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1. 发明授权

US5714237A Partially crosslinked microspheres 失效
标题翻译：部分交联微球
公开(公告)号：US5714237A
公开(公告)日：1998-02-03
申请号：US585795
申请日：1996-01-16
申请人： Terrence E. Cooprider , Michael D. Crandall , James E. Garbe , Richard J. Goetz , Michael R. Kesti
发明人： Terrence E. Cooprider , Michael D. Crandall , James E. Garbe , Richard J. Goetz , Michael R. Kesti
IPC分类号： C08F2/44 , C08F8/00 , C08F20/10 , C08F20/18 , C09J121/00 , C09J133/06 , C09J201/00 , B32B3/00
CPC分类号： C09J133/06 , C08F20/18 , C08L2205/18 , Y10T428/24893
摘要： An adhesive composition is provided comprising: (a) a plurality of polymeric, elastomeric microspheres wherein the microspheres are the reaction product of reactants comprising polymerizable starting materials comprising at least one C.sub.4 -C.sub.14 alkyl (meth)acrylate monomer and optionally at least one comonomer and have a solvent soluble portion that is 30-98% of the microsphere.
摘要翻译：提供了一种粘合剂组合物，其包括：（a）多个聚合弹性体微球，其中所述微球是包含可聚合起始材料的反应物的反应产物，其包含至少一种（甲基）丙烯酸烷基酯单体和任选的至少一种共聚单体，具有溶剂可溶部分，为微球的30-98％。

2. 再颁专利

USRE37563E1 Partially crosslinked microspheres 有权
标题翻译：部分交联微球
公开(公告)号：USRE37563E1
公开(公告)日：2002-02-26
申请号：US09443254
申请日：1999-11-18
申请人： Terrence E. Cooprider , Michael D. Crandall , James E. Garbe , Richard J. Goetz , Michael R. Kesti
发明人： Terrence E. Cooprider , Michael D. Crandall , James E. Garbe , Richard J. Goetz , Michael R. Kesti
IPC分类号： B32B300
CPC分类号： C09J133/06 , C08F20/18 , C08L2205/18 , Y10T428/24893
摘要： An adhesive composition is provided comprising: (a) a plurality of polymeric, elastomeric microspheres wherein the microspheres are the reaction product of reactants comprising polymerizable starting materials comprising at least one C4-C14 alkyl (meth)acrylate monomer and optionally at least one comonomer and have a solvent soluble portion that is 30-98% of the microsphere.
摘要翻译：提供了一种粘合剂组合物，其包括：（a）多个聚合弹性体微球，其中所述微球是包含可聚合起始材料的反应物的反应产物，其包含至少一种（甲基）丙烯酸烷基酯单体和任选的至少一种共聚单体，具有溶剂可溶部分，为微球的30-98％。

3. 发明授权

US06905763B2 Microsphere adhesive coated article for use with coated papers 有权
标题翻译：用于涂布纸的微球粘合剂涂层制品
公开(公告)号：US06905763B2
公开(公告)日：2005-06-14
申请号：US09891014
申请日：2001-06-25
申请人： Michael D. Crandall , Terrence E. Cooprider
发明人： Michael D. Crandall , Terrence E. Cooprider
IPC分类号： B42D5/00 , C09J7/02 , C09J9/00 , C09J133/06 , C09J133/14 , C09J133/26 , B32B7/12
CPC分类号： C09J133/14 , C08L2205/18 , C08L2666/04 , C08L2666/06 , C09J7/385 , C09J133/06 , C09J133/064 , C09J133/26 , C09J2205/11 , C09J2400/283 , C09J2433/00 , Y10T428/28 , Y10T428/2861 , Y10T428/2887 , Y10T428/2891 , Y10T428/2982 , Y10T428/2985 , Y10T442/2754
摘要： An adhesive coated article comprises a layer of microsphere adhesive onto a portion of at least one major surface of a substrate. The microspheres in the adhesive are obtained as the reaction product of (a) at least one alkyl (meth)acrylate ester wherein the alkyl group contains four to about 14 carbon atoms, preferably four to about 10 carbon atoms and (b) a comonomer(s). The comonomer may be a nonpolar, ionic, polar comonomer or mixtures of such monomers. This microsphere adhesive either contains a (meth)acrylamide comonomer or a polyacrylamide material is post-added to the microsphere adhesive. The adhesive exhibits a lower than expected adhesion to coated papers without sacrificing the adhesion to standard uncoated (bond) papers and preferably, the 90° peel adhesion, as measured on Kromkote® paper (used as an industry standard) is in the range of 20 to 250 grams/inch.
摘要翻译：粘合剂涂覆的制品包括在基材的至少一个主表面的一部分上的微球粘合剂层。获得粘合剂中的微球作为（a）至少一种（甲基）丙烯酸烷基酯（其中烷基含有4至约14个碳原子，优选4至约10个碳原子）的反应产物和（b）共聚单体（ s）。共聚单体可以是非极性的，离子的，极性的共聚单体或这些单体的混合物。该微球粘合剂含有（甲基）丙烯酰胺共聚单体，或将聚丙烯酰胺材料后添加到微球粘合剂中。粘合剂对涂布纸的粘附性低于预期的粘合性，而不牺牲与标准的未涂布（粘合）纸的粘合性，并且优选地，在Kromkote纸（用作工业标准）上测量的90°剥离粘合力在该范围内为20至250克/英寸。

4. 发明授权

US06296932B1 Microsphere adhesive coated article for use with coated papers 有权
标题翻译：用于涂布纸的微球粘合剂涂层制品
公开(公告)号：US06296932B1
公开(公告)日：2001-10-02
申请号：US09211157
申请日：1998-12-14
申请人： Michael D. Crandall , Terrence E. Cooprider
发明人： Michael D. Crandall , Terrence E. Cooprider
IPC分类号： C09J702
CPC分类号： C09J133/14 , C08L2205/18 , C08L2666/04 , C08L2666/06 , C09J7/385 , C09J133/06 , C09J133/064 , C09J133/26 , C09J2205/11 , C09J2400/283 , C09J2433/00 , Y10T428/28 , Y10T428/2861 , Y10T428/2887 , Y10T428/2891 , Y10T428/2982 , Y10T428/2985 , Y10T442/2754
摘要： An adhesive coated article comprises a layer of microsphere adhesive onto a portion of at least one major surface of a substrate. The microspheres in the adhesive are obtained as the reaction product of (a) at least one alkyl (meth)acrylate ester wherein the alkyl group contains four to about 14 carbon atoms, preferably four to about 10 carbon atoms and (b) a comonomer(s). The comonomer may be a nonpolar, ionic, polar comonomer or mixtures of such monomers. This microsphere adhesive either contains a (meth)acrylamide comonomer or a polyacrylamide material is post-added to the microsphere adhesive. The adhesive exhibits a lower than expected adhesion to coated papers without sacrificing the adhesion to standard uncoated (bond) papers and preferably, the 90° peel adhesion, as measured on Kromkote® paper (used as an industry standard) is in the range of 20 to 250 grams/inch.
摘要翻译：粘合剂涂覆的制品包括在基材的至少一个主表面的一部分上的微球粘合剂层。获得粘合剂中的微球作为（a）至少一种（甲基）丙烯酸烷基酯（其中烷基含有4至约14个碳原子，优选4至约10个碳原子）的反应产物和（b）共聚单体（ s）。共聚单体可以是非极性的，离子的，极性的共聚单体或这些单体的混合物。该微球粘合剂含有（甲基）丙烯酰胺共聚单体，或将聚丙烯酰胺材料后添加到微球粘合剂中。粘合剂对涂布纸的粘附性低于预期的粘合性，而不牺牲与标准的未涂布（粘合）纸的粘合性，优选地，在Kromkote纸（用作工业标准）上测量的90°剥离粘合力在该范围内为20至250克/英寸。

5. 发明授权

US5461125A Waterborne core-shell latex polymers 失效
标题翻译：水性核 - 壳胶乳聚合物
公开(公告)号：US5461125A
公开(公告)日：1995-10-24
申请号：US56380
申请日：1993-04-30
申请人： Ying-Yuh Lu , Chi-Ming Tseng , James E. Bunker , Terrence E. Cooprider , Ronald W. Most , Gregory J. Stanich
发明人： Ying-Yuh Lu , Chi-Ming Tseng , James E. Bunker , Terrence E. Cooprider , Ronald W. Most , Gregory J. Stanich
IPC分类号： C08F265/00 , C08F265/04 , C08F265/06 , C09D151/00
CPC分类号： C09D151/003 , C08F265/04 , C08F265/06 , Y10S525/902
摘要： The present invention provides:A core-shell insert latex composition comprising latex particles, each latex particle comprising:(a) a core comprising a (co)polymer comprising (meth)acrylate ester;(b) a shell, surrounding the core, comprising a copolymer, wherein the copolymer comprises:(i) a nitrogen-bearing ethylenically-unsaturated free-radically polymerizable monomer;(ii) at least one (meth)acrylate ester of about a C.sub.1 to about a C.sub.14 alcohol; and(iii) an optional ethylenically-unsaturated free-radically polymerizable silane monomer; wherein the nitrogen-bearing ethylenically-unsaturated free-radically polymerizable monomer comprises from about 15 to about 60 percent by weight of the shell and further wherein the core comprises from about 40 to about 85 percent of the weight of the total core-shell latex particle.The invention also relates to the use of the core-shell latex composition as a binder or primer for coatings and adhesives.
摘要翻译：本发明提供：包含胶乳颗粒的核 - 壳嵌入胶乳组合物，每个胶乳颗粒包含：（a）包含（（甲基）丙烯酸酯的（共））聚合物的芯; （b）围绕所述芯的壳，包含共聚物，其中所述共聚物包含：（i）含氮烯键式不饱和可自由基聚合单体; （ii）至少一种约C1至约C14醇的（甲基）丙烯酸酯; 和（iii）任选的烯键式不饱和可自由基聚合的硅烷单体; 其中所述含氮烯属不饱和可自由基聚合单体占所述壳的约15至约60重量％，并且其中所述核包含总核 - 壳胶乳颗粒重量的约40至约85重量％。本发明还涉及核 - 壳胶乳组合物作为涂料和粘合剂的粘合剂或底漆的用途。

6. 发明授权

US07625605B2 Method for coating a surface with a pattern of coating fluid 有权
标题翻译：用涂布液图案涂覆表面的方法
公开(公告)号：US07625605B2
公开(公告)日：2009-12-01
申请号：US11027542
申请日：2004-12-30
申请人： Terrence E. Cooprider , Laura M. Rider , Ronald W. Most
发明人： Terrence E. Cooprider , Laura M. Rider , Ronald W. Most
IPC分类号： B05D1/28
CPC分类号： B05C1/0839 , B05C1/0817 , B05C1/0834 , B05C1/165 , B05D1/28 , B05D5/06 , B05D2252/02 , D21H19/68 , D21H21/54 , D21H23/58
摘要： A method of defining a pattern of coating fluid on a surface includes introducing coating fluid containing microspheres onto a surface of an applicator roll, wherein the topography of the applicator roll surface comprises at least one longitudinally extending circumferential, helical groove portion which is sized to at least partially receive the microspheres of the coating fluid therein, and at least one circumferential, longitudinally extending smooth surface portion. The method further includes engaging the applicator roll surface with a doctor blade to remove coating fluid from the smooth surface portions thereof and to limit the amount of microspheres advanced past the doctor blade by the helical groove portion of the applicator roll surface. Thus, a pattern of coating fluid containing microspheres remains on the applicator roll surface which is defined by the helical groove portion thereon and is formed to define at least one stripe of coating fluid containing microspheres. The pattern of coating fluid is transferred from the applicator roll surface to a moving web by a reverse kiss coating.
摘要翻译：在表面上限定涂布液体的图案的方法包括将包含微球体的涂布流体引入涂布辊的表面上，其中涂布辊表面的形貌包括至少一个纵向延伸的周向螺旋槽部分，其尺寸设定为在其中最少部分地接收涂覆流体的微球体，以及至少一个圆周的，纵向延伸的光滑表面部分。该方法还包括使涂布辊表面与刮刀接合以从其平滑表面部分去除涂布流体，并且通过施加器辊表面的螺旋槽部分限制微球超过刮刀的量。因此，包含微球的涂布液的图案保留在由其上的螺旋槽部分限定的涂布辊表面上，并且形成为限定至少一条含有微球体的涂布液条纹。涂布液的图案通过反向接触涂层从涂布辊表面转移到移动的网。

7. 发明授权

US07655296B2 Ink-receptive foam article 失效
标题翻译：吸墨泡沫制品
公开(公告)号：US07655296B2
公开(公告)日：2010-02-02
申请号：US11460436
申请日：2006-07-27
申请人： Christopher K. Haas , Robert D. Taylor , William B. Black , James M. Jonza , Terrence E. Cooprider
发明人： Christopher K. Haas , Robert D. Taylor , William B. Black , James M. Jonza , Terrence E. Cooprider
IPC分类号： B32B27/00
CPC分类号： B32B27/16 , B32B5/18 , B32B27/065 , B32B27/306 , B32B27/308 , B32B27/40 , B32B27/42 , B32B2255/102 , B32B2255/26 , B32B2266/025 , B32B2274/00 , B32B2307/518 , B32B2307/538 , B32B2307/726 , B32B2307/75 , B32B2554/00 , B41M3/14 , B41M5/0047 , B41M5/5254 , Y10T428/24273 , Y10T428/24802 , Y10T428/249977 , Y10T428/249981 , Y10T428/249986 , Y10T428/249991 , Y10T428/249992
摘要： The present invention is directed an oriented, foamed article having an ink-receptive surface, and a method of making the article. The invention provides a printable substrate comprising at least one high melt-strength, oriented polypropylene foam layer having an ink-receptive surface. The high melt-strength polypropylene having a melt strength of 25 to 60 cN at 190° C. The ink-receptive surface may comprise and oxidizing treatment, such as corona or flame-treatment of the foam surface, or may comprise an ink-receptive coating, such as a primer coating, on the foam surface.The oriented foam article is particularly useful in the preparation of printed security documents such as currency, stock and bond certificates, birth and death certificates, land titles and abstracts and the like.
摘要翻译：本发明涉及一种具有吸墨表面的定向发泡制品，以及制造该制品的方法。本发明提供了一种可印刷基材，其包括至少一个具有油墨接受表面的高熔体强度取向的聚丙烯泡沫层。 190℃时熔体强度为25至60cN的高熔体强度聚丙烯。油墨接受表面可包括氧化处理，例如泡沫表面的电晕或火焰处理，或可包含油墨接收涂层，如底漆涂层，在泡沫表面上。定向泡沫制品在编制印刷安全文件如货币，股票和债券，出生和死亡证明，土地所有权和摘要等方面特别有用。

8. 发明授权

US5571617A Pressure sensitive adhesive comprising tacky surface active microspheres 失效
标题翻译：包含粘性表面活性微球的压敏粘合剂
公开(公告)号：US5571617A
公开(公告)日：1996-11-05
申请号：US270179
申请日：1994-07-01
申请人： Terrence E. Cooprider , Dale O. Bailey , Ronald W. Most
发明人： Terrence E. Cooprider , Dale O. Bailey , Ronald W. Most
IPC分类号： C08F265/04 , C08L33/06 , C09J7/02 , C09J11/00 , C09J133/00 , C09J133/06 , C09J133/14 , C09J133/26 , B32B7/12 , B32B27/30
CPC分类号： C09J7/0217 , C08F265/04 , C08L33/06 , Y10T428/1405 , Y10T428/1462 , Y10T428/254 , Y10T428/273 , Y10T428/28 , Y10T428/2848 , Y10T428/2861
摘要： A coated sheet material comprising a backing and a coating of repositionable pressure-sensitive adhesive comprising a plurality of solid microspheres, a polymeric stabilizer and an surfactant. Processes for preparing solid microspheres are also disclosed.
摘要翻译：一种涂覆片材，其包括背衬和可重新定位的压敏粘合剂涂层，其包含多个固体微球，聚合物稳定剂和表面活性剂。还公开了制备固体微球的方法。

9. 发明授权

US5871585A Apparatus for applying a fluid to a moving web of material 失效
标题翻译：用于将流体施加到移动的材料网的装置
公开(公告)号：US5871585A
公开(公告)日：1999-02-16
申请号：US619043
申请日：1996-03-20
申请人： Ronald W. Most , Terrence E. Cooprider
发明人： Ronald W. Most , Terrence E. Cooprider
IPC分类号： B05B9/06 , B05C5/02 , B05C9/06 , B05C3/02
CPC分类号： B05C5/0254 , B05B9/06 , B05C5/027 , Y10S118/18
摘要： An apparatus that comprises a body including a reservoir adapted for receiving a quantity of fluid and a plurality of fluid distribution channels each having a length and a cross-sectional area and being in fluid communication with and extending from the reservoir from a first end and terminating at a second, distal end in an orifice. The apparatus further comprises a distribution chamber in the body for commonly receiving the fluid exiting each of the orifices, for merging the fluid exiting each of the orifices into at least one continuous coating stream, and for equalizing the pressure of the fluid, the distribution chamber having a first side in fluid communication with the plurality of fluid distribution channels and a second side that is open to allow the fluid to exit the body for uniform distribution onto the web. In addition, the apparatus comprises a smoothing surface on the body adjacent the second side of the distribution chamber to smooth the fluid on the moving web as the fluid exits the second side of the distribution chamber and is deposited on the moving web and a fluid supply means for supplying fluid to the reservoir and for maintaining the fluid under pressure in the reservoir, whereby the fluid moves under pressure from the reservoir through the fluid distribution channels to the first side of the distribution chamber, through the distribution chamber to exit the second side of the distribution chamber, and onto the moving web.
摘要翻译：一种装置，其包括主体，其包括适于接收一定量的流体的储存器和多个流体分配通道，每个流体分配通道具有长度和横截面积，并且与第一端部从储存器流体连通并从储存器延伸并终止在孔的第二远端。该装置还包括在主体中的分配室，用于共同地接收离开每个孔的流体，用于将离开每个孔的流体合并成至少一个连续的涂覆流，并且为了均衡流体的压力，分配室具有与所述多个流体分配通道流体连通的第一侧和敞开的第二侧，以允许流体离开所述主体以均匀分布到所述幅材上。此外，该装置包括在分配室的第二侧附近的主体上的平滑表面，以便当流体离开分配室的第二侧时平滑移动的幅材上的流体并沉积在移动的幅材上，并且流体供给用于将流体供应到储存器并用于将流体保持在储存器内的压力下的装置，由此流体在压力下从储存器通过流体分配通道移动到分配室的第一侧，通过分配室离开第二侧的分配室，并且移动到移动的网上。

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