会员体验
专利管家(专利管理)
工作空间(专利管理)
风险监控(情报监控)
数据分析(专利分析)
侵权分析(诉讼无效)
联系我们
交流群
官方交流:
QQ群: 891211   
微信请扫码    >>>
现在联系顾问~
热词
    • 3. 发明授权
    • Silver halide photographic emulsion
    • 卤化银照相乳剂
    • US4040841A
    • 1977-08-09
    • US602508
    • 1975-08-06
    • Masanao HinataHaruo TakeiAkira SatoTadashi IkedaAtsuo Iwamoto
    • Masanao HinataHaruo TakeiAkira SatoTadashi IkedaAtsuo Iwamoto
    • G03C1/28G03C1/29G03C1/14
    • G03C1/29
    • A silver halide photographic emulsion spectrally sensitized in the relatively shorter wavelength region ranging from blue to green with a supersensitizing combination of at least one sensitizing dye represented by the general formula (I) ##STR1## WHEREIN Z.sup.1 represents the atoms necessary to form a benzimidazole ring, an oxazole ring, a benzoxazole ring or a naphthoxazole ring; Z.sup.2 represents the atoms necessary to form a thiazole ring, a benzothiazole ring, a naphthothiazole ring, a selenazole ring, a benzoselenazole ring or a naphthoselenazole ring; R.sup.1 and R.sup.2 each represents an aliphatic group containing up to 8 carbon atoms, which may be unsubstituted or substituted, and the carbon chain of which may be interrupted with an oxygen atom or a sulfur atom; R.sup.3 represents an alkyl group containing up to 3 carbon atoms, an aryl group or an aralkyl group; X.sup.1 represents an acid anion; and m represents 1 or 2, wherein m equals 1 when the dye forms an intramolecular salt; and at least one dye selected from the group consisting of a simple merocyanine and a dimethinemerocyanine dye, or with a supersensitizing combination of at least one sensitizing dye represented by the general formula (I) as defined above and at least one sensitizing dye represented by the general formula (II) ##STR2## wherein Z.sup.3 represents the atoms necessary to form a 5- or 6-membered heterocyclic ring; Q represents the atoms necessary to form a rhodanine ring, a thiohydantoin ring or a 2-thioxazolidinedione ring; R.sup.4 represents an aliphatic group containing up to 4 carbon atoms, which may be unsubstituted or substituted and the carbon chain of which may be interrupted by an oxygen atom or a sulfur atom; R.sup.5 represents a hydrogen atom, an alkyl group, an aryl group or an aralkyl group; and n represents 1 or 2.
    • 在由蓝色到绿色的相对短的波长区域中进行光谱增感的卤化银照相乳剂,其具有由通式(I)(I)表示的至少一种敏化染料的超敏化组合,其中Z1表示形成所需的原子 苯并咪唑环,恶唑环,苯并恶唑环或萘并恶唑环; Z2表示形成噻唑环所需的原子,苯并噻唑环,萘并噻唑环,硒咯环,苯并硒唑环或萘并吩唑环。 R1和R2各自表示含有至多8个碳原子的脂族基团,其可以是未取代的或取代的,并且其碳链可以被氧原子或硫原子间隔; R3表示含有至多3个碳原子的烷基,芳基或芳烷基; X1表示酸性阴离子; m表示1或2,当染料形成分子内盐时,m等于1; 和至少一种选自简单的部花菁和二甲基异亮氨酸染料的染料,或与如上定义的由通式(I)表示的至少一种敏化染料的超敏化组合和至少一种由 通式(II)(II)其中Z 3表示形成5-或6-元杂环所必需的原子; Q表示形成绕丹宁环所需的原子,硫代乙内酰脲环或2-噻恶唑烷二酮环; R4表示含有至多4个碳原子的脂族基团,其可以是未取代的或取代的,并且其碳链可被氧原子或硫原子间隔; R5表示氢原子,烷基,芳基或芳烷基; n表示1或2。
    • 5. 发明授权
    • Spectrally sensitized silver halide photographic emulsion
    • 光谱增感卤化银照相乳剂
    • US4010037A
    • 1977-03-01
    • US653995
    • 1976-01-28
    • Masanao HinataHaruo TakeiTadashi IkedaMitsuo Iwamoto
    • Masanao HinataHaruo TakeiTadashi IkedaMitsuo Iwamoto
    • G03C1/29G03C1/14
    • G03C1/29
    • A silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye of the following general formula (I) ##STR1## wherein Z.sub.1 and Z.sub.2 each represents an atomic group required for forming a benzimidazole ring; R.sub.1 and R.sub.2 each represents an aliphatic group and at least one of R.sub.1 and R.sub.2 represents an alkyl group having a carboxy group, a hydroxyalkyl group or an alkyl group having a sulfo group; X.sub.1 represents an acid anion; and m is 1 or 2, m being 1 when the dye forms an inner salt (a betaine-like structure) and at least one sensitizing dye of the following general formula (II) ##STR2## wherein Z.sub.3 represents an atomic group required for forming a benzoxazole ring or a .beta.-naphthoxazole ring; Z.sub.4 represents an atomic group required for forming a benzothiazole ring, a benzoselenazole ring, a .beta.-naphthothiazole ring or a .beta.-naphthoselenazole ring; R.sub.3 and R.sub.4 each represents an aliphatic group and at least one of R.sub.3 and R.sub.4 represents an alkyl group having a carboxy group or an alkyl group having a sulfo group; R.sub.5 represents a hydrogen atom or an alkyl group; X.sub.2 represents an acid anion; and n is 1 or 2, n being 1 when the dye forms an inner salt.
    • 一种卤化银照相乳剂,其组合含有至少一种以下通式(I)的敏化染料的超敏化剂,其中Z1和Z2各自表示形成苯并咪唑环所需的原子团; R 1和R 2各自表示脂族基,R 1和R 2中的至少一个表示具有羧基,羟基烷基或具有磺基的烷基的烷基; X1表示酸性阴离子; m为1或2,当染料形成内盐(甜菜碱样结构)时,m为1,以及至少一种以下通式(II)的增感染料,其中Z 3表示原子团 形成苯并恶唑环或β-萘恶唑环所需的; Z4表示形成苯并噻唑环,苯并硒唑环,β-萘噻唑环或β-萘并噻唑环所需的原子团; R 3和R 4各自表示脂族基,R 3和R 4中的至少一个表示具有羧基或具有磺基的烷基的烷基; R5表示氢原子或烷基; X2表示酸性阴离子; n为1或2,当染料形成内盐时,n为1。
    • 9. 发明授权
    • Silver halide photographic emulsion containing cyanine and hemicyanine
sensitizing dyes
    • 含有花青和半花青素敏化染料的卤化银照相乳剂
    • US4152163A
    • 1979-05-01
    • US777229
    • 1977-03-14
    • Akira SatoTadashi IkedaTakeo SakaiHaruo TakeiJun Hayashi
    • Akira SatoTadashi IkedaTakeo SakaiHaruo TakeiJun Hayashi
    • G03C1/28G03C1/14G03C1/19
    • G03C1/28
    • A spectrally sensitized silver halide photographic emulsion comprising a silver halide emulsion containing a combination of at least one sensitizing dye represented by the following general formula (I): ##STR1## at least one sensitizing dye represented by the following general formula (II): ##STR2## and at least one organic heterocyclic compound represented by the following general formula (III) or (IV): ##STR3## wherein Z.sup.1 and Z.sup.2, which may be the same or different, each represents a group of atoms necessary for forming a thiazole nucleus or a selenazole nucleus; Z.sup.3 has the same meaning as Z.sup.1 and Z.sup.2 ; Z.sup.4 represents a group of atoms necessary for forming an imidazole nucleus or an oxazole nucleus; Z.sup.5 represents a group of atoms necessary for forming an imidazole nucleus; R.sup.1, R.sup.2, R.sup.4, R.sup.5 and R.sup.7, which may be the same or different, each represents an alkyl group, with at least one of R.sup.1, R.sup.2, R.sup.4 and R.sup.5 being an alkyl group substituted with a carboxy group, a hydroxy group or a sulfo group; R.sup.3 and R.sup.6, which may be the same or different, each represents a lower alkyl group, an aryl group or a hydrogen atom; R.sup.8 represents a hydrogen atom or an alkylene group necessary for forming a ring through a combination with R.sup.7 ; R.sup.9 represents an aryl group (including a monocyclic aryl group and a bicyclic aryl group); X.sub.1.sup.-, X.sub.2.sup.- and X.sub.3.sup.- each represents an acid anion; m, n and p each represents 1 or 2, but when m, n or p is 1, the dye forms an intramolecular salt.The photographic emulsion exhibits a high sensitivity with a reduced fog and stain, and a good stability with the lapse of time during and after production, and further an improved latent image stability with the lapse of time of from image-wise exposure to development.
    • 包含含有由以下通式(I)表示的至少一种敏化染料的组合的卤化银乳剂的光谱增感卤化银照相乳剂:(I)至少一种由以下通式(II)表示的增感染料 )(II)和由以下通式(III)或(IV)表示的至少一种有机杂环化合物:其中Z 1和Z 2可以是 相同或不同,每个表示形成噻唑核或硒唑核所需的一组原子; Z3与Z1和Z2具有相同的含义; Z4表示形成咪唑核或恶唑核所需的一组原子; Z5表示形成咪唑核所需的一组原子; R 1,R 2,R 4,R 5和R 7可以相同或不同,各自表示烷基,R 1,R 2,R 4和R 5中的至少一个为被羧基,羟基或 磺基; R 3和R 6可以相同或不同,各自表示低级烷基,芳基或氢原子; R8表示通过与R 7的组合形成环所需的氢原子或亚烷基; R9表示芳基(包括单环芳基和双环芳基); X 1,X 2和X 3各自表示酸性阴离子; m,n和p各自表示1或2,但当m,n或p为1时,染料形成分子内盐。
    • 10. 发明授权
    • Supersensitized silver halide photographic emulsion
    • US4018610A
    • 1977-04-19
    • US599517
    • 1975-07-28
    • Masanao HinataHaruo TakeiAkira SatoTadashi Ikeda
    • Masanao HinataHaruo TakeiAkira SatoTadashi Ikeda
    • G03C1/28G03C1/29G03C1/14
    • G03C1/29Y10S430/15
    • A spectrally sensitized silver halide photographic emulsion containing, in combination, supersensitizing amounts of at least one sensitizing dye represented by the following general formula (I): ##STR1## wherein Z.sup.1 and Z.sup.2 each represents an atomic group necessary for completing a benzimidazole nucleus, an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus or a naphthoselenazole nucleus excepting that both of Z.sup.1 and Z.sup.2 do not simultaneously represent an atomic group necessary for completing an oxazole nucleus, a benzoxazole nucleus or a naphthoxazole nucleus; R.sup.1 and R.sup.2 each represents an aliphatic group which may be substituted and the carbon chain of which may be interrupted with an oxygen atom or a sulfur atom; R.sup.0 represents a hydrogen atom, an alkyl group or an aralkyl group; X.sub.(1).sup.- represents an anion; and m is 1 or 2, with m being 1 when the dye forms an intramolecular salt; and at least one sensitizing dye represented by the following general formula (II): ##STR2## wherein Z.sup.3 and Z.sup.4 each represents an atomic group necessary for completing a pyrroline nucleus, a pyridine nucleus, an indolenine nucleus, a benzimidazole nucleus, an oxazole nucleus, a benzoxazole nucleus, a naphthoxazole nucleus, a thiazoline nucleus, a thiazole nucleus, a benzothiazole nucleus, a naphthothiazole nucleus, a selenazole nucleus, a benzoselenazole nucleus, or a naphthoselenazole nucleus; R.sup.3 and R.sup.4 each represents an aliphatic group which may be substituted and the carbon chain of which may be interrupted with an oxygen atom or a sulfur atom, and at least one of R.sup.3 and R.sup.4 represents an aliphatic group containing a hydroxy group, a carboxy group or a sulfo group; X.sub.(2).sup.- represents an anion; and n is 1 or 2, with n being 1 when the dye forms an intramolecular salt.