the C3 olefin to a propylene recovery unit, and (4) a third line in fluid communication with the separator system for conveying the C8 aromatic compounds to a xylene recovery unit.
摘要翻译：本发明提供了一种反应器系统，其具有：（1）第一反应器，其接收含氧化合物组分和烃组分，并且能够将含氧化合物组分转化为轻质烯烃并将烃组分转化为烷基芳族化合物; （2）用于提供含有C 3烯烃的第一产物流，含有C 7芳族化合物的第二料流和含有C 8芳族化合物的第三料流的分离器系统; （3）将分离器连接到第一反应器的入口的第一管线，用于将第二流输送到第一反应器; （4）与用于将C3烯烃输送到丙烯回收单元的分离器系统流体连通的第二管线，和（4）与分离器系统流体连通以将C8芳族化合物输送到二甲苯回收单元的第三管线。

8. 发明授权

US07732650B2 Oxygenate conversion to olefins with metathesis 有权
标题翻译：复合转化烯烃转化为烯烃
公开(公告)号：US07732650B2
公开(公告)日：2010-06-08
申请号：US12536820
申请日：2009-08-06
申请人： Andrea G. Bozzano , Bryan K. Glover
发明人： Andrea G. Bozzano , Bryan K. Glover
IPC分类号： C07C1/207 , C07C6/04
CPC分类号： C07C11/06 , C07C1/20 , C07C6/04 , Y02P30/42 , C07C11/02
摘要： A processing scheme and system for enhanced light olefin production, particularly for increased relative yield of propylene, involves oxygenate conversion to olefins and subsequent oxygenate conversion effluent stream treatment including cross-metathesis of 1-butene with 2-butene, metathesis of 2-butene with ethylene, conversion or removal of at least a portion of the isobutene, and/or isomerization of at least a portion of 1-butene to 2-butene to produce additional propylene. The processing scheme and system may further involve a reaction with distillation column for the metathesis of butenes with ethylene to produce propylene and/or a reaction with distillation column for the conversion of isobutenes with an oxygenate-containing material to produce a tertiary ether or alcohol.
摘要翻译：用于增强轻烯烃生产的加工方案和系统，特别是用于增加丙烯的相对产率，涉及含氧化合物转化为烯烃和随后的含氧化合物转化流出物流处理，包括1-丁烯与2-丁烯的交错复分解，2-丁烯的复分解乙烯，至少一部分异丁烯的转化或除去，和/或至少一部分1-丁烯异构化成2-丁烯以产生另外的丙烯。处理方案和系统可以进一步包括与用乙烯使乙烯复分解以产生丙烯和/或与蒸馏塔反应以使异丁烯与含氧化合物转化以产生叔醚或醇的反应。

9. 发明授权

US07722825B1 Preparing a light-olefin containing product stream from an oxygenate-containing feed stream using reactors directing a flow of a fluidized dual-function catalyst system 有权
标题翻译：使用引导流化双功能催化剂体系流的反应器从含氧化合物的进料流中制备含轻烯烃的产物流
公开(公告)号：US07722825B1
公开(公告)日：2010-05-25
申请号：US11461288
申请日：2006-07-31
申请人： Andrea G. Bozzano , Bryan K. Glover , Peter R. Pujado
发明人： Andrea G. Bozzano , Bryan K. Glover , Peter R. Pujado
IPC分类号： F27B15/00 , C07C1/00
CPC分类号： C07C11/06 , C07C1/20 , C07C4/06 , C07C2529/40 , C07C2529/85
摘要： The present invention provides a reactor system for converting an oxygenate-containing feed stream to an olefin-containing product stream. The system includes: (1) a first fluidized catalytic reactor for converting methanol to propylene, the first reactor having a fluidized catalyst system comprising a first catalyst and a second catalyst; (2) a second fluidized catalytic reactor communicating with the first fluidized catalytic reactor for cracking heavy olefins having four carbon atoms or greater into propylene, the second reactor having the fluidized catalyst system; (3) wherein the first catalyst is a non-zeolite molecular sieve catalyst; and (4) wherein the second catalyst is a zeolite molecular sieve catalyst.
摘要翻译：本发明提供了一种用于将含氧化合物的进料流转化为含烯烃的产物流的反应器系统。该系统包括：（1）用于将甲醇转化成丙烯的第一流化催化反应器，所述第一反应器具有包含第一催化剂和第二催化剂的流化催化剂体系; （2）与第一流化催化反应器连通的第二流化催化反应器，用于将具有四个或更多碳原子的重质烯烃裂解成丙烯，第二反应器具有流化催化剂体系; （3）其中第一催化剂是非沸石分子筛催化剂; 和（4）其中第二催化剂是沸石分子筛催化剂。

10. 发明申请

US20100021357A1 Integrated Oxygenate Conversion and Product Cracking 有权
公开(公告)号：US20100021357A1
公开(公告)日：2010-01-28
申请号：US12571841
申请日：2009-10-01
申请人： Tom N. Kalnes , Robert B. James, JR. , Daniel H. Wei , Bryan K. Glover
发明人： Tom N. Kalnes , Robert B. James, JR. , Daniel H. Wei , Bryan K. Glover
IPC分类号： B01J19/00
CPC分类号： C07C1/20 , C07C1/24 , C07C4/06 , C10G3/42 , C10G3/57 , C10G11/18 , C10G2400/20 , Y02P30/42 , Y02P30/48 , C07C11/02
摘要： Improved processing of an oxygenate-containing feedstock for increased production or yield of light olefins. Such processing involves oxygenate conversion to olefins and subsequent cracking of heavier olefins wherein at least a portion of the products from each of the reactors is elevated in pressure, using a common compressor, prior to being routed to a common product fractionation and recovery section. In one particular embodiment, the cracked product gas can be treated to remove acid gas therefrom. In another embodiment, the olefin cracking reactor is a moving bed reactor.

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